Professional Documents
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4541/1
Kimia
Kertas 1
September
2004
1 jam
KIMIA
http://cikguadura.wordpress.com/
Kertas 1
Satu jam lima belas minit
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2.
3.
Answer each question by blackening the correct space on the answer sheet.
4.
5.
If you wish to change your answer, erase the blackened mark that you have made.
Then blacken the space for the new answer
6.
The diagrams in the questions provided are not drawn to scale unless stated
7.
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Question 1 to Question 50, are followed by four options A, B, C, and D. Choose the best
option for each question and blacken the corresponding space on the objective
answer sheet.
1
FIGURE 1
What is the nucleon number for atom Y?
A
11
B
12
C
23
D
34
2
X
9
FIGURE 2
Which of the following group in the Periodic Table is X found?
A
1
B
7
C
9
D
17
3
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The following equation represents a reaction between propanoic acid and ethanol.
C2H5COOH + C2H5OH
Q + H2O
Figure 3 shows the apparatus set up for the separation of silver chloride salt from
the mixture of reaction products.
FIGURE 3
Which of the following reactants is most suitable for the preparation of silver
chloride?
A
Silver and hydrochloric acid
B
Aqueous silver nitrate and aqueous sodium chloride
C
Solid silver carbonate and hydrochloric acid
D
Aqueous silver nitrate and sodium hydroxide
6
FIGURE 4
What is X?
A
Zinc
B
Lead
C
Carbon
D
Tin
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No resistance to heat
Malleable
conc. H2SO4
C2H4
+ H2O
FIGURE 5
Which of the followingIUPAC nomenclature represents the compound in Figure 5?
A
3, 4 - dimethyl pent-2-ene
B
2, 3 - dimethyl pent-3-ene
C
1,2,3 trimethyl but-1-ene
D
3 propyl but-2-ene
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10
11
Which of the following pairs is true about the additives in detergents and their
function?
Additive
Function
A
Phosphate compounds
Whitens cloth
Fluorescent compounds
Biological enzyme
Whitening agent
12
13
The following equation represents the main reaction in the preparation of sulphuric
acid.
Catalyst K
2SO2
O2
2SO3
What is catalyst K?
A
Iron
B
Platinum
C
Vanadium(V) oxide
D
Aluminium(III) oxide
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E
TABLE 1
Which of the following are the characteristics of element E?
I
Can form complex ions.
II
Low melting and boiling points.
III
Can form coloured compounds.
IV
Can be used as catalyst.
A
I and II only
B
II and IV only
C
I, III and IV only
D
I, II, III and IV
15
The acidity of hydrogen chloride gas cannot be shown when dissolved in the
following solvents
I
water
II
ethanol
III
benzene
IV
tetra chloromethane
A
I and II only
B
III and IV only
C
I and III only
D
II, III and IV only
16
Which of the following ions will form precipitates that do not dissolve in excess
aqueous ammonia?
I
Copper(II) ions
II
Aluminium ions
III
Lead(II) ions
IV
Zinc ions
A
I and IV only
B
II and III only
C
I, II and III only
D
II, III and IV only
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17
18
19
Which of the following homologous series and its functional group are correctly
paired?
Homologous Series
A
B
C
D
20
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Functional group
Ester
-COOH
II
Alkene
-C=C-
III
Alcohol
-OH
IV
Carboxyllic acid
-COO-C-
Excess powdered metal Z was added to aqueous copper(II) sulphate and stirred.
After a few minutes, the solution turned colourless. Z could be
I
Mg
II
Ag
III
Al
IV
Zn
A
I and III only
B
II and IV only
C
I, II and III only
D
I, III and IV only
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FIGURE 6
The bigger the mass of a particle, the slower the velocity of the particle.
Based on the above statement, where will the white fumes of ammonium chloride
first formed? [Molar mass: NH3 ; 17 gmol-1 , HCl ; 36.5 gmol-1 ]
A
P
B
Q
C
R
D
S
22
Curve I in Figure 7 was obtained when 2.0 g magnesium strips react with nitric
acid at 40 oC.
FIGURE 7
Which of the following will produce curve II?
A
Using 2.0 g of powdered magnesium
B
Raising the temperature of nitric acid to 50 oC
C
Using 1.0 g magnesium strips.
D
Adding distilled water to nitric acid
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FIGURE 8
valence electron for Z atom
valence electron for Y atom
Which of the following pairs is the correct groups in which elements Y and Z
belong to in the Periodic Table?
24
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17
16
17
14
16
17
16
Which of the following diagram represents the correct electron configuration for
sulphide ion?
