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EENADU Vijayosthu Mock EAMCET - 2014

Engineering
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Code E 2014 A

E
MATHEMATICS

1. If,, are the roots of the equation 8x3 + 1002x + 2016 = 0, then
( +)3 + ( +)3 + ( +)3 =

,, ' 8x3 + 1002x + 2016 = 0 O'--

j, (

+)3 + ( +)3 + ( +)3 =


(1) 567

(2) 576

(3) 765

(4) 756

7Z1
2. The complex numbers Z1 and Z2 are such that is purely imaginary.
5Z2
2Z1 + 3Z2
T
h
e
n

2Z1 - 3Z2

gu'

7Z
12

-Lp-

2Z1 + 3Z2

P 'u
Z
1

5Z

1 =

2Z1 - 3Z2

Z
2

(
1
)

(2)
4

(3)
2

(4)
4

1
3. A and B are two events such that P(Ac) = 0.3, P(B) = 0.4 and P(A Bc) = 0.5.

Then P A BBc

(')

A
,

'j,

B
P(Ac) = 0.3, P(B) = 0.4, P(A Bc) = 0.5

Pc =

'

()
AB
1
(
1
)

1
(2)
3

1
(3)
4
Space for rough work

1
(4)
5

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Code E 2014 A

4. Assuming that half the population is vegetarian, each of 128 researchers collects a
sample of 10 individuals to see whether they are vegetarians or not. The number of
researchers would you expect to report 2 people or less are vegetarians is

' --'-' Nh, 128 'C


J--x \\ --
10 'C uh-' '-E ---' ElJ-h'. 2 \
'-' El-J
J--- u
(1) 7

(2) 17

(3) 5

(4) 15

5. The area of the region bounded by the curve y = 2x, the parabola y = 2x - x2 and the
line x = 2 is

--', x = 2 'u
J-l''u ju
y=2x v, y = 2x - x2
2
4
(1) -
log 3
3

3
4
(2) -
log 2
3

2
3
(3) +
log 3
4

3
3
(4) +
log 2
4

x
(3)
y

y
(4)
x

dy
6. If (x + y)7 = x4 . y3, then dx =
dy
(x + y)
7 = x4 . y3

(
1
)

= dx
(2) y

x
7. An open cylindrical can is made out of a tin sheet of area 100 square metres. If
the
volume of the can is maximum, then the ratio of the base radius of the can to its
height is
100 -O'xju--o

- \ '*

-E n-- '' '


'. ''--J- J-e-'i-p' ' u-l, 'h EpAh
(1) 1 : 1

(2) 1 : 2

(3) 2 : 1
Space for rough work

(4) 2 : 3

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Code E 2014 A

8. The rate of increase of volume of a sphere is c.c./ sec. At the instant when the
radius is 1 cm, the rate at which the surface area increases is

'--J- J '
ul
-s
- J
ju J '
(1) cm2/ sec
9.

Lim
x

(2)2 cm2/ sec

-
.O'.

c.c./ sec.
1

(3) 2 cm2/ sec

(4) 22 cm2/ sec

(3) e2

1
(4)
e2

()
x
+1
2x + 1

=
x+2
(
1
)
e

1
(2)

10. The algebraic sum of the intercepts made by the plane x + 3y - 4z + 6 = 0 with
the
coordinate axes is

E ~-
x + 3y - 4z + 6 = 0
H@' h
(1) -11

(2) -13

(3) 121

(4) 13

11. The maximum value of xy + 5 subject to 2x +


y - 4 = 0 is

EJt

2x + y - 4 = 0

Je
(1) 2

%du
N'

xy+5

(2) 4

(3) 5

(4) 7

12. The locus of centroid of a triangle formed by a tangent to the parabola y2 = 36x with
the coordinate axes is given by the equation
y2 =36x ----E

Upz-E- ~ L vA'-Eo EJth, vA'


v- G' O'--
(1) y2 = 9x

(2) y2 = 3x

(3) y2 = -9x

Space for rough work

(4) y2 = -3x

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Code E 2014 A

13. The equation of a hyperbola, conjugate to the hyperbola x2 + 3xy + 2y2 + 2x + 3y = 0 is


x2 + 3xy + 2y2 + 2x + 3y = 0 * A------E t

A----' O'
(1) x2 + 3xy + 2y2 + 2x + 3y + 1 = 0
(2) x2 + 3xy + 2y2 + 2x + 3y - 1 = 0 (3)
x2 + 3xy + 2y2 + 2x + 3y + 2 = 0 (4) x2 +
3xy + 2y2 + 2x + 3y - 2 = 0
14. If the tangent at any point on the curve x + y = 4 meets the coordinate axes at A
2

and B, then the length AB is

23

x +y =4 v-E j

G'
2

AB

lUpz-
E- ~-'

(1) 8

(2) 6

(3) 4

3x +
15. If y = f
5x + 4

5
x

l
L
h,

(4) 2

is equal to
and f'(x) = tan2 x,

()

then

( )

dy

( )

3x +
y=f

A,B-

dx x = 0

, f'(x) = tan2

dy

()
dx x = =
0

5 + 12
(1)
16

12 - 5
(2)
16

5 + 12
(3)
16

5 - 12
(4)
16

16. The value of x in [4, 9] at which f(x) = satisfies mean value theorem is x

f(x)=
'u' N' l-Eo

%h'h, [4, 9] x
N'
(
1
)
2
5

C x
25
(3)
4

(2) 4

Space for rough work

4
(4)
25

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17. If (Max, Min) of

1 + sin2 x
sin2 x

sin2 x
1 + sin2 x
sin2 x

s
i
n

Code E 2014 A

E
cos x

sin 2x
sin 2x

1 + cos2 x

is (,), then +99 =

cos2 x 1 + sin 2x
sin 2x
cos2 x
sin 2x
1 + cos2 x

cos2 x 1 + sin 2x

\ (Je, Ee) C
+99 =
(1) 1

(2) 2

(,)

(3) 3

(4) 4

18. In ABC, if 2a2 + 4b2 + c2 = 2ac + 4ab where a, b, c represent the sides, then match
the following:
A
B
C

v
A

'
-

'

b
,

'

'

-:
I
(A) cos A
(B) cos B

2a2 +4b2 +c2 =2ac+4ab -* p'


h,
II
(p) 1 (q)
0

(C) cos (A - C)

(r)7
8
1
(s)
4

(
D
)
s
i
n
(
A
C
)

(t)3
4

Correctmatch(j
):
ABCD
ABC D
(1) s r p q
(2) s r q p (3) p
qrs
(4) p t s q

Space for rough work

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Code E 2014 A

19. The smallest integer greater than the S.D. of the data 1, 3, 5, 7, ........., 2013 is
1, 3, 5, 7, ........., 2013

h -\ v' N-
\- Ee g
(1) 382

(2) 482

(3) 582

(4) 682

20. A man throws a fair coin quite a number of times and gets 2 points for each head he
throws and 1 point for each tail. The probability that he gets exactly 6 points is

uh Eo Eo-'x --h, -- vA-J 't 2 'x, '-'


1 'p'-'. ' J_ 6
'x -u
41
(1)
64

43
(2)
64

23
(3)
32

21
(4)
32

21. Two sides of a triangle are represented by the roots of the equation
x2 - 7x + 8 = 0. If 60 is the angle included between the sides, then the product of
the circumradius and the inradius of the triangle is:

vA' ' '' x2 - 7x + 8 = 0 -O'-


*'. ' 'u
60 vA' J-%h ul,
--%h u-l l
2
(1)

5
(2)
2

(3) 3
5

22. If y = cos-1 (8x4 - 8x2 + 1), then (1- x2) =

()

dy
dx

y = cos-1 (8x4 - 8x2 + 1)

(1- x2) =

()

dy 2

(4) 5
3

dx
(1) 4

(2) 16

(3) 32
Space for rough work

(4) 64

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Code E 2014 A

23. Assertion (A): The number of common values of '' belonging to


and satisfying the equations

[0, 2]

2sin2 - cos2 = 0 and 2 cos2 - 3 sin = 0 is 6.

