INSTITUT KIMIA MALAYSIA

"#331*!s:r{9.

it

ri

)5

r ri.
', r'\\

KUIZ KIMIA KEBANGSAAN MALAYSIA (KsM) 2008

Peringkat Lanjutan
Tingkatan 6 dan Matrikulasi

Tarikhz 17 fulai, 2008(Khamis)

Masa:L0.00pagi - 11.20pag
Arahan:

1,. Anda dilarang membuka kertas soalan ini sehingga diarahkan oleh guru pengawas
anda.
2. Kertas soalan ini mengandungi 14 muka surat.
3. Kertas soalan ini mengandungi 40 soalarusoalan t hingga 40 adalah dalam Bahasa
Inggeris. Anda dikehendaki menjawab semua soalan dalam jangka masa 1,jam20
minit. 10 minit tambahan diberikan untuk mengisi dan menghitamkan nama
peserta, nombor kad pengenalan peserta, kod sekolah, nama sekolah, alamat
sekolah,tingkatan dan poskod.
4. Semuajawapan hendaklah ditanda dalam Borang JawapanOMR yang dibekalkan
denganmenggunakanpensel28.
5. Penggunaankalkulator yang tidak boleh diprogramkan adalah dibenarkan.
@InstitutKimisMalaysia,IKM
Tiada sebarangbahagiandaripada kertassoalanini boleh dicetak semulatanpa kebenaran
darinada IKM.

- t\

Kuiz Kimia Kebangsaan Malavsia (&M

A.
B.
\

D.

It is dark blue.
There are 1 qpes of bonding in the compound.
\\tren I mole of the compoundis dissolr-edin water, 2 moles of ions are formed.
A blue precipitateis formed u'hen aqueoussodiumhydroxidesolutionis adde4 i

Which of the following Groups of elements react to form crystals of high solubility in
water?

'A.
B.
C.
D.

4.

T-shape
Tetrahedral
Trigonal pyramidal
Planar with bond angle I20o

Which of the following is NOT true of [Cu(NHr)+]SO+?

A.
B.
t.
D.

3.

Peringkat Lanjutan

Basedon the valence shell electronpair repulsion theory, what is the generalshapeof
NFr?

1.

2.

2008

GroupsI and17
Groups2 and16
Groups13and 16
Groups14 and1,7

Wirelessrouter,which transmitsmicrowaveradiation,shouldnot be placednear an

aquariumasthis would causesignaldegradation.
Why is this so?
A.
B.
C.
D.

Aquarium glassblocks the microwave signal.

Water in the aquarium absorbsmicrowave signal.
Glass of the aquarium reflects the microwave signal.
Temperatureof the aquarium affects the microwave transmission.

Kuiz Kimia Kebangsaan Malaysia 63M

5.

2008

An unknown organic compound, Z, analysedby mass spectromerry gave a molecular

mass of ll4 g mol-t. An elementalanalysiswas also periormed which showedthat the
compoundcontained630 C,9% H and28o/oO by mass.Which one of the followine is
compound Z?

A.

,,"/

\"t-""\"/o

!-

5' r^fl

ij..

.-

f,')

OH

_",'\\\ri_

r-\

ii
*r"/

"\"/"'

"-'"{tt\o,
, !"

il

C.

/""

Htc' -.-t\

-cri, ---t\

-cfi-

D.
o
\
\

C-CHC

/\
/\

c n2

HC.

\/
\/
U-Un.

/
HO

{'l

Kuiz Kimia Kebangsaan Malaysia (K3M 2008

Peringkat Lanjutan

What is the hybridization of carbon atoms \,2, and 3, respectively in the structure
of the following compound?

F'rrf

'+V2?,\"---.o*

iiil

r-r

tn

,.2?--.-"

* f , ".-' .
{? \

''r

'*"'

'>

':-/

**-4'-

7.