[Proton Number: S, 16]
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25
The reaction between chlorine water and iron(II) sulphate solution is a redox
reaction. Which of the following is true?
A
Iron(II) ion is an oxidizing agent.
B
Electron is transferred from chlorine to iron(II) ion.
C
The oxidation number of chlorine reduces from 0 to -1.
D
The colour of the mixture changes from brown to green.
26
FIGURE 9
Which of the following is true?
A
Magnesium electrode is the positive terminal.
B
Reduction occurs at the copper electrode
C
Copper is more electropositive than magnesium.
D
Electron flows from copper to magnesium through the external circuit.
27
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Which of the following apparatus set-up will not cause changes in silver nitrate
concentration?
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Below are two thermo chemical equations for the neutralization process.
NaOH + HCl NaCl
NaOH + CH3COOH
CH3COONa + H2O
H2O
H = -57 kJ mol-1
H = -55 kJ mol-1
The value of the heat of neutralization for both processes are different because
A
the ethanoic acid is less soluble in water.
B
the production of sodium ethanoate salt absorbs heat.
C
the ethanoic acid produces only a small amount of hydrogen ions.
D
greater amount of heat is absorbed to ionize the ethanoic acid molecule.
30
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Brown
Colourless
Purple
Brown
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Figure 10 shows the apparatus set up for the reaction between oxide T and
mixture U.
FIGURE 10
Which of the following pairs will react when heated strongly?
Mixture U
32
Oxide T
Magnesium oxide
Zinc oxide
Lead(II) oxide
Aluminium oxide
Zinc
II
III
IV
Sodium chloride
Helium
Oxygen
FIGURE 11
Which pairs of the arrangement of particles and the name of the substances are
paired correctly?
A
B
C
D
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Table 2 shows the elements found in Period Three of the Periodic Table.
Na
Mg
Al
Si
Cl
Ar
TABLE 2
Which of the following statements is true?
I
The boiling point of sulphur is higher than chlorine.
II
Aluminium is less electropositive than magnesium.
III
The size of sodium ion is bigger than magnesium ion.
IV
Oxide of elements changes from acidic to base as we go from left to right in
Period Three.
A
B
C
D
34
I dan II sahaja
III dan IV sahaja
I, II dan III sahaja
I, II, III dan IV
Figure 12 shows the apparatus set-up to determine the rate of reaction between
calcium carbonate and hydrochloric acid.
FIGURE 12
Which of the following is not correct in the apparatus set-up for this experiment?
I
Fixing of cork
II
Position of thistle funnel
III
Position of the delivery tube in the basin.
IV
Position of the delivery tube in the conical flask.
A
B
C
D
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2O2
CO2
+ 2H2O
H = -X kJ mole-1
M
12
12
T
9
10
What is the molar mass of the compound formed when M and T react with each
other?
A
62 g mol-1
B
43 g mol-1
C
32 g mol-1
D
30 g mol-1
37
The equation below represents the reaction between hydrogen and oxygen gas to
form water.
2H2
+ O2
2H2O
Calculate the volume of oxygen required at room condition when 0.24 dm3
hydrogen gas reacts completely.
[1 mole of gas occupies 24 dm3 at room condition]
A
0.12 dm3
B
0.24 dm3
C
0.48 dm3
D
2.40 dm3
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14 x
9x
6x
3x
1023
1023
1023
1023
FIGURE 13
The experimental results are as follows:
Mass of an empty combustion tube
Mass of combustion tube + iron oxide
Mass of combustion tube + iron that is produced
=
=
=
262.20 g
264.92 g
264.44 g
Proton number
17
20
TABLE 3
Which of the following pairs will form compounds with high melting and boiling
points?
A
P and Q
B
Q and S
C
P and R
D
Q and R
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FIGURE 14
Which of the following is true for substance J?
Physical state at room
Types of particles
temperature
Molecule
Solid
A
42
Liquid
Molecule
Solid
Ion
Gas
Atom
The reaction between lead(II) nitrate solution and potassium iodide solution can be
represented by the following equation:
Pb(NO3)2 (ak) +
2KI
(ak)
25.0 cm3 potassium iodide solution 1.0 mol dm-3 is added to 25.0 cm3
lead(II)nitrate solution 1.0 mol dm-3 . What is the maximum mass of lead(II) iodide
produced in this reaction?
[ Relative Atomic Mass: I , 127 ; Pb , 207 ]
A
4.175 g
B
5.76 g
C
8.35 g
D
11.52 g
43
W(NO3)2 + 2H2O
20 cm3 of aqueous W hydroxide 0.5 mol dm-3 neutralizes 20 cm3 of nitric acid.
