Professional Documents
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2009
Energy
journal homepage: www.elsevier.com/locate/energy
Simple methodology for sizing of absorbers for TEG (triethylene glycol) gas
dehydration systems
Alireza Bahadori*, Hari B. Vuthaluru
Department of Chemical Engineering, Curtin University of Technology, GPO Box U1987, Perth, WA 6845 Australia
a r t i c l e i n f o
a b s t r a c t
Article history:
Received 19 May 2009
Received in revised form
30 July 2009
Accepted 30 July 2009
Available online 31 August 2009
Natural gas is an important source of primary energy and it is saturated with water vapor under normal
production conditions. In the design of natural gas dehydration systems, correct estimation of absorption
column size is crucial. Once the lean TEG (Triethylene glycol) concentration has been established, the
circulation rate of TEG and number of trays (height of packing) must be determined. The current
methods to correlate the TEG circulation rate, TEG purity, water removal efciency, number of equilibrium stages (or height of packing) and the diameter of contactor employs rigorous calculation techniques
involving more complicated and longer computations. The aim of this study is therefore to develop
a simple-to-use method, by employing basic algebraic equations to correlate water removal efciency as
a function of TEG circulation rate and TEG purity for appropriate sizing of the absorber at wide range of
operating conditions of TEG dehydration systems. Estimates from simplied approach were found to be
quite reliable and accurate, as evidenced by the comparisons with literature data where the average
absolute deviation percent from reported data in the literature shown to be around 0.05%.
2009 Elsevier Ltd. All rights reserved.
Keywords:
Natural gas
Gas dehydration
Absorber
Triethylene Glycol (TEG)
1. Introduction
Most natural gas producers use TEG (triethylene glycol) to
remove water from the natural gas stream in order to meet the
pipeline quality standards, Natural gas is saturated with water
vapor. Water vapor increases natural gases corrosivity, especially
when acid gases are present [1]. Extensive literature is available on
common gas dehydration systems including solid and liquid
desiccant and refrigeration-based systems[14]. Glycols are very
good absorbers for water because the hydroxyl groups in glycols
form similar associations with water molecules [2]. The contact
between a wet gas and glycol can be made in any gasliquid contact
device. Liquid desiccant systems are very established dehydration
systems. They are relatively simple to operate and maintain and it is
possible to automate them for unmanned operations [2,5]. Natural
gas usually contains water, in liquid or vapor form, at source or as
a result of sweetening with an aqueous solution. Operating experience and thorough engineering have proved that it is necessary to
reduce and control the water content of gas to ensure safe processing and transmission. Removal of the water vapor that exists in
solution in natural gas requires a more complex treatment. This
treatment consists of dehydrating the natural gas, which is
Nomenclature
A
B
C
D
Cb
Cp
Db
Dp
G
_
m
N
NOP
R
W
X
rv
rL
j
coefcient
coefcient
coefcient
coefcient
coefcient for bubble cap column
coefcient for packed column
bubble cap Diameter, m
packed column Diameter, m
mass velocity, kg/(m2 h)
mass ow rate, kg/h
number of theoretical stages
number of data points
water removal efciency
water content of gas, mg/(Sm3)
triethylene glycol purity, mass fraction
vapour density, kg/m3
liquid density, kg/m3
TEG circulation rate, TEG, m3/kg H2O
the reboiler strips absorbed water and VOCs out of the glycol as it
rises up the packed bed [6,7]. The water vapor and desorbed natural
gas are vented from the top of the stripper. The hot regenerated
lean glycol ows out of the reboiler into the accumulator (surge
tank) where it is cooled via cross exchange with returning rich
glycol; it is pumped to a glycol/gas heat exchanger and back to the
top of the absorber. Fig. 1 illustrates a typical TEG-Natural Gas
Dehydration System [7].
Traditionally, the glycol absorber (contactor) contains trays that
provide an adequate contact area between the gas and the glycol.
One other option to the trayed TEG contactor is the use of structured packing. Structured packing was developed as an alternative
to random packing to improve mass transfer control by use of
a xed orientation of the transfer surface. The combination of high
gas capacity and reduced height of an equilibrium stage, compared
with trayed contactors, makes the application of structured packing
desirable for both new contactor designs and existing trayed-
Fig. 1. Water removal efciency vs. TEG circulation rate at various TEG concentrations
(Number of theoretical stages, N 1) in comparison with data [3].
