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Astrophysicists use the term metal to collectively describe all elements other than hydrogen and helium. In
that sense, the metallicity of an object is the proportion
of its matter made up of chemical elements other than
hydrogen and helium.[4]
Many elements and compounds that are not normally
classied as metals become metallic under high pressures;
these are formed as metallic allotropes of non-metals.
Properties
4 Na + O2 2 Na2 O (sodium oxide)
1
2 PROPERTIES
2 Ca + O2 2 CaO (calcium oxide)
2.2
Physical
When considering the electronic band structure and binding energy of a metal, it is necessary to take into account
the positive potential caused by the specic arrangement
of the ion cores which is periodic in crystals. The most
important consequence of the periodic potential is the
formation of a small band gap at the boundary of the
Brillouin zone. Mathematically, the potential of the ion
cores can be treated by various models, the simplest being
the nearly free electron model.
2.4 Mechanical
Mechanical properties of metals include ductility, i.e.
their capacity for plastic deformation. Reversible elastic
deformation in metals can be described by Hookes Law
3
for restoring forces, where the stress is linearly propor- 3 Alloys
tional to the strain. Forces larger than the elastic limit, or
heat, may cause a permanent (irreversible) deformation Main article: Alloy
of the object, known as plastic deformation or plasticity.
This irreversible change in atomic arrangement may ocAn alloy is a mixture of two or more elements in which
cur as a result of:
the main component is a metal. Most pure metals are either too soft, brittle or chemically reactive for practical
The action of an applied force (or work). An applied use. Combining dierent ratios of metals as alloys modforce may be tensile (pulling) force, compressive ies the properties of pure metals to produce desirable
(pushing) force, shear, bending or torsion (twisting) characteristics. The aim of making alloys is generally to
make them less brittle, harder, resistant to corrosion, or
forces.
have a more desirable color and luster. Of all the metallic alloys in use today, the alloys of iron (steel, stainless
A change in temperature (heat). A temperature steel, cast iron, tool steel, alloy steel) make up the largest
change may aect the mobility of the structural proportion both by quantity and commercial value. Iron
defects such as grain boundaries, point vacancies, alloyed with various proportions of carbon gives low, mid
line and screw dislocations, stacking faults and twins and high carbon steels, with increasing carbon levels rein both crystalline and non-crystalline solids. The ducing ductility and toughness. The addition of silicon
movement or displacement of such mobile defects will produce cast irons, while the addition of chromium,
is thermally activated, and thus limited by the rate nickel and molybdenum to carbon steels (more than 10%)
results in stainless steels.
of atomic diusion.
Other signicant metallic alloys are those of aluminium,
titanium, copper and magnesium. Copper alloys have
been known since prehistorybronze gave the Bronze
Age its nameand have many applications today, most
importantly in electrical wiring. The alloys of the other
three metals have been developed relatively recently; due
to their chemical reactivity they require electrolytic extraction processes. The alloys of aluminium, titanium and
magnesium are valued for their high strength-to-weight
ratios; magnesium can also provide electromagnetic
shielding. These materials are ideal for situations where
high strength-to-weight ratio is more important than material cost, such as in aerospace and some automotive applications.
Alloys specially designed for highly demanding applications, such as jet engines, may contain more than ten elements.
4 Categories
4.1 Base metal
Main article: Base metal
In chemistry, the term base metal is used informally to
refer to a metal that gets oxidized or corroded easily, and
reacts easily with dilute hydrochloric acid (HCl) to form
hydrogen. Examples include iron, nickel, lead and zinc.
Copper is considered a base metal as it gets oxidized relatively easily, although it does not react with HCl. Base
metal is commonly used in opposition to noble metal.
In alchemy, a base metal was a common and inexpensive
metal, as opposed to precious metals, mainly gold and
silver. A longtime goal of the alchemists was the transmutation of base metals into precious metals.
EXTRACTION
A gold nugget
4.3
Noble metal
5 Extraction
4.4
Precious metal
5
usually by chemical or electrolytic reduction. 8 Applications
Pyrometallurgy uses high temperatures to convert
ore into raw metals, while hydrometallurgy employs
aqueous chemistry for the same purpose. The methods Some metals and metal alloys possess high structural
used depend on the metal and their contaminants.
strength per unit mass, making them useful materials for
When a metal ore is an ionic compound of that metal and carrying large loads or resisting impact damage. Metal
a non-metal, the ore must usually be smelted heated alloys can be engineered to have high resistance to shear,
with a reducing agent to extract the pure metal. Many torque and deformation. However the same metal can
common metals, such as iron, are smelted using carbon also be vulnerable to fatigue damage through repeated
as a reducing agent. Some metals, such as aluminium and use or from sudden stress failure when a load capacity
sodium, have no commercially practical reducing agent, is exceeded. The strength and resilience of metals has
led to their frequent use in high-rise building and bridge
and are extracted using electrolysis instead.[8][9]
construction, as well as most vehicles, many appliances,
Sulde ores are not reduced directly to the metal but are tools, pipes, non-illuminated signs and railroad tracks.
roasted in air to convert them to oxides.
