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DOI 10.1007/s12145-015-0244-0
RESEARCH ARTICLE
Introduction
* Surendra P. Verma
spv@ier.unam.mx
Lorena Daz-Gonzlez
ldg@uaem.mx
John S. Armstrong-Altrin
armstrong@cmarl.unam.mx
1
Computer program
General description
Figure 1 presents a simplified flow diagram of the computer program TecSand (Tectonic discrimination of
DF1ArcRiftColm1 0:26268557180321067 lnTiO2 =SiO2 adj
0:60368524343983732 lnAl2 O3 =SiO2 adj 1:72489248177453480 ln Fe2 Ot3 =SiO2 adj
0:66041836652887831 lnMnO=SiO2 adj 2:19127622323789280 lnMgO=SiO2 adj
0:14421062320062730 lnCaO=SiO2 adj 1:30431903641646780 lnNa2 O=SiO2 adj
0:05449428500688245 lnK2 O=SiO2 adj 0:33001729950322428 lnP2 O5 =SiO2 adj
1:58815020644808
DF2ArcRiftColm1 1:19586124907348950 lnTiO2 =SiO2 adj
1:06399204492462900 lnAl2 O3 =SiO2 adj 0:30341274376808475 ln Fe2 Ot3 =SiO2 adj
0:43567169774073294 lnMnO=SiO2 adj 0:83804666408979545 lnMgO=SiO2 adj
0:40664743236659878 lnCaO=SiO2 adj 1:02139743398723120 lnNa2 O=SiO2 adj
1:70581653140239940 lnK2 O=SiO2 adj 0:12642549004651965 lnP2 O5 =SiO2 adj
1:06800987330049950
(2)
(3)
(4)
The subscripts arc, rift, and col., refer to the three
tectonic fields (island or continental arc, continental rift,
and collision/convergent) that can be discriminated from
these diagrams; the subscripts m1 and m2 are for the
high-silica and low-silica diagrams, respectively. Note
more exact coefficients with larger number of digits
than reported by Verma and Armstrong-Altrin (2013)
were programmed in eqs. 1 to 4; this was done to
minimise the effects of rounding errors and achieve
the most exact DF1-DF2 functions for each sample.
This provides the exact probability values, so the sample counting for the different tectonic fields becomes
more accurate.
Another salient feature of TecSand is that it calculates the probability distribution of an individual sample
belonging to one of the three tectonic settings. For these
calculations, the DF1-DF2 values of the three centroids
(corresponding to the three tectonic settings) are required. The rounded values reported by Verma and
Armstrong-Altrin (2013) are as follows: (0.175,
1.269) for arc; (1.321, 0.841) for continental rift;
and (1.516, 0.570) for collision/convergent. Similarly,
for the low-silica diagram the centroids are as follows:
(1.650, 0.308) for arc; (0.744, 1.568) for continental
rift; and (1.767, 1.098) for collision/convergent.
However, the exact values for these centroids were programmed in TecSand. The equations for the probability
calculations have been given by Verma and Agrawal
(2011) and Verma (2012); for the sake of brevity, they
are not included here. The exact unrounded values must
be used for coefficients in eqs. 1 to 4 so that the results
of actual counting of samples in a diagram coincide
Program availability
An executable version of TecSand (TecSand.jar), related libraries, and Excel input-output data files are available for
download from tlaloc.ier.unam.mx. Program code is also
available from the same website.
Application
The coherent statistical technique of log-ratio transformation
and linear discriminant analysis are highly desirable for the
construction of discrimination diagrams (e.g., Aitchison 1986;
Egozcue et al. 2003; Agrawal and Verma 2007; Verma 2015).
These were adopted by Verma and Armstrong-Altrin (2013)
for the proposal of two diagrams for siliciclastic sediments.
These authors also extensively tested the diagrams from geochemical data of known tectonic settings. Both diagrams provided accurate results. The effects of chemical changes caused
by analytical errors and element mobility were also extensively evaluated by the original authors (Verma and
Armstrong-Altrin 2013). The diagrams provided consistent
indications in spite of the chemical changes of up to 40 %
in element concentrations, because the centroids stayed in the
original tectonic fields (Verma and Armstrong-Altrin 2013).
Therefore, these aspects are not repeated in the present work.
Instead, the emphasis is on the successful use of TecSand.
The application case studies are summarised in Table 1.
Their locations are schematically shown in Fig. 2. The application localities or regions are by age from oldest to youngest.