1911
1912
Table 1
Tuned coefcients for various number of theoretical stages N 1, 1.5 and 2.
Coefcient
A1
B1
C1
D1
A2
B2
C2
D2
A3
B3
C3
D3
A4
B4
C4
D4
1.51750000734 105
4.5287844071 105
4.50515787525 105
1.49387377624 105
1.1316270524 104
3.3777842508 104
3.3607087 104
1.11455135941 104
2.4475093673 102
7.3073793526 102
7.2722549748 102
2.41238559437 102
1.62668383278
4.85801145745
4.8359647407
1.6046374352
1.36318190812 104
4.1087635096 104
4.1278286256 104
1.38224984469 104
1.07128653518 103
3.22852999323 103
3.24270631055 103
1.08546448915 103
3.97385136272 101
1.19123690208 102
1.1902390712 102
3.96388087735 101
3.76154014912 101
1.1251621391
1.1218236382
3.7281593611 101
1.27155870163 105
3.78535979271 105
3.75616159919 105
1.24236038846 105
1.16335738747 104
3.46339151846 104
3.43686140202 104
1.1368271474 104
3.3397932662 102
9.94295556513 102
9.8669620555 102
3.2637991018 102
2.856748838
8.50453031755
8.4391925267
2.7914105909
W Wout
R in
Win
(1)
Cubic meter of TEG
kg H2 O
ln R a
j2
j3
(2)
Where:
a A1
B1 C1 D1
2 3
X
X
X
(3)
b A2
B2 C2 D2
2 3
X
X
X
(4)
c A3
B3 C3 D3
2 3
X
X
X
(5)
d A4
B4 C4 D4
2 3
X
X
X
(6)
Table 2
Tuned coefcients for various number of theoretical stages N 2.5, 3 and 4.
Coefcient
A1
B1
C1
D1
A2
B2
C2
D2
A3
B3
C3
D3
A4
B4
C4
D4
3.65792068453 104
1.09019787644 105
1.08309529773 105
3.58689467686 104
2.59663054678 103
7.74050225267 103
7.69127114067 103
2.54739956763 103
5.39404855899 101
1.60845322929 102
1.59871276975 102
5.29664543317 101
3.3504537023 101
9.9951682574 101
9.93899634714 101
3.2942824495 101
1.72521576917 106
5.16460399496 106
5.1535751573 106
1.7141869357 106
1.26805051527 105
3.79545983218 105
3.78677891486 105
1.25936959826 105
3.20022637366 103
9.57833625744 103
9.5560237605 103
3.1779138752 103
2.45377077254 101
7.34407625715 101
7.3268643351 101
2.43655884304 101
7.38643001783 107
2.21479386633 108
2.21365910392 108
7.37508239331 107
4.97389685515 106
1.49140002987 107
1.4906312923 107
4.96620947993 106
1.049098764 105
3.14566557041 105
3.14403546725 105
1.04746866096 105
6.77322483974 102
2.030910371004 103
2.02985369484 103
6.7626580778 102
1913
0.95
0.9
0.85
0.8
0.75
0.7
0.65
0.6
0.55
0.01
0.015
0.02
0.025
0.03
0.035
0.04
0.045
0.05
G Cb
p
rv rL rv
(7)
r
4m
Db
Gp
(8)
s
Cb
Db
DP
CP
(9)
4. Example
3. Results
Figs. 27 compare the results of new proposed correlation for
predicting the water removal efciency vs. TEG circulation rate at
various TEG concentrations and number of theoretical stages with
some of the reported data [3]. As can be seen, there is a good
agreement between predicted and reported values. The proposed
simple method shows consistently accurate results within the
investigated range for number of theoretical stages up to 4 and
glycol purity up to 0.9999 mass fraction. Table 3 shows the accuracy
and the error analysis of proposed method in terms of average
absolute deviation percent. This table illustrates that the proposed
0.95
0.9
0.85
0.8
0.75
0.7
0.65
0.6
0.55
0.01
0.015
0.02
0.025
0.03
0.035
0.04
0.045
0.05
1914
1
0.98
0.96
0.94
0.92
0.9
0.88
0.86
0.84
0.82
0.8
0.015
0.02
0.025
0.03
0.035
0.04
