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Appendix F -63

F.10 SIZING AND COSTING FOR HEAT EXCHANGER


HeatExchanger,X5
Heatexchangertype
Designtype
Heatexchangerorientation
Tubeinletdirection
Numberofparallelplate
Tubesidestreamfeed
Tubeside
Shellside
Heatduty(kW)
a)Equipmentsizing

2shelland4tubes
Splitringfloatinghead
Horizontal
Horizontal
1
1
Ng
Steam
11666.670

Stream
Tin(K)

shell
Steam

tube
NG

617.60

330.86

Tout(K)

579.55

607.25

T1

T2

t2
t1

T1=inlettemperaturetoshell
T2=outlettemperaturefromshell
t1=inlettemperaturetotube
t2=outlettemperaturefromtube

T1(oC) =

344.10

T2(oC) =

306.40

t1(oC) =

57.71

t2( C) =

334.10

R= (T1T2)/(t2t1)
=
0.138

(eqn.12.6)

S= (t2t1)/(T1t1)
=
0.964

(eqn.12.7)

Ftcanbeobtainedfromfig12.19(vol.6),
Ft=
0.8900

Production of 100,000 MTA Hydrogen

Appendix F -64

Tlm can be calculated from the equation,

T lm =

( T 1 t 2 )( T 2 t 1 )
(T 1 t 2 )
ln
(T 2 t 1 )
Tlm=

(eqn.12.4)

74.9681

Therefore,theactualtemperaturedifferenceis
FtTlm=
66.7216
Assumption:(Table12.1,'Chem.Eng',Vol.6)
U

454.264 W/(C.m2)

Provisionalareaofheatexchanger,Acanbeobtainedtroughtheformulae,
lm

Q=UA Talignl

A=

Q
UT lm

Provisionalarea,A

384.9216 m2
4143.2620 ft2

b)Tuberating(App.5.2,TranportProcesses)
Material
BWGnumber
LengthoftubeLt(m)

Carbonsteel
18
2.44

Outerdiameter,Dto(mm)

19.05

Innerdiameter,Dti(mm)

16.56
16.3

MaterialThermalConductivity(W/m.K)
Heattransferareaofatube,At
to

A t = Lt Dalignl

Areaofonetube,At(m2)

0.1460
1.5718

(ft2)
Numberoftube,Nt

Nt=
Numberoftube,Nt

A
At
2636

Tubepitchisthedistancebetweentubecentresandformulatedas
Production of 100,000 MTA Hydrogen

Appendix F -65

Pt =1. 25D to
Tubepitch,Pt(mm)

23.8125

FromTable12.4,ChemicalEngineering,Vol.6(1stEdition)
TriangularpitchK1
0.249
(2passes)n

2.207

Thebundlediameter,Db
(eqn.12.3b)

1/ n

D b = D to ( N t / K 1 )
Bundlediameter,Db(mm)

1269.1683

FromChemicalEngineering,Vol.6(figure12.10)
Shellbundleclearance(mm)

72

ForSplitringfloatinghead,
Ds=Db+shellbundleclearance
Shellinternaldiameter,Ds(m)

1.3412

c)Tubesidecoefficient
Meantemperature(K)
Tmean=(Tc.in+Tc,out)/2
Meantemperature(K)

469.0550

Tubecrosssectionalarea,At

Tubecrosssectionalarea,At

ti2

4
At=

Tubecrosssectionalarea,At
Tubeperpass=Nt

215.4105 mm2
659

Totalflowarea(m2),AT

A T = N t At
Totalflowarea(m2),AT

Production of 100,000 MTA Hydrogen

0.1420

Appendix F -66

Massflowrate(insidetube),m

10.1183

kg/s

Fluidvelocity,f

v f =m / A T
massvelocity,f

71.2794 kg/m2.s

Physicalpropertiesofthetubesidefluid
PhysicalpropertiesofWater
water density, t

1015.2654 kg/m3

Viscosity of water, tL

7.94E04 Ns/m2

Heatcapacity,Ctp

4.1717236904 kJ/kg.K

Thermalconductivity,ktf

0.0948882897 W/m.K

Linearvelocity,u

u= v f /
Reynoldnumber,Re

Re=
Prandtlnumber,Pr

Pr =

uD ti

Cp

linearvelocity,u(m/s)
Reynoldnumber,Re
Prandtlnumber,Pr
L/Dti

kf

0.0702
1486.072
34.9211
147.3430

Fromfigure12.23,ChemicalEngineering,Vol.6
Heattransferfactor,jh
0.0035
Tubesideheattransfercoefficient,hi

k f j h RePr 0 .33
hi =
D ti
w

0. 14

( )

Tubesideheattransfercoefficient,hi

(eqn.12.15)

96.26738 W/m2.C
(assumingviscosityofthefluidisidenticalatthewallandofthebulkfluid)
d)Tubesidepressuredrop
Fromfigure12.24'ChemicalEngineering'.Vol.6

Production of 100,000 MTA Hydrogen

Appendix F -67

frictionfactor,jf

0.0030

Tubesidepressuredrop,Pt
2

u s
m
P s = N p [ 8 j f ( L / Dti )(
) + 2. 5 ]
w
2
where m = 0.25 for laminar flow, Re<2100
m = 0.14 for turbulent flow, Re>2100
Np = number of tube side passes

Tubesidepressuredrop,
Pt

(eqn.12.20)

0.0302 kPa

e)Shellsidecoefficient
Shelldiameter,Ds

(acceptable)

1.3412 m

Baffle Spacing , l B =0. 9Ds

Baffle Diameter= Ds 0.0016


Bafflespacing,lB

1.2071 m
1.3396 m

BaffleDiameter
Tubepitch,Pt

23.8125 mm

Crossflowarea,As

A s=

( pt D to ) D s l B
pt

Crossflowarea,As

(eqn.12.21)
0.3238 m2

Shellsidemassvelocity,Gs
G s w s / As

Massflow(insideshell),Ws

204583 kg/hr

Shellsidemassvelocity,Gs

175.5206 kg/s.m2

Shellsideequivalentdiameter,De

D e=

1.1
( p2z 0 . 971 D 2to )
D to

Production of 100,000 MTA Hydrogen

(eqn.12.23)

Baffle
diameter

Appendix F -68

Shellsideequivalentdiameter,De

13.5265 mm

Meantemperature(C)
Tmean=(Tshell.in+Tshell.out)/2
Meantemperature(C)

598.5750

Physicalpropertiesofshellfluid(lighthydrocarbon)
Physicalproperties
Fluid density, s

3.9318 kg/m3

Viscosity, sL

3.3589E05 Ns/m2

Heatcapacity,Csp

2.6068251014 kJ/kg.K

Thermalconductivity,ksf

0.1718 W/m.K

Reynoldnumber,Re

Re=G s D e /
Reynoldnumber,Re
Prandtlnumber,Pr

(eqn.12.24)
2989.010
0.5096

Selecting15%forbafflecut
Fromfigure12.29,ChemicalEngineering,Vol.6
HeatTransferFactor,jh
0.0100
Shellsideheattransfercoefficient,hs

k f j h RePr 1/ 3
h s=
De
w

0 . 14

( )

Shellsideheattransfercoefficient,hs

(eqn.12.25)
303.966 W/m2.C

f)Shellsidepressuredrop
Linearvelocity,us

us =G s /
Linearvelocity,us
Fromfigure12.30'ChemicalEngineering'.Vol.6
frictionfactor,jf
0.0800
Production of 100,000 MTA Hydrogen

44.6413 m/s

Appendix F -69

Shell side presure drop, Ps

k f j h RePr 1/ 3
h s=
De
w

0 . 14

( )

(eqn.12.26)

26979084.0816 Pa

Shell side presure drop,


Ps

(acceptable)

26979.0841 kPa

g)OverallCoefficient
Outsidefluidfilmcoefficient,hs,W/m2.oC

303.966

Insidefluidfilmcoefficient,hi,W/m . C
2 o

96.26738

Outsidedirtcoefficient(foulingfactor),hod,W/m . C

5000

Insidedirtcoefficient,hid,W/m . C(fromTable12.2,vol.Six)

5500

Thermalconductivityofthetubewallmaterial,kw,W/m.oC

16.3

2 o

2 o

Tubeinsidediameter,Dti,m

0.01656

Tubeoutsidediameter,Dto,m

0.01905

Overallheattransfercoefficientcanbecalculatedbyusingtheformula

1
1 1 d to ln ( d to / d ti ) d to 1 d to 1
= +
+
+ +
U o h s hod
2 kw
d ti hid d ti hi

Therefore,

1/Uo=
Uo=

0.0157305122
63.5707208245 W/m2.C

h)Numberofbaffle,Nb
Numberofbaffle,Nb

N b =( L /l B )1
Nbaffle

Production of 100,000 MTA Hydrogen

(eqn.12.1)

Appendix F -70

Costing
Type
Area(m2)

Shellandtube
384.9216
CarbonSteel
5.07bar

Material
FeedPressure

WithreferencetocostingmethodproposedbyL.T.Biegler,
BaseCost,C

C=C0 ( S / S0 )
BareModuleCost,BMC

BMC =BC ( C )MF


MaterialsandPressureCorrectionFactor,MPF

MPF=Fm ( F p + F d )
Totalarea(ft2)
Basecost,C($)
Modularfactor,MF
Designfactor,Fd
Pressurefactor,Fp
Materialfactor,Fm
MPF
Baremodulecost($)
Baremodulecost(RM)

Production of 100,000 MTA Hydrogen

For100<S<10000ft2,
Co
5000
So
400
a
0.65
UF
3.219048

4143.26
22850.9134
3.29
1.0 (Floatinghead)
0
1 (CS/CS)
1
242,006.407
919,624.348

Appendix F -71

HeatExchanger,X11
Heatexchangertype
Designtype
Heatexchangerorientation
Tubeinletdirection
Numberofparallelplate
Tubesidestreamfeed
Tubeside
Shellside
Heatduty(kW)

1shelland2tubes
Splitringfloatinghead
Horizontal
Horizontal
1
1
organicsolvents
methanol
3321.390

a)Equipmentsizing
Stream
Tin(K)
Tout(K)

shell
methanol

tube
organicsolvent

300.15

284.15

294.15

289.79

T1
t2

T2

t1
T1=inlettemperaturetoshell
T2=outlettemperaturefromshell
t1=inlettemperaturetotube
t2=outlettemperaturefromtube

R= (T1T2)/(t2t1)
R=
1.064

(eqn.12.6)

S= (t2t1)/(T1t1)
S=
0.353
Ftcanbeobtainedfromfig12.19(vol.6),
Ft=
0.9800

(eqn.12.7)

Tlm can be calculated from the equation,

T lm =

( T 1 t 2 )( T 2 t 1 )
(T 1 t 2 )
ln
(T 2 t 1 )

Production of 100,000 MTA Hydrogen

Appendix F -72

T lm =

( T 1 t 2 )( T 2 t 1 )
(T 1 t 2 )
ln
(T 2 t 1 )

(eqn.12.4)

Tlm=

10.1789
Therefore,theactualtemperaturedifferenceis
FtTlm=
9.9754
Assumption:(Table12.1,'Chem.Eng',Vol.6)
U

900 W/(C.m2)

Provisionalareaofheatexchanger,Acanbeobtainedtroughtheformulae,
lm

Q=UA Talignl

A=

Q
UT lm

Provisionalarea,A

369.9549 m2
3972.9842 ft2

b)Tuberating(App.5.2,TranportProcesses)
Material
BWGnumber
LengthoftubeLt(m)

Carbonsteel
18
2.44

Outerdiameter,Dto(mm)

19.05

Innerdiameter,Dti(mm)

16.56
16.3

MaterialThermalConductivity(W/m.K)
Heattransferareaofatube,At
to

A t = Lt Dalignl

Areaofonetube,At(m2)

0.1460
1.5718

(ft2)
Numberoftube,Nt

N t=
Numberoftube,Nt

A
At
2533

Tubepitchisthedistancebetweentubecentresandformulatedas

Pt =1. 25Dto
Tubepitch,Pt(mm)

Production of 100,000 MTA Hydrogen

23.8125

Appendix F -73

FromTable12.4,ChemicalEngineering,Vol.6(1stEdition)
TriangularpitchK1
0.249
(2passes)n

2.207

Thebundlediameter,Db
(eqn.12.3b)

1/ n

D b = D to ( N t / K 1 )
Bundlediameter,Db(mm)

1246.5656

FromChemicalEngineering,Vol.6(figure12.10)
Shellbundleclearance(mm)

78

ForSplitringfloatinghead,
Ds=Db+shellbundleclearance
Shellinternaldiameter,Ds(m)

1.3246

c)Tubesidecoefficient
Meantemperature(K)
Tmean=(Tc.in+Tc,out)/2
Meantemperature(K)

286.9700

Tubecrosssectionalarea,At

Tubecrosssectionalarea,At

ti2

4
At=

Tubecrosssectionalarea,At
Tubeperpass=Nt

215.4105 mm2
633

Totalflowarea(m2),AT

A T = N t At
Totalflowarea(m2),AT
Massflowrate(insidetube),m
Fluidvelocity,f
Production of 100,000 MTA Hydrogen

0.1364
166.1064

kg/hr

Appendix F -74

v f =m / A T
massvelocity,f

1217.4888 kg/m2.s

Physicalpropertiesofthetubesidefluid
Physicalproperties
density, t

838.4112 kg/m3

Viscosity, tL

5.15E04 Ns/m2

Heatcapacity,Ctp

3.5453121354 kJ/kg.K

Thermalconductivity,ktf

0.579725796 W/m.K

Linearvelocity,u

u= v f /
Reynoldnumber,Re

Re=
Prandtlnumber,Pr

Pr =

uD ti

Cp

linearvelocity,u(m/s)
Reynoldnumber,Re
Prandtlnumber,Pr
L/Dti

kf

1.4521
39166.029
3.1481
147.3430

Fromfigure12.23,ChemicalEngineering,Vol.6
Heattransferfactor,jh
0.0037
Tubesideheattransfercoefficient,hi

k f j h RePr 0 .33
hi =
D ti
w

0. 14

( )

Tubesideheattransfercoefficient,hi

(eqn.12.15)

7406.777 W/m2.C
(assumingviscosityofthefluidisidenticalatthewallandofthebulkfluid)
d)Tubesidepressuredrop
Fromfigure12.24'ChemicalEngineering'.Vol.6
frictionfactor,jf
0.0034
Tubesidepressuredrop,Pt

Production of 100,000 MTA Hydrogen

Appendix F -75

u s
m
) + 2. 5 ]
w
2
where m = 0.25 for laminar flow, Re<2100
m = 0.14 for turbulent flow, Re>2100
Np = number of tube side passes
P s = N p [ 8 j f ( L / D ti )(

(eqn.12.20)

11.5054 kPa

Tubesidepressuredrop,
Pt
e)Shellsidecoefficient
Shelldiameter,Ds

(acceptable)

1.3246 m

Baffle Spacing , l B =0. 9D s

Baffle Diameter= Ds 0.0016


Bafflespacing,lB

1.1921 m
1.3230 m

BaffleDiameter
Tubepitch,Pt

23.8125 mm

Crossflowarea,As

A s=

( pt D to ) D s l B
pt

Crossflowarea,As

(eqn.12.21)
0.3158 m2

Shellsidemassvelocity,Gs
G s w s / As

Massflow(insideshell),Ws
Shellsidemassvelocity,Gs

720925.4752 kg/hr
634.1155 kg/s.m2

Shellsideequivalentdiameter,De

D e=

1.1
( p2z 0 . 971 D 2to )
D to

Shellsideequivalentdiameter,De

Meantemperature(C)

Production of 100,000 MTA Hydrogen

(eqn.12.23)

13.5265 mm

Baffle
diameter

Appendix F -76

Tmean=(Tshell.in+Tshell.out)/2
Meantemperature(C)

297.1500

Physicalpropertiesofshellfluid
Physicalproperties
Fluid density, s

799.8603 kg/m3

Viscosity, sL

5.1581E04 Ns/m2

Heatcapacity,Csp

3.6981344329 kJ/kg.K

Thermalconductivity,ksf

0.6155 W/m.K

Reynoldnumber,Re

Re=G s D e /
Reynoldnumber,Re
Prandtlnumber,Pr

(eqn.12.24)
16662.361
3.0990

Selecting15%forbafflecut
Fromfigure12.29,ChemicalEngineering,Vol.6
HeatTransferFactor,jh
0.0055
Shellsideheattransfercoefficient,hs

k f j h RePr 1/ 3
h s=
De
w

0 . 14

( )

Shellsideheattransfercoefficient,hs

(eqn.12.25)
6057.223 W/m2.C

f)Shellsidepressuredrop
Linearvelocity,us

us =G s /
Linearvelocity,us

0.7928 m/s

Fromfigure12.30'ChemicalEngineering'.Vol.6
frictionfactor,jf
0.0630
Shell side presure drop, Ps

k f j h RePr 1/ 3
h s=
De
w

0 . 14

( )

Production of 100,000 MTA Hydrogen

Appendix F -77

k f j h RePr 1/ 3
h s=
De
w

0 . 14

( )

Shell side presure drop,


Ps

(eqn.12.26)

1495229.0275 Pa

(acceptable)