If iodd'ethaneis heatedwith ammonia in a sealedtube, which one of the folfowitrg h@

!
one of tbellqducts?
,
4'i
-,-?*i
rri,1i.1.
I
A. C2HINH24- !- ' 1
iD
2
)

"J' !c:I:![f \

J :.
fl' u"i'

l -Q ,} "

I,rdr" -

/1'
-**-*
(**

,/

L8
**

\'

i*prrr" ru*pbor@F9g{h.
pjecipitation
o{theironas
]reag31t".t-q$gp
iron(Ilf hydroff;Pffie precipitatewasheate@nd,}lgp! of Fe2O3
wasobtdined.
What is the percentage
of FeEO+
in the

,:}\

t ^ i. ,-l &
" /J

,,^
L- 1rr
\ ' " \*'

Rg
- ,1, I S g{ : '
D. CzHsNHCzHs

tii-J )'crrH.\ -)

I
";1ei"$d^pt:?;t*t

l ^ . r1r) {r
'
u l\r
u

't/
\F-\/

' ) ?{ , t t , ' i
'

qt

-'-'

i' l^

/\- - - +
-?

\ t-^ .ri ' \j J . )/

.-/

ffi

"

'

.;'

Kuiz Kimia Kebangsaan Malaysia (K:M 2008

Peringkat Lanjutan

The acid dissociation constantfor propanoic acid is 1.35x 10-5mol dm-3at 298 K. The
pH of 0.100mol dm-'of the acidis2.93.
Which of the followine state
0.010mol dm-3?
/

A.
-B.

The pH value is 3.

is-trueof the acid if it is diluted to

It ,.@

-)

Theacidbecom#w.ft...
Thedegreeof@ocblionircreases. ,
+,*fr.r|.'1, c
'
The aciddissociationconstantis decr$(d.

Limonene is an oil found in the peel of citrus fruits.

"*1,

CHz

Q
CH.

',.t
u I

tl

\tl':
\

.l ,, n

) . \ 'v t Y v

" ,,Ii
iIAl

\
./\
V'1S
:
i-i',,.

o\

\C,

,.d
1

) r'lu\fl
,At

When limoneneis left to be oxidisedby a strongoxidisin$,agent,whichof the following

doesnot react with the product?
\

A.

C.

12.

Alkaline iodine V

,/

Brominewater VS,
Sodiumhydroxidb'solution
"'
2,4-dinitrophenylhydrazinev/r, ".. !

,"r- ?"''

Nitrobenzene,C6H5NO2,is formed from nitration of benzene.

Why aniline, CoHsNH2,is not formed from the direct reaction between benzene and
ammonia?
A.
B"
C.
\

Ammonia is a nucleophile.
Ammonia is a Lewis acid.
Ammonia has lone pair electrons.
Benzenecannot undergo electrophilic addition reaction.

ft -

<

Peringkat Lanjutan

Kuiz Kimia Kebangsaan Malaysia (K3M 2008

A sample of ethylbenzene,C6H5CHzCH:,is heatedwith an excessof alkaline potassium

maflg;narc(Vll) solution. A white precipitate is obtained when a mineral acid is addedto
\
the mixture.
\ r'^rr

13.

^ 'O\

What is the maximum mass of the white precipitate formed from 5.00 g of ethylbenzene?

cat\ceaw

Ctt4tfiy(#t t \-01 o

5.7 5g
B. - 6.4 1g
C . 7 .8 3g
D . S3 l g

: '5,-lf

\\tren >olid silr er chloride is shaken*'ith aqueouspotassiumiodide, the colour of the

solid gradualll-rurnsfrom *'hite to 1'ellon'.

l{.

What causesthis to happen?

A.

-B'C.
D.

* y.-\''

k-c r

The Cl- ion diplacesthe I- ion.

The K,o of AgI is lower than the K'o of AgCl.
The K,o of AgCl is lower than the Kp of AgI.
Chlorine is a strongeroxidising agentthan iodine.

A liquidXis distilled togetherwith steamat95.6oC and

15.

/-\l

pressure
ofw

Given the relatir-emoleculqmass of X i s/ | 6l and

temperatureis 8.5 x l0{ Pa.what is the mi(ofX

lat that

-,_____--

B.
\

D.