For a statistically significant result, total percent probability
values must exceed the by-chance probability of ~33.3 %.
Case study A1
The first application will be described in greater detail than the
other application studies. Data for 9 sandstone samples
(Group 1 and Group 2) of the Lower Cambrian (~520 Ma)
Nama Group (Namibia) were compiled from Blanco et al.
(2014). Group 3 samples (black sands) were not considered
because they represented unusual clastic rocks extremely
enriched in Ti and Fe. These rocks are significantly different
f r o m t h e r o c k t y p e s c o n s i d e r e d b y Ve r m a a n d
Armstrong-Altrin (2013) in the original diagrams. The data
were adjusted to 100 % on an anhydrous basis and total Fe
as Fe2O3T, with results showing 7 samples of high-silica and 2
of low-silica (Table 1).
For illustration purposes, we present the high-silica diagram (Arc-Rift-Col)m1 in Fig. 3. Six out of seven samples plot
in the continental rift field and showed average probability
values of 0.743 0.231 and a range of 0.42840.9904
(Table 1; open circles in Fig. 3). The remaining (one) sample
plots in the arc field with a very low probability of 0.3599
(Table 1; open square in Fig. 3). The probability value for a
given sample plotting in a tectonic field gives an indication of
how far inside that particular sample will plot. In order to more
accurately explain the probability concept, aside to the tectonic field boundaries (solid lines in Fig. 3), we have included the
70 % (or 0.70) and 90 % (0.90) probability curves (dotted and
dashed-dotted curves, respectively; Fig. 3). Any tectonic
boundary away from the triple point the intersection of the
three boundaries represents equal probability of approximately 0.50 for the two tectonic fields it separates and a very
small, negligible probability of the third field. At the triple
point, the three fields have the same probability values of
approximately 0.333. A high probability value for a given
tectonic field implies that the sample will plot well inside that
field, away from the boundaries whereas a low value will plot
close to the tectonic field boundary.
In our first application (A1), 2 samples plotted well inside
the continental rift field; they have probability values >0.90
because they plotted inside the 0.90 probability curve (Fig. 3).
One of them has the highest value of 0.9904 shown in the
range of values (0.42840.9904; Table 1) and the other sample
has a value of 0.9379 (not shown in Table 1). As an example,
such a high probability value (0.9904) for the rift field automatically means that the total probability for the other two
fields is only approximately 0.0096, which is extremely low.
Two other samples plotted between the 0.70 and 0.90 probability curves. The remaining 2 samples of the rift field plotted
very close to the field boundaries; they therefore have probability <0.70. One of them has the value of 0. 4284, being the
lowest value of the range of 0.42840.9904 (Table 1); the
other sample has a value of 0.4972 (not shown in Table 1).
The average value is approximately 0.743 (with standard deviation of 0.231) for the 6 samples in the rift field (Table 1),
which implies these samples, on average, would plot well
inside the continental rift field (Fig. 3).
The low value of 0.3599 for the only sample that plotted in
the arc field implies that this sample would plot very close to
the boundary of the field which had the next highest probability value, in this case, the rift field (Fig. 3). The probability of
this sample for the rift field was approximately 0.3533 (value
not shown in Table 1), which is only slightly lower than
0.3599 for the arc field. This is a clear example where plotting
of the sample in the diagram does not aid the decision of
which tectonic field the sample belongs to, but the small difference in the probability values (0.3599 for arc against
0.3533 for rift) suggests that the sample would plot in the
arc field close to the arc-rift boundary.
For the low-silica diagram (Arc-Rift-Col)m2 (not shown here)
of Verma and Armstrong-Altrin (2013), only 2 samples were
available for this case study (Table 1). Use of such a small
number of samples is not recommended, especially if no samples were available for the other diagram. This is not the case
here however, because the high-silica diagram had 7 samples.
The results of the low-silica diagram are included in Table 1,
to combine them with the other diagram (Fig. 3). The probability calculations clearly indicate that both samples would
plot well inside the rift field because their probability values
for this field are very high (0.9849 and 0.9860; Table 1).