What is the concentration of the nitric acid?
A
0.25 mol dm-3
B
0.50 mol dm-3
C
1.00 mol dm-3
D
2.00 mol dm-3
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b O2
c CO2 +
d H2O
45
Table 4 shows the total volume of gas evolved at different intervals for the
dissociation of hydrogen peroxide.
Time (min)
Volume of gas
(cm3)
0.0
1.0
1.5
2.0
2.5
3.0
0.0
10.0
20.0
28.0
35.0
35.0
TABLE 4
What is the average rate of reaction in the second minute?
A
B
C
D
46
14.0
16.0
18.0
28.0
cm3 min -1
cm3 min -1
cm3 min -1
cm3 min -1
2FeCl3
H = - y kJ
What is the amount of heat released if 1 mol iron reacts with 3 mol chlorine gas?
A
B
C
D
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y/3
y/2
y
2y
kJ
kJ
kJ
kJ
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48
A
B
C
D
Which of the following statements are true regarding the magnesium chloride and
hydrogen chloride?
I
Both are soluble in water producing colourless solutions.
II
Magnesium chloride has a higher melting point than hydrogen chloride.
III
Hydrogen chloride dissolves in methylbenzene while magnesium chloride
does not.
IV
Solid magnesium chloride can conduct electricity while hydrogen chloride
does not.
A
B
C
D
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FIGURE 15
Which of the following is true about the above process?
I
Bromide ions lose electron.
II
Shiny grey solid formed at anode.
III
Oxidation number of bromine changes from -1 to 0
IV
Lead(II) ions undergo oxidation.
A
B
C
D
50
An experiment was carried out to determine the heat of precipitation for the
reaction between silver nitrate and sodium chloride. Table 5 shows the temperature
reading of both solutions.
Initial temperature for 50 cm3 silver nitrate 1 mol dm-3
30 oC
30 oC
35 oC
TABLE 5
Based on Table 5, which of the following is true?
[Specific heat capacity: 4.0 J g-1 oC-1 ; Relative atomic mass: Ag , 108 ; Cl , 35.5 ]
I
7.2 g white precipitate is formed.
II
Heat released during the experiment is 2000 J
III
The amount of silver nitrate used is 0.05 mole
IV
Heat released during the formation of bonds is more than heat absorbed
during the breaking of bonds.
A
B
C
D
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Kimia
Kertas 2
Sept
2004
2 jam
4541/2
NAMA: .
ANGKA GILIRAN: .
KIMIA
Kertas 2
Dua jam tiga puluh minit
JANGAN BUKA KERTAS SOALAN INI
SEHINGGA DIBERITAHU
1. Tuliskan nama dan angka giliran anda
pada ruang yang disediakan.
2. Kertas soalan ini bahasa Inggeris.
3. Calon dibenarkan menjawab
keseluruhan atau sebahagian soalan
sama ada dalam bahasa Melayu atau
bahasa Inggeris.
Kod Pemeriksa
Bahagian Soalan Markah
Penuh
1
8
2
8
A
3
10
4
11
5
11
6
12
1
20
B
2
20
3
20
C
4
20
Jumlah
Markah
Diperoleh
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Section A
For
Examiners
Use
[60 marks]
Answer all questions in this section.
The time suggested to complete Section A is 90 minutes.
1
Table 1 shows the proton number and part of the nucleon number for the elements
C, O, Na and Cl.
Elements
Proton number
Nucleon number
C
6
__
O
8
16
Na
11
23
Cl
17
__
TABLE 1
1 (a)
(a)
(b)
1 (b)
[ 1 mark ]
Write the atomic symbol for sodium including the proton number and
nucleon number in the box provided.
[ 1 mark ]
1 (c)
1 (d)(i)
1 (d)(ii)
(c)
(d)
[ 1 mark ]
Element C has a few isotopes.
(i)
(ii)
[ 1 mark ]
Name an isotope that is radioactive.
[ 1 mark ]
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For
Examiners
Use
1 (e)
(e)
[ 1 mark ]
(f)
1 (f)
[ 2 marks ]
18
2
Na Mg
13
14
15
16
17
Al
Si
Cl
Ar
FIGURE 1
Based on Figure 1, answer the following questions:
2 (a)
(a)
[ 1 mark ]
(b)
2 (b)
[ 2 marks ]
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Use
(c)
2 (c)(i)
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The elements Mg and S can react with oxygen to form their oxides.
(i)
(ii)
[ 1 mark ]
Compare the chemical properties of these oxides.
