Sol Aits Jeea FT IV Paper 2

AITS-FT-IV-(Paper-2)-PCM(S)-JEE(Advanced)/13
JEE(Advanced)-2013
FIITJEE
ANSWERS, HINTS & SOLUTIONS

FULL TEST IV
(Paper-2)
ALL INDIA TEST SERIES
From Long Term Classroom Programs and Medium / Short Classroom Program 4 in Top 10, 10 in Top 20, 43 in Top
100, 75 in Top 200, 159 in Top 500 Ranks & 3542 t o t a l s e l e c t i o n s i n I I T - J E E 2 0 1 2
Q. No.
1.
PHYSICS
C
CHEMISTRY
C
MATHEMATICS
A
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
A, B, C
A,C
A, B
16.
A, B, C
A,C
A, B, C, D
17.
A, D
B,D
A, B, C
18.
A, B, D
B,D
C, D
19.
A, C, D
A, B, D
A, C
20.
C, D
B, C, D
A, C
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website: www.fiitjee.com
Physics
PART I
SECTION A
1.
A is at rest instantaneously (for no slipping at A)

1
V
V B V A = B 0 (2R) 2
2
R
1
V
B 0(
VC VA =
2
R
1
V
B 0
VB VC =
2
R
2.
3 R) 2
BV0R
2
[R ] =
2
force = (P P0) A = Ma
by P1V1 = P2V2
P0hA = P(h x) A
P0h
P=
hx
Ph
A
=a
So force = 0 P0
h
M
a=
P0 Ax
P Ax
0
; (for small x)
M(h x)
Mh
T = 2
3.
Mh
P0 A
restoring = (mg sin L + (mg sin
L
2
L
L KL
L
sin
+ K sin +
4
4 2
2
2
3mg 5KL
restoring = 2 + 16 ( : small)
3mg 5kL2
+
1
2
16
frequency of oscillation) =
2
mL2 4mL2
=
where = mL2 +
3
3
4.
From law of radioactive decay.

Activity Number of nuclear of that nucleus present in the sample.
Activity does not depend upon the rate of the formation of nucleus.
In given reaction B decays into E and C.
Total activity of B = rate of decay of B into E + rate of decay of B into C = l5N2 + l3N2
5.
The EMF will be induced in the loop, only when there is a change in the flux through the loop.
When the loop was completely inside the field region, for some time (say t1) there is no change in
the flux, hence that time would not be included in the calculation.
The time for which EMF was induced =
b b 2b
+ =
v v
v
6.
That wire will break first whose stress reaches the breaking stress (for that
material) first.
F
F
=
Stress =
where F is the tension in the wire. F is same in both the wires.
A r 2
1
Thus stress 2 for the wire of smaller radius, the stress is more.
r
Thus the wire with smaller radius will break first.
If rA < rB, then wire A will break first.
If rA > rB, then wire B will break first.
If rA = rB, either of them could break.
8.
As the magnetic field is uniform and the particle is projected in a direction perpendicular to the
field, it will describe a circular path. The particle will not hit the yz-plane if the radius of the circle is
mv
= d.
smaller than d. For the maximum value of v, the radius is just equal to d. Thus
Bq
Bqd
v=
m
9.
F = A
u u0
y
F
y + u0
A
1
y + 1 = 100 y + 1
u = 2
10 1
u =
10.
The velocity of upper plate is same as that of the layer in contact with the plate i.e. layer at y = 2
cm.
u = 100 (0.02) + 1 = 3 m/s
11.
T2 r3 (Kepler's law)
TA2
TB2
12.
rA3
rB3
r3
3
(4r)
T
1
1
Get A =
64
TB 8
For geostationary satellite, time period = 1 planet day (by def.)

Let T = 1 planet day
T0 = 1 planet year
4 2 3
4 2 3 m
rG =
Now T2 =
r
Gm
Gm M
4 2 3
r = T03 or T = T0
GM
13-14. =
k
k
, =
=
M
M+m
2500
= 10 rad/sec
25
M
M+m
x1 = A sin 1
1 2 1
kx1 = M2 sin2 1
2
2
Let v and v be the velocity of system just before collision and just after collision, so using COLM
Mv
MA cos
v =
=
(M + m )
(M + m )
Potential energy stored in the spring at (t = t1) =
1 2 1(
kx1 + M + m ) v 2
2
2
2
2
M + msin
1
1 2 M + m sin
= MA 2 2
= kA
=8J
2
M+m
2
M+m
Total energy after collision = PE + KE =
M + m sin2
1(
1
M + m ) A 2 2 = MA 2 2
M+m
2
2
15.
Imax (a1 + a2 )2
=
Imin (a1 a2 )2
a1
I
= 1 =
a2
I2
4 2
=
9 3
Imax
= 25
Imin
If an identical paper is pasted across second slit shifted C.B.F. will back in central point.
tD
shift = ( 1)
d
n D
fringe width =
d
shift
( 1)t
n=
=
= 15 .
fringe width
16.
The change in magnetic flux is zero, hence the current in the ring will be zero.
17.
Both (A) and (D) depend on g.