As TecSand also combines the results of the 2 diagrams and
presents an overall synthesis, we can now briefly consider
them in the discussion. For both diagrams the total number
{n} {prob}
[%prob]
high-silica (Arc-Rift-Col)m1
low-silica (Arc-Rift-Col)m2
{n} {prob}
[%prob]
3
7
low-silica (Arc-Rift-Col)m2
{n} {prob}
[%prob]
high-silica (Arc-Rift-Col)m1
20
15
35
{n} {prob}
0
12
12
1
12
high-silica (Arc-Rift-Col)m1
low-silica (Arc-Rift-Col)m2
low-silica (Arc-Rift-Col)m2
{n} {prob}
[%prob]
low-silica (Arc-Rift-Col)m2
{n} {prob}
[%prob]
high-silica (Arc-Rift-Col)m1
10
{n} {prob}
[%prob]
high-silica (Arc-Rift-Col)m1
11
5
5
high-silica (Arc-Rift-Col)m1
low-silica (Arc-Rift-Col)m2
11
4
15
low-silica (Arc-Rift-Col)m2
high-silica (Arc-Rift-Col)m1
Figure type*
0 (0)
10 [0.9600.046]
(0.8471-0.9967)
{10} {9.6025}
{0} {0}
[0 %]
{0} {0}
[0 %]
20 [0.8070.164] (0.4509-0.9717)
5 [0.9640.049]
(0.8783-0.9995)
{25} {20.9516}
{0} {0}
[0 %]
0 (0)
0 (0)
{0} {0}
[0 %]
3 [0.8200.152]
(0.7120-0.9933)
0 (0)
{3} {2.4588}
[27 %]
0 (0)
0 (0)
0 (0)
6 [0.7430.231]
(0.4284-0.9904)
2 [0.98550.0008]
(0.9849, 0.9860)
{8} {6.4302}
[95 %]
0 (0)
1 (0.3939)
{1} {0.3939}
[3 %]
Continental rift
[pRift]
{1} {0.9969}
[15 %]
0 (0)
0 (0)
0 (0)
{8} {5.9225}
[64 %]
1 (0.9969)
5 [0.8440.148] (0.6035-0.9675)
5 [0.99530.0055]
(0.9857-0.9992)
{10} {9.1950}
[100 %]
8 [0.7400.179] (0.4529-0.9731)
{1} {0.3599}
[5 %]
11 [0.9560.075] (0.7368-0.9987)
2 [0.7230.126] (0.6343, 0.8126)
{13} {11.9664}
[93 %]
0 (0)
1 (0.3599)
Arc
[pArc]
Application of the two discriminant function based multi-dimensional diagrams for clastic sedimentary rocks
Table 1
{0} {0}
0 (0)
0 (0)
1 (0.7988)
{1} {0.7988}
[9 %]
3 [0.9380.105]
(0.8163-1.0000)
3 [0.99970.0002]
(0.9995-0.9998)
{6} {5.8125}
[85 %]
12 [0.8800.137]
(0.5992-0.9998)
{12} {10.5553}
[100 %]
{0} {0}
[0 %]
0 (0)
0 (0)
0 (0)
{0} {0}
[0 %]
0 (0)
1 (0.4877)
{1} {0.4877}
[4 %]
0 (0)
0 (0)
Collision
[pCol]
38
{n} {prob}
[%prob]
high-silica (Arc-Rift-Col)m1
85
60
{n} {prob}
[%prob]
{n} {prob}
[%prob]
high-silica (Arc-Rift-Col)m1
35
low-silica (Arc-Rift-Col)m2
14
25
low-silica (Arc-Rift-Col)m2
54
{n} {prob}
[%prob]
high-silica (Arc-Rift-Col)m1
71
15
low-silica (Arc-Rift-Col)m2
high-silica (Arc-Rift-Col)m1
39
542
0
542
0
16
{n} {prob}
[%prob]
high-silica (Arc-Rift-Col)m1
low-silica (Arc-Rift-Col)m2
{n} {prob}
[%prob]
high-silica (Arc-Rift-Col)m1
low-silica (Arc-Rift-Col)m2
11
low-silica (Arc-Rift-Col)m2
16
27
[%prob]
high-silica (Arc-Rift-Col)m1
Figure type*
Table 1 (continued)
{0} {0}
[0 %]
0 (0)
0 (0)
{0} {0}
[0 %]
0 (0)
[69 %]
27 [0.7480.138]
(0.4881-0.9655)
8 [0.9600.072]
(0.7889-0.9999)
{35} {27.8858}
[93 %]
13 [0.8750.155]
(0.5475-0.9998)
{13} {11.3808}
[79 %]
5 [0.55700.0447]
(0.4959-0.6151)
{5} {2.7850}
[0.6 %]
8 [0.8520.188]
(0.5054-0.9814)
3 [0.8770.187]
(0.6613-0.9916)
{11} {9.4471}
[20 %]
0 (0)
Arc
[pArc]
16 [0.7800.147]
(0.5607-0.9606)
2 [0.6350.182]
(0.5064, 0.7643)
{18} {13.7583}
[19 %]
{1} {0.5549}
[1 %]
1 (0.5549)
2 [0.8210.132]
(0.7271, 0.9145)
{2} {1.6416}
[3 %]
0 (0)
{0} {0}