EPa-y (A): [0,2] --E ', 2 sin2 -cos 2 = 0, 2


cos2 - 3 sin = 0

O'---' %-h-J
\ 't N'- u 6.
Reason (R): The general solution of sin = 0 is = n, n Z.

(R) : sin = 0 y-vA

= n, n Z.
Which one of the following is correct?

C-- C
jC?
(1) A, R both true; R is the correct explanation of A
A,R u; A R j

N-
(2) A, R both true; R is not the correct explanation of A
A,R u; A R j

N-'
(3) A is true, R is false

A u; R

u
(4) A is false, R is true

A u; R

u
24.,,, are the roots of the equation x4 - 3x3 - 2x2 - 3x + 1 = 0. If, represent
a conjugate complex pair of roots, then ( +) =

' x4 - 3x3 - 2x2 - 3x + 1 = 0 O'-- '. ,


t g
' *h ( +)
,,,

=
(1) 2

(2) 3

(3) 4
Space for rough work

(4) 6

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Code E 2014 A

12
25. If cos = and sin = where and are acute angles, then match the
5
13
following from List - I to List - II:
3
12
cos = , sin =5
13

' j C G - I
'* G - II

---
:
List - I (G - I)

List - II (G -- II)
33

(A) cos ( -) =

(1) -
65

(B) cos ( +) =

(2) 49

65
(
C
)
c
o
s

( )

63

(3)
65

= 2
+

(
D
)

( )

49
(4) -
65

= 2

s
i
n
2

(
Thecorrectmatch

(5) 64
ABCD

ABCD

) :

65

(1) 3

15

(2) 2 3

5(3)

12

(4) 2 3

Space for rough work

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2
6
.

x-2

2x - 3

3x - 4

x-4

2x - 9

3x - 16

x
8

2x - 27

3x - 64

()

1
(1) 2,
2

Code E 2014 A

()
= 0 x,
x
1

1
(3), 4

(2) 4,

()

()

1
(4), 2

()

tan[x]
27. If [x] denotes step function, then range of f(x) = is
1 + [x2] + sin[x]
[
x
]

v'Eo
*h

tan[x]
f(x) =
1 + [x2] + sin[x]
(3) {0}

(2) [1,)

u
h
(4) R - {0}

(1) R
28. The solution of y3 dx = (y2 + e2x) dy is
y3 dx = (y2 + e2x) dy

O'--


(1) logy + y2 e2x + c = 0

(2) 2 logy + y2 e2x + c = 0

(3) logy + y2 e-2x + c = 0

(4) 2 logy + y2 e-2x + c = 0

29. A, B are symmetric matrices of the same order. If (AB + BA) and (AB - BA) are
respectively denoted as X and Y, then (XY)T =

'--A C ' e vA-'.


BA), (AB - BA) '
'-
X,Y *h (XY)T =
A,B-

(1) XY

(2) YX

(3) -XY
Space for rough work

(4) -YX

(AB +

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Code E 2014 A

x2
y2
30. The eccentricity of the hyperbola - = 1 is reciprocal to the eccentricity of
a2
b2
the ellipse x2 + 4y2 = 4. If the hyperbola passes through the focus of the ellipse, then
equation of the hyperbola is
x2
y2
- =1 A----'

\-v,
%h\-v- uv\'.

x2 + 4y2 = 4 D`-

b2

D`-%hG y --x
A----' O'--(1) x2 - 3y2 = 3

(2) 3x2 - y2 = 3

(3) x2 - y2 = 3

(4) 3x2 - 4y2 = 12

31. fn (x) = tan (1 + sec x)(1 + sec 2x)(1 + sec 4x)......... (1 + sec 2n x), n N
x
2

[]
lim
x0

f (x)

= n

(1) 2n - 2

(2) 2n - 1

(3) 2n

2x

x3 + x2 - 16x + 20
32. f(x) = , x 2
(x - 2)2
= k, x = 2
is continuous at x = 2. Then 7k2 + 7k + 7 =
f(x) =x3 + x2 - 16x + 20 ,
x 2

(x - 2)2
= k, x = 2

v''

x=2 l

N-*a-o-

(4) 2n + 1

'i
(1) 199

7k2 + 7k + 7 =
(2) 299

(3) 399
Space for rough work

10

(4) 499

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Code E 2014 A

E
x2

y2
33. P(), Q() are two points on the ellipse +
a > b. If the chord PQ
a2 = 1 where
b2
subtends an angle at the centre of the ellipse and a2 + b2 tan tan = 0, then =
x2

y2
+2 =1,a>b D`-%-hj P(), Q()

'
'G'-'. D`-%h

vl

a2

PQ

EohC.
tan = 0 --p' =

(
1
)

a2 +b2 tan

(2)
3

(3)
4

(4)
6

34. If u = ex sin x and v = ex cos x, then which one of the following is


correct?
u = ex sin x, v = ex cos x

C--

jC C?
(1) v du - u dv = u2 + v2

dx

dx

d2v

(2)
d2u =
2v

(3) = -2u
dx2

dx2
(4) (1), (2), (3)

35. If one root of x2 - x - k = 0 is square of the other, k =


x2 -x-k=0 -\


-E_

'i,
(1) 23

k=
(2) 25

(3) 3 2

52
log2 (x + 3)
36. The domain of f(x) =
is
(x2 + 3x + 2)
log2 (x + 3)
f
(
x
)

(2) (3,)
(4) (-,)

Space for rough work

(x2 + 3x + 2)
(1) (-, 3)
(3) (-3,) - {-1, -2}

11

(4)

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Code E 2014 A

37. In the binomial expansion (a - b)n for n 5, the sum of 5th and 6th terms is zero.
Then

=a
b

(a - b)n Cy Nh-- 5, 6
h '-o =
n 5

n-5

(1) n - 4

(2)

(3) 4n 3+
5

(4) 5n + 4

38. A circle cuts an X - intercept of 2 units. If the tangent drawn to it at (3, 2) is 5


parallel to Y - axis, then the equation of the circle is

%h X - ~j 2E'x --
hC. (3, 2) 5
l%h-E
U pz
Y- ~-E
--,
%hO'--
(1) x2 + y2 - 4x + 5 = 0

(2) x2 + y2 - 4y + 5 = 0

(3) x2 + y2 - 12x - 4y + 31 = 0

(4) x2 + y2 - 4x - 12y + 31 = 0

39. The centre of the ellipse 25x2 + 16y2 - 150x - 175 = 0 is


25x2 + 16y2 - 150x - 175 = 0 *

D`-%h

v
(1) (4, 2)

(2) (4, 3)

(3) (0, 3)

(4) (3, 0)

40. The equation of the parabola which has focus at origin and the tangent at vertex as
y = x + 1 is

-G-'lG, Q{ l pz- y = x + 1
--' O'-

-
(1) x2 + 2xy + y2 - 4x + 4y - 4 = 0

(2) x2 - 2xy + y2 + 4x - 4y - 4 = 0

(3) x2 + 2xy - y2 + 4x - 4y + 4 = 0

(4) x2 - 2xy - y2 - 4x + 4y + 4 = 0

Space for rough work

12

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Code E 2014 A

41. Observe the following statements:

Cv---' JQ-L- :

