I) Write solubility product of: (units included)

1)
2)
3)
4)
5)
6)
7)

CaCl2
PbCl2
Al(OH)3
BaSO4
Ag2CO3
Fe(OH)2
Fe2S3

II) The solubility of silver chromate (Ag2CrO4) at t oC is 1.0 X 10-4 moldm-3.

Calculate its Ksp.
III) The solubility of lead (II) bromide in H2O is X moldm-3. Write an
expression for the solubility product of lead (II) bromide in terms of X
stating its units.
IV) A saturated solution of magnesium fluoride MgF2 has a solubility of
1.22 X 10-3 moldm-3. Calculate the value of Ksp together with its units.
V) Calculate the solubility of copper (II) sulphide in moldm-3, given Ksp of
CuS is 6.3 X 10-36 mol2dm-6
VI) The solubility of CaCO3 5.0 X 10-4 mol2dm-6. Calculate the solubility of
CaCO3 in gdm-3. Ar of Ca is 40, carbon: 12, oxygen 16.
VII) Write an expression for the solubility product Ksp for BaSO4 including
its units. The numerical data for Ksp is 1.30 X 10 -10. Calculate [Ba2+] in a
saturated solution of BaSO4.
VIII) The solubility product of AgCl is 1.0 X 10-6 mol2dm-6. Calculate
a) The solubility product of AgCl in H2O at t oC.
b) The solubility of AgCl in 0.01 moldm-3 NaCl.
IX) A commercial source of magnesium in sea water where [Mg2+ (aq)] is
0.0054 moldm-3. The magnesium is precipitated from solution by adding
calcium hydroxide.
Mg2+

(aq)

+ Ca(OH)2

(aq)

-> Ca2+

(aq)

+ Mg(OH)2

(aq)

Write an expression of Mg(OH)2, including its units. The numerical value for
Ksp is 2.00 X 10-11. Calculate [Mg2+] is a saturated solution of solution
[Mg(OH)2].
Hence calculate magnesium percentage of the original magnesium in the
seawater that this method can extract.
X) Write an expression for the solubility of lead(II)chloride. The solubility
of lead(II) iodide in H2O at 15.0 oC is 0.46 gdm-3. Calculate:
a) Concentration in moldm-3 of Pb2+
b) Concentration in moldm-3 of I-

Hence the Ksp

XI) Write an equation with state symbols for the formation by precipitation
of PbCrO4.
The solubility of product of PbCrO4 at 15oC is 1.69 X 10-14 mol2dm-6
a) Write an expression for the solubility product of PbCrO4.
b) What is the solubility in moldm-3 of PbCrO4?
XII) Write an expression for the solubility product of Ca(OH)2. A 20.0 cm3
sample of saturated aqueous calcium hydroxide required 18.2 cm3 of
0.050 moldm-3 HCl for neutralisation.
Calculate
a) The hydroxide ion concentration of the saturated solution
b) The pH of the saturated solution.
c) A value for the solubility product of Ca(OH)2 stating its units.
XIII) Copper(I) bromide CuBr is a sparingly soluble salt with Ksp 3.2 X 10-8
mol2dm-6. Calculate the solubility of CuBr in:
a) Pure H2O.
b) Aqueous solution of 0.0100 moldm-3 NaBr.
XIV) A buffer solution contains 6.00 g of ethanoic acid and 12.3 g of
sodium ethanoate in 200.00 cm3 of aqueous solution. What is the
concentration of ethanoic acid and sodium ethanoate in the buffer and
Calculate the pH of the buffer?
XV) CuS, Copper(II)sulfide contains 1.91 X 10-12 g of CuS dissolved in 1
dm3 of H2O.
Write an expression for the solubility product of Cu2S.
Calculate the value of the solubility product of Cu2S stating its units.
XVI) Copper (II) chromate has a solubility if 1.9 X 10 -3 moldm-3 in H2O.
Copper (II) sulphate has a solubility of 1.4 X 10-3 moldm-3 in H2O. What will
you observe when 10.00 cm3 of an aqueous solution of 0.0100 moldm-3
CuSO4 is added to an equal volume of a saturated solution of copper (II)
chromate. Explain your answer.