1495.2290 kPa

g)OverallCoefficient
Outsidefluidfilmcoefficient,hs,W/m2.oC

6057.223

Insidefluidfilmcoefficient,hi,W/m2.oC

7406.777

Outsidedirtcoefficient(foulingfactor),hod,W/m2.oC

5000

Insidedirtcoefficient,hid,W/m2.oC(fromTable12.2,vol.Six)

5500

Thermalconductivityofthetubewallmaterial,kw,W/m. C

16.3

Tubeinsidediameter,Dti,m

0.01656

Tubeoutsidediameter,Dto,m

0.01905

Overallheattransfercoefficientcanbecalculatedbyusingtheformula

1 1 1 d to ln (d to / d ti ) d to 1 d to 1
= + +
+ +
U o h s hod
2 kw
d ti hid d ti hi

Therefore,

1/Uo=
Uo=

0.0008114158
1232.4136954376 W/m2.C

h)Numberofbaffle,Nb
Numberofbaffle,Nb

N b =( L /l B )1
Nbaffle

=C)(S/0
BMC=()F
MPF=m(p+d)

Production of 100,000 MTA Hydrogen

(eqn.12.1)

Appendix F -78

Costing
Type
Area(m2)

Shellandtube
369.9549
CarbonSteel
24bar

Material
FeedPressure

WithreferencetocostingmethodproposedbyL.T.Biegler,
BaseCost,C

For100<S<10000ft2,
C=C0 ( S / S0 )
Co
5000
BareModuleCost,BMC
So
400
a
0.65
BMC =BC (C )MF
UF
3.219048
MaterialsandPressureCorrectionFactor,MPF

MPF=Fm ( F p + F d )
Totalarea(ft2)
Basecost,C($)
Modularfactor,MF
Designfactor,Fd
Pressurefactor,Fp
Materialfactor,Fm
MPF
Baremodulecost($)
Baremodulecost(RM)

Production of 100,000 MTA Hydrogen

3972.98
22236.0146
3.29
1.0 (Floatinghead)
0
1 (CS/CS)
1
$235,494
894,878

Appendix F -79

HeatExchanger,X13
Heatexchangertype
Designtype
Heatexchangerorientation
Tubeinletdirection
Numberofparallelplate
Tubesidestreamfeed
Tubeside
Shellside
Heatduty(kW)

1shelland2tubes
Splitringfloaringhead
Horizontal
Horizontal
1
1
Methanolrecovered
LightHydrocarbon
3057.170

a)Equipmentsizing
Stream
Tin(K)

shell
LightHydrocarbon

tube
Methanol

573.15

290.15

548.97

295.97

Tout(K)
T1

T2

t2
t1

T1=inlettemperaturetoshell
T2=outlettemperaturefromshell
t1=inlettemperaturetotube
t2=outlettemperaturefromtube

R= (T1T2)/(t2t1)
R=
4.155
S= (t2t1)/(T1t1)

(eqn.12.6)
(eqn.12.7)

S=
0.021
Ftcanbeobtainedfromfig12.19(vol.6),
Ft=
1.0000
Tlm can be calculated from the equation,

T lm =

( T 1 t 2 )( T 2 t 1 )
(T 1 t 2 )
ln
(T 2 t 1 )
Tlm=

267.8952

Therefore,theactualtemperaturedifferenceis

Production of 100,000 MTA Hydrogen

(eqn.12.4)

Appendix F -80

FtTlm=

267.8952

Assumption:(Table12.1,'Chem.Eng',Vol.6)
U

400 W/(C.m2)

Provisionalareaofheatexchanger,Acanbeobtainedtroughtheformulae,
lm

Q=UA Talignl

A=

Q
UT lm

Provisionalarea,A

28.5295 m2
307.0894 ft2

b)Tuberating(App.5.2,TranportProcesses)
Material
BWGnumber
LengthoftubeLt(m)

Carbonsteel
14
2.44

Outerdiameter,Dto(mm)

19.05

Innerdiameter,Dti(mm)

14.83
16.3

MaterialThermalConductivity(W/m.K)
Heattransferareaofatube,At
to

A t = Lt Dalignl

Areaofonetube,At(m2)

0.1460
(ft2)

Numberoftube,Nt

N t=
Numberoftube,Nt

A
At
195

Tubepitchisthedistancebetweentubecentresandformulatedas

Pt =1. 25D to
Tubepitch,Pt(mm)
FromTable12.4,ChemicalEngineering,Vol.6(1stEdition)
TriangularpitchK1
(2passes)n

Production of 100,000 MTA Hydrogen

23.8125

0.249
2.207

Appendix F -81

Thebundlediameter,Db
(eqn.12.3b)

D b = D to ( N t / K 1 )1 / n
Bundlediameter,Db(mm)

390.3703

FromChemicalEngineering,Vol.6(figure12.10)
Shellbundleclearance(mm)

57

ForSplitringfloatinghead,
Ds=Db+shellbundleclearance
Shellinternaldiameter,Ds(m)

0.4474

c)Tubesidecoefficient
Meantemperature(C)
Tmean=(Tc.in+Tc,out)/2
Meantemperature(K)

293.0600

Tubecrosssectionalarea,At

Tubecrosssectionalarea,At

ti2

4
At=

Tubecrosssectionalarea,At
Tubeperpass=Nt

172.7542 mm2
49

Totalflowarea(m2),AT

A T = N t At
Totalflowarea(m2),AT

0.0084

Massflowrate(insidetube),m

142.3730

kg/s

Fluidvelocity,f

v f =m / A T
Methanolmassvelocity,f

Production of 100,000 MTA Hydrogen

16873.2532 kg/m2.s

Appendix F -82

Physicalpropertiesofthetubesidefluid
PhysicalpropertiesofWater
Methanol density, t

803.3824 kg/m3

Viscosity of Methanol, tL

5.11E04 Ns/m2

Heatcapacity,Ctp

3.6895113236 kJ/kg.K

Thermalconductivity,ktf

0.6089021669 W/m.K

Linearvelocity,u

u= v f /
Reynoldnumber,Re

uDti

Re=
Prandtlnumber,Pr

Pr =

Cp

E.G.linearvelocity,u(m/s)
Reynoldnumber,Re
Prandtlnumber,Pr
L/Dti

kf

21.0028
489687.564
3.0963
164.5314

Fromfigure12.23,ChemicalEngineering,Vol.6
Heattransferfactor,jh
0.0030
Tubesideheattransfercoefficient,hi

k f j h RePr 0 .33
hi =
D ti

0. 14

( )

(eqn.12.15)

Tubesideheattransfercoefficient,hi(W/m2.C)

87584

(assumingviscosityofthefluidisidenticalatthewallandofthebulkfluid)

d)Tubesidepressuredrop
Fromfigure12.24'ChemicalEngineering'.Vol.6
frictionfactor,jf
0.0021
Tubesidepressuredrop,Pt
2

u s
m
P s = N p [ 8 j f ( L / D ti )(
) + 2. 5 ]
w
2
Production of 100,000 MTA Hydrogen

(eqn.12.20)

Appendix F -83

u s
m
P s = N p [ 8 j f ( L / D ti )(
) + 2. 5 ]
w
2
where m = 0.25 for laminar flow, Re<2100
m = 0.14 for turbulent flow, Re>2100
Np = number of tube side passes

Tubesidepressuredrop,
Pt

1865.5276 kPa(acceptable)

e)Shellsidecoefficient
Shelldiameter,Ds

0.4474 m

Baffle Spacing , l B = 0. 9D s

Baffle
diameter

Baffle Diameter= Ds 0 . 0016


Bafflespacing,lB

0.4026 m
0.4458 m

BaffleDiameter
Tubepitch,Pt

23.8125 mm

Crossflowarea,As

A s=

( pt D to ) D s l B
pt

Crossflowarea,As

(eqn.12.21)
0.0360 m2

Shellsidemassvelocity,Gs
G s w s / As

Massflow(insideshell),Ws
Shellsidemassvelocity,Gs

204584.6683 kg/hr
1577.4795 kg/s.m2

Shellsideequivalentdiameter,De

D e=

1.1
( p2z 0 . 971 D 2to )
D to

Shellsideequivalentdiameter,De

Meantemperature(C)
Tmean=(Tshell.in+Tshell.out)/2

Production of 100,000 MTA Hydrogen

(eqn.12.23)

13.5265 mm

Appendix F -84

Meantemperature(C)

561.0600

Physicalpropertiesofshellfluid(lighthydrocarbon)
Physicalproperties
Fluid density, s

8.3574 kg/m3

Viscosity, sL

1.2178E05 Ns/m2

Heatcapacity,Csp

2.9545313606 kJ/kg.K

Thermalconductivity,ksf

0.1169 W/m.K

Reynoldnumber,Re
(eqn.12.24)

Re=G s D e /
Reynoldnumber,Re
Prandtlnumber,Pr

41756.754
0.3079

Selecting15%forbafflecut
Fromfigure12.29,ChemicalEngineering,Vol.6
HeatTransferFactor,jh
0.0040
Shellsideheattransfercoefficient,hs

k f j h RePr 1/ 3
h s=
De
w

0 . 14

( )

(eqn.12.25)

Shellsideheattransfercoefficient,hs(W/m2.C)

978.2222

f)Shellsidepressuredrop
Linearvelocity,us

us =G s /
Linearvelocity,us

188.7524 m/s

Fromfigure12.30'ChemicalEngineering'.Vol.6
frictionfactor,jf

0.0590

Shell side presure drop, Ps

k f j h RePr
h s=
De

1/3

Production of 100,000 MTA Hydrogen

0 . 14

( )

(eqn.12.26)

k f j h RePr
h s=
De

1/3

0 . 14

Appendix F -85

( )

1794482930.0673 Pa(acceptable)

Shell side presure drop,


Ps

1794482.9301 kPa

g)OverallCoefficient
Outsidefluidfilmcoefficient,hs,W/m2.oC

978.2222

Insidefluidfilmcoefficient,hi,W/m2.oC

87584

Outsidedirtcoefficient(foulingfactor),hod,W/m2.oC

5000

Insidedirtcoefficient,hid,W/m . C(fromTable12.2,vol.Six)

5000

Thermalconductivityofthetubewallmaterial,kw,W/m. C

16.3

2 o

Tubeinsidediameter,Dti,m

0.01483

Tubeoutsidediameter,Dto,m

0.01905

Overallheattransfercoefficientcanbecalculatedbyusingtheformula

1
1
1 d to ln ( d to / d ti ) d to 1 d to 1
= +
+
+
+

U o h s hod
2 kw
d ti hid d ti hi

(eqn.12.1)

Therefore,

1/Uo=

0.0016401723

Uo=

609.6920328552 W/m2.C(acceptable)

h)Numberofbaffle,Nb
Numberofbaffle,Nb

N b =( L /l B )1
Nbaffle

Costing
Type
Area(m2)
Material
FeedPressure

Production of 100,000 MTA Hydrogen

Shellandtube
28.5295
CarbonSteel
24bar

Appendix F -86

WithreferencetocostingmethodproposedbyL.T.Biegler,
BaseCost,C
For100<S<10000ft2,
C =C 0 ( S / S0 )
Co
5000
BareModuleCost,BMC
So
400
a
0.65
BMC =BC ( C ) MF
UF
3.219048
MaterialsandPressureCorrectionFactor,MPF

MPF= Fm ( F p + F d )
Totalarea(ft2)
Basecost,C($)
Modularfactor,MF
Designfactor,Fd
Pressurefactor,Fp
Materialfactor,Fm
MPF
Baremodulecost($)
Baremodulecost(RM)

Production of 100,000 MTA Hydrogen

307.09
4210.6888
3.29
1.0 (Floatinghead)
0
1 (CS/CS)
1
$44,594
169,457

Appendix F -87

HeatExchanger,X16
Heatexchangertype
Designtype
Heatexchangerorientation
Tubeinletdirection
Numberofparallelplate
Tubesidestreamfeed
Tubeside
Shellside
Heatduty(kW)

1shelland2tubes
Splitringfloatinghead
Horizontal
Horizontal
1
1
Water
lighthydrocarbon
12112.210

a)Equipmentsizing
Stream
Tin(K)
Tout(K)

shell
LightHC

tube
Water

548.97

364.25

453.15

373.15

T1

T2

t2
t1

T1=inlettemperaturetoshell
T2=outlettemperaturefromshell
t1=inlettemperaturetotube
t2=outlettemperaturefromtube

R= (T1T2)/(t2t1)
R=
10.766

(eqn.12.6)

S= (t2t1)/(T1t1)
S=
0.048
Ftcanbeobtainedfromfig12.19(vol.6),
Ft=
1.0000

(eqn.12.7)

Tlm can be calculated from the equation,

T lm =

( T 1 t 2 )( T 2 t 1 )
(T 1 t 2 )
ln
(T 2 t 1 )

Production of 100,000 MTA Hydrogen

(eqn.12.4)

Appendix F -88

Tlm=

127.4583
Therefore,theactualtemperaturedifferenceis
FtTlm=
127.4583
Assumption:(Table12.1,'Chem.Eng',Vol.6)
U

500 W/(C.m2)

Provisionalareaofheatexchanger,Acanbeobtainedtroughtheformulae,
lm

Q=UA Talignl

A=

Q
UT lm

Provisionalarea,A

190.0576 m2
2045.7633 ft2

b)Tuberating(App.5.2,TranportProcesses)
Material
BWGnumber
LengthoftubeLt(m)

Carbonsteel
18
2.44

Outerdiameter,Dto(mm)

19.05

Innerdiameter,Dti(mm)

16.56
16.3

MaterialThermalConductivity(W/m.K)
Heattransferareaofatube,At
to

A t = Lt Dalignl

Areaofonetube,At(m2)

0.1460
1.5718

(ft2)
Numberoftube,Nt

N t=
Numberoftube,Nt

A
At
1302

Tubepitchisthedistancebetweentubecentresandformulatedas

Pt =1. 25Dto
Tubepitch,Pt(mm)

23.8125

FromTable12.4,ChemicalEngineering,Vol.6(1stEdition)

Production of 100,000 MTA Hydrogen

Appendix F -89

TriangularpitchK1

0.249
2.207

(2passes)n
Thebundlediameter,Db

(eqn.12.3b)

D b = D to ( N t / K 1 )1 / n
Bundlediameter,Db(mm)

921.8256

FromChemicalEngineering,Vol.6(figure12.10)
Shellbundleclearance(mm)

70

ForSplitringfloatinghead,
Ds=Db+shellbundleclearance
Shellinternaldiameter,Ds(m)

0.9918

c)Tubesidecoefficient
Meantemperature(C)
Tmean=(Tc.in+Tc,out)/2
Meantemperature(C)

368.7000

Tubecrosssectionalarea,At

Tubecrosssectionalarea,At

ti2

4
At=

Tubecrosssectionalarea,At
Tubeperpass=Nt

215.4105 mm2
325

Totalflowarea(m2),AT

A T = N t At
Totalflowarea(m2),AT
Massflowrate(insidetube),m

Production of 100,000 MTA Hydrogen

0.0701
326.2381

kg/s

Appendix F -90

Fluidvelocity,f

v f =m / A T
massvelocity,f

4654.5408 kg/m2.s

Physicalpropertiesofthetubesidefluid
PhysicalpropertiesofWater
density, t

1015.2654 kg/m3

Viscosity, tL

7.94E04 Ns/m2

Heatcapacity,Ctp

4.1715617374 kJ/kg.K

Thermalconductivity,ktf

0.6155814452 W/m.K

Linearvelocity,u

u= v f /
Reynoldnumber,Re

Re=
Prandtlnumber,Pr

Pr =

uD ti

Cp

linearvelocity,u(m/s)
Reynoldnumber,Re
Prandtlnumber,Pr
L/Dti

kf

4.5846
97040.408
5.3827
147.3430

Fromfigure12.23,ChemicalEngineering,Vol.6
Heattransferfactor,jh
0.0032

Tubesideheattransfercoefficient,hi

k f j h RePr 0 .33
hi =
D ti
w

0. 14

( )

(eqn.12.15)

Tubesideheattransfercoefficient,hi(W/m2.C)
(assumingviscosityofthefluidisidenticalatthewallandofthebulkfluid)

Production of 100,000 MTA Hydrogen

20116.7

Appendix F -91

d)Tubesidepressuredrop
Fromfigure12.24'ChemicalEngineering'.Vol.6
frictionfactor,jf
0.0028
Tubesidepressuredrop,Pt
2

u s
m
) + 2. 5 ]
w
2
where m = 0.25 for laminar flow, Re<2100
m = 0.14 for turbulent flow, Re>2100
Np = number of tube side passes
P s = N p [ 8 j f ( L / D ti )(

(eqn.12.20)

123.7765 kPa(acceptable)

Tubesidepressuredrop,
Pt
e)Shellsidecoefficient
Shelldiameter,Ds

0.9918 m

Baffle Spacing , l B = 0. 9D s

Baffle
diameter

Baffle Diameter= Ds 0. 0016


Bafflespacing,lB

0.8926 m
0.9902 m

BaffleDiameter
Tubepitch,Pt

23.8125 mm

Crossflowarea,As

A s=

( pt D to ) D s l B
pt

Crossflowarea,As

(eqn.12.21)
0.1771 m2

Shellsidemassvelocity,Gs
G s w s / As

Massflow(insideshell),Ws
Shellsidemassvelocity,Gs
Shellsideequivalentdiameter,De

Production of 100,000 MTA Hydrogen

206584.6683 kg/hr
324.0801 kg/s.m2

Appendix F -92

D e=

1.1
( p2z 0 . 971 D 2to )
D to

(eqn.12.23)