I
:

dx

= log

4x -

()

sin x - cos x 2

tan
8

dx

=
log

c
o
s
e
c

+c

x
c
o
t

+c

2
Which one of the following is correct? (C--

jC

C?)
(1) I, II both true (I, II

u)
u)
(3)Itrue,IIfalse(I u, II u )
u )

(2) I, II both false (I, II


(4) Ifalse,IItrue(I u, II

3 x sin x

dx = sin x

42. 0

52

32
(2)
2

(
1
)

(3)
4

(4)
2

2
43. The angle at which the curve y = kekx meets Y - axis
is:
y=kekx v Y -

(1) tan-1 (k2)

(2) cot-1 (k2)

44. The period of f(x) where f'(x) =

(3) tan-1 (k)

1 - 2 sin2 x
is:
2 f(x)

1 - 2 sin2 x
f

'

(4) cot-1 (k)

-- f(x) p' h:

2 f(x)
(
1
)

(3)
2

(2) 2

Space for rough work

13

(4)
3
2

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Code E 2014 A

()
x
45. cosh x = sec tanh2 =
2

(
1
)

(2)
cot

(4) tan2
2

(3)
cot2
2

t
a
n

2
46. cos-1 + sin-1

(
)

()

= tan-1 P - Q =

4
5

()

34

(1) 11

(2) 16

(3) 27

sin x

sin3 x
47. If dx =, then dx =
0

(4) 34

sin x

dx = -

sin3 x

dx =
0

(1)

(2)

(3)

(4)
6

+ 7x

8 2 dx =

8x

4
8
.

(1 + x + x )
x8

x7
(2)
1 + x + x8

(
1
)

x10

(4)
1 + x + x8

+c
+c

+
c
1 + x + x8
x9
(3) + c
1 + x + x8
49.

(log x)3 dx = x A(log x)3 + B(log x)2 + C(log x) + D + k A - D =

(2)

(3)
5

9
Space for rough work

7
3

14

C-B

(4)7
9

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Code E 2014 A

50. 63 + 73 + 83 + ........... + 133 + 143 + 153 =


(1) 14157

(2) 14175

(3) 17451

(4) 15417

+ i 3
51. If the complex number Z = , then Z 69 =
2
+ i

(3) -i

( )]

52. f(x) = cos (log x) f(x) . f(y) - f(xy) + f


2
y

(1) cos (log x)

(2) log (cos x)

(3) cos (log x + log y)

(4) 0

53. A + B = (1 + tan A)(cot A - 1)(1 + tan B)(cot B - 1) =


4
(1) 0

(2) 1

(3) 2

(4) 4

54. 3.C0 + 7.C1 + 11.C 2 + ........... + (4n + 3).Cn =


(1) (2n + 1) 2n
(2) (2n + 3)2n
(3) (2n + 1)2n - 1

(4) (2n + 3)2n - 1

55. OA = 2 + + 3k; AB =i + 2 - 2; = 3 - 2j +,
=i + +
i
j

k BC

k CD

OD =
(1) 7 - 2j - 3k
i

(2) 7i - 2 +
3

(3) 7i + 2 - 3
j
k

(4) 7i + 2j + 3
k

Space for rough work

jk

15

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Code E 2014 A

56. For the non-coplanar vectors,,, the line = (2 +) + t( -)


intersects the
abc
r
ab
bc
plane = + s( + ) + p( + 2 - ) at the
point
ra
bc
a
bc

M'C'
--p',

= (2 +) + t( -)

'
a
b
c
r

ab

bc

= + s( +) + p( + 2 -
)
r
a

bc

(1) 2 + 2 +

bc

Eo
G'

(2) 2 + 2

bc

-
a
(3) 2 - 2 +
a
bc

bc

(4) 2 - 2 -
a

bc

57. For any vector, ( ) + () + ()


=
a

a
i

() + () +

) =

a
(1)a
4a

ai

(2) 2a

aj
(3) 3a

58. . ( +) ( + +) =
c
bc
abc
(
1

ak
(4)

) [ ] cba

(4) []

(3) [] cab
acb

59. If n is an integer between 0 and 21, then the minimum value ofn is n 21
0,21

'u n

g
-'i,

(1)9 12

n n
21 -

(2)20

\
Ee N'
(3)21

(4)11 10
6

60. 50 C4 + (56 - r)C3 =


r=1
(1) 362790

(2) 367290

(3) 372690

Space for rough work

16

(4) 327690

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Code E 2014 A

61. Matchthefollowing:(C--E

--

-:)
List - I (G - I)

List - II (G - II)

(A) 21C(r - 4) = 21C(2r + 1) r =

(1) 13

(B) nC4 = 210 n =

(2) 2

(C) 10Cr + 10C(r + 1) + 11C(r + 2) = 12C(2r + 4) r =

(3) 10

(D) (n - 1)C5 + (n - 1)C6 = nC7 n =

(4) 8
(5) 12

Thecorrectmatch(j

):
AB C D

AB C D

(1) 4 3 1 2

(2) 1 2

34 (3) 4

321

(4) 1 2

43

62. In (x + a)5, T2 : T3 = 1 : 3 (x + 1) : (x - 1) =
(x + a)5 Nh-- T2 : T3 = 1 : 3 (x + 1) : (x 1) =
(1) (2a + 3) : (2a - 3)

(2) (a + 3) : (a - 3)

(3) (2a + 1) : (2a - 1)

(4) (a + 1) : (a - 1)

2x
A
63. + 2A + 3B =
1 + x2 + x4
1 + x + x2
(1) 4

(2) 3

B
1 - x + x2
(3) 2
Space for rough work

(4) 1

17

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Code E 2014 A

6
4
.

1 - arg . Z =
1+i

Z
=
(
1
)

(2)

4
(3)
4

(4)

65. X is a poisson variate such that P(X = 2) = P(X = 1). Then P(X = 4) =
P(X=2)=P(X=1) 'u X -

P(X = 4) =

(2)
3e2

(
1
)

-P
2

(3)
3e4

(4)
3e4

3e2

66., -, are the angles made by a straight line with X, Y, Z axes respectively.

2
Then 2 =

X,Y,Z ~-

'
'-

(
1
)

, -,

2 =

(2)
2

(3)
3

(4)
4

67. The circle x2 + y2 - 4x - 4y + 4 = 0 touches


x2 + y2 - 4x - 4y + 4 = 0 %h
(1) X - axis

X- ~Eo

(2) Y - axis

p%P-'hC
Y- ~Eop

%P-'hC
X,Y- ~-'F

(3) both the axes

p%P-'hC
X,Y- ~-'-F

(4) neither X - axis nor Y - axis

p%P-'
Space for rough work

18

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Code E 2014 A

68. The circles x2 + y2 + 4x - 14y + 28 = 0, x2 + y2 + 4x - 5 = 0 intersect each other


at an angle
x2 + y2 + 4x - 14y + 28 = 0, x2 + y2 + 4x - 5 = 0

%h -

p
(1)

(2)

(3)

(4)
4

3
69. The distance of the common chord of the circles x 2 + y2 - 2x + 4y - 4 = 0,
x2 + y2 + 4x - 6y - 3 = 0 from the point (1, 2) is
(1, 2)