157.2g
g
1 5 6 .0
1 6 6 .0g
1 6 7 .1g

'-t4^
l4a*'Pa
. =-liff

n6

q-r-:-fl,-4
What is an ideal solfitiort?

16.
\

B.
C.
D.

A
A
A
A

\t

\',

-t--t;-.

,}..

+{*- :

=..*} .- X) \
\.r

ffi|,u

', 'i '

f ) \ j - ''.
\- ..

.^

-(

/\\v

t-

\"
..)

. , , ', ) 1 t )

t ',\S. 4 f 1

solution which obeysRaoult's law.

solution that releasesheat when formed.
solution whose vapour follows the ideal gas law.
solution whose vapour shows ideal behaviour.

..

-: f

a.
1 Q.

) \ > -)bd -b

E
u
. ru\x\o
,
1.
t-

\ '5j>\
L
U. \ 1 1 > \ u -: . ?

7/-

*'

L
'r"
>1'Lx\-o )(
"' Ka

[.qv*-rut
1$1.,1-

/E

Kuiz Kimia Kebangsaan Malaysia (KjM) 2008

li'

t7.

Which of the following is,always correct for a systemin dynamic equilibrium?

A+ B

A.
B.

_c:
D.

tAl[B]:tcltDl
tcltDl> [A][B]
The rate of the fonvard reactionequalsthe rate of the re\ ersereaction.
The activationenergyfor the fonvard reactionequalsthe actir ation energyfor the
reversereaction.

The equilibrium constantKo for the following reaction is 3 l9 pa at 298 K and

1.8x 10)Pa at 5500K.

18.

CaCO3(s):

CaO(s)+ COz(S)

,f)

Which of the following statementis correct?

The forward reactionis endothermic.
\.
B. Increasingpressurewill increasethe yield of CO3.
C. The value of Ko dependson the amountof CaCO3used.
D. The amountof COzproducedis not affectedby temperature.

19.

TheEo valuesof two half cellsaregivenbelow:

2 CIO-+ 2HzO+ 2 e- --+
C l z +2 e ----* zcl '

Clzn4 OH-

Eo: +0.40V
Ee:+1.36V

If thecell reactionis:
cl2+ 2 oH-------+clo- + cf + H2o
Whatis the emf of the cell formed?
_A.

1i
'rtl

20.

c.
D.

(0.68- 0.40)V

(r.:o- o.4o)
v
(0.68+0.40)v
+ 2Y
(1.36- 0.40)

Given the standardelectrodepotential (ue) of a silver electrode,Rg*/ag1t.OM) is

+0.80 V, what is the electrodepotential(E) of a silver electrode,Ag*/Ag (0.5MX

A.
B.

g:

/D.

+ 0.68V
+ 0 .7 6 V

+ 0.78v

. 0 ,&t - o ,' t

r tlarj*o,r^
" + ..

+ 0.82V

{i'-) (*.-

Kuiz Kimia Kebangsaan Malaysia (K3M 2008

2*r)

Peringkat Lanjutan

Gold crystallisesin face centeredcubic lattice.

--:1

How many unit cells are therein a gold samplewhosemassis 1.560g?

(Relative atomic mass: Au, 196.97).

i. -'tl-i,n-.*,\ -

A.
B.

1.15x 1012
6.78x 1012
1.19x 1021
\
D . - 2.00xl0"

{ ,t} Y{ '
a----'

r_1

-\t high temperarure.nitrogenmonoxide,NO, reactswith hydrogenas shown in

tollo$ins e{u3tirrr1:

22.

2 \Otg) - lH:(g)

the

\:(gl -lHlO t g t

Table I shows the experimentalresults obtained durin-ea srud]'of the reaction at

temperatureZK.
Table I
Initial
Experimental Initial
Initial rate of reaction
-1 -l
number
concentrationof
concentrationof
/moldm-sHzlmol dm-3
NO /mol dm-3
I
0.0020
0.01Q
0.0028

0.010
0.020
0.030

0.0060
0.0020
0.0040

What is the expectedvalue of r ?

