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Written according to the New Text book (2012-2013) published by the Maharashtra State
Board of Secondary and Higher Secondary Education, Pune.
Std. XI Sci.
Triumph Chemistry
Prof. Santosh B. Yadav
(M.Sc., Chemistry)
Salient Features:
9
9
9
9
9
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9
Std. XI
Triumph Chemistry
Price : ` 200/-
Printed at:
Anjum Binding Work
Worli
Published by
PREFACE
With the change in educational curriculum its now time for a change in Competitive Examinations.
NEET and ISEET are all poised to take over the decade old MHT-CET. The change is obvious not merely
in the names but also at the competitive levels. The state level entrance examination is ushered aside and the
battleground is ready for a National level platform. However, keeping up with the tradition, Target Publications
is ready for this challenge.
To be at pace with the changing scenario and equip students for a fierce competition, Target Publications
has launched the Triumph series. Triumph Chemistry is entirely based on Std XI (Science) curriculum of the
Maharashtra Board. This book will not only assist students with MCQs of Std. XI but will also help them
prepare for NEET and ISEET.
The content of this book has evolved from the State Board prescribed Text Book and weve made every
effort to include most precise and updated information in it. Multiple Choice Questions form the crux of this
book. We have framed them on every sub topic included in the curriculum. Each chapter is divided into 3
sections:
Section 1 consists of basic questions.
Section 2 consists of questions which can be asked at a competitive level.
Section 3 consists of questions compiled from various competitive examinations.
To end on a candid note, we make a humble request for students: Preserve this book as a Holy Grail even
after your first year in junior college. This book would prove as an absolute weapon in your arsenal for your
combat against Medical and Engineering entrance examinations.
Yours faithfully
Publisher
Contents
No.
Topic Name
Page No.
States of Matter
17
Structure of Atom
37
Periodic Table
71
Redox Reactions
91
Chemical Equilibrium
109
Surface Chemistry
148
171
Hydrogen
211
10
s-Block Elements
230
11
250
12
270
13
Alkanes
292
14
Alkenes
309
15
Alkynes
326
16
Aromatic Compounds
338
17
Environmental Chemistry
355
TARGET Publications
01
Formulae
1.
2.
Number of moles,
mass of substance
n=
molar mass of substance
6.
7.
3.
Number of molecules
= n Avogadro number (NA)
4.
1.2
5.
8.
9.
10.
6.
SECTION - 1
1.0
Introduction
1.
2.
11.
12.
13.
14.
3.
4.
1.1
5.
TARGET Publications
15.
23.
16.
24.
17.
1.4
25.
26.
1.5
27.
28.
29.
1.6
30.
SI unit of mass is
(A) kg
(C) m
18.
1.3
19.
20.
21.
22.
(B)
(D)
g
m1
31.
32.
TARGET Publications
33.
34.
35.
36.
37.
38.
39.
(B)
(D)
43.
44.
45.
Avogadros number is
(A) number of atoms in one gram of element.
(B) number of millilitres which one mole of
a gaseous substance occupies at N.T.P.
(C) number of molecules present in one
gram molecular mass of a substance.
(D) number of elements in one gram of
compounds.
46.
47.
48.
49.
1
of O 16
14
1.66 1023 kg
40.
1.7
Avogadros Law
50.
41.
51.
42.
TARGET Publications
52.
53.
54.
55.
1.8
56.
57.
58.
59.
1.9
60.
61.
of
62.
63.
64.
Miscellaneous
65.
66.
67.
68.
69.
TARGET Publications
SECTION - 2
1.0
Introduction
1.
2.
1.1
3.
4.
5.
1.2
6.
SI unit of velocity is
(A) km s1
(C) m s2
7.
(B)
(D)
SI unit of temperature is
(A) K
(B)
(C) F
(D)
km hr1
m s1
C
D
8.
9.
10.
11.
1013.25 K pa
107 Nm
12.
13.
14.
1.3
15.
16.
17.
18.
19.
21.
22.