G' '* x2 + y2 - 2x + 4y - 4 = 0, x2 + y2 + 4x - 6y - 3 = 0
%h
'tu

21
(1)

23

11

(2)

(3)

13

1
3
6

(4)

136
1
3
6

136

70. A point (x, y) is given as (tan - sin, tan + sin). The equation to the locus of
(x, y) is:

G'

(x, y) C

(tan - sin,

tan + sin)

(x, y) G'-

-
O'
(1) x2 - y2 = 16 xy

(2) (x2 - y2)2 = 16xy

(3) x2 + y2 = 16 xy

(4) (x2 + y2)2 = 16xy

71. A triangle with vertices (cos 60, sin 60), (cos 45, sin 45), (cos 30, sin 30) has
its circumcentre at:
(cos 60, sin 60), (cos 45, sin 45), (cos 30, sin 30) Q{-'o

vA'
J-v

()

(
1
)

11

(2) ,
22

(
0
,
0
)

(
3
)

(4) ,

()

33

22

Space for rough work

19

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Code E 2014 A

72. x + y + 1 = 0, 3x + 2y - 5 = 0, 2x + y - 4 = 0 form a triangle of area:


x + y + 1 = 0, 3x + 2y - 5 = 0, 2x + y - 4 = 0- ' EJt

ju
(1) 1 sq.u. (-.-.)
(3) 3 sq.u. (-. -.)

vA'

(2) 2 sq.u. (-.-.)


(4) 4 sq.u. (-.-.)

73. A triangle has an area equal to 15 square units in a coordinate system. When the
origin of the system is translated to a point (3, -2), the area of the triangle in the new
system will become

E- u-n vA' ju 15 E'x. u-n-E G'-'


(3, -2) l - J-h Ch,
u-n vA' ju
(1) 5 sq.u. (-.-.)
(2) 6 sq.u. (-.-.)
(3) 10 sq.u. (-.-.)
(4) 15 sq.u. (-.-.)
74. A function f(x) is given as f(x) = x4 - 6x3 + 13x2 - 11x + 4. Its approximate value
at x = 2.01 is
f(x) = x4 - 6x3 + 13x2 - 11x + 4

C v''. x = 2.01 l DE

b- N'
(1) 2.21

(2) 2.12

(3) 2.01

75. f(x) = x . ex(1 - x) increases in

f(x)=x.ex(1 -

(4) 2.001
x)

(
(
1
)

(
-

(2) -, 1

(3) -, -

Space for rough work

20

4) (1,)

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Code E 2014 A

76. The pairs of straight lines x2 - 8x + 12 = 0 and y2 - 14y + 45 = 0 form a square.


If p is its perimeter and s is the area, then (p, s) =

-----t'
'--vEo EJt-h. E
''d-- p, ju s (p,
x2 - 8x + 12 = 0, y2 - 14y + 45 = 0

s)=
(1) (2, 4)

(2) (4, 8)

(3) (8, 16)

(4) (16, 16)

77. Assertion (A): The equation to the pair of lines passing through origin and
perpendicular to the pair of lines 2x2 + 5xy + 2y2 + 10x + 5y = 0 is
2x2 - 5xy + 2y2 = 0.

EPa-y (A): -G-' y -- 2x2 + 5xy + 2y2 + 10x + 5y


= 0 --
tE - t O'-- 2x2 5xy + 2y2 = 0.
Reason (R): If m1, m2 are the slopes of the lines represented by
ax2 + 2hxy + by2 + 2gx + 2fy + c = 0 then
-2h
a
m1 + m2 = ; m1m2 =.
b
b

(R): ax2 +2hxy+by2 +2gx

+2fy+c=0 O'--

*-

-- ''
m1, m2

-2h

m1 + m2 = ; m1m2 =.

Which one of the following is correct?

jC C?
(1) A, R true; R explains A correctly

A,R u; A ' R JN-J-

'hC
(2) A, R, true; R does not explain A

A,R u; A ' R N-J-

'
A u; R

(3) A is true, R is false

u
A u; R

(4) A is false, R is true

u
Space for rough work

21

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Code E 2014 A

78. If H, G, S, I denote respectively the orthocentre, centroid, circumcentre and incentre


of a triangle formed by the points (1, 2, 3), (2, 3, 1) and (3, 1, 2) then H + G + S + I =
(1,2,3),(2,3,1),(3,1,2) G'-- p-vA'--E H, G, S, I

'- -v,
v-, J-v, -v H + G + S + I =
(1) (2, 2, 2)

(2) (2, 4, 6)

(3) (6, 8, 8)

(4) (8, 8, 8)

a+b
x
y
79. For a non zero constant k = , the straight line + = 1 passes through the
ab
a
b
point

a+b
k=
ab

-p'

+ =1 -

--x
G'

(1) (k, k)
(2) k,

(
)

1
k

()

11
(3),
kk

'

()

(4)
,
k

80. If f(x) = (x - 3)4(x + 2)3, then as per Rolle's theorem the value of 'c' in (-2, 3)
is
f(x) = (x - 3)4(x + 2)3

v
1
(
1
)

ql
(-2, 3)

(2) 7

(3)

Space for rough work

22

'c' N'
1
(4)
2

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Code E 2014 A

E
PHYSICS

81. Match Column - 1 and Column - 2.

d
-1, d
- 2 '
.
Column - 1 (d - 1)

Column - 2

(d

- 2)
Units (v-

Dimensional formula (N'A--

')

't)

(A) Pas

(I) M0L2 T-2K-1

(B) Nm-1

(II) MLT-3K-1

(C) J kg-1 K-1

(III) ML-1T-1

(D) Wm-1 K-1

(IV) ML0 T-2

(1) A-II, B-I, C-III, D-IV

(2) A-III, B-II, C-IV, D-I

(3) A-III, B-IV, C-I, D-II

(4) A-III, B-I, C-IV, D-II

82. Rain is falling vertically down with a speed of 20 ms-1. Wind is blowing with a
speed of 15 ms-1 from west to east. A man is running in rain with a speed of 5 ms1 from west to east. The angle with the vertical at which the man should hold

umbrella so that he may not get drenched is


-1

{ Ed-E-'- 20 -O'.. '-C. L-'


'* 'p-
-1
15 -O'.. O-hC. uh { -'
-1
'* 'p- 5 -O'.. J''o'. {
---' -- -E Ed-E'-
'-'' Lq

()

)
(2) Tan-1

(
1
)

1
(3) Tan-1 4

T
a
n
1

3
S
p
a
c
e
f
o
r
r
o
u
g
h
w
o
r
k

()

(4) Tan-1 (2)

23

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Code E 2014 A

83. An object is projected at an angle to the horizontal from ground. When it is at its
highest point of its path, magnitude of its position vector with respect to the point of
projection is times to the maximum height reached by it. The angle of projection is 2

'h-' ~A - -E
h v~h --p' v~h
G' '*
Je 'h U n C J- Je 'h

JE
N'
(1) 45

'x C. -- v~h
(2) Tan-1(2)

(3) Tan-1(4)

(4) 60

84. A constant power 'P' is applied to a particle of mass 'm'. The distance travelled by the
particle when its velocity increases from V1 to V2 is (neglect friction)

n 'nu-Eo vT-'.
V1 '*
V2
JTp' v--*
('{ '-)
'm' vu-P o j 'P'

m
(
1
)

(
V
2

m
V
1)

3P

(V23 - V13) 3P

(2)
(3) 3P (V22 - V12)

(4) 3P (V23 - V13)