[0 %]
2 [0.5490.083]
(0.4907, 0.6081)
{2} {1.0988}
[0.2 %]
0 (0)
3 [0.6860.154]
(0.5673-0.8600)
{3} {2.0570}
[7 %]
0 (0)
[31 %]
0 (0)
Continental rift
[pRift]
55 [0.8810.139]
(0.4931-0.9999)
12 [0.8490.137]
(0.6092-1.0000)
{67} {58.6453}
[81 %]
{0} {0}
[0 %]
3 [0.98240.0304]
(0.9474-1.0000)
{3} {2.9473}
[21 %]
535 [0.8840.078]
(0.4837-0.9994)
{535} {473.0774}
[99.2 %]
31 [0.9010.179]
(0.4388-1.0000)
10 [0.8520.189]
(0.5770-1.0000)
{41} {36.4558}
[77 %]
25 [0.9470.096]
(0.6025-1.0000)
34 [0.9580.076]
(0.5885-1.0000)
{59} {56.2528}
[99 %]
0 (0)
[0 %]
0 (0)
Collision
[pCol]
33
71
104
low-silica (Arc-Rift-Col)m2
{n} {prob}
[%prob]
21
11
10
10
0
10
{n} {prob}
[%prob]
high-silica (Arc-Rift-Col)m1
high-silica (Arc-Rift-Col)m1
low-silica (Arc-Rift-Col)m2
{n} {prob}
[%prob]
high-silica (Arc-Rift-Col)m1
low-silica (Arc-Rift-Col)m2
48
1
47
17
17
{0} {0}
[0 %]
0 (0)
{0} {0}
[0 %]
0 (0)
0 (0)
{0} {0}
[0 %]
0 (0)
0 (0)
{5} {2.9304}
[9 %]
0 (0)
{0} {0}
[0 %]
0 (0)
5 [0.5860.148] (0.3957-0.8045)
Arc
[pArc]
1 (0.5860)
{1} {0.5860}
[6 %]
0 (0)
5 [0.9190.111]
(0.7252-0.9940)
{5} {4.5930}
[23 %]
2 [0.7010.194]
(0.5635, 0.8376)
57 [0.9620.057]
(0.7739-0.9999)
{59} {56.2276}
[59 %]
0 (0)
{0} {0}
[0 %]
0 (0)
16 [0.4910.085]
(0.3654-0.7308)
{16} {7.8513}
[26 %]
Continental rift
[pRift]
{45} {39.7491}
[41 %]
14 [0.8680.161] (0.5132-0.9810)
{16} {15.6410}
[77 %]
31 [0.8900.157] (0.5231-1.0000)
9 [0.97910.0344] (0.9155-0.9999)
{9} {8.8118}
[94 %]
11 [0.9680.087] (0.7070-1.0000)
5 [0.998850.00150] (0.9972-1.0000)
{27} {19.9071}
[65 %]
17 [0.9550.062] (0.7702-0.9989)
{17} {16.2371}
[100 %]
1 (0.8786)
26 [0.7320.189] (0.4125-0.9999)
Collision
[pCol]
high-silica is for (SiO2)adj = > 63 % 95 %; low-silica is for (SiO2)adj = > 35 % 63 %; Probability estimates for different tectonic groups are summarised after the number of discriminated samples
as follows: [pArc] mean, standard deviation, and range of probability values estimated for island or continental arc setting (Arc); [pRift]for continental rift setting (Rift); and [pCol]for collision setting
(Col). The statistical information of probability values [mean and standard deviation] is reported as rounded values according to the flexible rules put forth by Verma (2005); the range of probability values
(range) is reported as rounded to four decimal places. Boldface font shows the combined inference from both diagrams, depending on the availability of samples from a given locality. Refer to Fig. 2 for
localities (A1-A10)
{n} {prob}
[%prob]
low-silica (Arc-Rift-Col)m2
{n} {prob}
[%prob]
high-silica (Arc-Rift-Col)m1
low-silica (Arc-Rift-Col)m2
Figure type*
Table 1 (continued)
Fig. 2 A world map showing sample localities as numbered in the text for 10 case studies (case study A1-A10)
Fig. 3 Example of the high-silica diagram for samples from the Nama
group, Namibia (case study A1)
Xu et al. (2010) presented a study of sedimentary geochemistry and provenance of the Lower and Middle Devonian
Laojunshan Formation of the North Qilian Orogenic Belt.