A.
B.
c.

,-It** t

0.00s5
0.0165
0.0336

0.0248
0.0055
r
I

Ii

L\\'N0\T
r' rnr,\o(N
t---:

o.oeeo

An aqueoussolution containing I'- ions forms a precipitate when an aqueous.solutionof

potassiumiodide is addedto it. The solubility of the precipitateis 0.553 g dm-' and its
e
solubility product is 6.91 X 10-emol3dm- at 25"C.
What is the relative atomic mass of I?

\(D.

.(}.:

h5q-r

\\

*Rs)=L
-\,,

'--\
.\.-r..,
\ fi']"

137
207
226
461
cr'q5)

lU' tr i ''.'

"5

3,r--

'\

6.q\t[, L

,\ ' ^/ q\)'
- n --.w.
r( AfIr
\,\ AJ

-1

)
(,.., ' ::'')

'n

,4'\
1
U

Kuiz Kimia Kebangsaan Malaysia (K:M) 2008

24.

Peringkat Lanjutan

Figure1 is a mapof a countryside.

I
I rown
)C
|l -.,

Figure I
At points V, W, X, Y and Z, water samplesu'ere taken and thJconcentrations of various
analytesdetermined.The results are shou'n in the Table 2.
{
."t1
i'

-!

3
3.0

Sample number
Dissolvedoxygen (mg L-')
pH

8 .0
8 .0

7.0
8.2

Cl- (meL-')

0.s

I x 10-'

Ca'* (ms L-')

Coliform count (per 100 mL)

5 x 10-'
50

5x10
0

7.5

1x105 x 10-'

s000

4
2.5
i.3.5
)
6x

r0-"

5x 10-'
4000

8.(

6.2
I x 10-'

5x10
0

Table 2
Which one of the choices correctly matcheseach sampleto the location from which it
was taken?
Sample No.
A.

B.
C.
D.

Z
Z

w
Z

2
V

w
Z
V

3
Y
X
Y
X

4
X
YX
Y

f,

W
V
V

PeringkatLanjutan

Kuiz Kimia Kebangsaan Malaysia (K:M 2008

1r.-ii ,

The standardreduction poJentialsof silver and nickel are

25.

Yr*'rywt
. ' t)ql'u4\
E(Ag*I Ag) f.+ 0 80V and.E(Ni'-/Ni;: - 0.23V .
Which of the followine statementsis true?

A.
B.
C.
\

s?

Ag* is an oxidisin g agentbut Ni2* is a reducing agent.

Ag* is a better oxidising agent than Ni'* and Ag is a better reducing agentthan Ni.
Ni2* is a better oxidising agentthan Ag* and Ag is a better reducing agentthan Ni.
Ag* is a better oxidising agentthan Ni'* and Ni is a better reducing agentthan Ag.

20 mL of solution X was pipetted into a conical flask and titrated with solution y from a
burette. The pH was monitored with a pH meter throughout the experiment, and was
e the graph below.
plotted againstthe volume of solution Yadded to
-eir

26.

7.il
6.0

-+ -.F \+

5.0
I
o"

4.I
3.0
2.0
1.0
0.I

?u.0
35.0
tifmtfinll
Volumeof

Which of t\g following choicesbestidentifuthe solutionsX andY?

-^.'t'{\. \"
11..;

XY
K9\
\
B. - MHto3

cH3cooH
HBr --:-

-)

c.

cHteooH

NaHCO:
\

D.

HBr

NaHCO: $*

qr_)J
1L _.s*r\
'

l r l' t 1

n 1r' 1
, . , -' ; r b L iq t l,
"
\

Kuiz Kimia Kebangsaan Malaysia (&A/t 2008

27.

-\L4 \u ^ *a
u,\r, 1 l- 0r.

j\ l
- ra r\

\Lo a
i\**r^,)",;i,*,
1;t: 6-.1 + { Wt"
1

What is the enthalpy changefor the complete combustion of one mole of liquid
isopropanol (molecular formula C3H8O)?
3 C(s) + 4 Hz (d + y, Oz(g) ------+ C3H8O(/)
C(s) + Oz (g)
COz (s)
Hz (g) + YzOz (g) ------+ H:O (D
A.
B.