85. A block of mass 1 kg kept on rough inclined plane


is connected to a light spring of spring constant
100 Nm-1 as shown in the figure. The spring is
released from rest with spring in unstretched
position. The block moves 10 cm down the
incline before coming to rest. If g = 10 ms -2,
coefficient of friction between block and incline
3
-2
is g = 10 ms , sin 37 =
5

1k
g
37

1 .-v.vuP

o C't' 100Nm-1 vp n
o L vp
N d'. C't' Ea nA '* C-L
vp x --C 10 .-O'-. ' '
j v-* T--C. '- '{
' g = 10 ms-2, sin 37 =
(1)
0.125

(2) 0.25

(3) 0.4
Space for rough work

24

(4) 0.8

3
5

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Code E 2014 A

86. A solid cylinder rolls up inclined plane of inclination 30. At the bottom of inclined
plane, centre of mass of cylinder has speed of 5 ms -1. The maximum distance
travelled by cylinder up the plane is (neglect friction and take g = 10 ms-2)

'n 'x 30 '- o '-j v--*C. '- '-'-l


-1
o-p'hvu-P v 5 -O'.. C.
n '--j
vL Je
('{ ---2
', g = 10 -O'.. \)
(1) 1.75 m

(2) 2.5 m

(3) 3.25 m

(4) 3.75 m

87. A particle oscillating in SHM has maximum displacement of 4 cm. Its acceleration
at a distance of 1 cm from its mean position is 3 cm s-2. Its velocity at a distance of
2 cm from mean position is

----t 'ho E 'u


G' '* Je n-v 4 -.O'. --
-2
G''* 1 -.O'.ly 3 -.O'.. -'u G' '*
2 -.O'.l

(1) 6 cm/sec

(2) 12 cm/sec

(3) 18 cm/sec

(4) 24 cm/sec

88. Assertion (A): At critical temperature, surface tension of liquid becomes zero.

EPa
(A):
Cl g-v l
v --u u-'--'C.
Reason (R): At critical temperature, intermolecular forces for liquids and gases
become equal, and liquid can expand without any restriction.

(R): Cl g-v l v--', --x-E '- 'u '


'. p' v' u-*-h.
(1) Both A and R are true, R is correct explanation of A.

A, R E; A R

j
N-.

(2) Both A and R are true, but R is not correct explanation of A.


A , R E;

F A R j N
- '.
(3) A is true, R is false.
A E, R
p.
(4) A is false, R is true.
A p, R
E.
Space for rough work

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Code E 2014 A

89. A uniform meter stick is hinged about one end from a fixed point so that it is free to
rotate in a vertical plane. The stick is displaced until its centre of mass is at the same
level as the point of suspension and released. Angular velocity of stick as it passes
through the mean position in rad s-1 is (g = 10 ms-2)

KA O'' f E' ya AJ--N l \E L C.


fE ~A -- n-v C* CL E' Eo J '-'
E
-1
'
--'-. . (g=
-2
10 O'.. )

10
30
(1)
(2) 15
(3)
(4) 5
90. Same spring is attached with 1 kg, 2 kg, 3 kg blocks in three different cases as shown
in the figure. x1, x2,
x3 are the extensions
in the spring in three
different cases. Then

vp 1
.-v.,
2 .v-.,3 .-v.
vu

'
* N
L

x1

x2

x3

'{--E
'p y
-D'.
vp
2

kg

2
kg

3k
g

2
kg

'

'
x
1

,
x2,x3

(1) x1 = 0, x2 > x3

(2) x1 > x2 > x3 (3)

x3 > x2 > x1

(4) x2 > x1 > x3


Space for rough work

1k
g

2
kg

26

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Code E 2014 A

91. When a tensile force of 33,000 N is applied on a steel rod of area of cross section
10-3 m2, elongation is produced in the rod. The temperature rise required in the rod
to produce the same elongation due to heating is
(Ysteel = 3 1011 Nm-2,steel = 11 10-6/C)
2

'u-a -juo'd'fj 'j`u Eo v-T-*-p' -E '-


-E-*C. fE ' x u
p-- -f-E -Lq g-v -

10-3 O'

(Y'd' = 3 1011 Nm-2,'d' = 11 106/C)

(1) 20 C

(2) 10 C

(3) 50 C

(4) 80 C

92. Two blocks are connected with a light spring of spring constant 1000 N/m and forces
are applied as shown in the figure. The extension produced in the spring is (friction
is negligible)

'C't-' 1000N/m vpn o L


vp L C't-j -'
* N v-T-'. -
'{ -'- vp p
'-
m
4 kg

10 kg

2
0

(1) 10 cm

(2) 12 cm

(3) 16 cm

93. Two blocks of equal mass are tied with a light string which
passes over a pulley as shown. The magnitude of
acceleration of centre of mass of both blocks is (neglect
friction)

(4) 24 cm

160 N

'
C

't

'

'

l
G
T

'
p

j
-
'
-*

-,
-
''

'

30
60

j-N- -N--'. - ' C't vu-P v


\ y
g
(1
)

( - 1)g 3

(2) ( - 1)g
3

- 1)g 3

(3)

2
(4)

Space for
rough
work

27

4
2

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Code E 2014 A

94. A large tank is filled with water to a height H. A small hole is made at the bottom of
tank. It is found that time taken for water height to decrease to H is T1 and for rest

of water to come out is T2. If T1 = T2, value of 'K' is


K

l u' H 'h F E '' l


*o v '. F-'-d
H '* H _--E T1 , H '-* Jh S --E T2 -d. T1 = T2

'K'
N'
(1) 2

(2) 3

(3) 4

(4)
22

95. A Satellite revolving in an orbit around earth released some energy. Then

~u J-v-N'-'ho -v
hE _-J-*C. p' -v
a) it moves to lower
C~uorbit
v-Pb) it moves to upper orbit
'hC.
c) its orbital velocity increases
j~ud) its orbital velocity decreases
v-P
(1) a, d are correct a, d E
-'hC.
(3) b, d are correct b, d E
~u-
'-'-'C.
~u-
'_-'C.
(2) a, c are correct a, c E
(4) b, c are correct b, c E
96. A body is floating on a liquid. At two temperatures t1C and t2C of liquid, f1 and f2
fractions of volumes of body are immersed in the liquid. If expansion of body is

negligible, coefficient of volume expansion of liquid is

' C't v --'-'-C. t1C l f1


'J- ; t2C l f2
'J v E-T-C-. 'nE
u '. v '--J-
u '
N'
f

f -f 2 1

f +f 2

f +f

(
1
)

(2)

f t -f t
1
2

(3)

(4)

21

f t -f t
2
2

f t +f t

11

1
2

Space for rough


work

28

21

f t +f t
11

22

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Code E 2014 A

97. Temperature of Helium molecules at which their rms velocity becomes equal to rms
velocity of Hydrogen molecules at NTP is
NTP ljv---'--

',
--'--
g-v
(1) 273 K

(2) 64C

rms

rms 'L-''

(3) 844 K

(4) 273C

98. On investigation of light from three different stars A, B and C, it was found that in
their radiation spectra, the intensity of red colour is maximum in A, intensity of blue
colour is maximum in B, and intensity of yellow colour is maximum in C. If
TA, TB, TC are their absolute temperatures then
A,B,C '~-v '* _--''u N-

A g -' J-Q-L-'.
A g--', B g--F, C g--
'-a-'-- Je Bv-'
o. TA, TB, TC ' ~-v '
g-v-'
(1) TA = TB = TC