The geochemical data for the 4 localities sampled are considered separately: A3a Sunan; A3b Minle; A3c Gulang;
and A3d Jingyuan.
tectonic setting of an island arc on an active continental margin, which was related to the subduction of Izanagi Oceanic
plate under the Asian plate during the middle Jurassic and
early Cretaceous periods. Our inference of an arc setting is
consistent with this contention.
Case study A6
Rachold and Brumsack (2001) reported data for a very large
number of Albian (112.099.6 Ma) sediment samples from a
245 m core in the lower Saxony basin, Northwest Germany.
Data for 542 samples were compiled. All samples proved to
be of low-silica type. The application of TecSand showed a
collision/convergent setting for these samples with a very high
percent probability value of 99 % (Table 1). The original authors (Rachold and Brumsack 2001) did not comment on the
tectonic setting of these samples. However, Bruns and Littke
(2015) mentioned that the Carboniferous layers of the lower
Saxony basin have been uplifted and are situated at shallow
depths or even exposed at the surface. They further documented that two major phases of compression, uplift and erosion
affected the Lower Saxony basin: 1) The Variscan Orogeny
and 2) the collision of Europe and Africa (Voigt et al. 2008).
Other studies (Linnemann 1995; Linnemann and Romer
2002) also revealed that the lower Saxony basin became a part
of the Variscan Orogeny Belt during Devonian to Lower
Carboniferous collision processes. Hence, the collision/
convergent setting inferred through TecSand is consistent with
the geology of the lower Saxony basin, Northwest Germany.
Case study A7
Data for 39 samples of high-silica and 15 of low-silica clastic
rocks from the Asa basin, Central Tibet (Zhang 2004; Lower
Cretaceous - 145.5-99.6 Ma) clearly indicated a collision/
convergent setting (Table 1). For high-silica rocks, 31 out of
39 samples plotted in the collision/convergent setting, whereas for low-silica rocks, 10 out of 15 did so. The combined
inference was that the collision/convergent setting showed a
77 % total percent probability (Table 1). The arc field showed
the next highest total percent probability of 20 % (Table 1).
The original author (Zhang 2004) suggested a transitional
setting from collision/convergent to back-arc rifting. Zhang
(2004) used 3 ternary diagrams of Bhatia and Crook (1986)
to infer tectonic setting of the Tibetan samples. In two of these
diagrams, the samples showed a high scatter, with no clear
indications of a tectonic setting. In one diagram (Sc-Zr/
10-Th), they plotted in 4 fields, although primarily in continental island arc, active continental margin and passive continental
margin fields. Thus, none of the diagrams indicated a
transitional setting put forth by Zhang (2004) who also used
tectonic discrimination diagrams (Pearce and Norry 1979;
Pearce et al. 1984; Wood 1980) for Tibetan igneous rocks to
Case study A9
Our last case study is for clastic sediments from the northern
and south-eastern parts of Morocco. The study is subdivided
as follows: A10a Upper Triassic to Lower Jurassic (228.7
175.6 Ma) rocks from the Rif chain, north Morocco (Perri
2014); A10b Cretaceous (145.565.5 Ma) rocks from the
Tarfaya basin, south-west Morocco (Ali et al. 2014a, 2014b);
and A10c Miocene to Holocene (11.6080 Ma) rocks from
the Tarfaya basin, south-west Morocco (Ali et al. 2014a,
2014b).
A10a: Only 10 samples of high-silica type were available, 9 of which plotted in the collision/convergent field
and showed a percent probability of approximately 94 %
Conclusions
The new computer program TecSand has been created for
applying two multidimensional tectonic discrimination diagrams. TecSand was able to efficiently apply to decipher the
tectonic settings in 10 case studies. The following conclusions
were obtained from TecSand: (1) A continental rift setting for
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