18.
n(n 1)
=6 n=4
2
If the initial state were n = 3, in the emission spectrum, no wavelengths
shorter than 0 would have occurred. This is possible if initial state were n = 2
(A), (B) and (D)
n=4
3
2
1
19.
From COE (A) is correct.

The force outside the earth varies as inverse square of the distance.
motion is not simple harmonic. However, from symmetry of motion, the motion will be
periodic.
(C) is correct.
From COE
1
GMm 3GMm
mv 2 =

2
2R
2R
2GM
R
(A), (C) and (D) are correct.
20.
v=
The current through R1 is constant.
Chemistry
PART II
SECTION A
pKa1 + pKa2 4 + 9
=
= 6.5
2
2
1.
pH at isoelectric point =
2.
Net reaction does not involve any aqueous species.
5.
Cr ( SCN)2 (NH3 )4 , shows geometrical (or cis-trans) and linkage isomerism.
2+
6.
H3C
O
CH2
(i) EtO
CH2 CH3
O
(ii) H
H3C
H3C
CH C
CH2 O
CH
H3C
CH2 CH3
CH2 CH3
CH
CH2 CH3
CH2 OH
H3C
CH C
CH3
O
H3C
(Michael)
CH 2
, OH2
O
C
CH2 CH3
CH2
EtO
OH
O
C
CH3
CH2 CH3
O
C
Et
Li /
O
C
CH2 CH3
+ H2O + CO2 + Et OH
7.
FeSO4
Fe2O3 + SO3 + SO2
8.
Energy of e in H-atom = - E
Energy of e in Li+2 = - 9E
1
Energy supplied by photon = IE + mv 2
2
IE = E
Ep = 9E +
v=
1
mv 2
2
2 (Ep 9E )
m
9.
In reverse osmosis water moves from more concentrated to less concentrated solution
10.
= iCRT, (i=2)
7
11.
Let conc. of both reactants at equilibrium is x M
PbEDTA 2 H+

Keq =
2
x
x = 103
12.
Chelation increases stability of complexes

OH
14.
+
aq.K 2 CO3
H /H2 O
HCN
P + Q
R
S
heat
H2 O
H /H2 O
heat
OH
OH
OH
CN
OH
OH HO
(S)
HCN
O
O
+
aq. K 2 CO3
(P )
H
OH
(Q)
(R )
15.
Cl
KCN
Cl
Cl
H Pt
Cl
CN
NH2
H O+
CF CO H
HIO4
3
3
3
epoxide
diol
2CH3CHO
16.
Trans-2-butene
17.
He and H2 are not hydrogen like particles
18.
19.
Radius of cation is smaller than parent atom and that of anion is more than parent atom
O
(A)
O
H 2C
I
CH
C
O
O
CH2
I2 will attack the double bond to form a cyclic halonium ion. It then undergoes on intramolecular
reaction. Formation of five membered ring is favoured because (i) attack by a nucleophile on a
halonium ion normally takes place at the more substituted site.
(ii) Formation of five membered ring is more probable.
(B)
Br
O
H3C
Br
O
CH2
(C)
C
Option(C)gives
O
C
(D)
Option(D)gives
1, 4 and 1,5-dicarboxylic acids give anhydrides whereas 1,6 and 1, 7-diacids give ketones when
heated with P2O5.
Mathematics
PART III
SECTION A
1.
Normal to y2 = 4ax with slope m is