(2) TA > TB > TC

(3) TB < TC < TA

(4) TB > TC > TA

99. A calorimeter of water equivalent 10 gram contain 90 gram of water at 20C. If ice
of mass 10 gram at -20C is dropped into it, the temperature of mixture is
(Specific Heat of ice = 0.5 cal/gmC, specific heat of water = 1cal/gmC, Latent
heat of fusion of ice = 80 cal/gm)

'u 10 v' o JO'-' 90 v


F' 20 C l C.
-20 C l o 10 v ''' JO'-'- -N-'. L g-v
('' s = 0.5 cal/gmC, F' s = 1 cal/gmC, '' vO-- 'hg =
80 cal/gm)
(1) 2C

(2) 3C

(3) 5C

(4) 10C

Space for rough work

29

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Code E 2014 A

100. Two moles of Helium gas undergoes a cyclic process as shown in the figure.
Assuming the gas to be ideal, work done by gas is

'L-'' -j ( N)
v' vv' J'.
-z- - '-
, --C E
2

2 atm
1 atm

D
300 K

(1) 100 R ln 2

400 K

(2) 200 R ln 2

T
(3) 300 R ln 2

(4) 400 R ln 2

101. Length of a closed organ pipe is 120 cm. A tuning fork of frequency 330 Hz is
excited and kept above the mouth of open end. Water is slowly poured until
resonance is heard. Minimum height of water to be poured to produce resonance is
(neglect end correction)

d 120 .-O'., 330 db


"u o %AEo --
d*j-*,'t-CF'ho'. ' p-- d
LqF F 'h ( -' Nt-J-)
(1) 25 cm

(2) 45 cm

(3) 75 cm

(4) 15 cm
Space for rough work

30

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Code E 2014 A

102. A helicopter moving horizontally at a speed of 200 ms -1 at some height from


ground makes sound and passenger in it listens echo from ground after 105
second. If velocity of sound in air is 300 ms-1, height of helicopter from ground is

N' '* 'h l ~A -- 200


-1
-O'.. v--'ho L-d
y EE C. yE j --h
x a vA-y-EE L--d--E
v' 105 x
y No'. L
-1
yE 300 -O'.. N'j
'*L-d
'h
(1) 1250 m

(2) 1000 m 5

(3) 2500 m

(4) 5000 m

103. A triangular prism of glass is as shown in the figure. A light ray incident normally
on one face undergoes total internal reflection at the other face. If = 45,
refractive index of glass is

vA'--- V d j -'i A , l
g --h CC. = 45
V v-- ' N'

(1) <2

(2) =2

(3) >2

=3
Space for rough work

(4)

31

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Code E 2014 A

104. A long sighted person has least distance of distinct vision of 50 cm. In order to
reduce it to 25 cm, the power of lens he has to use in Dioptres is

%d o uh 50 .-O'. '- o 'h--' v' --'. pd%d Ee Eo 25 .-O'. T_-E


' --T--Lq 'nu
dx

(1) -2 D

(2) -4 D

(3) +2 D

(4) +4 D

105. Two glass plates of refractive indices 1.5 and 1.6 are introduced in the path of two
interfering beams in YOUNG'S double slit experiment. If there is no shift of
central bright, the ratio of thickness of 1st and 2nd plates is

'-<-Lv- ' <L- '* a A


- _x 1.5, 1.6
v- '' o ' V --' '.
vD' 'uA-'-'- n -'.
1, 2V- '-
EpAh
(1) 16 : 15

(2) 15 : 16

(3) 6 : 5

(4) 5 : 6

106. When a beam of monochromatic unpolarised light of wavelength in vacuum is


incident on the surface of a liquid at an angle '', the reflected light is completely
polarised. The wavelength of light inside the liquid is

u --j`u o -g --v'-
A v--j ' --'i-p'h A Jh -v' A.
v A j`u N'

(1) Tan

(2) Tan

(3) Sin

Space for rough work

32

(4)

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Code E 2014 A

107. Two identical charged spheres are suspended by strings of equal length. The strings
makes an angle of 30 with each other. When they are suspended in a liquid of
density 0.8 gm/cc, the angle remains same. If density of material of sphere is
1.6 gm/cc, dielectric constant of liquid is

'y--N'u---P -'
-'o G' '*
D'.p'--N 'u 30 a
--h . -' 0.8gm/cc v o
v -D---p' 'u
-'. - --n
v 1.6 gm/cc v
n N'
(1) 1

(2) 3

(3) 2

(4) 4

108. Capacity of a parallel plate capacitor with air between the plates is 10 F.
Separation between the plates is 'd'. The space between the plates is now filled with
two dielectrics. One dielectric has dielectric constant K1 = 3 and thickness
.d
Other dielectric has dielectric constant K2 = 6 and thickness
capacitor now becomes (Area of dielectrics is
2d , capacitance 3of
3
same as plates)

- -- - -q' -
'u L op' - 10F. - 'u
'd'. - 'u v-Eo '
-n E'. -E

n K1 = 3, ' . E 2d
- n K2 = 6, ' .
d

N'hg- N'hgE

-'i 'C - N'

(1) 5F

(2) 40F

(3) 45F

(4) 90F
Space for rough work

33

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Code E 2014 A

109. Ratio of de Broglie wavelengths of electron when accelerated through potential differences of 400 V, 900 V respectively is

-Zj
400V,900V -E{-' ' '-Jh-*--p' p vUx --j-`u
EpAh
(1) 1 : 1

(2) 4 : 9

(3) :
3
2

(4) 3 : 2

110. In the circuit shown a meter bridge is balanced. The meter bridge wire has a
resistance of 0.1/cm. The value of unknown resistance 'X' and the current drawn
from the battery of negligible internal resistance is
X

40 cm

60 cm
5V

*a--'--O'-'-vG-b'-CO''vGb
--C.O''vGbB E
0.1/cm L-'E -E 'X', -Jo- E
uK '* v-
N'-'
(1) 6, 0.1 Amp

(2) 10, 0.1 Amp

(3) 4, 1.0 Amp

(4) 12, 0.5 Amp


Space for rough work

34

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Code E 2014 A

111. Statement (A): According to Gauss' law in magnetism, total magnetic flux through
any closed surface is zero.

uu (A): '-\--y E'' v,


% ' y h
'\ G u.
Statement (B): Angle of dip is the angle between magnetic meridian and
geographic meridian.

uu (B): - () '-\
u-h -E, N' -R
(uN'-B') E'u
.
(1) Both A, B are true
A,B ' E
(2) Both A, B are false
A,B '
p
(3) Only A is true
A v' E
(4) Only B is true
B v' E
112. T0 is time period of oscillation of a magnetic needle in uniform horizontal
magnetic induction field B H of earth. Another magnetic field is applied
perpendicular to BH such that the needle deflects by '' for its equilibrium. Now time
period of oscillation in the combined field is T. Relation between T and T0 is

'-\ *-' -KA '-\ ~A


- ~v BH
p' h T0, '
'-\ ~vEo BH C
vTh'-\ * --h C
'-n-A *aC. 't '-\
~vp'
h 'T' T, T0 'u
(1) T2 = T02 cos