Shellsideequivalentdiameter,De

13.5265 mm

Meantemperature(C)
Tmean=(Tshell.in+Tshell.out)/2
Meantemperature(C)

501.0600

Physicalpropertiesofshellfluid(lighthydrocarbon)
Physicalproperties
Fluid density, s

8.2657 kg/m3

Viscosity, sL

1.7348E05 Ns/m2

Heatcapacity,Csp

2.3602862855 kJ/kg.K

Thermalconductivity,ksf

0.0933 W/m.K

Reynoldnumber,Re

Re=G s D e /
Reynoldnumber,Re
Prandtlnumber,Pr

(eqn.12.24)
5518.890
0.4391

Selecting15%forbafflecut
Fromfigure12.29,ChemicalEngineering,Vol.6
HeatTransferFactor,jh
0.0090

Shellsideheattransfercoefficient,hs

k f j h RePr 1/ 3
h s=
De
w

0 . 14

( )

Shellsideheattransfercoefficient,hs(W/m2.C)
f)Shellsidepressuredrop

Production of 100,000 MTA Hydrogen

(eqn.12.25)
260.998

Appendix F -93

Linearvelocity,us

us =G s /
Linearvelocity,us

39.2078 m/s

Fromfigure12.30'ChemicalEngineering'.Vol.6
frictionfactor,jf
0.0770
Shell side presure drop, Ps

k f j h RePr 1/ 3
h s=
De
w

0 . 14

( )

(eqn.12.26)

55360755.6653 Pa((acceptable)

Shell side presure drop,


Ps

55360.7557 kPa

g)OverallCoefficient
Outsidefluidfilmcoefficient,hs,W/m2.oC

260.998

Insidefluidfilmcoefficient,hi,W/m . C
2 o

20116.7

Outsidedirtcoefficient(foulingfactor),hod,W/m . C

5000

Insidedirtcoefficient,hid,W/m . C(fromTable12.2,vol.Six)

5000

Thermalconductivityofthetubewallmaterial,kw,W/m.oC

16.3

2 o

2 o

Tubeinsidediameter,Dti,m

0.01656

Tubeoutsidediameter,Dto,m

0.01905

Overallheattransfercoefficientcanbecalculatedbyusingtheformula

1 1 1 d to ln(d to / d ti ) d to 1 d to 1
= + +
+ +
U o h s hod
2k w
d ti hid d ti hi
Production of 100,000 MTA Hydrogen

(eqn.12.1)

Appendix F -94

=C)(S/0

Therefore,
1/Uo=

0.0044005603

Uo=

227.2437919956 W/m2.C

BMC=()F h)Numberofbaffle,Nb
Numberofbaffle,Nb

MPF=)+(dpm

N b =( L /l B )1

Nbaffle

Costing
Type
Area(m2)

Shellandtube
190.0576
CarbonSteel
24bar

Material
FeedPressure

WithreferencetocostingmethodproposedbyL.T.Biegler,
BaseCost,C

For100<S<10000ft2,
C=C0 ( S / S0 )
Co
5000
BareModuleCost,BMC
So
400
a
0.65
BMC =BC ( C )MF
UF
3.219048
MaterialsandPressureCorrectionFactor,MPF

MPF=Fm ( F p + F d )
Totalarea(ft2)
Basecost,C($)
Modularfactor,MF
Designfactor,Fd
Pressurefactor,Fp
Materialfactor,Fm
MPF
Baremodulecost($)
Baremodulecost(RM)

Production of 100,000 MTA Hydrogen

2045.76
14443.9845
3.29
1.0 (Floatinghead)
0
1 (CS/CS)
1
$152,971
581,291

Appendix F -95

HeatExchanger,X18
Heatexchangertype
Designtype
Heatexchangerorientation
Tubeinletdirection
Numberofparallelplate
Tubesidestreamfeed
Tubeside
Shellside
Heatduty(kW)

1shelland2tubes
Splitringfloatinghead
Horizontal
Horizontal
1
1
LightHydrocarbon
LightHydrocarbon
333.960

a)Equipmentsizing
Stream
Tin(K)
Tout(K)

Shell
LightHC

tube
LightHC

358.15

330.62

353.15

331.19

T1

T2

t2
t1

T1=inlettemperaturetoshell
T2=outlettemperaturefromshell
t1=inlettemperaturetotube
t2=outlettemperaturefromtube

R= (T1T2)/(t2t1)
R=
8.772
S= (t2t1)/(T1t1)

(eqn.12.6)
(eqn.12.7)

S=
0.021
Ftcanbeobtainedfromfig12.19(vol.6),
Ft=
0.9900
Tlm can be calculated from the equation,

T lm =

( T 1 t 2 )( T 2 t 1 )
(T 1 t 2 )
ln
(T 2 t 1 )
Tlm=

Production of 100,000 MTA Hydrogen

24.6788

(eqn.12.4)

Appendix F -96

Therefore,theactualtemperaturedifferenceis
FtTlm=
24.4320
Assumption:(Table12.1,'Chem.Eng',Vol.6)
U

300 W/(C.m2)

Provisionalareaofheatexchanger,Acanbeobtainedtroughtheformulae,
lm

Q=UA Talignl

A=

Q
UT lm

Provisionalarea,A

45.5632 m2
490.4386 ft2

b)Tuberating(App.5.2,TranportProcesses)
Material
BWGnumber
LengthoftubeLt(m)

Carbonsteel
12
2.44

Outerdiameter,Dto(mm)

19.05

Innerdiameter,Dti(mm)

13.51
16.3

MaterialThermalConductivity(W/m.K)
Heattransferareaofatube,At
to

A t = Lt Dalignl

Areaofonetube,At(m2)

0.1460
1.5718

(ft2)
Numberoftube,Nt

Nt=
Numberoftube,Nt

A
At
312

Tubepitchisthedistancebetweentubecentresandformulatedas

Pt =1. 25Dto
Tubepitch,Pt(mm)

23.8125

FromTable12.4,ChemicalEngineering,Vol.6(1stEdition)
TriangularpitchK1
0.249
(2passes)n
2.207

Production of 100,000 MTA Hydrogen

Appendix F -97

Thebundlediameter,Db
(eqn.12.3b)

1/ n

D b = D to ( N t / K 1 )
Bundlediameter,Db(mm)

482.6161

FromChemicalEngineering,Vol.6(figure12.10)
Shellbundleclearance(mm)

58

ForSplitringfloatinghead,
Ds=Db+shellbundleclearance
Shellinternaldiameter,Ds(m)

0.5406

c)Tubesidecoefficient
Meantemperature(C)
Tmean=(Tc.in+Tc,out)/2
Meantemperature(C)

330.9050

Tubecrosssectionalarea,At

Tubecrosssectionalarea,At

ti2

4
At=

Tubecrosssectionalarea,At
Tubeperpass=Nt

143.3695 mm2
78

Totalflowarea(m2),AT

A T = N t At
Totalflowarea(m2),AT

0.0112

Massflowrate(insidetube),m

165.3786

kg/s

Fluidvelocity,f
v

massvelocity,f

Production of 100,000 MTA Hydrogen

=m / A T

14787.7565 kg/m2.s

Appendix F -98

Physicalpropertiesofthetubesidefluid
Physicalproperties
density, t

838.8251 kg/m3

Viscosity, tL

5.16E04 Ns/m2

Heatcapacity,Ctp

3.5427474082 kJ/kg.K

Thermalconductivity,ktf

0.5803266637 W/m.K

Linearvelocity,u

u= v f /
Reynoldnumber,Re

uD ti

Re=
Prandtlnumber,Pr

Pr =

Cp

linearvelocity,u(m/s)
Reynoldnumber,Re
Prandtlnumber,Pr
L/Dti

kf

17.6291
387037.550
3.1512
180.6070

Fromfigure12.23,ChemicalEngineering,Vol.6
Heattransferfactor,jh
0.0030
Tubesideheattransfercoefficient,hi

k f j h RePr 0 .33
hi =
D ti

0. 14

( )

(eqn.12.15)

Tubesideheattransfercoefficient,hi

72842.92 W/m2.C

(assumingviscosityofthefluidisidenticalatthewallandofthebulkfluid)
d)Tubesidepressuredrop
Fromfigure12.24'ChemicalEngineering'.Vol.6
frictionfactor,jf
0.0020
Tubesidepressuredrop,Pt
2

u s
m
P s =N p [8 j f (L /D ti )( ) +2. 5 ]
w
2
Production of 100,000 MTA Hydrogen

(eqn.12.20)

P s =N p [8 j f (L /D ti )( )m+2. 5 ] s
w
2

Appendix F -99

where m = 0.25 for laminar flow, Re<2100


m = 0.14 for turbulent flow, Re>2100
Np = number of tube side passes
Tubesidepressuredrop,
Pt

1405.0723 kPa

e)Shellsidecoefficient
Shelldiameter,Ds

(acceptable)

0.5406 m

Baffle Spacing , l B = 0. 9D s

Baffle Diameter= Ds 0 . 0016


Bafflespacing,lB

0.4866 m
0.5390 m

BaffleDiameter
Tubepitch,Pt

23.8125 mm

Crossflowarea,As

A s=

( pt D to ) D s l B
pt

Crossflowarea,As

(eqn.12.21)
0.0526 m2

Shellsidemassvelocity,Gs
G s w s / As

Massflow(insideshell),Ws
Shellsidemassvelocity,Gs

95470.78911 kg/hr
504.1011 kg/s.m2

Shellsideequivalentdiameter,De

D e=

1.1
( p2z 0 . 971 D 2to )
D to

Shellsideequivalentdiameter,De

(eqn.12.23)

13.5265 mm

Meantemperature(C)
Tmean=(Tshell.in+Tshell.out)/2
Meantemperature(C)
Production of 100,000 MTA Hydrogen

355.6500

Baffle
diameter

Appendix F -100

Physicalpropertiesofshellfluid(lighthydrocarbon)
Physicalproperties
Fluid density, s

8.3574 kg/m3

Viscosity, sL

1.2178E05 Ns/m2

Heatcapacity,Csp

2.9545313606 kJ/kg.K

Thermalconductivity,ksf

0.1169 W/m.K

Reynoldnumber,Re

Re=G s D e /
Reynoldnumber,Re
Prandtlnumber,Pr

(eqn.12.24)
13209.823
0.3079

Selecting15%forbafflecut
Fromfigure12.29,ChemicalEngineering,Vol.6
HeatTransferFactor,jh
0.0057
Shellsideheattransfercoefficient,hs

k f j h RePr 1/ 3
h s=
De
w

0 . 14

( )

Shellsideheattransfercoefficient,hs

(eqn.12.25)
440.9838 W/m2.C

f)Shellsidepressuredrop
Linearvelocity,us

us =G s /
Linearvelocity,us

Fromfigure12.30'ChemicalEngineering'.Vol.6
frictionfactor,jf
0.0660

Production of 100,000 MTA Hydrogen

60.3179 m/s

Appendix F -101

Shell side presure drop, Ps

k f j h RePr 1/ 3
h s=
De
w

0 . 14

( )

(eqn.12.26)

172611790.8049 Pa

Shell side presure drop,


Ps

(acceptable)

172611.7908 kPa

g)OverallCoefficient
Outsidefluidfilmcoefficient,hs,W/m2.oC

440.9838

Insidefluidfilmcoefficient,hi,W/m . C
2 o

72842.92

Outsidedirtcoefficient(foulingfactor),hod,W/m . C

5000

Insidedirtcoefficient,hid,W/m2.oC(fromTable12.2,vol.Six)

5000

Thermalconductivityofthetubewallmaterial,kw,W/m.oC

16.3

2 o

Tubeinsidediameter,Dti,m

0.01351

Tubeoutsidediameter,Dto,m

0.01905

Overallheattransfercoefficientcanbecalculatedbyusingtheformula

1
1 1 d to ln ( d to / d ti ) d to 1 d to 1
= +
+
+ +
U o h s hod
2 kw
d ti hid d ti hi

Therefore,

1/Uo=

0.0029698341

Uo=

336.7191412722 W/m2.C

h)Numberofbaffle,Nb
Numberofbaffle,Nb

N b =( L /l B )1
Nbaffle

C=)(S/0

Costing

BMC=()F Type

Shellandtube

Area(m )
2

Material

MPF=)+(dpmFeedPressure

Production of 100,000 MTA Hydrogen

45.5632
CarbonSteel
24bar

(eqn.12.1)

Appendix F -102

WithreferencetocostingmethodproposedbyL.T.Biegler,
BaseCost,C

For100<S<10000ft2,
C =C 0 ( S / S0 )
Co
5000
BareModuleCost,BMC
So
400
a
0.65
BMC =BC ( C ) MF
UF
3.219048
MaterialsandPressureCorrectionFactor,MPF

MPF= Fm ( F p + F d )
Totalarea(ft2)
Basecost,C($)
Modularfactor,MF
Designfactor,Fd
Pressurefactor,Fp
Materialfactor,Fm
MPF
Baremodulecost($)
Baremodulecost(RM)

Production of 100,000 MTA Hydrogen

490.44
5708.3554
3.29
1.0 (Floatinghead)
0
1 (CS/CS)
1
$60,455
229,730

Appendix F -103

HeatExchanger,X21
Heatexchangertype
Designtype
Heatexchangerorientation
Tubeinletdirection
Numberofparallelplate
Tubesidestreamfeed
Tubeside
Shellside
Heatduty(kW)

1shelland2tubes
Splitringfloatinghead
Horizontal
Horizontal
1
1
OrganicSolvents
LightHydrocarbon
18412.370

a)Equipmentsizing
Stream
Tin(K)
Tout(K)

shell
LightHC

tube
organicsolvent

623.15

299.36

483.15

330.62

T1

T2

t2
t1

T1=inlettemperaturetoshell
T2=outlettemperaturefromshell
t1=inlettemperaturetotube
t2=outlettemperaturefromtube

R= (T1T2)/(t2t1)
R=
4.479
S= (t2t1)/(T1t1)

(eqn.12.6)
(eqn.12.7)

S=
0.097
Ftcanbeobtainedfromfig12.19(vol.6),
Ft=
0.9900
Tlm can be calculated from the equation,

T lm =

( T 1 t 2 )( T 2 t 1 )
(T 1 t 2 )
ln
(T 2 t 1 )
Tlm=

Production of 100,000 MTA Hydrogen

233.9635

(eqn.12.4)

Appendix F -104

Therefore,theactualtemperaturedifferenceis
FtTlm=
231.6238
Assumption:(Table12.1,'Chem.Eng',Vol.6)
U

350 W/(C.m2)

Provisionalareaofheatexchanger,Acanbeobtainedtroughtheformulae,
lm

Q=UA Talignl

A=

Q
UT lm

Provisionalarea,A

227.1216 m2
2444.7164 ft2

b)Tuberating(App.5.2,TranportProcesses)
Material
BWGnumber
LengthoftubeLt(m)

Carbonsteel
14
2.44

Outerdiameter,Dto(mm)

19.05

Innerdiameter,Dti(mm)

14.83
16.3

MaterialThermalConductivity(W/m.K)
Heattransferareaofatube,At
to

A t = Lt Dalignl

Areaofonetube,At(m2)

0.1460
1.5718

(ft2)
Numberoftube,Nt

Nt=
Numberoftube,Nt

A
At
1555

Tubepitchisthedistancebetweentubecentresandformulatedas

Pt =1. 25Dto
Tubepitch,Pt(mm)

23.8125

FromTable12.4,ChemicalEngineering,Vol.6(1stEdition)
TriangularpitchK1
0.249
(2passes)n

Production of 100,000 MTA Hydrogen

2.207

Appendix F -105

Thebundlediameter,Db
(eqn.12.3b)

1/ n

D b = D to ( N t / K 1 )
Bundlediameter,Db(mm)

999.3252

FromChemicalEngineering,Vol.6(figure12.10)
Shellbundleclearance(mm)

72

ForSplitringfloatinghead,
Ds=Db+shellbundleclearance
Shellinternaldiameter,Ds(m)

1.0713

c)Tubesidecoefficient
Meantemperature(K)
Tmean=(TK.in+TK,out)/2
Meantemperature(K)

314.9900

Tubecrosssectionalarea,At

Tubecrosssectionalarea,At

ti2

4
At=

Tubecrosssectionalarea,At
Tubeperpass=Nt

172.7542 mm2
389

Totalflowarea(m2),AT

A T = N t At
Totalflowarea(m2),AT

0.0672

Massflowrate(insidetube),m

166.1370

kg/s

Fluidvelocity,f

v f =m / A T
massvelocity,f

Production of 100,000 MTA Hydrogen

2473.2820 kg/m2.s

Appendix F -106

Physicalpropertiesofthetubesidefluid
Physicalproperties
density, t

838.4112 kg/m3

Viscosity, tL

5.15E04 Ns/m2

Heatcapacity,Ctp

3.5453121354 kJ/kg.K

Thermalconductivity,ktf

0.579725796 W/m.K

Linearvelocity,u

u= v f /
Reynoldnumber,Re

Re=
Prandtlnumber,Pr

Pr =

uD ti

Cp

linearvelocity,u(m/s)
Reynoldnumber,Re
Prandtlnumber,Pr
L/Dti

kf

2.9500
71252.324
3.1481
164.5314

Fromfigure12.23,ChemicalEngineering,Vol.6
Heattransferfactor,jh
0.0033
Tubesideheattransfercoefficient,hi

k f j h RePr 0 .33
hi =
D ti
w

0. 14

( )