..... (1)
y = mx 2am am3
(1) touches x2 y2 = a2 if
(2am am3)2 = a2 (m2 1)
..... (2)
i. e. if m6 + 4m4 + 3m2 + 1 = 0
(2) is a sixth degree equation in m with no odd power terms and whose coefficients are all
positive.
(2) has no real root
|S| = 0
2.
Given x + y + z = 5 (1)
and x2 + y2 + z2 = 9 (2)
1
2
We have yz = ( y + z ) y 2 + z2
2
1
2
= ( 5 x ) 9 x 2 (using) (1) & (2))
2
= x2 5x + 8
y, z must be the roots of the equation
(
(
u2 ( 5 x ) u + x 2 5x + 8 = 0 ( 3 )
As y, z are real, we must have discriminant of (3) 0

(5 x)2 4 (x2 5x + 8) 0
3x2 10x + 7 0
(3x 7) (x 1) 0
7
x 1,
3
Number of integer values that x can take is 2
3.
2 sin2x + sin2 2x = 2
2(1 sin2 x) + 4 sin2 x cos2 x = 0
cos2 x.cos 2x = 0 (1)
sin 2x + cos 2x = tan x
2 sin x cos2 x + cos 2x cos x = sin x
sin x cos 2x + cos 2x cos x = 0
cos 2x (sin x + cos x) = 0 (2)
Common roots of (1) and (2) are given by cos 2x = 0
( 2n 1)
,n N
x=
4
n
In [0, 4] we have x =
, where n = 1, 3, 5,,15 (3)
4
Now, 2 sin2 x + sin x 0
2 sin2 x sin x 0
(sin x) (2 sin x 1) 0
1
sin x [1, 0] or sin x 1 (4)
2
5 7 13 15
Among the 8 values given by (3), only 4 values, i.e., x =
, ,
,
satisfy (4)
4 4 4
4
10
4.
1
z
Take z = ei ( |z| = 1).
We have w = ei + ei = 2cos
We know that w is real and | w | 2
We have w = z +
x2 1
5.
The scalar triple product of the three given vectors is 2x 1
2x + 1
3x 2 + 2
x2 + 4
= x 1 2x 1 2x + 1
x +4
3x + 2
x +1
3x + 2
= x 1 2x 1 2x + 1
5x 2
x +4
3x + 2
x2 + 1
(using C3 C3 + C2 + C1)
5x + 7
= x 2 1 2x 2 1 2x 2 + 3
2
3 x 2 1
2 x2 1
5x
)(
5x 2
(using C2 C2 2C1)
5x + 7
= x 2 1 15x 4 + x 2 + 21
Vector are noncoplanar Scalar triple product 0 x2 1 0 ( 15x4 + x2 + 21 0) x 1

6.
We have f ( x ) = a xn
1/ n
so that
n
= a a x
g ( x ) = f f .....f ( x ) = x
f f ( x ) = f a xn
1/ n
1/ n
1/ n
( (
))
1/ n
= a a xn
2m times
dx
(g ( x ))
(1+ (g ( x )) )
n 1/ n
dx
n
1 t 1/ n+1
1
=
1 + x n
+c =
n 1
1 n
+ 1
n
7.
(1 + x )
n
1
n
1/ n
dx
n +1
(1 + x )
n
1/ n
dt
nt
1/ n
(using t = 1 + xn)
+c
Given y = f ( x ) ,z = g ( x ) we have
d2 y
d f dx
dy dy / dx f ( x )
gf f g 1
=
.
=
and
=
=

2
dz dz / dx g ( x )
dx
g
dz
dz

( g)2 g
8.
f ( x ) is continuous at x = 3
( )
( )
f 3 = f ( 3 ) = f 3+
( )=
Now f 3
lim
x 3
a | x2 x 6 |
6+xx
= lim
x 3
a x 2 x 6
6+xx
)=a
11
( )
f 3 + = lim+
x 3
x [x]
x3
= lim+
=1
x 3 x 3
x3
x 2 + tdt
x
x tdt 0
3
f ( 3 ) = b lim 3
= 9b
form = b lim
x 3
x 3
1
x 3 0
1
a = 9b = 1 b =
and a = 1
9
9.
Vn =
r = n (n + 1)
Sr = 2
r =1
lim
10.
Vn
n
r =1
= lim
n +1
=1
n
(i) Vn = n (n + 1) V1 < V2 < V3 < .....

Statement 2 is true
n
(ii) Qn =
1
1
=
S
S
4
r =1 r r +1
1
1
=
r
r
1
4
+
)
r =1 (
r r + 1 = 4 1 n + 1
1
r =1
Q1 < Q2 < Q3 < .

