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Inventory
Volume
Steady Flow
Source
Bypass
Bypass
Valve
Fan
Duct
CFV
Tank
Inlet
Valve
Fan
Collection
Tank
Vacuum
Exhaust
Valve
3
& net = dM
m
(1)
dt
where the total mass M in the control volume is the
sum of M T , the mass in the collection tank, and
6th ISFFM
M = M T + MI
(2)
& net = m
& +m
& leak
m
and VI are
(3)
(4)
M I = ( If Ii )VI
(6b)
M T + M I
(8)
t
where the effect of leaks is omitted in calculating
the CFV mass flow, but accounted for in the mass
flow uncertainty. Furthermore, by substituting the
M T
and
M I
given in
definitions of
Eqns. 7a and 7b into Eqn. 8, the CFV mass flow is
also given by
& =
m
M Ru
& =
m
t
PTi
PT
Z Tf T Tf Z Ti TTi
Pf
Pi
+ I I
Z f T f Z iT i
I I
I I
(5)
(6a)
M = (M Tf M Ti ) + (MIf MIi ) = M T + M I
M T = ( Tf Ti )VT
dM M
=
dt
t
V
T
V
I
(9)
The change in the collection tank volume due its elasticity and
thermal expansion between its evacuated and filled conditions
makes a negligible contribution to the uncertainty in mass flow
and is neglected.
6th ISFFM
Density-Matching Technique
The density-matching inventory volume mass
cancellation technique introduced in this work is a
refinement of the pressure-matching scheme
described in [3]. In the pressure-matching scheme,
6th ISFFM
60
R1
R2
a b c
45
MT (kg)
R3
R4
R5
a b c
75
50
M I (g)
density
overlap region
30 t
1
t2
15
0
ti
tf
25
0
time
Figure 2. The history of the mass in the inventory volume
( M I ), and the mass in the collection tank ( M T ) for a
typical calibration cycle. Note that M T (
on the left y-axis while M I (
axis.
) is plotted
6th ISFFM
match min
max min
= 100
80000 L/min
0.01
0.005
t12 (s)
-0.005
-0.01
-0.015
-0.02
(10)
(11)
20
40
60
80
100
t = + t 12
and
6th ISFFM
Molecular Mass
The relative molecular mass has two sources of
uncertainty: 1) a Type B uncertainty attributed to the
-6
air moisture level (37 10 ), and 2) a Type A
uncertainty resulting from the variation in the
-6
composition of dry air [5 7] (35 10 ). The rootsum-square of these components yields a
combined relative standard uncertainty of
[u (M ) M ] = 51 10-6.
Collection Time
The collection time, defined previously in Eqn. 11,
consist of the base time, , and the time
adjustment factor, t 12 . The total relative standard
uncertainty
for
the
collection
time
is
[u (t ) t ] = 15 10-6. It is comprised of the
following two components: 1) the base time
-6
measurement (2 10 ), and 2) the time adjustment
-6
factor (14 10 ). These components are itemized
in Table 1 for a 20 s collection period (i.e., the
shortest collection period used) and the uncertainty
value of each is discussed here.
Abs.
Unc.
Sens.
Coeff.
Perc.
Contrib.
Unc.
Type
(ms)
Rel.
Std.
Unc.
(k=1)
-6
( 10 )
Collection time, t = 20 s
(-----)
(%)
(-----)
Base time,
0.04
1.9
Comments
Calib. of Counters
6th ISFFM
0.29
14
Combined Uncertainty
0.29
15
98.1
A, B
100
to
t 2
-6
(10 10 ),
and
the
6th ISFFM
Density
Overlap
Region
2nd Flow
Diversion
P (kPa) 200
150
100
1st Flow
Diversion
50
0
-0.4
-0.2
0.2
0.4
t (s)
315
T (K)
305
Density
Overlap
Region
2nd Flow
Diversion
295
285
1st Flow
Diversion
275
-0.4
-0.2
0.2
0.4
t (s)
Figure 4. Histories of the inventory volume pressure (top)
and temperature (bottom) during the first and
second flow diversions for a nominal flow of
0.4 kg/s.