0.045
0.05
0.055
0.06
4.1. Solution
Win Wout
1436 110
0:922
Win
1436
Win Wout
0:9115062770from equation 2
Win
Win Wout
0:885from equation 2
Win
1
0.98
0.96
0.94
0.92
0.9
0.88
0.86
0.01
0.015
0.02
0.025
0.03
0.035
0.04
0.045
0.05
0.055
0.06
1915
0.99
0.98
0.97
0.96
0.95
0.94
0.01
0.015
0.02
0.025
0.03
0.035
0.04
0.045
0.05
0.055
0.06
1
0.999
0.998
0.997
0.996
0.995
TEG Purity, Mass fraction=0.999
Data
TEG Purity, Mass fraction=0.9995
data4
TEG Purity, Mass fraction=0.9999
data6
TEG Purity, Mass fraction=0.99995
data8
0.994
0.993
0.992
0.991
0.99
0.01
0.015
0.02
0.025
0.03
0.035
0.04
0.045
0.05
0.055
0.06
Table 3
Error analysis and accuracy of proposed method for prediction water removal efciency at various TEG circulation rates and TEG concentrations in comparison with the
reported data [3].
TEG circulation rate,
cubic meter per kg H20
TEG purity in
mass fraction
0.02
0.985
0.05
0.999
0.013
0.99
0.045
0.995
0.06
0.985
0.03
0.99
0.015
0.999
0.013
0.985
0.03
0.99
0.05
0.9995
0.05
0.995
0.03
0.999
0.015
0.9999
0.013
0.999
0.02
0.9999
0.05
0.99995
Average absolute deviation percent (AADP)a
a
1
NOP
Number of
theoretical stages
Reported data
Water removal [3] K
Absolute
deviation percenta
1
1
1.5
1.5
2
2
2
2.5
2.5
2.5
3
3
3
4
4
4
0.7093
0.9086
0.7796
0.9479
0.9211
0.9239
0.9098
0.8749
0.9445
0.9969
0.9772
0.9928
0.9816
0.99035
0.9981
0.99948
0.71
0.91
0.78
0.95
0.921
0.925
0.91
0.875
0.945
0.997
0.977
0.993
0.981
0.9904
0.9982
0.9995
0.1
0.15
0.051
0.22
0.01
0.12
0.02
0.01
0.05
0.01
0.02
0.02
0.06
0.005
0.01
0.002
0.05
PNOP reported
n1
valuescalculated values
reported values
100.
1916
Win Wout
0:9405953from equation 2
Win
So, use N 2.
2 theoretical stages are approximately 8 bubble cap trays at
0.6 m tray spacing.
2 theoretical stages is approximately 3 m of structuring packing.
4.1.2. Size the contactor
Bubble caps, 0.6 m tray spacing, so mass velocity (G) is
calculated:
G Cb
p
rv rL rv
G 176
p
321119:7 32 32 800 kg=m2 h
:m
28211
!
1 kmol
0:65 28:97 kg
1 day
23:64
kmol
24h
kg
h
m
28211
0:86 m2
G
32800
Db
r
4A
r
4 0:86
1:05 m
p
3:14
s
r
Cb
176
Db
1:05 0:73 m
DP
CP
366
5. Conclusions
The correlation proposed in the present work is novel and
unique expression, which is non-existent in the literature and is
recommended for appropriate sizing of the absorber at wide range
of conditions of TEG dehydration systems. Results illustrate that
a designer may consider this correlation as appropriate estimation
Acknowledgement
The lead author acknowledges the Australian Department of
Education, Science and Training for Endeavour International Postgraduate Research Scholarship (EIPRS), the Ofce of Research &
Development at Curtin University of Technology, Perth, Western
Australia for providing Curtin University Postgraduate Research
Scholarship and the State Government of Western Australia for
providing top up scholarship through Western Australian Energy
Research Alliance (WA:ERA). Useful comments from anonymous
reviewers and the editor are also acknowledged which led to
improvements in the original version of the paper.
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