2 (c)(ii)
[ 1 mark ]
(d)
2 (d)(i)
[ 2 marks ]
2 (d)(ii)
(ii)
[ 1 mark ]
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Figure 2 shows the apparatus set-up for the electrolysis of copper(II) chloride
solutions of different concentration.
FIGURE 2
3 (a)
(a)
(b)
3 (b)
(c)
Write the formulae of all the ions present in the copper(II) chloride solution.
[ 1 mark ]
State the observation that can be seen at the electrode S during the
electrolysis.
[ 1 mark ]
(i)
Name the products formed at electrode P and R.
3 (c)(i)
Electrode P: ..
(ii)
3 (c)(ii)
Electrode R: ..
[ 1 mark ]
Explain your answer.
[ 2 marks]
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(d)
(i)
3 (d)(i)
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(ii)
3 (d)(ii)
[ 1 mark ]
(iii)
3 (d)(iii)
Write the ionic equation for the reaction that occurred in the
test tube.
[ 1 mark ]
(e)
3 (e)
CELL Y
[ 2 marks ]
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For
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(ak)
Solution E
Mg
Gas R
Phase I
Phase II
+ Pb(NO3)2
Mixture of
Mg(NO3)2 + Substance G
FIGURE 3
(a)
4 (a)
Substance G :
[ 2 marks ]
(b)
4 (b)
Explain how you can identify and confirmed the presence of gas R.
[ 2 marks ]
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( c)
4 (c)(i)
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(ii)
4 (c)(ii)
[3 marks ]
4 (d)(i)
(d)
(i)
(ii)
4 (d)(ii)
...
...
[2 marks ]
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For
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Time ( s )
Total volume
of CO2 gas
evolved
( cm3 )
20
40
60
80
100
120
140
160
0.00
24.00
33.00
39.00
43.50
46.50
48.00
49.00
49.00
TABLE 2
5 (a)
(a)
5 (b)
(b)
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Draw the graph of the volume of carbon dioxide gas against time on the
graph paper on page 19.
[4 marks ]
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For
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Use
(c)
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Based on the graph in (b), how does the rate of reaction changes with time?
Explain your answer.
5 (c)
[2 marks ]
(d)
5 (d)
[2 marks ]
(e)
5 (e)
...
[2 marks ]
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For
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H H H H
H C C C C H
H C C C C H
H OH H H
Compound J
Compound K
FIGURE 4
(a)
6 (a)
Compound K:
[1 mark ]
(b)
6 (b)(i)
(i)
Name compound K.
.
[1 mark ]
(ii)
6 (b)(ii)
(c)
6 (c)
[2 marks ]
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(d)
For
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6 (d)(i)
(i)
(ii)
.
[1 mark]
Draw the structural formula of this new substance.
6 (d)(ii)
[1 mark]
(e)
6 (e)(i)
6 (e)(ii)
(ii)
.
[1 mark ]
Write an equation for this reaction.
.
[1 mark ]
(f)
..
6 (f)
..
[3 marks ]
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Section B
[20 marks]
Answer any one question from this section.
The time suggested to complete Section B is 30 minutes.
1
CH2O
(a)
(b)
(c)
Experiment
II
Set-up of
apparatus
FIGURE 5
(i)
(ii)
(iii)
(iv)
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(a)
A student holding an ice cube discovers that ice turned into water after a
few minutes. Explain this phenomenon.
[2 marks]
(b)
Methane is the main component in liquid natural gas while butane is the
main component in liquid petroleum gas. Both gases are used as fuel.
The complete combustion of methane and butane can be shown by the
following equations:
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CH4
2O2
C4H10
13/2 O2
CO2
4CO2
2H2O
+
5H2O
= - 890 kJmol-1
= - 2882 kJmol-1
(i)
(ii)
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(c)
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II
Set-up of apparatus
Initial temperature
of solutions
Maximum
temperature
of mixture
sodium sulphate +
lead(II) nitrate
calcium nitrate +
sodium carbonate
Sodium sulphate : 27 0C
Lead(II) nitrate : 27 0C
Calcium nitrate
: 27 0C
Sodium carbonate : 27 0C
38 0C
24 0C
TABLE 3
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(i)
(ii)
(iii)
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SECTION C
[ 20 marks ]
Answer any one question from this section.
The time suggested to complete Section C is 30 minutes.
3
(a)
(b)
Figure 6 shows two beakers containing 0.1 mol dm-3 solution X and
solution Y and their pH readings.
FIGURE 6
Compare and contrast both solution X and solution Y in terms of their
physical and chemical properties. Give a suitable example for both
solutions X and Y.