Tubesideheattransfercoefficient,hi

(eqn.12.15)

13419.93 W/m2.C
(assumingviscosityofthefluidisidenticalatthewallandofthebulkfluid)

d)Tubesidepressuredrop
Fromfigure12.24'ChemicalEngineering'.Vol.6
frictionfactor,jf
0.0029

Production of 100,000 MTA Hydrogen

Appendix F -107

Tubesidepressuredrop,Pt
2

u s
m
P s =N p [ 8 j f ( L / D ti )(
) + 2. 5 ]
w
2
where m = 0.25 for laminar flow, Re<2100
m = 0.14 for turbulent flow, Re>2100
Np = number of tube side passes

Tubesidepressuredrop,
Pt

(eqn.12.20)

46.0903 kPa

e)Shellsidecoefficient
Shelldiameter,Ds

(acceptable)

1.0713 m

Baffle Spacing , l B = 0. 9Ds

Baffle Diameter= Ds 0.0016


Bafflespacing,lB

0.9642 m
1.0697 m

BaffleDiameter
Tubepitch,Pt

23.8125 mm

Crossflowarea,As

A s=

( pt D to ) D s l B
pt

Crossflowarea,As

(eqn.12.21)
0.2066 m2

Shellsidemassvelocity,Gs
G s w s / As

Massflow(insideshell),Ws
Shellsidemassvelocity,Gs

204584.0255 kg/hr
275.0769 kg/s.m2

Shellsideequivalentdiameter,De

De=

1.1
( p2z 0 . 971 D 2to )
D to

Shellsideequivalentdiameter,De

Production of 100,000 MTA Hydrogen

(eqn.12.23)

13.5265 mm

Baffle
diameter

Appendix F -108

Meantemperature(C)
Tmean=(Tshell.in+Tshell.out)/2
Meantemperature(C)

553.1500

Physicalpropertiesofshellfluid(lighthydrocarbon)
Physicalproperties
Fluid density, s

6.0172 kg/m3

Viscosity, sL

2.3856E05 Ns/m2

Heatcapacity,Csp

2.4104009125 kJ/kg.K

Thermalconductivity,ksf

0.1416 W/m.K

Reynoldnumber,Re

Re=G s D e /
Reynoldnumber,Re
Prandtlnumber,Pr

(eqn.12.24)
7228.068
0.4062

Selecting15%forbafflecut
Fromfigure12.29,ChemicalEngineering,Vol.6
HeatTransferFactor,jh
0.0070
Shellsideheattransfercoefficient,hs

k f j h RePr 1/ 3
h s=
De
w

0 . 14

( )

Shellsideheattransfercoefficient,hs

(eqn.12.25)
393.3391 W/m2.C

f)Shellsidepressuredrop
Linearvelocity,us

us =G s /
Linearvelocity,us

Fromfigure12.30'ChemicalEngineering'.Vol.6
frictionfactor,jf
0.0720

Production of 100,000 MTA Hydrogen

45.7151 m/s

Appendix F -109

Shell side presure drop, Ps

k f j h RePr 1/ 3
h s=
De
w

0 . 14

( )

Shell side presure drop,


Ps

(eqn.12.26)

48784382.0918 Pa

(acceptable)

48784.3821 kPa

g)OverallCoefficient
Outsidefluidfilmcoefficient,hs,W/m2.oC

393.3391

Insidefluidfilmcoefficient,hi,W/m . C
2 o

13419.93

Outsidedirtcoefficient(foulingfactor),hod,W/m . C

5000

Insidedirtcoefficient,hid,W/m2.oC(fromTable12.2,vol.Six)

5000

Thermalconductivityofthetubewallmaterial,kw,W/m.oC

16.3

2 o

Tubeinsidediameter,Dti,m

0.01483

Tubeoutsidediameter,Dto,m

0.01905

Overallheattransfercoefficientcanbecalculatedbyusingtheformula

1
1 1 d to ln ( d to / d ti ) d to 1 d to 1
= +
+
+ +
U o h s hod
2 kw
d ti hid d ti hi

Therefore,

1/Uo=
Uo=

0.0032412991
308.5182732742 W/m2.C

h)Numberofbaffle,Nb
Numberofbaffle,Nb

N b =( L /l B )1
Nbaffle

C=)(S/0

Production of 100,000 MTA Hydrogen

(eqn.12.1)

Appendix F -110

Costing

BMC=()F Type

Shellandtube

Area(m2)

227.1216
CarbonSteel
23bar

Material
FeedPressure

MPF=)+(dpm

WithreferencetocostingmethodproposedbyL.T.Biegler,
BaseCost,C
For100<S<10000ft2,
C=C0 ( S / S0 )
Co
5000
BareModuleCost,BMC
So
400
a
0.65
BMC =BC ( C )MF
UF
3.219048
MaterialsandPressureCorrectionFactor,MPF

MPF=Fm ( F p + F d )
Totalarea(ft2)
Basecost,C($)
Modularfactor,MF
Designfactor,Fd
Pressurefactor,Fp
Materialfactor,Fm
MPF
Baremodulecost($)
Baremodulecost(RM)

Production of 100,000 MTA Hydrogen

2444.72
16217.3365
3.29
1.0 (Floatinghead)
0
1 (CS/CS)
1
$171,752
652,659

Appendix F -111

HeatExchanger,X25
Heatexchangertype
Designtype
Heatexchangerorientation
Tubeinletdirection
Numberofparallelplate
Tubesidestreamfeed
Tubeside
Shellside
Heatduty(kW)

1shelland2tubes
Splitringfloatinghead
Horizontal
Horizontal
1
1
Methanol
NaturalGases
1088.150

a)Equipmentsizing
Stream
Tin(K)
Tout(K)

shell
NaturalGases

tube
Methanol

429.30

295.97

387.57

298.04

T1

T2

t2
t1

T1=inlettemperaturetoshell
T2=outlettemperaturefromshell
t1=inlettemperaturetotube
t2=outlettemperaturefromtube

R= (T1T2)/(t2t1)
R=
20.159
S= (t2t1)/(T1t1)

(eqn.12.6)
(eqn.12.7)

S=
0.016
Ftcanbeobtainedfromfig12.19(vol.6),
Ft=
1.0000
Tlm can be calculated from the equation,

T lm =

( T 1 t 2 )( T 2 t 1 )
(T 1 t 2 )
ln
(T 2 t 1 )
Tlm=

Production of 100,000 MTA Hydrogen

110.2436

(eqn.12.4)

Appendix F -112

Therefore,theactualtemperaturedifferenceis
FtTlm=
110.2436
Assumption:(Table12.1,'Chem.Eng',Vol.6)
U

300 W/(C.m2)

Provisionalareaofheatexchanger,Acanbeobtainedtroughtheformulae,
lm

Q=UA Talignl

A=

Q
UT lm

Provisionalarea,A

32.9014 m2
354.1476 ft2

b)Tuberating(App.5.2,TranportProcesses)
Material
BWGnumber
LengthoftubeLt(m)

Carbonsteel
14
2.44

Outerdiameter,Dto(mm)

19.05

Innerdiameter,Dti(mm)

14.83
16.3

MaterialThermalConductivity(W/m.K)
Heattransferareaofatube,At
to

A t = Lt Dalignl

Areaofonetube,At(m2)

0.1460

(ft2)

1.5718

Numberoftube,Nt

N t=
Numberoftube,Nt

A
At
225

Tubepitchisthedistancebetweentubecentresandformulatedas

Pt =1. 25D to
Tubepitch,Pt(mm)

23.8125

FromTable12.4,ChemicalEngineering,Vol.6(1stEdition)
TriangularpitchK1
0.249
(2passes)n

Production of 100,000 MTA Hydrogen

2.207

Appendix F -113

Thebundlediameter,Db
(eqn.12.3b)

1/ n

D b = D to ( N t / K 1 )
Bundlediameter,Db(mm)

416.4211

FromChemicalEngineering,Vol.6(figure12.10)
Shellbundleclearance(mm)

55

ForSplitringfloatinghead,
Ds=Db+shellbundleclearance
Shellinternaldiameter,Ds(m)

0.4714

c)Tubesidecoefficient
Meantemperature(K)
Tmean=(Tc.in+Tc,out)/2
Meantemperature(K)

297.0050

Tubecrosssectionalarea,At

Tubecrosssectionalarea,At

ti2

4
At=

Tubecrosssectionalarea,At
Tubeperpass=Nt

172.7542 mm2
56

Totalflowarea(m2),AT

A T = N t At
Totalflowarea(m2),AT

0.0097

Massflowrate(insidetube),m

143.4985

kg/s

Fluidvelocity,f

v f =m / A T
massvelocity,f

Production of 100,000 MTA Hydrogen

14746.8378 kg/m2.s

Appendix F -114

Physicalpropertiesofthetubesidefluid
Physicalproperties
density, t

814.0675 kg/m3

Viscosity of E.G, tL

5.30E04 Ns/m2

Heatcapacity,Ctp

3.6632887656 kJ/kg.K

Thermalconductivity,ktf

0.6095936878 W/m.K

Linearvelocity,u

u= v f /
Reynoldnumber,Re

Re=
Prandtlnumber,Pr

Pr =

uD ti

Cp

linearvelocity,u(m/s)
Reynoldnumber,Re
Prandtlnumber,Pr
L/Dti

kf

18.1150
412575.610
3.1854
164.5314

Fromfigure12.23,ChemicalEngineering,Vol.6
Heattransferfactor,jh
0.0028
Tubesideheattransfercoefficient,hi

k f j h RePr 0 .33
hi =
D ti
w

0. 14

( )

Tubesideheattransfercoefficient,hi

(eqn.12.15)

69599.49 W/m2.C
(assumingviscosityofthefluidisidenticalatthewallandofthebulkfluid)

d)Tubesidepressuredrop
Fromfigure12.24'ChemicalEngineering'.Vol.6
frictionfactor,jf
0.0019

Production of 100,000 MTA Hydrogen

Appendix F -115

Tubesidepressuredrop,Pt
2

u s
m
P s =N p [ 8 j f ( L / D ti )(
) + 2. 5 ]
w
2
where m = 0.25 for laminar flow, Re<2100
m = 0.14 for turbulent flow, Re>2100
Np = number of tube side passes

Tubesidepressuredrop,
Pt

(eqn.12.20)

1335.9295 kPa

e)Shellsidecoefficient
Shelldiameter,Ds

(acceptable)

0.4714 m

Baffle Spacing , l B=0. 9D s

Baffle Diameter= Ds 0.0016


Bafflespacing,lB

0.4243 m
0.4698 m

BaffleDiameter
Tubepitch,Pt

23.8125 mm

Crossflowarea,As

A s=

( pt D to ) D s l B
pt

Crossflowarea,As

(eqn.12.21)
0.0400 m2

Shellsidemassvelocity,Gs
G s w s / As

Massflow(insideshell),Ws
Shellsidemassvelocity,Gs

40225.6368 kg/hr
279.3250 kg/s.m2

Shellsideequivalentdiameter,De

D e=

1.1 2
( p z 0 . 971 D 2to )
D to

Shellsideequivalentdiameter,De

Production of 100,000 MTA Hydrogen

(eqn.12.23)

13.5265 mm

Baffle
diameter

Appendix F -116

Meantemperature(C)
Tmean=(Tshell.in+Tshell.out)/2
Meantemperature(C)

408.4350

Physicalpropertiesofshellfluid(lighthydrocarbon)
Physicalproperties
Fluid density, s

1.9887 kg/m3

Viscosity, sL

1.8326E05 Ns/m2

Heatcapacity,Csp

2.9956912165 kJ/kg.K

Thermalconductivity,ksf

0.0745 W/m.K

Reynoldnumber,Re

Re=G s D e /
Reynoldnumber,Re
Prandtlnumber,Pr

(eqn.12.24)
7127.829
0.7367

Selecting15%forbafflecut
Fromfigure12.29,ChemicalEngineering,Vol.6
HeatTransferFactor,jh
0.0075
Shellsideheattransfercoefficient,hs

k f j h RePr 1/ 3
h s=
De
w

0 . 14

( )

Shellsideheattransfercoefficient,hs

(eqn.12.25)
266.2769 W/m2.C

f)Shellsidepressuredrop
Linearvelocity,us

us =G s /
Linearvelocity,us

Fromfigure12.30'ChemicalEngineering'.Vol.6
frictionfactor,jf
0.0730

Production of 100,000 MTA Hydrogen

140.4561 m/s

Appendix F -117

Shell side presure drop, Ps

k f j h RePr 1/ 3
h s=
De
w

0 . 14

( )

Shell side presure drop,


Ps

(eqn.12.26)

267886243.7284 Pa

(acceptable)

267886.2437 kPa

g)OverallCoefficient
Outsidefluidfilmcoefficient,hs,W/m2.oC

266.2769

Insidefluidfilmcoefficient,hi,W/m . C
2 o

69599.49

Outsidedirtcoefficient(foulingfactor),hod,W/m . C

5000

Insidedirtcoefficient,hid,W/m2.oC(fromTable12.2,vol.Six)

5000

Thermalconductivityofthetubewallmaterial,kw,W/m.oC

16.3

2 o

Tubeinsidediameter,Dti,m

0.01483

Tubeoutsidediameter,Dto,m

0.01905

Overallheattransfercoefficientcanbecalculatedbyusingtheformula

1
1 1 d to ln ( d to / d ti ) d to 1 d to 1
= +
+
+ +
U o h s hod
2 kw
d ti hid d ti hi

Therefore,

1/Uo=
Uo=

0.0043771889
228.4571256926 W/m2.C

h)Numberofbaffle,Nb
Numberofbaffle,Nb

N b =( L /l B )1
Nbaffle

C=)(S/0

Production of 100,000 MTA Hydrogen

(eqn.12.1)

Appendix F -118

Costing

=
C
M
B
FType
()

Shellandtube

Area(m2)

32.9014
CarbonSteel
24bar

Material
FeedPressure

=
F
P
M
(dpm
)+

WithreferencetocostingmethodproposedbyL.T.Biegler,
BaseCost,C
For100<S<10000ft2,
C=C0 ( S / S0 )
Co
5000
BareModuleCost,BMC
So
400
a
0.65
BMC =BC (C )MF
UF
3.219048
MaterialsandPressureCorrectionFactor,MPF

MPF=Fm ( F p + F d )
Totalarea(ft2)
Basecost,C($)
Modularfactor,MF
Designfactor,Fd
Pressurefactor,Fp
Materialfactor,Fm
MPF
Baremodulecost($)
Baremodulecost(RM)

Production of 100,000 MTA Hydrogen

354.15
4619.5617
3.29
1.0 (Floatinghead)
0
1 (CS/CS)
1
$48,924
185,912

Appendix F -119

HeatExchanger,X26
Heatexchangertype
Designtype
Heatexchangerorientation
Tubeinletdirection
Numberofparallelplate
Tubesidestreamfeed
Tubeside
Shellside
Heatduty(kW)

1shelland2tubes
Splitringfloatinghead
Horizontal
Horizontal
1
1
Methanol
Water
1107.710

a)Equipmentsizing
Stream
Tin(K)

shell
Water

tube
Methanol

358.15

298.04

Tout(K)

349.12

300.15

T1

T2

t2
t1

T1=inlettemperaturetoshell
T2=outlettemperaturefromshell
t1=inlettemperaturetotube
t2=outlettemperaturefromtube

R= (T1T2)/(t2t1)
R=
4.280
S= (t2t1)/(T1t1)

(eqn.12.6)
(eqn.12.7)

S=
0.035
Ftcanbeobtainedfromfig12.19(vol.6),
Ft=
1.0000
Tlm can be calculated from the equation,

T lm =

( T 1 t 2 )( T 2 t 1 )
(T 1 t 2 )
ln
(T 2 t 1 )
Tlm=

Production of 100,000 MTA Hydrogen

54.4668

(eqn.12.4)

Appendix F -120

Therefore,theactualtemperaturedifferenceis
FtTlm=
54.4668
Assumption:(Table12.1,'Chem.Eng',Vol.6)
U

500 W/(C.m2)

Provisionalareaofheatexchanger,Acanbeobtainedtroughtheformulae,
lm

Q=UA Talignl

A=

Q
UT lm

Provisionalarea,A

40.6747 m2
437.8190 ft2

b)Tuberating(App.5.2,TranportProcesses)
Material
BWGnumber
LengthoftubeLt(m)

Carbonsteel
14
2.44

Outerdiameter,Dto(mm)

19.05

Innerdiameter,Dti(mm)