(2) T = T0 cos

T02

T0

(4) T2 =
cos

(
3
)

c
o
s

Space for
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Code E 2014 A

113. To convert 800 mV range milli Voltmeter of resistance 40 in to milli ammeter of


100 mA range, the resistance to be connected is
800 mV C

o 'd O'' E
40 'd
O'-''
100mA C
o
O't'a--E
-Lq E
(1) 10 in series v 10
(2) 1 in parallel
- 1
(3) 1 in series
v 1 (4) 10 in parallel - 10
114. A wire of 40 cm length is bent into a rectangular loop 15 cm 5 cm and kept
perpendicular to magnetic field of flux density 0.8 Wb m-2. With in 0.5 second, the
rectangular loop is changed in to square loop of each side 10 cm and flux density
is increased to 1.4 Wb m-2. Magnitude of average induced e.m.f. is
40 .-O'.

oB' 15 .-O'. 5 .-O'. '


D`'--v- p-2
J* 0.8 -- -O'. '-\ G--~-v-E
'. 0.5 -' vA ' 10 .-O'. o
'--v Ja '-\ G- v-' 1.4
-2
---O'. a'. ' vJ
N'ua- J-
(1) 16 10-3 V

(2) 6 10-3 V

(3) 14 10-3 V

(4) 20 10-3 V

115. When LR combination is connected in series with 12 V - 50 Hz supply, a current


of 0.5 A flows through the combination. If the current differs in phase with applied
voltage by rad, resistance R in the circuit is

12 V - 50 Hz a.c. -' L, R

--'
v-T-*d>

v-L-'. 0.5 A
' v--'hC.
',
'u ---

rad

C.-'-E
E R N'

(1) 6

(2) 24

(3) 12
Space for rough work

36

(4) 3

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Code E 2014 A

116. A plane electromagnetic wave of frequency 30 MHz travels in free space along
X - direction. The electric field component of the wave at a particular point of
space and time is E = 6 Vm-1 along Y - direction. Its magnetic field component
'B' at this point will be

'-N'u--'-\ - 30 MHz "--u-


--- X - ~ j
vh--C. G' l ~-
N'u~v E = 6 Vm-1,
Y- C-C. G' l '-'- '-\ ~v
B N'
(1) 2 10-8 T along Y - direction (2)

2 10-8 T, Y

2 10-8 T along Z - direction (3) 6

C 2 10-8 T,
Z C 6 10-8
T, X C 6
10-8 T, Z C

10-8 T along X - direction (4) 6


10-8 T along Z - direction
117. The circuit given below is equivalent to

*a---E'u'iy
(1) NOR gate

(2) OR gate

(3) AND gate

(4) NAND gate

118. A small photocell is placed at a distance of '4 m' from a light source. When mono
chromatic light falls on it, the current is 5 mA, and stopping potential is 4 V. If
distance of cell is decreased to '1 m', the current and stopping potential are

A - '-* '4 m' - A N'u '---Eo -'. N'u '-j g


A-'--'i--p'p' 5 mA, --E{-' 4 V. A 'Eo
'1m' --*p', --E{-' N'-'
5

(3) 80 mA, 4 V

(
1
)
1
.
2
5
m
A
,
1
V
(
2
)

m
A
,
4
V
16
Space for rough work

(4) 80 mA, 16 V

37

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Code E 2014 A

119. Second member of Lyman series in Hydrogen spectrum has wavelength of 5400 A,
wavelength of first member of Lyman series is

jv-g---j'v-E 2
j`u
5400A -- j'
v-E-
j`u
(1) 6400 A

(2) 8100 A

(3) 2700 A

120. Graph represents the


decay of a newly Number of Atoms
prepared sample of
radioactive nuclide 'X'
into stable nuclide 'Y'.
The growth curve of 'Y'
intersects the decay curve
of 'X' at time 't'.

(4) 3646 A
Y

Time

If half life
period of 'X' O
is 'T', value of 't' is
'X' Jt

- N'-- C 'Y'
n---- '-'C. 'X' l
@N-- T.'X' ~v, 'Y' -%Cl v t l
'-'--'-o-. - 't' N'
(1) T

()

T
(2
)
ln
(T
)

(3) T

Space for

(4) ln
2

rough work

38

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Code E 2014 A

E
CHEMISTRY

121. The reaction becomes spontaneous at high temperature when


H - , S -, G - are respectively
r

C g-v l u '-Bo-% -E
rH - ,rS -,rG ' '
(1) -ve, -ve, -ve

(2) +ve, +ve, -ve

(3) -ve, -ve, +ve

(4) +ve, -ve, -ve

122. Dispersed phase and dispersion medium in Pumice stone are respectively

u'i N~h v
n, N~- -' '-
(1) Gas, Solid
n, '--n
(2) Solid, Gas
'-n, -n
(3) Solid, Solid
'-n, '--n
(4) Liquid, Solid
v--n,
'--n
123. Hydroformylation of Olefins yields a compound 'X' which further undergo
reduction to give 'Y'. Where 'X' and 'Y' are respectively

L--- jv--j t-- J- 'X'


't- 'hC. DEo 'Sx ~'--
--Ch
'Y' ' t- 'hC.
u 'X', 'Y' '-
(1) Carboxylic acid, Aldehyde
s-q-L

'x, Lf-j
,\-

(2) Ketone, Alcohol

Lf-j,\-

(3) Aldehyde, Alcohol

\-,

(4) Alcohol, Aldehyde

Lf-j
Space for rough work

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Code E 2014 A

124. Antacid(s) among the following is/are

C 'x NC/-'x N-''


(1) CaCO3

(2) Zantac

(4) All the above

(3) Tegamet

-'

Fo
1) C2H5OH
125. Na2B4O7 + Conc. H2SO4 A B (Green edged flame)
2) Ignite
Identify A and B in the above reaction
1) C2H5OH
a2B4O7 + .
H2SO4 A B
(--aE

j u
B '

2) '-

A,

(1) A = NaBO2, B = B2O3


(2) A = H3BO3, B = (C2H5)3 BO3
(3) A = H3BO3, B = B2O3
(4) A = B2H6, B = Na2SO4
126. Amorphous form of Silica used in filtration plants is

-'v--x --T
p- - L
(1)Kieselghur --'

(2) Quartz

'
y)

(3) JASPER

'i

ydb
(4)Tridimite v-

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Code E 2014 A

127. The following reaction that does not give N2 gas is

C ux N2 '
'--J-Eu
Heat
(1) (NH4)2Cr2O7

'

Heat

(
2
)

'

N
a
N
3

(3) 3 HNO2
(4) NH4Cl (aq.

.v.) + NaNO2 (aq. .v.)

128. Incorrect statement among the following is

C--
J-E uu
(1) S - S - S bond angle in S8 ring in rhombic Sulphur is greater than that of
S - S - S bond angle in S6 chair form.
S6 Ka

Et- S - S - S S8 ' S - S - S - \.
(2) S - S bond length in S8 ring in rhombic Sulphur is less than that of S - S bond
length in S6 chair form.

Et- S-S j` u
S8 -' S-S j` u
\.

S6 Ka

(3) At 1000 K, S2 is the dominant species and is paramagnetic.

1000K l S2 '-

vp-o-,----D-E '\-y 'C.


(4) S2 molecule is diamagnetic.

' -'\y
'C.
S2

Space for rough work

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Code E 2014 A

E
C--

129. Incorrect match among the following is

J-E
(1) ClO2 - bleaching agent for paper pulp

T-'Vb' N-

ClO2 -

(2) I2O5 - used in the estimation of CO

' '-E
-'
I2O5 - CO

(3) IF5 - colourless gas below 77 K


IF5 - 77 K

-C'-- '-
E
(4) HOCl - oxidising agent and bleaching agent
HOCl - q--,

N---
130. XeF6 on hydrolysis gives
XeF6 '

-N-x--h aC
(1) XeO3 & HF

(2) XeOF4 & HF

(3) XeO2F2 & HF

(4) All the above

Fo
131. A photon of wavelength 4 10-5 cm strikes on metal surface, the work function
of the metal is 2.13 e.V. The kinetic energy of emitted electron is
4 10-5 .O'.

j`u
-J--Eo dC. E

v'' 2.13e.V. '---Z


A--h
(1) 4.26 e.V.

