Professional Documents
Culture Documents
Chapter-6
Gases
Part-3
9 October 2002
Chemistry Research: Some History
George B. Kistiakowsky
Dudley R. Herschbach
Kinetic-Molecular Theory
How does a gas behave at the molecular scale?
Key Observations/Assumptions
• Structure
Gas consists of large number of molecules or atoms whose size
is negligible relative to volume
• Motion
Gas molecules are in constant random motion, and travel in
straight-line trajectories between collisions.
• Forces
Gas molecules do not influence one another; assume attractive
and repulsive forces are negligible except during collisions.
• Collisions
Gas molecules collide with each other and container walls.
Individual molecules gain/lose energy during collisions,
although total energy is conserved; collisions are elastic.
• Energy
The average kinetic energy of gas molecules is proportional to
the absolute temperature. At a given temperature, all gases have
the same average kinetic energy (but not speed).
Origin of Pressure
Molecular collisions & pressure
P = (impulse)x(collision frequency)
P = 1/3 (N/V)mu2
Molecular Speeds
How do properties of ideal gas molecules affect
properties such a speed?
Assume we have a mole of gas, then
PV = nRT = RT and N = NA
urms = (3RT/M)1/2
Solve for T
T = (M/3R)u2
Graham’s Law:
The rates of effusion of two different gases are inversely
proportional to the square roots of their molar masses.
Diffusion
What is diffusion?
Diffusion of a gas corresponds to gradual mixing of two or
more gases due to random molecular motions of the gas
molecules.