14.83
16.3

MaterialThermalConductivity(W/m.K)
Heattransferareaofatube,At
to

A t = Lt Dalignl

Areaofonetube,At(m2)

0.1460
1.5718

(ft2)
Numberoftube,Nt

Nt=
Numberoftube,Nt

A
At
279

Tubepitchisthedistancebetweentubecentresandformulatedas

Pt =1. 25D to
Tubepitch,Pt(mm)

23.8125

FromTable12.4,ChemicalEngineering,Vol.6(1stEdition)
TriangularpitchK1
0.249
(2passes)n

Production of 100,000 MTA Hydrogen

2.207

Appendix F -121

Thebundlediameter,Db
(eqn.12.3b)

1/ n

D b = D to ( N t / K 1 )
Bundlediameter,Db(mm)

458.4250

FromChemicalEngineering,Vol.6(figure12.10)
Shellbundleclearance(mm)

72

ForSplitringfloatinghead,
Ds=Db+shellbundleclearance
Shellinternaldiameter,Ds(m)

0.5304

c)Tubesidecoefficient
Meantemperature(K)
Tmean=(Tc.in+Tc,out)/2
Meantemperature(K)

299.0950

Tubecrosssectionalarea,At

Tubecrosssectionalarea,At

ti2

4
At=

Tubecrosssectionalarea,At
Tubeperpass=Nt

172.7542 mm2
70

Totalflowarea(m2),AT

A T = N t At
Totalflowarea(m2),AT
Massflowrate(insidetube),m

Production of 100,000 MTA Hydrogen

0.0120
143.3087

kg/s

Appendix F -122

Fluidvelocity,f

v f =m / A T
E.Gmassvelocity,f

11912.7959 kg/m2.s

Physicalpropertiesofthetubesidefluid
Physicalproperties
density, t

814.0675 kg/m3

Viscosity, tL

5.30E04 Ns/m2

Heatcapacity,Ctp

3.6632887656 kJ/kg.K

Thermalconductivity,ktf

0.6095936878 W/m.K

Linearvelocity,u

u= v f /
Reynoldnumber,Re

uD ti

Re=
Prandtlnumber,Pr

Pr =

Cp

linearvelocity,u(m/s)
Reynoldnumber,Re
Prandtlnumber,Pr
L/Dti

kf

14.6337
333286.982
3.1854
164.5314

Fromfigure12.23,ChemicalEngineering,Vol.6
Heattransferfactor,jh
0.0029
Tubesideheattransfercoefficient,hi

k f j h RePr 0 .33
hi =
D ti
w

0. 14

( )

(eqn.12.15)

Tubesideheattransfercoefficient,hi
(assumingviscosityofthefluidisidenticalatthewallandofthebulkfluid)
d)Tubesidepressuredrop
Fromfigure12.24'ChemicalEngineering'.Vol.6
frictionfactor,jf
0.0020

Production of 100,000 MTA Hydrogen

58231.88 W/m2.C

Appendix F -123

Tubesidepressuredrop,Pt
2

u s
m
P s = N p [ 8 j f ( L / D ti )(
) + 2. 5 ]
w
2
where m = 0.25 for laminar flow, Re<2100
m = 0.14 for turbulent flow, Re>2100
Np = number of tube side passes

Tubesidepressuredrop,
Pt

(eqn.12.20)

894.7384 kPa

e)Shellsidecoefficient
Shelldiameter,Ds

(acceptable)

0.5304 m

Baffle Spacing , l B = 0. 9D s

Baffle Diameter= Ds 0 .0016


Bafflespacing,lB

0.4774 m
0.5288 m

BaffleDiameter
Tubepitch,Pt

23.8125 mm

Crossflowarea,As

A s=

( pt D to ) D s l B
pt

Crossflowarea,As

(eqn.12.21)
0.0506 m2

Shellsidemassvelocity,Gs
G s w s / As

Massflow(insideshell),Ws
Shellsidemassvelocity,Gs

109113.8792 kg/hr
598.4902 kg/s.m2

Shellsideequivalentdiameter,De

D e=

1.1
( p2z 0 . 971 D 2to )
D to

Shellsideequivalentdiameter,De

Production of 100,000 MTA Hydrogen

(eqn.12.23)

13.5265 mm

Baffle
diameter

Appendix F -124

Meantemperature(C)
Tmean=(Tshell.in+Tshell.out)/2
Meantemperature(C)

353.6350

Physicalpropertiesofshellfluid
Physicalproperties
Fluid density, s

965.3964 kg/m3

Viscosity, sL

5.8331E04 Ns/m2

Heatcapacity,Csp

4.1817378916 kJ/kg.K

Thermalconductivity,ksf

1.1730 W/m.K

Reynoldnumber,Re

Re=G s D e /
Reynoldnumber,Re
Prandtlnumber,Pr

(eqn.12.24)
15272.299
2.0794

Selecting15%forbafflecut
Fromfigure12.29,ChemicalEngineering,Vol.6
HeatTransferFactor,jh
0.0055
Shellsideheattransfercoefficient,hs

k f j h RePr 1/ 3
h s=
De
w

0 . 14

( )

(eqn.12.25)

Shellsideheattransfercoefficient,hs

9275 W/m2.C

f)Shellsidepressuredrop
Linearvelocity,us

us =G s /
Linearvelocity,us
Fromfigure12.30'ChemicalEngineering'.Vol.6
frictionfactor,jf
0.0650

Production of 100,000 MTA Hydrogen

0.6199 m/s

Appendix F -125

Shell side presure drop, Ps

k f j h RePr 1/ 3
h s=
De
w

0 . 14

( )

(eqn.12.26)

2624542.4541 Pa

Shell side presure drop,


Ps

(acceptable)

2624.5425 kPa

g)OverallCoefficient
Outsidefluidfilmcoefficient,hs,W/m2.oC

9275

Insidefluidfilmcoefficient,hi,W/m . C
2 o

58231.88

Outsidedirtcoefficient(foulingfactor),hod,W/m . C

5000

Insidedirtcoefficient,hid,W/m2.oC(fromTable12.2,vol.Six)

5000

Thermalconductivityofthetubewallmaterial,kw,W/m.oC

16.3

2 o

Tubeinsidediameter,Dti,m

0.01483

Tubeoutsidediameter,Dto,m

0.01905

Overallheattransfercoefficientcanbecalculatedbyusingtheformula

1
1 1 d to ln ( d to / d ti ) d to 1 d to 1
= +
+
+ +
U o h s hod
2 kw
d ti hid d ti hi

Therefore,

1/Uo=

0.0007331192

Uo=

1364.0346495463 W/m2.C

h)Numberofbaffle,Nb
Numberofbaffle,Nb

N b =( L /l B )1
Nbaffle

Costing
Type
Area(m2)
Material
FeedPressure

Shellandtube
40.6747
CarbonSteel
1.01325bar

Production of 100,000 MTA Hydrogen

(eqn.12.1)

Appendix F -126

WithreferencetocostingmethodproposedbyL.T.Biegler,
BaseCost,C

For100<S<10000ft2,
C =C0 ( S / S0 )
Co
5000
BareModuleCost,BMC
So
400
a
0.65
BMC =BC ( C ) MF
UF
3.219048
MaterialsandPressureCorrectionFactor,MPF

MPF=Fm ( F p + F d )
Totalarea(ft2)
Basecost,C($)
Modularfactor,MF
Designfactor,Fd
Pressurefactor,Fp
Materialfactor,Fm
MPF
Baremodulecost($)
Baremodulecost(RM)

Production of 100,000 MTA Hydrogen

437.82
5302.4006
3.29
1.0 (Floatinghead)
0
1 (CS/CS)
1
$56,156
213,393

Appendix F -127

HeatExchanger,X28
Heatexchangertype
Designtype
Heatexchangerorientation
Tubeinletdirection
Numberofparallelplate
Tubesidestreamfeed
Tubeside
Shellside
Heatduty(kW)

1shelland2tubes
Splitringfloatinghead
Horizontal
Horizontal
1
1
OrganicSolvents
Water
5635.519

a)Equipmentsizing
Stream
Tin(K)

shell
Water

tube
organicsolvent

349.12

289.79

Tout(K)

303.15

299.36

T1

T2

t2
t1

T1=inlettemperaturetoshell
T2=outlettemperaturefromshell
t1=inlettemperaturetotube
t2=outlettemperaturefromtube

R= (T1T2)/(t2t1)
R=
4.804
S= (t2t1)/(T1t1)

(eqn.12.6)
(eqn.12.7)

S=
0.161
Ftcanbeobtainedfromfig12.19(vol.6),
Ft=
0.9600
Tlm can be calculated from the equation,

T lm =

( T 1 t 2 )( T 2 t 1 )
(T 1 t 2 )
ln
(T 2 t 1 )
Tlm=

27.6817

Therefore,theactualtemperaturedifferenceis
FtTlm=
26.5745

Production of 100,000 MTA Hydrogen

(eqn.12.4)

Appendix F -128

Assumption:(Table12.1,'Chem.Eng',Vol.6)
U

600 W/(C.m2)

Provisionalareaofheatexchanger,Acanbeobtainedtroughtheformulae,
lm

Q=UA Talignl

A=

Q
UT lm

Provisionalarea,A

353.4419 m2
3804.4172 ft2

b)Tuberating(App.5.2,TranportProcesses)
Material
BWGnumber
LengthoftubeLt(m)

Carbonsteel
16
2.44

Outerdiameter,Dto(mm)

19.05

Innerdiameter,Dti(mm)

15.75
16.3

MaterialThermalConductivity(W/m.K)
Heattransferareaofatube,At
to

A t = Lt Dalignl

Areaofonetube,At(m2)

0.1460
1.5718

(ft2)
Numberoftube,Nt

N t=
Numberoftube,Nt

A
At
2420

Tubepitchisthedistancebetweentubecentresandformulatedas

Pt =1. 25Dto
Tubepitch,Pt(mm)

23.8125

FromTable12.4,ChemicalEngineering,Vol.6(1stEdition)
TriangularpitchK1
0.249
(2passes)n

Production of 100,000 MTA Hydrogen

2.207

Appendix F -129

Thebundlediameter,Db
(eqn.12.3b)

D b = D to ( N t / K 1 )1 / n
Bundlediameter,Db(mm)

1221.0397

FromChemicalEngineering,Vol.6(figure12.10)
Shellbundleclearance(mm)

78

ForSplitringfloatinghead,
Ds=Db+shellbundleclearance
Shellinternaldiameter,Ds(m)

1.2990

c)Tubesidecoefficient
Meantemperature(K)
Tmean=(Tc.in+Tc,out)/2
Meantemperature(K)

294.5750

Tubecrosssectionalarea,At

Tubecrosssectionalarea,At

ti2

4
At=

Tubecrosssectionalarea,At
Tubeperpass=Nt

194.8531 mm2
605

Totalflowarea(m ),AT
2

A T = N t At
Totalflowarea(m2),AT

0.1179

Massflowrate(insidetube),m

166.2194

kg/hr

Fluidvelocity,f

v f =m / A T
massvelocity,f

Production of 100,000 MTA Hydrogen

1409.7780 kg/m2.s

Appendix F -130

Physicalpropertiesofthetubesidefluid
Physicalproperties
density, t

838.8215 kg/m3

Viscosity, tL

5.16E04 Ns/m2

Heatcapacity,Ctp

3.5427474082 kJ/kg.K

Thermalconductivity,ktf

0.5803266637 W/m.K

Linearvelocity,u

u= v f /
Reynoldnumber,Re

Re=
Prandtlnumber,Pr

Pr =

uD ti

Cp

linearvelocity,u(m/s)
Reynoldnumber,Re
Prandtlnumber,Pr
L/Dti

kf

1.6807
43015.675
3.1512
154.9206

Fromfigure12.23,ChemicalEngineering,Vol.6
Heattransferfactor,jh
0.0036
Tubesideheattransfercoefficient,hi

k f j h RePr 0 .33
hi =
D ti
w

0. 14

( )

(eqn.12.15)

Tubesideheattransfercoefficient,hi

8333.3 W/m2.C

(assumingviscosityofthefluidisidenticalatthewallandofthebulkfluid)
d)Tubesidepressuredrop
Fromfigure12.24'ChemicalEngineering'.Vol.6
frictionfactor,jf
0.0033
Tubesidepressuredrop,Pt
P s = N p [ 8 j f ( L / D ti )(

u 2s
m
) + 2. 5 ]
w
2

where m = 0.25 for laminar flow, Re<2100


m = 0.14 for turbulent flow, Re>2100
Np = number of tube side passes

Production of 100,000 MTA Hydrogen

(eqn.12.20)

Appendix F -131

Tubesidepressuredrop,
Pt

15.6139 kPa

e)Shellsidecoefficient
Shelldiameter,Ds

(acceptable)

1.2990 m

Baffle Spacing , l B = 0. 9D s

Baffle Diameter= Ds 0.0016


Bafflespacing,lB

1.1691 m
1.2974 m

BaffleDiameter
Tubepitch,Pt

23.8125 mm

Crossflowarea,As

A s=

( pt D to ) D s l B
pt

Crossflowarea,As

(eqn.12.21)
0.3038 m2

Shellsidemassvelocity,Gs
G s w s / As

Massflow(insideshell),Ws
Shellsidemassvelocity,Gs

109113.8792 kg/hr
99.7838 kg/s.m2

Shellsideequivalentdiameter,De

D e=

1.1
( p2z 0 . 971 D 2to )
D to

Shellsideequivalentdiameter,De

(eqn.12.23)

13.5265 mm

Meantemperature(C)
Tmean=(Tshell.in+Tshell.out)/2
Meantemperature(C)
Physicalpropertiesofshellfluid

Production of 100,000 MTA Hydrogen

326.1350

Baffle
diameter

Appendix F -132

Physicalproperties
Fluid density, s

965.3964 kg/m3

Viscosity, sL

5.8331E04 Ns/m2

Heatcapacity,Csp

4.1834076276 kJ/kg.K

Thermalconductivity,ksf

1.1730 W/m.K

Reynoldnumber,Re

Re=G s D e /
Reynoldnumber,Re
Prandtlnumber,Pr

(eqn.12.24)
2614.806
2.0803

Selecting15%forbafflecut
Fromfigure12.29,ChemicalEngineering,Vol.6
HeatTransferFactor,jh
0.0130
Shellsideheattransfercoefficient,hs

k f j h RePr 1/ 3
h s=
De
w

0 . 14

( )

Shellsideheattransfercoefficient,hs

(eqn.12.25)
3753.935 W/m2.C

f)Shellsidepressuredrop
Linearvelocity,us

us =G s /
Linearvelocity,us

0.1034 m/s

Fromfigure12.30'ChemicalEngineering'.Vol.6
frictionfactor,jf
0.0850
Shell side presure drop, Ps

k f j h RePr
h s=
De

1/ 3

0 . 14

( )

Production of 100,000 MTA Hydrogen

(eqn.12.26)

Appendix F -133

42201.6211 Pa

Shell side presure drop,


Ps

(acceptable)

42.2016 kPa

g)OverallCoefficient
Outsidefluidfilmcoefficient,hs,W/m2.oC
Insidefluidfilmcoefficient,hi,W/m2.oC

3753.935
8333.3

Outsidedirtcoefficient(foulingfactor),hod,W/m2.oC

5000

Insidedirtcoefficient,hid,W/m2.oC(fromTable12.2,vol.Six)

5500

Thermalconductivityofthetubewallmaterial,kw,W/m.oC

16.3

Tubeinsidediameter,Dti,m

0.01575

Tubeoutsidediameter,Dto,m

0.01905

Overallheattransfercoefficientcanbecalculatedbyusingtheformula

1
1 1 d to ln ( d to / d ti ) d to 1 d to 1
= +
+
+ +
U o h s hod
2 kw
d ti hid d ti hi

Therefore,

1/Uo=

0.0009426041

Uo=

1060.8908096623 W/m2.C

h)Numberofbaffle,Nb
Numberofbaffle,Nb

N b =( L /l B )1
Nbaffle

Costing
Type
Area(m2)
Material
FeedPressure

Shellandtube
353.4419
CarbonSteel
25.7bar

WithreferencetocostingmethodproposedbyL.T.Biegler,
BaseCost,C

C=C0 ( S / S0 )

Production of 100,000 MTA Hydrogen

(eqn.12.1)

Appendix F -134

BareModuleCost,BMC

BMC =BC ( C )MF


MaterialsandPressureCorrectionFactor,MPF

MPF=Fm ( F p + F d )
Totalarea(ft2)
Basecost,C($)
Modularfactor,MF
Designfactor,Fd
Pressurefactor,Fp
Materialfactor,Fm
MPF
Baremodulecost($)
Baremodulecost(RM)

Production of 100,000 MTA Hydrogen

For100<S<10000ft2,
Co
5000
So
400
a
0.65
UF
3.219048

3804.42
21618.1387
3.29
1.0 (Floatinghead)
0
1 (CS/CS)
1
$228,951
870,012

Appendix F -135

HeatExchanger,X29
Heatexchangertype
Designtype
Heatexchangerorientation
Tubeinletdirection
Numberofparallelplate
Tubesidestreamfeed
Tubeside
Shellside
Heatduty(kW)