Statement 1 is false
11.
We have
2a x ,
x<0
f (x) =
x
x
a + a , x 0
Clearly, f(x) is continuous in R.
a2x 1
log a
For x > 0, f ( x ) = a x loge a + a x loge a = ( a x a x) loge a =
a x e > 0 for x > 0
f ( x ) is monotonic increasing for x > 0

For x < 0, f ( x ) = 2a x f ( x ) = 2a x loge a < 0
f ( x ) is monotonic decreasing for x < 0

0
12.
Required area =
2a
dx +
(a
x
2a
dx =
loge a
x
x
a + a
+
loge a
3a 2a 1
1
1 1
2 ( 2a ) +
+ a 0 =
aloge a
loge a
loge a a
15.
+a
2 2
The equation of the line is b 3 y + a 3 x + a 3 b 3 = 0

1
This can be written as y =
a3
1
b3
Consider the parabola y2 = 4ax
2 1
a3 b3
m=
a 3
1
, c = a 3 b 3
b3
12
a
=
m
a 3
1
3
ab
1
= a 3 b 3 = c
a3
b3
Condition for tangency for the parabola y2 = 4ax is satisfied
The given line touches y2 = 4ax
Similarly the line touches x2 = 4by
16.
( x + iy ) 5
= a + ib
x + iy = ( a + ib)5 = a5 + 5a4 (ib) + 10a3 ( b2) + 10a2 (ib3) + 5ab4 + ib5

Equating the real and imaginary parts x = a5 10a3b2 + 5ab4 y = 5a4b 10a2b3 + b5
x y
4
2 2
4
4
2 2
4
4
4
4
4
p = = (a 10a b + 5b ) (5a 10a b + b ) = 4a + 4b = 4 (a b )
a b
= 4(a2 b2) (a2 + b2) = 4(a + b)( a b) ( a +ib) (a ib)
a b, a + b, a + ib and a ib are all factors of p.
17.
Since 0 < <
,0 < sin2 , cos2 , tan2 < 1

4
( A ) sin2k =
k =0
(B)
cos
2k
k =0
(C)
tan2k =
k =0
1
1 sin2
= s ec 2
1
2
1 cos
1
1 tan2
(D) cot > 1 in 0 < <
= cosec 2
cos2
cos2 sin2
. Hence,
4
19.
3y = 9 3x 9 3x > 0 x < 2
Similarly, y < 2
20.
Area ( T ) =
cot
2k
cos2
cos 2
does not exist.
k =0
c.c 2 c 3
=
2
2
c
c3
Area (R ) =
x 2 dx
2
c
c
c
=
2
3
6
Area ( T )
c3 6
lim+
= lim+ . 3 = 3
c 0 Area (R )
R 0 2 c
=

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AITS-FT-IV-(Paper-2)-PCM(S)-JEE(Advanced)/13

ANSWERS, HINTS & SOLUTIONS

ALL INDIA TEST SERIES

A is at rest instantaneously (for no slipping at A)

restoring = (mg sin L + (mg sin

From law of radioactive decay.

The time for which EMF was induced =

For geostationary satellite, time period = 1 planet day (by def.)

Potential energy stored in the spring at (t = t1) =

Total energy after collision = PE + KE =

Both (A) and (D) depend on g.

From COE (A) is correct.

The current through R1 is constant.

Net reaction does not involve any aqueous species.

Cr ( SCN)2 (NH3 )4 , shows geometrical (or cis-trans) and linkage isomerism.

Let conc. of both reactants at equilibrium is x M

Chelation increases stability of complexes

He and H2 are not hydrogen like particles

Normal to y2 = 4ax with slope m is

As y, z are real, we must have discriminant of (3) 0

The scalar triple product of the three given vectors is 2x 1

Vector are noncoplanar Scalar triple product 0 x2 1 0 ( 15x4 + x2 + 21 0) x 1

(i) Vn = n (n + 1) V1 < V2 < V3 < .....

Q1 < Q2 < Q3 < .

f ( x ) is monotonic increasing for x > 0

f ( x ) is monotonic decreasing for x < 0

The equation of the line is b 3 y + a 3 x + a 3 b 3 = 0

This can be written as y =

x + iy = ( a + ib)5 = a5 + 5a4 (ib) + 10a3 ( b2) + 10a2 (ib3) + 5ab4 + ib5

Since 0 < <

,0 < sin2 , cos2 , tan2 < 1

(D) cot > 1 in 0 < <

does not exist.

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