6th ISFFM
[u u (PI f )
PI
Abs.
Unc.
Perc.
Contrib.
Unc.
Type
(kPa)
Rel.
Std.
Unc.
(k=1)
(%)
(%)
A or B
4.41
2.3
24.6
0.12
0.1
0.0
Manuf. spec.
Sensor repeatability
0.17
0.1
0.0
Manuf. spec.
0.75
0.4
0.7
7.68
4.0
74.7
0.0
0.0
0.0
4.41
2.3
24.6
7.72
4.0
75.4
Combined Uncertainty
8.89
4.7
100
Comments
Uncorrelated Unc.
Correlated Unc.
Abs.
Unc.
(k=1)
Rel.
Std.
Unc.
Perc.
Contrib.
(K)
(%)
(%)
(A or B)
6.0
1.7
3.1
Repeatability
0.2
0.1
0.0
33.3
9.5
95.0
4.7
1.4
1.9
Unc. Comments
Type
Uncorrelated Unc.
Correlated Unc.
6th ISFFM
6.0
1.7
3.1
33.6
9.6
96.9
Combined Uncertainty
34.1
9.7
100
The
correlated
and
is [u c (TIi )] = 33.6 K.
uncorrelated components are propagated to give a
total
relative
standard
uncertainty
of
[u (TIi )] = 34.1 K.
The uncertainty of the final inventory volume
temperature, [u (TI f )] = 34.8 K, is comparable to the
initial value. The uncorrelated uncertainty is
[u u (TI f )] = 6.0 K while the correlated uncertainty is
f
[u c (TI )] = 34.3 K.
Inventory Volume: Initial and Final Compressibility Factors
The initial and final compressibility factors of the
gas in the inventory volume are determined using
the REFPROP Thermodynamic Database [1].
During flow diversions in the inventory volume, the
temperature can range from 290 K to 340 K while
3
the pressures can vary from 100 kPa to 450 kPa.
The relative standard uncertainty in the
compressibility factory associated with this range of
conditions is a Type B uncertainty that is
conservatively estimated to be no more than
-6
100 10 for both [u (Z Ii ) Z Ii] and [u (Z If ) Z If ].
Abs.
Unc.
(k=1)
Rel.
Std.
Unc.
Perc.
Unc.
Contrib. Type
Comments
(Pa)
( 10 )
-6
(%)
(-----)
Transducer Accuracy
0.125
1250
4.2
Manuf. Spec.
0.160
1600
6.8
0.557
5774
89.0
6th ISFFM
0.001
14
0.0
Combined Uncertainty
0.612
6120
100
Abs.
Unc.
(Pa)
Rel.
Perc. Unc.
Std. Contrib Type
Unc.
.
(k=1)
-6
( 10 )
(%) (A or B)
Comments
1.6
17
2.1
5.7
60
25.9
9.5
100
72.0
0.05
0.5
0.0
Combined Uncertainty
11.2
118
100
Abs.
Unc.
(mK)
Unc.
Rel.
Perc.
Std. Contrib. Type
Unc.
(k=1)
-6
( 10 )
(%)
(A or B)
Comments
1.2
0.0
1.0
0.0
Fit residuals
7.0
24
1.2
6th ISFFM
28.9
98
20.0
Radiation, self-heating
1.8
0.1
2.5
0.1
57.3
195
78.6
Combined Uncertainty
64.6
220
100
VT =
M cyl
Tf - Ti
- Vc
(12)
25.915
Tank Volume (m 3)
25.910
25.905
25.900
VT
25.895
old
VT
25.890
25.885
25.880
25.875
1
Measurement No.
Figure 5. Shows eight measurements (four with argon and
four with nitrogen) based on gravimetric weighing
technique used to determine the collection tank
internal volume ( VT ), and the standard deviation
of repeated measurements ( V ).