The two most commonly used structural metals, iron and
aluminium, are also the most abundant metals in the
Earths crust.[13]
Recycling
Metallurgy
9 Trade
10 HISTORY
10
History
The nature of metals has fascinated humans for many centuries, because these materials provided people with tools
of unsurpassed properties both in war and in their preparation and processing. Pure gold and silver were known to
humans since the Stone Age. Lead and silver were fused
from their ores as early as the fourth millennium BC.[16]
Ancient Latin and Greek writers such as Theophrastus,
Pliny the Elder in his Natural History, or Pedanius
Dioscorides, did not try to classify metals. The ancient
Europeans never attained the concept metal as a distinct
elementary substance with xed, characteristic chemical and physical properties. Following Empedocles, all
substances within the sublunary sphere were assumed to
vary in their constituent classical elements of earth, water, air and re. Following the Pythagoreans, Plato assumed that these elements could be further reduced to
plane geometrical shapes (triangles and squares) bounding space and relating to the regular polyhedra in the
sequence earth:cube, water:icosahedron, air:octahedron,
fire:tetrahedron. However, this philosophical extension
did not become as popular as the simple four elements,
after it was rejected by Aristotle. Aristotle also rejected
the atomic theory of Democritus, since he classied the
implied existence of a vacuum necessary for motion as a
contradiction (a vacuum implies nonexistence, therefore
cannot exist). Aristotle did, however, introduce underlying antagonistic qualities (or forces) of dry vs. wet and
cold vs. heat into the composition of each of the four elements. The word metal originally meant mines and
only later gained the general meaning of products from
materials obtained in mines. In the rst centuries A.D. a
relation between the planets and the existing metals was
assumed as Gold:Sun, Silver:Moon, Electrum:Jupiter,
Iron:Mars, Copper:Venus, Tin:Mercury, Lead: Saturn.
After electrum was determined to be a combination of
silver and gold, the relations Tin:Jupiter and Mercury:
Mercury were substituted into the previous sequence.[17]
Arabic and medieval alchemists believed that all metals,
and in fact, all sublunar matter, were composed of the
principle of sulfur, carrying the combustible property,
and the principle of mercury, the mother of all metals
and carrier of the liquidity or fusibility, and the volatility properties. These principles were not necessarily the
common substances sulfur and mercury found in most
7
with the colour of the mineral calamine. And
yet if any should be dug up, it would be a proper
metal. Black and white copper seem to be different from the red kind. Metal, therefore, is by
nature either solid, as I have stated, or uid, as
in the unique case of quicksilver. But enough
now concerning the simple kinds.[18]
11
See also
Amorphous metal
Carolyn
Fry,
Ductility
[16] Der Groe Brockhaus (in German). 7: L-MIJ (Sixteenth, altogether newly prepared ed.). Wiesbaden: Bibliographisches Institut & F. A. Brockhaus. 1955. p. 715.
[17] John Maxson Stillman, The Story of Early Chemistry D.
Appleton (1924)
[18] Georgius Agricola, De Re Metallica (1556) Tr. Herbert
Clark Hoover & Lou Henry Hoover (1912); Footnote
quoting De Natura Fossilium (1546), p. 180
13 External links
Structural steel
Transition metal
12
References
[1] Henry George Liddell, Robert Scott, A GreekEnglish Lexicon, on Perseus Digital Library
[2] metal, on Oxford Dictionaries
[3] metal. Encyclopdia Britannica
[4] John C. Martin. What we learn from a stars metal content. New Analysis RR Lyrae Kinematics in the Solar
Neighborhood. Retrieved September 7, 2005.
[5] Holleman, A. F.; Wiberg, E. Inorganic Chemistry Academic Press: San Diego, 2001. ISBN 0-12-352651-5.
[6] Mortimer, Charles E. (1975). Chemistry: A Conceptual
Approach (3rd ed.). New York:: D. Van Nostrad Company.
[7] Ductility strength of materials
[8] Los Alamos National Laboratory Sodium. Retrieved
2007-06-08.
[9] Los Alamos National Laboratory Aluminum. Retrieved 2007-06-08.
14
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