1shelland2tubes
Splitringfloatinghead
Horizontal
Horizontal
1
1
lighthydrocarbon
naturalgases
2437.400

a)Equipmentsizing
Stream
Tin(K)
Tout(K)

shell
NaturalGases

tube
LightHydrocarbon

387.57

284.15

294.15

333.15

T1

T2

t2
t1

T1=inlettemperaturetoshell
T2=outlettemperaturefromshell
t1=inlettemperaturetotube
t2=outlettemperaturefromtube

R= (T1T2)/(t2t1)
R=
1.907
S= (t2t1)/(T1t1)

(eqn.12.6)
(eqn.12.7)

S=
0.474
Ftcanbeobtainedfromfig12.19(vol.6),
Ft=
0.8000
Tlm can be calculated from the equation,

T lm =

( T 1 t 2 )( T 2 t 1 )
(T 1 t 2 )
ln
(T 2 t 1 )
Tlm=

Production of 100,000 MTA Hydrogen

26.2197

(eqn.12.4)

Appendix F -136

Therefore,theactualtemperaturedifferenceis
FtTlm=
20.9758
Assumption:(Table12.1,'Chem.Eng',Vol.6)
U

300 W/(C.m2)

Provisionalareaofheatexchanger,Acanbeobtainedtroughtheformulae,
lm

Q=UA Talignl

A=

Q
UT lm

Provisionalarea,A

387.3361 m2
4169.2514 ft2

b)Tuberating(App.5.2,TranportProcesses)
Material
BWGnumber
LengthoftubeLt(m)

Carbonsteel
16
2.44

Outerdiameter,Dto(mm)

19.05

Innerdiameter,Dti(mm)

15.75
16.3

MaterialThermalConductivity(W/m.K)
Heattransferareaofatube,At
to

A t = Lt Dalignl

Areaofonetube,At(m2)

0.1460
1.5587

(ft2)
Numberoftube,Nt

Nt=
Numberoftube,Nt

A
At
2652

Tubepitchisthedistancebetweentubecentresandformulatedas

Pt =1. 25Dto
Tubepitch,Pt(mm)

23.8125

FromTable12.4,ChemicalEngineering,Vol.6(1stEdition)
TriangularpitchK1
0.249
(2passes)n

Production of 100,000 MTA Hydrogen

2.207

Appendix F -137

Thebundlediameter,Db
(eqn.12.3b)

1/ n

D b = D to ( N t / K 1 )
Bundlediameter,Db(mm)

1272.7693

FromChemicalEngineering,Vol.6(figure12.10)
Shellbundleclearance(mm)

77

ForSplitringfloatinghead,
Ds=Db+shellbundleclearance
Shellinternaldiameter,Ds(m)

1.3498

c)Tubesidecoefficient
Meantemperature(K)
Tmean=(Tc.in+Tc,out)/2
Meantemperature(K)

308.6500

Tubecrosssectionalarea,At

Tubecrosssectionalarea,At

ti2

4
At=

Tubecrosssectionalarea,At
Tubeperpass=Nt

194.8531 mm2
663

Totalflowarea(m2),AT

A T = N t At
Totalflowarea(m2),AT

0.1292

Massflowrate(insidetube),m

4.5877

Fluidvelocity,f

massvelocity,f

Production of 100,000 MTA Hydrogen

kg/s

v f =m / A T
35.5055 kg/m2.s

Appendix F -138

Physicalpropertiesofthetubesidefluid
Physicalproperties
density, t

2.6873 kg/m3

Viscosity, tL

8.10E06 Ns/m2

Heatcapacity,Ctp

10.8426291636 kJ/kg.K

Thermalconductivity,ktf

0.1432749949 W/m.K

Linearvelocity,u

u= v f /
Reynoldnumber,Re

Re=
Prandtlnumber,Pr

Pr =

uDti

Cp

linearvelocity,u(m/s)
Reynoldnumber,Re
Prandtlnumber,Pr
L/Dti

kf

13.2123
69081.032
0.6126
154.9206

Fromfigure12.23,ChemicalEngineering,Vol.6
Heattransferfactor,jh
0.0038
Tubesideheattransfercoefficient,hi

k f j h RePr 0 .33
hi =
D ti
w

0. 14

( )

Tubesideheattransfercoefficient,hi

(eqn.12.15)

2031.431 W/m2.C
(assumingviscosityofthefluidisidenticalatthewallandofthebulkfluid)

d)Tubesidepressuredrop
Fromfigure12.24'ChemicalEngineering'.Vol.6
frictionfactor,jf
0.0035

Production of 100,000 MTA Hydrogen

Appendix F -139

Tubesidepressuredrop,Pt
2

u s
m
P s = N p [ 8 j f ( L / D ti )(
) + 2. 5 ]
w
2
where m = 0.25 for laminar flow, Re<2100
m = 0.14 for turbulent flow, Re>2100
Np = number of tube side passes

Tubesidepressuredrop,
Pt

(eqn.12.20)

3.2077 kPa

e)Shellsidecoefficient
Shelldiameter,Ds

(acceptable)

1.3498 m

Baffle Spacing , l B =0. 9D s

Baffle Diameter= Ds 0.0016


Bafflespacing,lB

1.2148 m
1.3482 m

BaffleDiameter
Tubepitch,Pt

23.8125 mm

Crossflowarea,As

A s=

( pt D to ) D s l B
pt

Crossflowarea,As

(eqn.12.21)
0.3279 m2

Shellsidemassvelocity,Gs
G s w s / As

Massflow(insideshell),Ws
Shellsidemassvelocity,Gs

40225.6368 kg/hr
34.0729 kg/s.m2

Shellsideequivalentdiameter,De

D e=

1.1
( p2z 0 . 971 D 2to )
D to

Shellsideequivalentdiameter,De

Production of 100,000 MTA Hydrogen

(eqn.12.23)
13.5265 mm

Baffle
diameter

Appendix F -140

Meantemperature(C)
Tmean=(Tshell.in+Tshell.out)/2
Meantemperature(C)

340.8600

Physicalpropertiesofshellfluid(stream)
Physicalproperties
Fluid density, s

1.9887 kg/m3

Viscosity, sL

1.8326E05 Ns/m2

Heatcapacity,Csp

2.9956912165 kJ/kg.K

Thermalconductivity,ksf

0.0745 W/m.K

Reynoldnumber,Re

Re=G s D e /
Reynoldnumber,Re
Prandtlnumber,Pr

(eqn.12.24)
56934.549
0.7367

Selecting15%forbafflecut
Fromfigure12.29,ChemicalEngineering,Vol.6
HeatTransferFactor,jh
0.0025
Shellsideheattransfercoefficient,hs

k f j h RePr 1/ 3
h s=
De
w

0 . 14

( )

Shellsideheattransfercoefficient,hs

(eqn.12.25)
708.9748 W/m2.C

f)Shellsidepressuredrop
Linearvelocity,us

us =G s /
Linearvelocity,us
Fromfigure12.30'ChemicalEngineering'.Vol.6
frictionfactor,jf
0.0500

Production of 100,000 MTA Hydrogen

17.1332 m/s

Appendix F -141

Shell side presure drop, Ps

k f j h RePr 1/ 3
h s=
De
w

0 . 14

( )

Shell side presure drop,


Ps

(eqn.12.26)

1334974.4710 Pa

(acceptable)

1334.9745 kPa

g)OverallCoefficient
Outsidefluidfilmcoefficient,hs,W/m2.oC

708.9748

Insidefluidfilmcoefficient,hi,W/m . C
2 o

2031.431

Outsidedirtcoefficient(foulingfactor),hod,W/m . C

5000

Insidedirtcoefficient,hid,W/m2.oC(fromTable12.2,vol.Six)

5000

Thermalconductivityofthetubewallmaterial,kw,W/m.oC

16.3

2 o

Tubeinsidediameter,Dti,m

0.01575

Tubeoutsidediameter,Dto,m

0.01905

Overallheattransfercoefficientcanbecalculatedbyusingtheformula

1
1 1 d to ln ( d to / d ti ) d to 1 d to 1
= +
+
+ +
U o h s hod
2 kw
d ti hid d ti hi

Therefore,

1/Uo=
Uo=

0.0025589571
390.7841929138 W/m2.C

h)Numberofbaffle,Nb
Numberofbaffle,Nb

N b =( L /l B )1
Nbaffle

Production of 100,000 MTA Hydrogen

(eqn.12.1)

Appendix F -142

Costing
Type
Area(m2)

Shellandtube
387.3361
CarbonSteel
5.07bar

Material
FeedPressure

WithreferencetocostingmethodproposedbyL.T.Biegler,
BaseCost,C
For100<S<10000ft2,
C=C0 ( S / S0 )
Co
5000
BareModuleCost,BMC
So
400
a
0.65
BMC =BC (C )MF
UF
3.219048
MaterialsandPressureCorrectionFactor,MPF

MPF=Fm ( F p + F d )
Totalarea(ft2)
Basecost,C($)
Modularfactor,MF
Designfactor,Fd
Pressurefactor,Fp
Materialfactor,Fm
MPF
Baremodulecost($)
Baremodulecost(RM)

Production of 100,000 MTA Hydrogen

4169.25
22943.9805
3.29
1.0 (Floatinghead)
0
1 (CS/CS)
1
$242,992
923,370

Appendix F -143

HeatExchanger,X30
Heatexchangertype
Designtype
Heatexchangerorientation
Tubeinletdirection
Numberofparallelplate
Tubesidestreamfeed
Tubeside
Shellside
Heatduty(kW)

1shelland2tubes
Splitringfloatinghead
Horizontal
Horizontal
1
1
OrganicSolvent
Methanol
1044.601

a)Equipmentsizing
Stream
Tin(K)
Tout(K)

shell
Methanol

tube
OrganicSolvent

294.15

263.15

292.26

284.15

T1

T2

t2
t1
T1=inlettemperaturetoshell
T2=outlettemperaturefromshell
t1=inlettemperaturetotube
t2=outlettemperaturefromtube

R= (T1T2)/(t2t1)
R=
0.090
S= (t2t1)/(T1t1)

(eqn.12.6)
(eqn.12.7)

S=
0.677
Ftcanbeobtainedfromfig12.19(vol.6),
Ft=
0.9800
Tlm can be calculated from the equation,

T lm =

( T 1 t 2 )( T 2 t 1 )
(T 1 t 2 )
ln
(T 2 t 1 )
Tlm=

17.8860

Therefore,theactualtemperaturedifferenceis
FtTlm=
17.5283

Production of 100,000 MTA Hydrogen

(eqn.12.4)

Appendix F -144

Assumption:(Table12.1,'Chem.Eng',Vol.6)
U

450 W/(C.m2)

Provisionalareaofheatexchanger,Acanbeobtainedtroughtheformulae,
lm

Q=UA Talignl

A=

Q
UT lm

Provisionalarea,A

132.4336 m2
1425.5029 ft2

b)Tuberating(App.5.2,TranportProcesses)
Material
BWGnumber
LengthoftubeLt(m)

Carbonsteel
16
2.44

Outerdiameter,Dto(mm)

19.05

Innerdiameter,Dti(mm)

15.75
16.3

MaterialThermalConductivity(W/m.K)
Heattransferareaofatube,At
to

A t = Lt Dalignl

Areaofonetube,At(m2)

0.1460
1.5587

(ft2)
Numberoftube,Nt

N t=
Numberoftube,Nt

A
At
907

Tubepitchisthedistancebetweentubecentresandformulatedas

Pt =1. 25Dto
Tubepitch,Pt(mm)

23.8125

FromTable12.4,ChemicalEngineering,Vol.6(1stEdition)
TriangularpitchK1
0.249
(2passes)n
Thebundlediameter,Db

Production of 100,000 MTA Hydrogen

2.207

Appendix F -145

(eqn.12.3b)

1/ n

D b = D to ( N t / K 1 )
Bundlediameter,Db(mm)

782.6410

FromChemicalEngineering,Vol.6(figure12.10)
Shellbundleclearance(mm)

73

ForSplitringfloatinghead,
Ds=Db+shellbundleclearance
Shellinternaldiameter,Ds(m)

0.8556

c)Tubesidecoefficient
Meantemperature(K)
Tmean=(Tc.in+Tc,out)/2
Meantemperature(K)

273.6500

Tubecrosssectionalarea,At

Tubecrosssectionalarea,At

ti2

4
At=

Tubecrosssectionalarea,At
Tubeperpass=Nt

194.8531 mm2
227

Totalflowarea(m ),AT
2

A T = N t At
Totalflowarea(m2),AT

0.0442

Massflowrate(insidetube),m

4.5877

kg/s

Fluidvelocity,f

v f =m / A T
massvelocity,f

Production of 100,000 MTA Hydrogen

103.8450 kg/m2.s

Appendix F -146

Physicalpropertiesofthetubesidefluid
Physicalproperties
density, t

2.6873 kg/m3

Viscosity, tL

8.10E06 Ns/m2

Heatcapacity,Ctp

10.8426291636 kJ/kg.K

Thermalconductivity,ktf

0.1432749949 W/m.K

Linearvelocity,u

u= v f /
Reynoldnumber,Re

Re=
Prandtlnumber,Pr

Pr =

uD ti

Cp

linearvelocity,u(m/s)
Reynoldnumber,Re
Prandtlnumber,Pr
L/Dti

kf

38.6429
202045.508
0.6126
154.9206

Fromfigure12.23,ChemicalEngineering,Vol.6
Heattransferfactor,jh
0.0030
Tubesideheattransfercoefficient,hi

k f j h RePr 0 .33
hi =
D ti
w

0. 14

( )

(eqn.12.15)

Tubesideheattransfercoefficient,hi(W/m2.C)

4690.6177761291
(assumingviscosityofthefluidisidenticalatthewallandofthebulkfluid)
d)Tubesidepressuredrop
Fromfigure12.24'ChemicalEngineering'.Vol.6
frictionfactor,jf
0.0023
Tubesidepressuredrop,Pt
2

u s
m
P s =N p [ 8 j f ( L / D ti )(
) + 2. 5 ]
w
2
where m = 0.25 for laminar flow, Re<2100

Production of 100,000 MTA Hydrogen

(eqn.12.20)

Appendix F -147

m = 0.14 for turbulent flow, Re>2100


Np = number of tube side passes
21.4710 kPa

Tubesidepressuredrop,
Pt
e)Shellsidecoefficient
Shelldiameter,Ds
Baffle Spacing , l B =0. 9D s

(acceptable)

0.8556 m
Baffle
diameter

Baffle Diameter= Ds 0.0016


Bafflespacing,lB

0.7701 m
0.8540 m

BaffleDiameter
Tubepitch,Pt

23.8125 mm

Crossflowarea,As

A s=

( pt D to ) D s l B
pt

Crossflowarea,As

(eqn.12.21)
0.1318 m2

Shellsidemassvelocity,Gs
G s w s / As

Massflow(insideshell),Ws
Shellsidemassvelocity,Gs

720925.4752 kg/hr
1519.6103 kg/s.m2

Shellsideequivalentdiameter,De

D e=

1.1
( p2z 0 . 971 D 2to )
D to

Shellsideequivalentdiameter,De

(eqn.12.23)

13.5265 mm

Meantemperature(C)
Tmean=(Tshell.in+Tshell.out)/2
Meantemperature(C)

Production of 100,000 MTA Hydrogen

293.2065

Appendix F -148

Physicalpropertiesofshellfluid(stream)
Physicalproperties
Fluid density, s

799.8603 kg/m3

Viscosity, sL

5.1581E04 Ns/m2

Heatcapacity,Csp

3.6981344329 kJ/kg.K

Thermalconductivity,ksf

0.6155 W/m.K

Reynoldnumber,Re

Re=G s D e /
Reynoldnumber,Re
Prandtlnumber,Pr

(eqn.12.24)
2539213.908
3.0990

Selecting15%forbafflecut
Fromfigure12.29,ChemicalEngineering,Vol.6
HeatTransferFactor,jh
0.0008
Shellsideheattransfercoefficient,hs

k f j h RePr 1/ 3
h s=
De
w

0 . 14

( )

Shellsideheattransfercoefficient,hs(W/m2.C)

(eqn.12.25)
134265.25076058

f)Shellsidepressuredrop
Linearvelocity,us

us =G s /
Linearvelocity,us

Fromfigure12.30'ChemicalEngineering'.Vol.6
frictionfactor,jf
0.0320

Production of 100,000 MTA Hydrogen

1.8998 m/s

Appendix F -149

Shell side presure drop, Ps


1/ 3
k f j h RePr

h s=
De
w

0 . 14

( )

(eqn.12.26)
6319096.4457 Pa

Shell side presure drop,


Ps

(acceptable)

6319.0964 kPa

g)OverallCoefficient
Outsidefluidfilmcoefficient,hs,W/m2.oC

134265.25076058

Insidefluidfilmcoefficient,hi,W/m . C
2 o

4690.6177761291

Outsidedirtcoefficient(foulingfactor),hod,W/m . C
2 o

5000

Insidedirtcoefficient,hid,W/m . C(fromTable12.2,vol.Six)

5000

Thermalconductivityofthetubewallmaterial,kw,W/m. C

16.3

2 o

Tubeinsidediameter,Dti,m

0.01575

Tubeoutsidediameter,Dto,m

0.01905

Overallheattransfercoefficientcanbecalculatedbyusingtheformula

1
1 1 d to ln (d to / d ti ) d to 1 d to 1
= +
+
+ +
U o h s hod
2 kw
d ti hid d ti hi