TARGET Publications
1.4
23.
1.5
24.
25.
1.6
26.
27
14
6
(D)
16
8
28.
29.
30.
31.
1.7
Avogadros Law
32.
33.
34.
35.
36.
6.023
9.108
37.
TARGET Publications
38.
39.
40.
41.
42.
43.
44.
47.
48.
49.
50.
1.9
51.
52.
53.
Miscellaneous
54.
1.8
45.
55.
46.
56.
TARGET Publications
4.
5.
58.
6.
59.
7.
8.
9.
10.
SECTION - 3
1.2
1.
1.3
2.
3.
TARGET Publications
1.4
11.
1.5
12.
13.
1.6
14.
15.
16.
17.
18.
19.
20.
21.
1.7
Avogadros Law
22.
23.
24.
25.
1.8
26.
27.
28.
TARGET Publications
1.9
30.
31.
32.
Miscellaneous
33.
34.
35.
36.
1.
11.
21.
31.
41.
51.
61.
(A)
(C)
(C)
(C)
(B)
(A)
(D)
2.
12.
22.
32.
42.
52.
62.
(B)
(C)
(C)
(A)
(D)
(C)
(B)
3.
13.
23.
33.
43.
53.
63.
(D)
(A)
(B)
(C)
(C)
(A)
(A)
4.
14.
24.
34.
44.
54.
64.
(D)
(D)
(C)
(C)
(A)
(B)
(C)
5.
15.
25.
35.
45.
55.
65.
(B)
(B)
(D)
(A)
(C)
(A)
(A)
6.
16.
26.
36.
46.
56.
66.
(B)
(D)
(A)
(A)
(C)
(C)
(A)
7.
17.
27.
37.
47.
57.
67.
(D)
(D)
(A)
(A)
(C)
(A)
(C)
8.
18.
28.
38.
48.
58.
68.
(A)
(D)
(B)
(A)
(B)
(B)
(B)
9.
19.
29.
39.
49.
59.
69.
(B)
(C)
(D)
(A)
(C)
(D)
(A)
10.
20.
30.
40.
50.
60.
(D)
(B)
(A)
(C)
(D)
(C)
6.
16.
26.
36.
46.
56.
(D)
(C)
(C)
(D)
(B)
(B)
7.
17.
27.
37.
47.
57.
(A)
(B)
(D)
(D)
(C)
(C)
8.
18.
28.
38.
48.
58.
(C)
(D)
(C)
(C)
(A)
(A)
9.
19.
29.
39.
49.
59.
(A)
(B)
(C)
(C)
(A)
(C)
10.
20.
30.
40.
50.
(A)
(D)
(C)
(A)
(A)
6.
16.
26.
36.
(C)
(A)
(A)
(B)
7. (A)
17. (D)
27. (B)
Section 2
1.
11.
21.
31.
41.
51.
(C)
(C)
(D)
(A)
(C)
(B)
2.
12.
22.
32.
42.
52.
(C)
(B)
(B)
(B)
(C)
(B)
3.
13.
23.
33.
43.
53.
(C)
(C)
(D)
(A)
(B)
(A)
4.
14.
24.
34.
44.
54.
(A)
(C)
(D)
(A)
(A)
(A)
5.
15.
25.
35.
45.
55.
(C)
(A)
(B)
(C)
(A)
(B)
Section 3
1.
11.
21.
31.
10
(A)
(B)
(C)
(A)
2.
12.
22.
32.
(C)
(D)
(D)
(C)
3.
13.
23.
33.
(A)
(B)
(A)
(C)
4.
14.
24.
34.
(D)
(C)
(B)
(C).
5.
15.
25.
35.
(C)
(A)
(A)
(C)
8. (B)
18. (B)
28. (B)
9. (A)
19. (A)
29. (D)
10. (D)
20. (C)
30. (C)
TARGET Publications
36.
39.
41.
47.
50.
51.
52.
1 mole of ozone(O3) = 48 g
0.5 mole of ozone(O3) = ?