6th ISFFM
indicated
by
the
two
dashed
lines
-6
( V VT = 318 10 ). The relative standard
uncertainty attributed to repeated volume
measurements equals to the standard deviation of
the mean,
V VT
N
-6
= 113 10 , where N = 8.
3
3
Rel.
Std.
Unc.
(k=1)
-6
( 10 )
Sen.
Coeff.
(%)
(A or B)
0.0
-4
0.1
A, B
i
i
Based on PT and T T meas.
82.3
A, B
0.0
58940 -5.0 10
8988
250
7.4 10
Comments
-6
(-----)
Effects of Leaks
Perc.
Unc.
Contrib. Type
-1.0
Measured Geometrically
1.7 10
-5
Negligible
6th ISFFM
28
1.0
1.0
A, B
113
1.0
16.6
8 VT
Combined Uncertainty
276
100
6th ISFFM
4.
PVTt MASS FLOW UNCERTAINTY
The time-averaged CFV mass flow for this PVTt
system was given previously in Eqn. 9. Applying the
propagation of uncertainty to this equation gives the
following expression for the mass flow uncertainty
& )
u( m
m
&
Mf
+ T
M T
u (Ru )
u (M )
u (t )
=
+
+
t
M
Ru
2
2
2
2
i
i
M i u (PTi )
+ u (TT ) + u (ZT )
+ T
MT P i
Ti
Zi
T
T
T
f
f
f
u (PT ) + u (TT ) + u (Z T )
P i
Ti
Zi
T
T
T
(13)
u(VT )
MI
+
+
VT
M T
u(VI )
VI
& leak )
u( m
2
+
+ ss
& leak
m
u c (P i ) u c (P f )
I
I
[utot (P )]
i
f
PI
PI
2
2
2
uu (PIf )
M i uu (PIi )
+ I
+
Pf
MT P i
I
I
2
Inv =
[utot (T )]
2
Inv =
Mi
I
M
T
MIi
M T
Mi
+ I
M T
uc (TIi ) uc (TI f )
f
Ti
T
I
I
i
f
uu (TI ) + uu (TI )
T i
Tf
I
I
(14)
& CFV =
m
(15)
i
f
i
(16)
[utot (Z )] MI uc (Zi I ) uc (Zf I )
ZI
M T ZI
Po A t C s C d
R uTo
M
(17)
6th ISFFM
Rel.
Sen.
Perc.
Unc.
Std.
Coeff. Contrib. Type
Unc.
(k=1)
-6
( 10 ) (-----)
(%)
(A, B)
Comments
276
38.7
A, B
Table 7
4115
0.001
0.0
A, B
Reference [12]
220
-1.001
24.7
A, B
6120
-0.001
0.0
A, B
Table 4
= 95.246 kPa
118
1.001
7.1
A, B
Table 5
50
0.001
0.0
50
-1.001
1.3
166
14.0
A, B
Equation 14
123
7.7
A, B
Equation 15
0.0
Equation 16
250000
0.0
Geometrically Measured
51
1.3
A, B
1.7
-1
0.0
15
0.1
A, B
100
5.1
0.0
f
TT
= 294 K
f
PT
f
ZT
=1
Z iI
Z If
&
Reference Properties
Molecular mass,
Timing Uncertainties
Collection time, t = 20 s
443
5. CONCLUSIONS
This document addresses the flow measurement
3
capabilities of the 26 m PVTt system, the United
States primary standard for measuring the flow of
dry air. Flow measurements are conducted at
ambient temperatures, at pressures ranging from
150 kPa to 800 kPa, and at flows extending from
200 standard L/min to 77000 standard L/min. This
100
6th ISFFM
[9]
REFERENCES
[1] Lemmon, E. W., McLinden, M. O., and Huber,
M. L., REFPROP 23: Reference Fluid
Thermodynamic and Transport Properties,
NIST Standard Reference Database 23,
Version 7, National Institute of Standards and
Technology, Boulder, Colorado, 2002.
[2]
[3]
[4]
[5]
[6]
[7]
[8]