Therefore,

1/Uo=

0.000818373

Uo=

1221.9366306095 W/m2.C

h)Numberofbaffle,Nb
Numberofbaffle,Nb

N b =( L /l B )1
Nbaffle

Costing
Type
Area(m2)
Material
FeedPressure

Shellandtube
132.4336
CarbonSteel
5.07bar

Production of 100,000 MTA Hydrogen

(eqn.12.1)

Appendix F -150

WithreferencetocostingmethodproposedbyL.T.Biegler,
BaseCost,C

C=C0 (S/ S0 )
BareModuleCost,BMC

BMC =BC ( C )MF


MaterialsandPressureCorrectionFactor,MPF

For100<S<10000ft2,
Co
5000
So
400
a
0.65
UF
3.219047619

MPF=Fm ( F p + F d )
Totalarea(ft2)
Basecost,C($)
Modularfactor,MF
Designfactor,Fd
Pressurefactor,Fp
Materialfactor,Fm
MPF
Baremodulecost($)
Baremodulecost(RM)

Production of 100,000 MTA Hydrogen

1425.50
11421.1619
3.29
1.0 (Floatinghead)
0
1 (CS/CS)
1
$120,958
459,639

Appendix F -151

Heater X-34
Heatexchangertype
Designtype
Heatexchangerorientation
Tubeinletdirection
Numberofparallelplate
Tubesidestreamfeed
Tubeside
Shellside
Heatduty(kW)(Q)

Splitflowshelland2tubes
FixedandUTube
Horizontal
Horizontal
1
1
Organicsolvent
Steam
12935.46000

a)Equipmentsizing
shell(t)
Steam

tube(T)
Organic
solvent

Tin(K)

523.15

331.19

Tout(K)

423.15

353.15

Stream

T1

T2

t2
t1
T1=inlettemperaturetotube
T2=outlettemperaturefromtube
t1=inlettemperaturetoshell
t2=outlettemperaturefromshell

R= (T1T2)/(t2t1)
R=
4.5537340619
S= (t2t1)/(T1t1)
S=
0.1144
Ftcanbeobtainedfromeqn12.8(vol.6),
Ft=
0.976

Production of 100,000 MTA Hydrogen

(eqn.12.6)

(eqn.12.7)

Appendix F -152

Tlm can be calculated from the equation,


T lm =

( T 1 t 2 )( T 2 t 1 )
(T 1 t 2 )
ln
(T 2 t 1 )

Tlm=

(eqn.12.4)

127.0090

Therefore,theactualtemperaturedifferenceis
Tm = FtTlm =
124.0151
Assumption:(Table12.1,'Chem.Eng',Vol.6)
U

800 W/(C.m2)

Provisionalareaofheatexchanger,Acanbeobtainedtroughtheformula,
lm

Q
UT lm

Q=UA Talignl

A=

Provisionalarea,A=

130.3819 m2
1403.4194 ft2

=
b)Tuberating(FromApp.5.
2,TranportProcesses
by,ChristieJ.Geankoplis)
Material
BWGnumber
LengthoftubeLt(m)

StainlessSteel
16
4.88

Outerdiameter,Dto(mm)

19.05

Innerdiameter,Dti(mm)

15.75
44.0

MaterialThermalConductivity(W/m.K)
Heattransferareaofatube,At
to

A t = Lt Dalignl

Areaofonetube,At(m )=
2

(ft2)=

Production of 100,000 MTA Hydrogen

0.2921
3.1437

Appendix F -153

Numberoftube,Nt

N t=

A
At

Numberoftube,Nt

446

Tubepitchisthedistancebetweentubecentresandformulatedas

Pt =1. 25Dto
Tubepitch,Pt(mm)

23.8125

FromTable12.4,ChemicalEngineering,Vol.6(1stEdition),page523
Triangularpitch
K1
0.249
(2passes)
n
2.207

Pt

Thebundlediameter,Db

1/ n

D b = D to ( N t / K 1 )
Bundlediameter,Db(mm)
FromChemicalEngineering,Vol.6(figure12.10)
Shellbundleclearance(mm)

(eqn.12.3b)
567.6654

60

ForSplitringfloatinghead,
Ds=Db+shellbundleclearance
Shellinternaldiameter,Ds(m)

0.62767

c)Tubesidecoefficient
Meantemperature(C)
Tmean=(TH.in+TH,out)/2
Meantemperature(C)

Production of 100,000 MTA Hydrogen

342.1700

Appendix F -154

Tubecrosssectionalarea,At

ti2

Tubecrosssectionalarea,At

At=

194.8531 mm2

Tubeperpass=Nt

223

Totalflowarea(m2),AT

A T = N t At
Totalflowarea(m2),AT

0.0434941

Massflowrate(insidetube),m

216.6034

kg/s

Fluidvelocity,f

v f =m / A T
Fluidmassvelocity,f

4980.0634 kg/m2.s

Physicalpropertiesofthetubesidefluid(simulationresult)
Physicalpropertiesoforganicsolvent
organic solvent density, t

838.4112 kg/m3

Viscosity of , tL

5.15E04 Ns/m2

Heatcapacity,Ctp
Thermalconductivity,ktf

3.5453121354 kJ/kg.K
0.579725796 W/m.K
1cp(Ns/m2)=

Linearvelocity,u

u= v f /
Reynoldnumber,Re

Re=

uD ti

Production of 100,000 MTA Hydrogen

Prandtlnumber,Pr

Pr =

Cp
kf

1.00E03

Appendix F -155

steamlinearvelocity,u(m/s)
Reynoldnumber,Re
Prandtlnumber,Pr
L/Dti

5.9399
1.5237E+05
3.1481
309.8413

Fromfigure12.23,ChemicalEngineering,Vol.6
Heattransferfactor,jh
0.00320
Tubesideheattransfercoefficient,hi

k f j h RePr 0 .33
hi =
D ti

0. 14

( )

(eqn.12.15)

Tubesideheattransfercoefficient,hi

26202.7833

(assumingviscosityofthefluidisidenticalatthewallandofthebulkfluid)

d)Tubesidepressuredrop
Fromfigure12.24'ChemicalEngineering'.Vol.6
frictionfactor,jf
0.00250
Tubesidepressuredrop,Pt
2

u s
m
P s = N p [ 8 j f ( L / D ti )(
) + 2. 5 ]
w
2
where m = 0.25 for laminar flow, Re<2100
m = 0.14 for turbulent flow, Re>2100
Np = number of tube side passes

Tubesidepressuredrop,
Pt(atm)

Production of 100,000 MTA Hydrogen

(eqn.12.20)

257.2607 kPa
2.538965529

Appendix F -156

e)Shellsidecoefficient
Shelldiameter,Ds
Baffle Spacing , l B = 0. 9D s

0.6277 m
Baffle
diameter

Baffle Diameter= D s 0 . 0016


Bafflespacing,lB

0.5649 m
0.6261 m

BaffleDiameter
Tubepitch,Pt

23.8125 mm

Crossflowarea,As

A s=

( pt D to ) D s l B
pt

Crossflowarea,As

(eqn.12.21)
0.070913 m2

Shellsidemassvelocity,Gs

G s ws / As
Massflow(insideshell),Ws
Shellsidemassvelocity,Gs

65.102979 kg/s
918.0619 kg/s.m2

Shellsideequivalentdiameter,De

D e=

1.1
( p2z 0 . 971 D 2to )
(eqn.12.23)
D to

Shellsideequivalentdiameter,De

13.5265 mm

Meantemperature(C)
Tmean=(Tshell.in+Tshell.out)/2
Meantemperature(C)

Physicalpropertiesofshellfluid(steam)

Production of 100,000 MTA Hydrogen

473.1500

Appendix F -157

Physicalproperties
Fluid density, s

0.4211 kg/m3

Viscosity, sL

1.82E-05 Ns/m2
1.98692E+00 kJ/kg.K

Heatcapacity,Csp
Thermalconductivity,ksf
Reynoldnumber,Re

0.0381499 W/m.K

Re G s De /

(eqn.12.24)

Reynoldnumber,Re
Prandtlnumber,Pr

6.8153E+05
0.9490

Selecting15%forbafflecut
Fromfigure12.29,ChemicalEngineering,Vol.6
HeatTransferFactor,jh
0.0009
Shellsideheattransfercoefficient,hs

k f j h RePr 1/ 3
h s=
De
w

0 . 14

( )

(eqn.12.25)

Shellsideheattransfercoefficient,hs(W/m2.C)

1700.3221358651

f)Shellsidepressuredrop
Linearvelocity,us

us =G s /
Linearvelocity,us

2179.9965 m/s

Fromfigure12.30'ChemicalEngineering'.Vol.6
frictionfactor,jf
0.0340

Shell side presure drop, Ps

u2s 0 .14
P s =8 j f ( D s / D e )( L /l B )
(
)
2
w
Shell side presure drop,
Ps (atm)

Production of 100,000 MTA Hydrogen

(eqn.12.26)

109108878.2618 Pa
109108.8783 kPa

1076.8209056181

Appendix F -158

g)OverallCoefficient
Outsidefluidfilmcoefficient,hs,W/m2.oC

1700.3221358651

Insidefluidfilmcoefficient,hi,W/m . C
2 o

26202.7833

Outsidedirtcoefficient(foulingfactor),hod,W/m . C
2 o

5000

Insidedirtcoefficient,hid,W/m . C(Table12.2,vol.Six)

5000

Thermalconductivityofthetubewallmaterial,kw,W/m. C

44.0

2 o

Tubeinsidediameter,Dti,m

0.01575

Tubeoutsidediameter,Dto,m

0.01905

Overallheattransfercoefficientcanbecalculatedbyusingtheformula

1
1
1 d to ln ( d to / d ti ) d to
1 d
1
= +
+
+
+ to
U o h s hod
2 kw
d ti hid d ti hi (eqn.12.2)
Therefore,
1/Uo=
Uo=

0.0011173685
894.959896056 W/m2.C

h)Numberofbaffle,Nb
Numberofbaffle,Nb

N b =( L /l B )1
Nbaffle

i)Costing(Guthrie'sModularMethod)
TotalareaoftheHeatExchanger=
OperatingPressure=
CEPlantCostIndexfor2003,CEI03=
CEPlantCostIndexfor19681/2,CEI68=
Updatefactor=
=

130.3819 m
= 1403.4180838 ft2
4.75 bar
405.6
2

126.00

405.6
126.00
3.219047619

With reference to costing method proposed in Systematic Method of Chemical Process

Design by L.T. Biegler.

Production of 100,000 MTA Hydrogen

Appendix F -159

Base Cost,
C0=
S0=
=
Updated Bare Module Cost :

5000
400
0.65
BMC= (UF)(MPF+MF-1) (BC)

Materials and Pressure Correction Factor, MPF

Total area (ft2)


Base cost, C ($)
Modular factor, MF
Design factor, Fd
Pressure factor, Fp
Material factor, Fm
MPF

1,403.41808
11,305.834
3.2900
0.8500
0.0000
2.5000
2.1250

Updated bare module


cost ($)
Bare module cost (RM)

160,679.59
610,582.44

Utility cost:
H (250C, 475 kPa,super) =
H (150C, saturated)
=
H

2961.85
632.1
2329.75

kJ/kg
kJ/kg
kJ/kg

Steam flow, mc

Qmax/H
=
=
5.5523
=
5552.3
=
308
The amout of water need to be heated to obtain the amount of steam;
=
5.5523
=
19988
=
=

19.9883

kg/s
g/s
gmol/s
kg/s
kg/hr
m3/hr

172,698.5933 m3/yr

Assume the water will be flowed to the incinerator to generate steam before flowing to the

heater, therefore, no extra heating cost is needed.


Assume water cost = RM
Total cost of water RM/yr =

Production of 100,000 MTA Hydrogen

1.15 /m3
198,603.38

Appendix F -160

Cooler X-35
Heatexchangertype
Designtype
Heatexchangerorientation
Tubeinletdirection
Numberofparallelplate
Tubesidestreamfeed
Tubeside
Shellside
Heatduty(kW)(Q)

Splitflowshelland2tubes
FixedandUTube
Horizontal
Horizontal
1
1
R12
water
68805.55600

a)Equipmentsizing
Stream
Tin(K)
Tout(K)

shell(t)
Methanol

tube(T)
R12

299.82

479.75

324.82

368.15

T1

T2

t2
t1
T1=inlettemperaturetotube
T2=outlettemperaturefromtube
t1=inlettemperaturetoshell
t2=outlettemperaturefromshell

R= (T1T2)/(t2t1)
R=
0.2240143369
S= (t2t1)/(T1t1)

(eqn.12.6)
(eqn.12.7)

S=
0.6202
Ftcanbeobtainedfromfig12.19(vol.6),
Ft=
0.950
Tlm can be calculated from the equation,
T lm =

( T 1 t 2 )( T 2 t 1 )
(T 1 t 2 )
ln
(T 2 t 1 )

Tlm=

Production of 100,000 MTA Hydrogen

105.7872

(eqn.12.4)

Appendix F -161

Therefore,theactualtemperaturedifferenceis
Tm = FtTlm =
100.4978
Assumption:(Table12.1,'Chem.Eng',Vol.6)
U

454.264 W/(C.m2)

Provisionalareaofheatexchanger,Acanbeobtainedtroughtheformula,
lm

Q
UT lm

Q=UA Talignl

A=

Provisionalarea,A=

150.7157 m2
1622.2900 ft2

=
b)Tuberating
Material
BWGnumber
LengthoftubeLt(m)

StainlessSteel
16
4.88

Outerdiameter,Dto(mm)

19.05

Innerdiameter,Dti(mm)

15.75
44.0

MaterialThermalConductivity(W/m.K)
Heattransferareaofatube,At
to

A t = Lt Dalignl

Areaofonetube,At(m )=
2

(ft2)=

0.2921
3.1437

Numberoftube,Nt

Nt=

A
At

Numberoftube,Nt

516

Tubepitchisthedistancebetweentubecentresandformulatedas

Pt =1. 25D to

Production of 100,000 MTA Hydrogen

Appendix F -162

Tubepitch,Pt(mm)

23.8125

FromTable12.4,ChemicalEngineering,Vol.6(1stEdition),page523
Triangularpitch
K1
0.249
(2passes)
n
2.207

Pt

Thebundlediameter,Db

D b = D to ( N t / K 1 )1/ n
Bundlediameter,Db(mm)

(eqn.12.3b)
606.1934

FromChemicalEngineering,Vol.6(figure12.10)
Shellbundleclearance(mm)

63

ForSplitringfloatinghead,
Ds=Db+shellbundleclearance
Shellinternaldiameter,Ds(m)

0.66919

c)Tubesidecoefficient
Meantemperature(C)
Tmean=(TH.in+TH,out)/2
Meantemperature(C)
Tubecrosssectionalarea,At

423.9500

ti2

Tubecrosssectionalarea,At

At=

Tubeperpass=Nt

194.8531
258

Totalflowarea(m2),AT

A T = N t At
Totalflowarea(m2),AT

Production of 100,000 MTA Hydrogen

0.0502772

Appendix F -163

Massflowrate(insidetube),m

12.7199

Fluidvelocity,f

v f =m / A T
Fluidmassvelocity,f

252.9944

Physicalpropertiesofthetubesidefluid(simulationresult)
Physicalpropertiesoforganicsolvent
organic solvent density, t

5.9838 kg/m3

Viscosity of , tL

1.06E05 Ns/m2

Heatcapacity,Ctp

0.5676501811 kJ/kg.K

Thermalconductivity,ktf

0.0083412529 W/m.K
1cp=

Linearvelocity,u

u= v f /
Reynoldnumber,Re

Re=

Prandtlnumber,Pr

uD ti

Pr =

steamlinearvelocity,u(m/s)
Reynoldnumber,Re
Prandtlnumber,Pr
L/Dti

kf

42.2799
3.7741E+05
0.7185
309.8413

Fromfigure12.23,ChemicalEngineering,Vol.6
Heattransferfactor,jh
0.00270
Tubesideheattransfercoefficient,hi

k f j h RePr 0 .33
hi =
D ti
w

0. 14

( )

(eqn.12.15)

Tubesideheattransfercoefficient,hi
(assumingviscosityofthefluidisidenticalatthewallandofthebulkfluid)
d)Tubesidepressuredrop

Production of 100,000 MTA Hydrogen

Appendix F -164

Fromfigure12.24'ChemicalEngineering'.Vol.6
frictionfactor,jf
0.00170
Tubesidepressuredrop,Pt
P s = N p [ 8 j f ( L / D ti )(

where m = 0.25 for laminar flow, Re<2100


m = 0.14 for turbulent flow, Re>2100
Np = number of tube side passes
Tubesidepressuredrop,
Pt

u2s
m
) + 2. 5 ]
w
2

71.8151 kPa

e)Shellsidecoefficient
Shelldiameter,Ds

0.6692

Baffle Spacing , l B = 0. 9D s

Baffle Diameter= Ds 0.0016


Bafflespacing,lB

0.6023
0.6676

BaffleDiameter
Tubepitch,Pt

23.8125

Crossflowarea,As

A s=

( pt D to ) D s l B
pt

Crossflowarea,As

(eqn.12.21)
0.080608

Shellsidemassvelocity,Gs

G s ws / As
Massflow(insideshell),Ws

200.257076

Shellsidemassvelocity,Gs

2484.3456

Shellsideequivalentdiameter,De

D e=

1.1
( p2z 0 . 971 D 2to )
D to

Production of 100,000 MTA Hydrogen

(eqn.12.23)