-362kJ
-998 kJ
-2008kJ
\
D. - -4016kJ

A H: -3 1 8k J mo l-'
AH: -394kJ mol-r
A H: -2 8 6k J mo l-r
I
i

\') '

-1

r - l - 'i
l--

-L

l|

,t.

).

I
11

A useful acid-baseindicator is quinaldine red. In solution with pH below 1.5, it is

colourlesswhile it is red in solutionwith pH greaterthan 3.5.
Which of the following solution will turn red if a few drops of quinaldine \\'ere added?
I.
II.

0.1 M HCI
0.05 M NH3

ru. 0.0005
M cH3cooH
A.
B.
t}..-D.

29.

I and II
I and III
il and III
I. II and III

In order to determine the sulphate composition of a fertiliser, a chemist dissolved 2.00 g

of fertiliser in 100 mL of water, and added barium nitrate solution. The chemist noticed
the formation of a white solid, and kept adding the barium nitrate solution until no more
solid is formed. The white solid was filtered and, after drying, weighed 1.90g.
f1"{ViJl
f
What is the percentageby massof sulphatein the fertiliser?
J$ * 'i
\$
(Relativeatomicmass:Ba,I37;5,32; 0,16)
? o$l
-N,'L

f
/

3e.2
B.- 41.0

iVtrtur

c. 78.r
D.

\ ,'l

9s.5

IL
l

.\'(

/ {.1,. ; u,J , Q^g#,

(,

/1,

Q lr
-trr
J i) ^t v

-,

l $ i \1 ,u l Y -:,' { \

z\

\ IJ , iq ) . l( )

\'
l'no

F
t

t *$\

i r tl i 0r nL
t-

''{

10

i qi\

r,

.9

Peringkat Lanjutan

Kuiz Kimia Kebangsaan Malaysia (K3M 2008

30.

The following equationrepresentsthe oxidation of an organicpollutantby potassium

dichromate(Vl)in the determinationof the extentof pollution.
4cfn+ 3COz + 8HzO
+ 2cf]p72-+ rcH*---+
3[organicpollutant]
1 11 o *L
\" t q n L
If the volume of dichromate(Vl)reactedwith 1.5 mL of the organicpollutantis 10.30
mL and its molariry is 0.0933M, what is the concentrationof the organicpollutantin
millimole per litre?
a
\"< XY\
)' -

A. 427
B. 641
-\c._ 961
D. l44r

31.

. , , n T o 0 r0 i] )
\ l" -ll

!- 1

\\'

f \ jii

i-" l

In the charactertzationof water or wastewater sample. total solids (TS) determination is

performed to assess the total amount of soluble and insoluble solids present by
ivaporating the water to dryness; whereas total volatile solids (TVS) is the organic
portion in TS and it is obtainedby heating TS at 550'C.
Weight of empty crucible
weight of crucible+ dry solids after evaporationof water
at 550oc
u
Lsrheatingo"
weight of crucible+ unburnedsolidsafter
""u
'edL'r,
volume of water sample

: 48.6212g
: 48.6432g
: 48.6300g
: 15 mL

What are the values of.TS and TVS in mglL?

lrlttl ftL,J l{1,'"it,;is;-ioYh( f &r, q

TVS(mg/L)
rS (mg/L)
t470
220
22.0
l .4 l

31

4q tol{l
;( L{u/&

T{hlb;#

o'TtLo
0'00yY

-/snL
{))
?4

880

--

s87

\
x 112'

t)

13.2
0.88

l
$,rt)l x16
fs$r15\{0-J

An element exists in two solid forms M and M'. The standardenthalpiesof combustions
to the oxides MOz and M'Oz at 298 K are - 400 kJ mol-' and - 405 kJ mol-'
respectively.
What is the enthalpy changefor the transition from M to M' under standardconditions at
298 K?
llj
-*31\ it .
'/J Z

.**-.4

A.
B1
- 'C .
D.

,,!