0.5 48
0.5 mole of ozone(O3) =
= 24 g.
1
16 1
=
32 2
14 1
=
14g N2 has number of moles =
28 2
Number of moles are same, so number of molecules are same.
53.
56.
12
100 = 20 %
60
Section 2
16.
17.
11
TARGET Publications
28.
16.428 g 16428 mg
29.
30.
x
11022
=
or
6.02 1023
250
x=
250 11022
6.02 1023
x = 4.159 g
1
amu
3
x atom of He 6 amu
x
16=
3
x = 6 3 = 18.
32.
33.
n=
34.
36.
31.
1 atom of He
1 kg
Mass
=
= 55.56 mol
-3
Molar mass 1810 kg mol-1
1
9.108 10 6.023 1023
1
108
=
9.108 6.023
31
37.
39.
40.
41.
42.
12
1
6.022 1023
= 1.6 1024 g
Some Basic Concepts of Chemistry
TARGET Publications
45.
46.
% Composition
75.8
24.2
Atomic ratio
75.8
= 1.011
75
24.2
= 1.513
16
Simplest ratio
1.011
=1
1.011
1.513
= 1.5 2
1.011
48.
In C6H6,
Total number of C = 12 6 = 72
Total number of H = 1 6 = 6
Molecular mass = 78.
Molecular mass of Urea i.e. H2N C NH2 is 60.
||
O
28
% of N in urea =
100 = 46.6 %
60
49.
50.
51.
52.
44
=1
44
Volume of O2 required = 1 22.4 L = 22400 mL
n=
13
TARGET Publications
2H2 + O2 2H2O
53.
36
36
2
= 2 Actual amount 3 g of H2 and 29 g of O2.
1
3
29
1.5
= 1.5 mol of H2 and
= 0.91 mol of O2. Ratio of actual moles of H2 : O2 =
= 1.66 Theoretical
2
32
0.91
ratio of moles of H2 : O2 = 2 Actual ratio of moles of H2 : O2 = 1.66 Hence H2 is limiting reactant and O2 is
excess reactant.
54.
55.
N2 +
3 H2 2 NH3
(1 vol.) (3 vol.)
(2 vol.)
1
: 3
:
2
x
0.36 : 3 0.36 :
2 1.08
3
x=
= 0.72 dm
3
56.
58.
Elements
% Composition
Atomic Mass
25
12.5
75
37.5
Moles
Ratio
25
=2
12.5
75
=2
37.5
2
=1
2
2
=1
2
N2 + 3H2 2NH3
(28 g) (6 g)
(34 g)
6 gms of H2 produces 34 gms NH3
34 200
200 gms of H2 produces
= 1133.3 gms
6
Section 3
12.
14
6 1023
4.25
17
6 1023 4.25
4 = 6 1023.
Number of atoms =
17
Some Basic Concepts of Chemistry
TARGET Publications
13.
16.
19.
21.
22.
d=
M
(d = density, M= mass, V =volume)
V
Since d = 1
So, M = V
18 gm = 18 mL
18 ml = NA molecules (NA = Avogadro's number)
N
1000 mL = A 1000 = 55.555 NA.
18
23.
24.
25.
26.
28.
1
1
1.5 =
= 0.5
3
2
16
100 = 40% oxygen.
40
15
C = 24 g, H = 4 g, O = 32 g
So, Molecular formula = C2H4O2
So, Empirical formula = CH2O
(Simplest formula).
30.
% of P2O5 =
62+80=142
142
weight of P2O5
100 =
100 = 53.78 %
264
weight of salt
31.
32.
In Fe (CNS)3.3H2O
3 18
100 = 19%
% of H2O =
284
Molecular mass
Vapour density =
2
Molecular mass
22 =
2
22 2 = molecular mass
44 = molecular mass.
35.
36.
TARGET Publications
9
mole
100
CaCO3 CO2 = 0.09 mole
At NTP Vol. CO2 = 0.09 22.4 = 2.016 L.
90 % pure 9 g =
16