D e=

Appendix F -165

1.1
( p2z 0 . 971 D 2to )
D to

Shellsideequivalentdiameter,De

13.5265

Meantemperature(C)
Tmean=(Tshell.in+Tshell.out)/2
Meantemperature(C)

312.3200

Physicalpropertiesofshellfluid(steam)
Physicalproperties
Fluid density, s

799.8603 kg/m3

Viscosity, sL

5.16E-04 Ns/m2
3.69813E+00 kJ/kg.K

Heatcapacity,Csp
Thermalconductivity,ksf
Reynoldnumber,Re

0.6155396 W/m.K

Re G s De /

Reynoldnumber,Re
Prandtlnumber,Pr

(eqn.12.24)
6.5148E+04
3.0990

Selecting15%forbafflecut
Fromfigure12.29,ChemicalEngineering,Vol.6
HeatTransferFactor,jh
0.0028
Shellsideheattransfercoefficient,hs

k f j h RePr 1/ 3
h s=
De
w

0 . 14

( )

(eqn.12.25)

Shellsideheattransfercoefficient,hs
f)Shellsidepressuredrop
Linearvelocity,us

us =G s /
Linearvelocity,us
Fromfigure12.30'ChemicalEngineering'.Vol.6

Production of 100,000 MTA Hydrogen

3.1060

Appendix F -166

frictionfactor,jf

0.0500

Shell side presure drop, Ps

u2s 0 .14
P s =8 j f ( D s / D e )( L /l B )
(
)
2 w
618633.2884 Pa

Shell side presure drop,


Ps

618.6333 kPa

g)OverallCoefficient
Outsidefluidfilmcoefficient,hs,W/m2.oC
Insidefluidfilmcoefficient,hi,W/m2.oC
Outsidedirtcoefficient(foulingfactor),hod,W/m2.oC
Insidedirtcoefficient,hid,W/m2.oC(Table12.2,vol.Six)
Thermalconductivityofthetubewallmaterial,kw,W/m.oC
Tubeinsidediameter,Dti,m
Tubeoutsidediameter,Dto,m
Overallheattransfercoefficientcanbecalculatedbyusingtheformula

1
1
1 d to ln ( d to / d ti ) d to
1 d
1
= +
+
+
+ to
U o h s hod
2 kw
d ti hid d ti hi
Therefore,
1/Uo=
Uo=

0.0019335603
517.1806525014 W/m2.C

h)Numberofbaffle,Nb
Numberofbaffle,Nb

N b =( L /l B )1
Nbaffle

Production of 100,000 MTA Hydrogen

Appendix F -167

i)Costing(Guthrie'sModularMethod)
TotalareaoftheHeatExchanger=
=
OperatingPressure=
CEPlantCostIndexfor2003,CEI03=
CEPlantCostIndexfor19681/2,CEI68=
Updatefactor=

150.7157
1622.2884624286
4.75
405.6
126.00

405.6
126.00

3.219047619

With reference costing method proposed in Systematic Method of Chemical Process


Design by L.T. Biegler.
Base Cost,
C0=
S0=
=
Updated Bare Module Cost :

5000
400
0.65
BMC= (UF)(MPF+MF-1) (BC)

Materials and Pressure Correction Factor, MPF

Total area (ft2)


Base cost, C ($)
Modular factor, MF
Design factor, Fd
Pressure factor, Fp
Material factor, Fm
MPF

1,622.28846
12,422.650
3.2900
0.8500
0.0000
2.5000
2.1250

Updated bare module


cost ($)
Bare module cost (RM)

176,551.89
670,897.18

Production of 100,000 MTA Hydrogen

Appendix F -168

Cost of Coolant:
Mass flowrate of R-12 needed
=
-12.7199
Assume that the coolant R-12 will be recycled in a cycle in 10 minutes, which equal to 600s.
Total of coolant needed
=
-7631.9152
From the website, we obtained 50 pound of R-12a is sold at US 160;
Price for coolant
= US
3.2
/pound
= RM
27.02
/kg
The cost for coolant = RM
-206231.309417173
Cost of Mechanical Refrigeration Unit:
For the coolant/refrigerate to cold down to its initial temperature for recycling to the cooler X-35,
an air cooled mechanical refrigeration unit is installed.
From Ulrich (1984);
The rate of heat absorbtion, Q
=
68805.55600
The temperature of coolant
=
479.75000
=
206.60000
From Figure 5-11, Ulrich (1984);
Bare module cost for the air-cooled refrigeration unit = US $
Updated factor
=
1.29
Updated module cost, BMC
= US $
1,935,000.00
= RM
7,353,000.00

Production of 100,000 MTA Hydrogen

Appendix F -169

Splitflowshelland2tubes
FixedandUTube
Horizontal
Horizontal
1
1
R12
water
68805.55600

Production of 100,000 MTA Hydrogen

Appendix F -170

(standard length of tubes are


8,12,or16ft,pg520,Vol6)
(A.316)

Production of 100,000 MTA Hydrogen

Appendix F -171

mm2

Production of 100,000 MTA Hydrogen

Appendix F -172

kg/s

kg/m2.s

1.00E03 Ns/m2

mber,Pr

kf

483.8899 W/m2.C

Production of 100,000 MTA Hydrogen

Appendix F -173

(eqn.12.20)

0.7087598514 atm

Baffle
m

diameter

m
m
mm

m2

kg/s
kg/s.m2

Production of 100,000 MTA Hydrogen

Appendix F -174

mm

12056.9102221634 W/m2.C

m/s

Production of 100,000 MTA Hydrogen

Appendix F -175

(eqn.12.26)

6.1054358586 atm

12056.9102221634
483.8899
5000
5000
44.0
0.01575
0.01905

(eqn.12.2)

Production of 100,000 MTA Hydrogen

Appendix F -176

ft2

bar

hemical Process

Production of 100,000 MTA Hydrogen

Appendix F -177

kg/s
tes, which equal to 600s.
kg

recycling to the cooler X-35,

KW
K
oC
1,500,000

Production of 100,000 MTA Hydrogen

Appendix F -169

Cooler X-35
Heatexchangertype
Designtype
Heatexchangerorientation
Tubeinletdirection
Numberofparallelplate
Tubesidestreamfeed
Tubeside
Shellside
Heatduty(kW)(Q)

Splitflowshelland2tubes
FixedandUTube
Horizontal
Horizontal
1
1
R12
methanol
26.08619

a)Equipmentsizing
Stream
Tin(K)

shell(t)
Methanol

tube(T)
R12

294.15

263.15

293.15

278.15

Tout(K)

T1

T2

t2
t1
T1=inlettemperaturetotube
T2=outlettemperaturefromtube
t1=inlettemperaturetoshell
t2=outlettemperaturefromshell

R= (T1T2)/(t2t1)
R=
0.0666666667
S= (t2t1)/(T1t1)

(eqn.12.6)
(eqn.12.7)

S=
0.4839
Ftcanbeobtainedfromfig12.19(vol.6),
Ft=
0.980
Tlm can be calculated from the equation,
T lm =

( T 1 t 2 )( T 2 t 1 )
(T 1 t 2 )
ln
(T 2 t 1 )

Tlm=

22.2714

Therefore,theactualtemperaturedifferenceis
Tm = FtTlm =
21.8260

Production of 100,000 MTA Hydrogen

(eqn.12.4)

Appendix F -170

Assumption:(Table12.1,'Chem.Eng',Vol.6)
U

800 W/(C.m2)

Provisionalareaofheatexchanger,Acanbeobtainedtroughtheformula,
lm

Q
UT lm

Q=UA Talignl

A=

Provisionalarea,A=

1.4940 m2
16.0811 ft2

b)Tuberating(FromApp.5.2,TranportProcesses
by,ChristieJ.Geankoplis)
Material
BWGnumber
LengthoftubeLt(m)

StainlessSteel
16
4.88

Outerdiameter,Dto(mm)

19.05

Innerdiameter,Dti(mm)

15.75
44.0

MaterialThermalConductivity(W/m.K)
Heattransferareaofatube,At
to

A t = Lt Dalignl

Areaofonetube,At(m )=
2

(ft2)=

0.2921
3.1437

Numberoftube,Nt

Nt=

A
At

Numberoftube,Nt

Tubepitchisthedistancebetweentubecentresandformulatedas

Pt =1. 25Dto
Tubepitch,Pt(mm)

Production of 100,000 MTA Hydrogen

23.8125

Appendix F -171

FromTable12.4,ChemicalEngineering,Vol.6(1stEdition),page523
Triangularpitch
K1
0.249
(2passes)
n
2.207

Pt

Thebundlediameter,Db

D b = D to ( N t / K 1 )1/ n (eqn.12.3b)
Bundlediameter,Db(mm)

74.9336

FromChemicalEngineering,Vol.6(figure12.10)
Shellbundleclearance(mm)

50

ForSplitringfloatinghead,
Ds=Db+shellbundleclearance
Shellinternaldiameter,Ds(m)

0.12493

c)Tubesidecoefficient
Meantemperature(C)
Tmean=(TH.in+TH,out)/2
Meantemperature(C)
Tubecrosssectionalarea,At

270.6500

ti2

Tubecrosssectionalarea,At

At=

Tubeperpass=Nt

194.8531 mm2
3

Totalflowarea(m2),AT

A T = N t At
Totalflowarea(m2),AT
Massflowrate(insidetube),m

Production of 100,000 MTA Hydrogen

0.0004984
2.8719

kg/s

Appendix F -172

Fluidvelocity,f

v f =m / A T
Fluidmassvelocity,f

5762.4214 kg/m2.s

Physicalpropertiesofthetubesidefluid(simulationresult)
Physicalpropertiesoforganicsolvent
organic solvent density, t

5.9838 kg/m3

Viscosity of , tL

1.26E05 Ns/m2

Heatcapacity,Ctp

0.6055562135 kJ/kg.K

Thermalconductivity,ktf

0.0106691796 W/m.K
1cp=

1.00E03 Ns/m2

Linearvelocity,u

u= v f /
Reynoldnumber,Re

Re=

Prandtlnumber,Pr

uD ti

Pr =

steamlinearvelocity,u(m/s)
Reynoldnumber,Re
Prandtlnumber,Pr
L/Dti

Cp
kf

963.0037
7.2007E+06
0.7154
309.8413

Fromfigure12.23,ChemicalEngineering,Vol.6
Heattransferfactor,jh
0.00270
Tubesideheattransfercoefficient,hi

k f j h RePr 0 .33
hi =
D ti

0. 14

( )

(eqn.12.15)

Tubesideheattransfercoefficient,hi
(assumingviscosityofthefluidisidenticalatthewallandofthebulkfluid)

Production of 100,000 MTA Hydrogen

11791.9849 W/m2.C

Appendix F -173

d)Tubesidepressuredrop
Fromfigure12.24'ChemicalEngineering'.Vol.6
frictionfactor,jf
0.00170
Tubesidepressuredrop,Pt
u 2s
m
P s = N p [ 8 j f ( L / D ti )(
) + 2. 5 ]
w
2
where m = 0.25 for laminar flow, Re<2100
m = 0.14 for turbulent flow, Re>2100
Np = number of tube side passes

Tubesidepressuredrop,
Pt

(eqn.12.20)

37256.6692 kPa
367.6947371 atm

e)Shellsidecoefficient
Shelldiameter,Ds

Baffle
0.1249 m

Baffle Spacing , l B = 0. 9D s

Baffle Diameter= Ds 0 . 0016


Bafflespacing,lB

0.1124 m
0.1233 m

BaffleDiameter
Tubepitch,Pt

23.8125 mm

Crossflowarea,As

A s=

( pt D to ) D s l B
pt

Crossflowarea,As

(eqn.12.21)
0.002810 m2

Shellsidemassvelocity,Gs

G s ws / As
Massflow(insideshell),Ws

11.173788 kg/s

Shellsidemassvelocity,Gs

3977.1254 kg/s.m2

Production of 100,000 MTA Hydrogen

diameter

Appendix F -174

Shellsideequivalentdiameter,De

De=

1.1
( p2z 0 . 971 D 2to )
D to
(eqn.12.23)

Shellsideequivalentdiameter,De

13.5265 mm

Meantemperature(C)
Tmean=(Tshell.in+Tshell.out)/2
Meantemperature(C)

293.6500

Physicalpropertiesofshellfluid(steam)
Physicalproperties
Fluid density, s

1.9887 kg/m3

Viscosity, sL

1.83E-05 Ns/m2
2.99569E+00 kJ/kg.K

Heatcapacity,Csp
Thermalconductivity,ksf
Reynoldnumber,Re

0.0745250 W/m.K

Re G s De /

Reynoldnumber,Re
Prandtlnumber,Pr

(eqn.12.24)
2.9355E+06
0.7367

Selecting15%forbafflecut
Fromfigure12.29,ChemicalEngineering,Vol.6
HeatTransferFactor,jh
0.0008

Shellsideheattransfercoefficient,hs

k f j h RePr 1/ 3
h s=
De
w

0 . 14

( )

Shellsideheattransfercoefficient,hs

Production of 100,000 MTA Hydrogen

(eqn.12.25)

11697.42886 W/m2.C

Appendix F -175

f)Shellsidepressuredrop
Linearvelocity,us

us =G s /
Linearvelocity,us

1999.8619 m/s

Fromfigure12.30'ChemicalEngineering'.Vol.6
frictionfactor,jf
0.0320

Shell side presure drop, Ps


2

us 0 .14
P s =8 j f ( D s / D e )( L /l B )
(
)
2
w

(eqn.12.26)

408105712.7656 Pa

Shell side presure drop,


Ps

408105.7128 kPa

4027.690232 atm

g)OverallCoefficient
Outsidefluidfilmcoefficient,hs,W/m2.oC

11697.42886

Insidefluidfilmcoefficient,hi,W/m . C
2 o

11791.9849

Outsidedirtcoefficient(foulingfactor),hod,W/m . C
2 o

5000

Insidedirtcoefficient,hid,W/m . C(Table12.2,vol.Six)

5000

Thermalconductivityofthetubewallmaterial,kw,W/m. C

44.0

2 o

Tubeinsidediameter,Dti,m

0.01575

Tubeoutsidediameter,Dto,m

0.01905

Overallheattransfercoefficientcanbecalculatedbyusingtheformula

d to ln ( d to / d ti ) d to
1
1
1
1 d to 1 (eqn.12.2)
= +
+
+

U o h s hod
2 kw
d ti hid d ti hi
Therefore,
1/Uo=
Uo=

0.0006711451
1489.990789297 W/m2.C

h)Numberofbaffle,Nb
Numberofbaffle,Nb

N b =( L /l B )1

Production of 100,000 MTA Hydrogen

Appendix F -176

Nbaffle

42

i)Costing(Guthrie'sModularMethod)
TotalareaoftheHeatExchanger=
OperatingPressure=
CEPlantCostIndexfor2003,CEI03=
CEPlantCostIndexfor19681/2,CEI68=
Updatefactor=
=

1.4940 m
= 16.0811302128 ft2
4.75 bar
405.6
2

126.00

405.6
126.00
3.219047619

With reference to costing method proposed in Systematic Method of Chemical Process


Design by L.T. Biegler.
Base Cost,
C0=
S0=
=
Updated Bare Module Cost :

5000
400
0.65
BMC= (UF)(MPF+MF-1) (BC)

Materials and Pressure Correction Factor, MPF

Total area (ft2)


Base cost, C ($)
Modular factor, MF
Design factor, Fd
Pressure factor, Fp
Material factor, Fm
MPF

16.08113
619.066
3.2900
0.8500
0.0000
2.5000
2.1250

Updated bare module


cost ($)
Bare module cost (RM)

8,798.22
33,433.24

Production of 100,000 MTA Hydrogen

Appendix F -177

Utility cost:
Cost of Coolant R-12:
Mass flowrate of R-12 needed
=
2.8719 kg/s
Assume that the coolant R-12 will be recycled in a cycle in 10 minutes, which equal to 600s.
Total of coolant needed
=
1723.1226 kg
From the website, we obtained 50 pound of R-12a is sold at US 160;
Price for coolant
= US
3.2
/pound
= RM
27.02
/kg
The cost for coolant = RM
46562.6019443245
Cost of Mechanical Refrigeration Unit:
For the coolant/refrigerate to cold down to its initial temperature for recycling to the
cooler X-36, an air cooled mechanical refrigeration unit is installed.
From Ulrich (1984);
The rate of heat absorbtion, Q
=
26.08619 KW
The temperature of coolant
=
263.15000 K
=
-10.00000 oC
From Figure 5-11, Ulrich (1984);
Bare module cost for the air-cooled refrigeration unit = US $
15,000
Updated factor
=
1.29
Updated module cost, BMC
= US $
19,350.00
= RM
73,530.00

Production of 100,000 MTA Hydrogen

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