Professional Documents
Culture Documents
Note: 420042
Key Words
Total Sulfur
ASTM D5453
Fuel
Hydrocarbons
Oil
Ultraviolet
fluorescence
Introduction
Principle
Analysis
Oxygen injection
Argon injection
Oxygen combustion
300 mL/min
100 mL/min
100 mL/min
Furnace temperature I
Furnace temperature II
Inlet temperature
Injection speed
Sample volume
MEAN AREA
RSD (%)
23142
42268
97649
1.44
1.77
4.25
Curve I
16000
R2 = 0.999
14000
12000
10000
Response
Std 1,000
Std 2,000
Std 5,000
8000
6000
4000
1000 C
1000 C
500 C
0.2 - 1 L /sec
20 - 100 L
2000
0
0
10
Sulfur (mg/L)
0.5
1.0
2.5
5.0
10.0
Injection speed
1 L /sec
injection volume
100 L
CURVE II
SULFUR IN mg/kg
5
25
50
100
150
250
Injection speed
1 L /sec
injection volume
20 L
CURVE III
SULFUR IN mg/kg
Curve II
18000
1000
2000
5000
R 2 = 0.9996
16000
14000
12000
Injection speed
0.2 L /sec
injection volume
20 L
Response
CURVE I
SULFUR IN mg/kg
10000
8000
6000
4000
2000
0
50
100
150
200
250
Sulfur (mg/L)
Results
The calibration data for curve I, II and II are listed in
table 3, table 4, table 5 respectively.
MEAN AREA
RSD (%)
756
1702
4046
7475
14821
0.66
0.54
Curve III
100000
90000
0.65
2.00
2.00
RSD (%)
Std 5
Std 25
349
1780
0.90
0.28
Std 50
Std 100
Std 150
Std 250
3576
7345
10589
17456
0.63
0.64
1.78
1.63
R2 = 0.999
80000
70000
60000
Response
Std 0.5
Std 1.0
Std 2.5
Std 5.0
Std 10.0
50000
40000
30000
20000
10000
0
0
500
1000
1500
2000
2500
3000
Sulfur (mg/L)
3500
4000
4500
5000
Conclusions
Discussion
(1)
(2)
0.5
1.0
2.5
5.0
10.0
25
50
100
150
250
500
1000
2000
5000
Table 6: Repeatability
max (mg/L)
0.006
0.01
0.04
0.2
0.4
0.1
0.6
1.4
0.4
1.6
9.6
22
21
70
0.1
0.2
0.4
0.6
1.0
1.9
3.4
5.8
7.6
11.2
13.4
77.2
64.7
166.9
In addition to these
offices, Thermo Electron
Corporation maintains
a network of representative organizations
throughout the world.
Australia
+61 2 8844 9500
Austria
+43 1 333 50340
Belgium
+32 2 482 30 30
Canada
+1 800 532 4752
China
+86 10 5850 3588
France
+33 1 60 92 48 00
Germany
+49 6103 4080
India
+91 22 2778 1101
Italy
+39 02 950 591
Japan
+81 45 453 9100
Netherlands
+31 76 587 98 88
Scandinavia
+46 8 556 468 00
South Africa
+27 11 570 1840
Spain
+34 91 657 4930
Switzerland
+41 61 48784 00
UK
+44 1442 233555
USA
+1 800 532 4752
www.thermo.com
Thermo Electron
Corporation, Delft,
the Netherlands is
ISO certified
The method of sample treatment described in this publication should be performed only by a competent chemist or technician trained in the use of safe
techniques in analytical chemistry. Users should acquaint themselves with particular hazards which may be incurred when toxic materials are being analyzed
and handled in the instruments, and the instrument must be used in accordance with the operating and safety instructions given in the Operators manual.
Although the contents have been checked and tested, this document is supplied for guidance on the strict understanding that neither Thermo Electron, nor any
other person, firm, or company shall be responsible for the accuracy or reliability of the contents thereof, nor shall they be liable for any loss or damage to
property or any injury to persons whatsoever arising out of the use or application of this method.
AN420042_E 11/05C