[ 8 marks ]
(c)
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You are required to prepare dry pure zinc carbonate salt. The chemicals
supplied are
Zinc oxide powder
Dilute nitric acid
Sodium carbonate solution
Describe a laboratory experiment to prepare the salt. In your description,
include the chemical equations involved.
[ 9 marks ]
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(a)
The iron grills of houses situated near beaches become rusty easier than
those situated away from beaches.
Explain this phenomenon.
[ 2 marks ]
(b)
Fe 2+
Fe 3+
Step II
Step III
Fe
FIGURE 7
Complete the flow chart by using named reagent to show the changes in
step I,II and III. Include the observation and ionic equations for each step.
[ 9 marks ]
(c)
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Untuk
Kegunaan
Pemeriksa /
For
examiners
use
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Nama : .....
No Giliran : ..
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Kimia
Kertas 3
September
2004
1 jam
KIMIA
Kertas 3
Satu jam tiga puluh minit
Kod Pemeriksa
JANGAN BUKA KERTAS SOALAN INI
SEHINGGA DIBERITAHU
1.
2.
3.
4.
Soalan
Markah
Penuh
21
12
3
Markah
Kecemerlangan
15
Markah
Diperoleh
Jumlah
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2.
Write your answers for Question 1 and Question 2 in the spaces provided in the
question paper.
Write your answers for Question 3 in the lined pages provided at the end of this
question paper.
3.
Answer the questions in detail. Answers should be clear and logical. Equations,
diagrams, tables, graphs and other suitable methods can be used to explain your
answer
4.
If you wish to cancel any answer, neatly cross out the answer.
5.
Diagrams in the questions provide you with useful information. The diagrams in the
questions provided are not drawn to scale unless stated
6.
7.
Marks awarded:
Mark
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Description
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For
Examiners
Use
4541/3
A student carried out an experiment to determine the end point for the neutralization
process between 50.0 cm3 barium hydroxide 0.1 mol dm-3 solution and sulphuric acid.
The apparatus set up for this experiment is shown in Figure 1.
sulphuric acid
A
barium
hydroxide
0.1 mol dm-3
carbon electrodes
FIGURE 1
Table 1 shows several ammeter readings for every addition of 1.0 cm3 of sulphuric
acid to barium hydroxide solution.
Volume of
H2SO4
(cm3)
Ammeter
readings
(A)
0.0
1.0
2.0
3.0
4.0
0.5
0.4
0.3
0.2
0.1
5.0
6.0
7.0
8.0
9.0
TABLE 1
Figure 2 shows the ammeter readings when 5.0 cm3, 6.0 cm3 and 7.0 cm3 sulphuric
acid were added.
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Use
KK0503
KK0501
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(a)
Referring to Figure 2, record the ammeter readings for the addition of 5.0 cm3,
6.0 cm3 and 7.0 cm3 of sulphuric acid in Table 1.
(b)
(c)
Based on your answer in (b) what is your inference for this experiment?
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(d)
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Plot a graph of ammeter reading against the volume of sulphuric acid added
on the graph paper on page 7.
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(e)
On the graph plotted in (d), mark and write down the minimum volume
of sulphuric acid needed to neutralize 50.0 cm3 of aqueous barium
hydroxide 0.1 mol dm-3.
(f)
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(g)
0.0
1.0
2.0
3.0
4.0
5.0
6.0
7.0
0.8
0.7
0.6
0.5
0.3
0.2
0.4
0.6
TABLE 2
Derive a relationship between the end point of neutralization and the
ammeter readings in Table 1 and 2.
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iron
iron
magnesium
silver
M
FIGURE 3
Beaker
Observation
TABLE 3
(a)
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Constant variable:
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(b)
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(c)
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(d)
Categorize the metals used in beakers M and N into anode and cathode.
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Experiment I:
When strips of silver and copper are immersed in sulphuric acid solution,
the
[Lihat sebelah
voltmeter shows a reading and the copper strip acts as the negative[Lihat
terminal
sebelah
Experiment II:
When the silver strip is replaced with magnesium coil, the voltmeter reading
increases and the copper strip act as the positive terminal
Referring to the above observation, design a laboratory experiment to compare
the magnitude of different chemical cells potential between copper and the
following metals; silver, iron, aluminium and magnesium. In addition, you need
to identify the polarity of the cells.
In designing your experiment it must include the following items:
(i)
Problem statement
(ii)
Hypothesis
(iii)
(iv)
Procedure
(v)
Tabulation of data
[KK051201 Stating the problem]
[KK051202 Making the hypothesis]
[KK051203 Displaying the plan]
[KK051204 Choosing the technique]
[KK051205 Listing the substances and apparatus]
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