-5kJmol-r
- 805 kJ mol-'
+5kJmol-r
+ 10 kJ mol-r

f., t,, --= \'l \ r,

t

it1

p4

)l

'-'')

\f.
1 "

1l

i.-

"- 1 fr *,

-> i1'0r

n
- 9CI*

ri"

-)

__1
+l ra' '(1
6r,1t'":- i
t
-1

1*

bes
-*-a

'

qt I

Kuiz Kimia Kebsngsoan Malaysia (K3M) 2008

33.

Peringkat Lanjutan

A current of 5.0 A is passedfor 5 minutes through five aqueoussolutions connectedin

series.The anode in each solution is the metal of the cation in the same solution while
the cathodeis carbon.
Which of the following cell anodewill have the largestchangein mass?
I
. A. A g.'A s . 1.0mol L

ny nri , t.omolL.r

C. Cu/Cu2-,2.0mol L-'
D. ZnlZn2*,2.5mol L-r

34. The amount of oxygen required to oxidise an organic substanceto carbon dioxide and
water cgn be calculated by stoichiometry if the chemical composition of the substanceis
known.(his amountof oxygen is known as the theoreticaloxygen demand(ThOD).)

Whatis the ThODof 108.8mglL of glucose?

(Relative
atomicmass:C,l2; H,I; O,16)
\A.
\
C.
D.

Jf,.

I9.3 mslL
116 mglL
180mg/L
192 mglL

The vapourpressureof benzeneis 9.90 x 10'Pa at 300 K.

What is the vapour pressureof a solution containing 12.8 g of naphthalene,CroHs, in
100 g of benzeneatthe sametemperature?
,- \ ,- - i \
\:.
\

1 '-\1. r r

i\'\\\
c'\
x
qqqr-\>

9.18x 103P a

B. \9.2s x ro3Pa
C.
D.

9.90x103Pa
20.0x103Pa

/1

U.\

T'

i
i

36.

Consider the followins reaction:

Hz(g)+ Iz(g) :

2HI(g)

AH: - 9.6 kJ

What is the effect of increasingpressure?

A.
B.

Increasesthe rate of the forward reaction only.

Increasesthe rate of the reversereaction only.
Increasesthe rate of both forward and reversereactionsby the same factor.
\r.
D. -'Increasesthe rate of forward reaction more than the rate of the reversereaction.

l2

c- t l
I

Peringkat Lanjutan

Kuiz Kimia Kebangsaan Malaysia (K3M 2008

37.

The activation energy of the following reaction is 99 kJ.

2Nocl(g)---+ 2No(g)+ clz(e)

.:._: -1
1

F[t+

Which of the following statementsis correct?

A.
B.
C.
-R\

38.

The enthalpy of reaction is * 99 kJ/mol.

The activation energy for the reversereaction is -99 kJ.
The enthalpyof formation of NOCl(g) is - 49.5kJ/mol.
ln the presenceof a suitable catalyst,the activation energywill be lower than 99 kJ.

of fir e elementsare given in the table below:

The electrone-sativities
P

Element

Electronesativitv

0 .7

1.1

1.6

2.6

T
1.7

Which of the following bonds has the least ionic character?

/

# . R -T .j ,\
IB. P -S ;
C.
D.

r' \ l

Q-T
P-Q

trL{

Given the following reaction,

)
Pa(s) + 5Oz@)

-----+2P2O5(s)

If the initial rate of reaction consumesI mole per secondof phosphorus,Qglvhat is the
initial rate of consumptionof oxygen?
_ A.
\
.e.
(A
\_./

0.2 molesper second

I mole per second
2 moles per second
5 moiesper second

13

Kuiz Kimia Kebangsaan Malaysia (K3M) 2008

40.

Peringkat Lanjutan

Consider the Maxwell-Boltzmann distribution curvesbelow.

Nq, of molecdes

EI

What is the fraction of moleculeshaving energv

than E 1 at temperatureT2?
-seater

A.

R +Q
P +Q

B.

R +Q
P

C.

R
P +Q

D.

R +Q
P +Q-R

t4