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Chapter-7
Thermochemistry
Part-1
16 October 2002
Themodynamics–Introduction
What is thermodynamics?
Key Points:
• System– liquid and beaker
• Surroundings– the environment
• System is open to Surroundings
Classification of Systems
Three Cases:
kinetic energy
• is the energy of a moving object
• k.e. = 1/2m.u2
potential energy
• is the stored energy
• tightly wound spring has high
potential energy
Thermal energy
• is the energy associated with
random molecular motions
Heat
Energy and Heat:
Heat is the transfer of energy from regions of high
temperature to regions of low temperature; for
example, between system and surroundings.
Demonstration:
Specific Heat
Heat Capacity
• The quantity heat required to change the temperature
of a system by one degree is called the heat capacity.
• On a per weight basis this is referred to as the specific
heat capacity or specific heat.
• For H2O, specific heat = 1 cal/g.K = 4.18 J/g.K
Specific heat and quantity of heat
A difference in temperature leads to energy transfer,
with the heat (q) lost related to
• sample mass, m
• change in T, ∆T
• specific heat capacity
Specific heat = q/m.∆T or q = m x specific heat x ∆T
Conservation of Energy
qsys + qsurr = 0 or qsys = -qsurr
Heats of Chemical Reaction
Demonstrations:
• CaCl2 + H2O Gives off heat to surroundings
• NH4Cl + H2O Takes heat from surroundings
Heat of Reaction
The heat of reaction, qrxn, is the quantity of heat
transferred between system and surroundings during a
chemical reaction.
Heat reaction reflects changes in internal energies of
reactants and products.
Exothermic and Endothermic Reactions
Exothermic– gives off heat to surroundings
Endothermic-- takes heat from surroundings