(2) 0.97 e.V.

(3) 0.49 e.V.

(4) 2.97 e.V.


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Code E 2014 A

132. When a graph is plotted betweenG - Vs T for formation of some oxides


(Ellingham diagram), a straight line with negative slope is given by

Eojq'xp---p'G -, T 'u v Uh,


' ' ---' aC
(1) 2 Mg + O2 2 MgO

(2) 2 CO + O2 2 CO2

(3) 2 C + O2 2 CO

(4) 4 Cu + O2 2 Cu2O

133. Spontaneous abortions and birth of deformed babies are caused due to

v-'-os-v -, -ju o P-' Et---E


(1) Increased CO level in blood due to smoking

-- x h
CO n
-
(2) Excess Nitrate in drinking water

F- jv
--C ---
(3) Excess Sulphate in drinking water

F-
p --C --
(4) Excess Polychlorinated biphenyls in water

FM-x-J--jjq --C ---


134. The formula of the compound which gives violet colour in Lassaigne's test for
Sulphur with Sodium nitroprusside is

p''Jh---E ' jv-v-j j K-~ p -'

't-
't

(1) Na4 [Fe(CN)6 S]

(2) Na4 [Fe(CN)5 NCS]

(3) Na4 [Fe(CN)5 NOS]

(4) Na2 [Fe(CN)5 NOS]


Space for rough work

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Code E 2014 A

135. Arrange the following carbanions in increasing order of their stability

Cs-E-x' ny
J v' '-a.
(CH3)3C-, Cl3C-, (CH3)2CH-, C6H5CH2(1) (CH3)2CH- > Cl3C- > C6H5CH2- > (CH3)3C(2) Cl3C- > C6H5CH2- > (CH3)2CH- > (CH3)3C(3) (CH3)3C- > (CH3)2CH- > C6H5CH2- > Cl3C(4) C6H5CH2- > Cl3 C- > (CH3)3C- > (CH3)2CHKMnO4
136. (CH3)2C = CH2 A
+ CO2 + H2O

H+
KMnO4
CH3 - CH

= CH - CH3 2 B

H+

A and B are in the above reactions are

j ux A,
B '
(1) A = CH3CHO, B = CH3COCH3
(2) A = CH3COCH3, B = CH3CHO
(3) A = CH3COOH, B = CH3COCH3
(4) A = CH3COCH3, B = CH3COOH
Space for rough work

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Code E 2014 A

1) DIBAL - H
137. CH3(CH2)9COOC2H5 X
2) H2O
'X' in the above reaction is

(1) CH3(CH2)9CHO

j u
'X' C
(2) CH3(CH2)9COOH

(4) CH3(CH2)9OC3H7
(3) CH3(CH2)10OH
138. Assertion (A): The boiling points of the cis - isomers are higher than those of
corresponding trans isomers.

EPa (A): - %-u- 'p-- n',


-C vq - %-u- \.
Reason (R): The boiling points of isomeric compounds depend upon
dipole - dipole interactions.

(R): %-u- 'p- n' Cyv' Cyv' -{--j -- .


Thecorrectansweris j
(1) Both (A) and (R) are correct, (R) is the correct explanation of (A).

j-N,
(R) j
(A), (R)

(A)

N-.

(2) Both (A) and (R) are correct, (R) is not the correct explanation of (A).
(A),(R) j-N, (A) (R)

j
N-

'.
(3) (A) is correct, but (R) is not correct.
(A) jC,

F
(R) jC '.

(4) (A) is not correct, but (R) is correct.

(A) jC

',F
(R) jC.
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Code E 2014 A

139. The reactivity in SN2 reactions follows the order

ux u-Q '-J v'


SN2

(1) C6H5C(CH3)(C6H5)Br

>

C6H5CH(C6H5)Br

>

C6H5CH(CH3)Br

>

<

C6H5CH(C6H5)Br

<

C6H5CH(CH3)Br

<

C6H5CH2Br
(2) C6H5C(CH3)(C6H5)Br
C6H5CH2Br
(3) C6H5CH2Br < C6H5C(CH3)(C6H5)Br < C6H5CH(C6H5)Br < C6H5CH(CH3)Br
(4) C6H5CH2Br >

C6H5C(CH3)(C6H5)Br

>

C6H5CH(C6H5)Br

>

C6H5CH(CH3)Br
OH
Br2
1
4
0
.

Br2 in CS2
A + B
273 K

A, B, C in the above reaction are respectively

A C
H
, '
(1)
B
,
H

O
H
B
r
,

O
Br

O
H

B
r
O
H

( H
2
)
B
r

OH
O
Br

Br ,

Br

O
H
(
3

Br ,

O
H
Br

(4)

Br

Br ,

,
Br

Space for rough work

46

Br
Br

Br
Br

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Code E 2014 A

OH
H

1
4
1
.

NaOH A 1) CO B + (CH CO) O+ C + CH COOH

+2

2) H

The use of C in the series of above reactions is

juv C N'-
j-
(yE-J) (2) non - narcotic analgesic

\- EJ
(3) both 1 & 2
1, 2
(4) Tranquilizer
vyj-
(1) antipyretic

142. CH3CH2 - CH = NOH + (CH3 - CO)2O X + 2 CH3COOH

C2H5NH2 + CHCl3 + 3 KOH Y + 3 KCl + 3 H2O


Where 'X' and 'Y'
\ 'X', 'Y'
are
(1) Geometrical Isomers
(2) Functional Isomers
(3) Chain Isomers
(4) Optical Isomers
143. The element not present in saccharin is

-J-
E

'
~v
%-u'
-v-'-'-
%-u-'
%
%-u-

'
% %(1) P

u-'
(2) S

(3) N
Space for rough work

47

(4) O

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Code E 2014 A

144. n X (X)n L-'-K-

Polymerisation
n X + n 1, 3 buta diene (Y)n
n X + n 1, 3

'uj

(Y)n
(X)n is used to make toys and TV cabinets.
(X)n E

'h-',L-N-G---''
'E --T-h'.
(Y)n is used as foot wear component.
(Y)n E

pN K --T-h'.
Where 'X' is
\ 'X'
C
(1) Polystyrene
M-kd-K (2)Vinylchloride Nj
xj
(3) Acrylonitrile
wj--j-wj
(4)
Styrene
kdK
145. Correct statements among the following is

j uu'
a) Glucose on reaction with bromine water gives gluconic acid.

x vN' u J
'x-E xEo 'hC.
b) Glucose or gluconic acid on oxidation with HNO3 both yield saccharic acid.

x 'x-E xEo
HNO3
q-- h -J

'x 'hC.
c) - form of glucose is obtained by the crystallisation from concentrated
solution of glucose at 303 K.
303K l

x v-Eo p-- h
- x
'hC.
d) - form of glucose is obtained by the crystallisation of hot and saturated
aqueous glucose solution at 423 K.
423 K lo%hx v-Eo

p--- h
x
'hC.
(1) a, b, d

(2) b, c, d

(3) a, b, c

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48

(4) a, b, c, d

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Code E 2014 A

146. The total number of nodes of 5s, 5p, 5d are respectively

h
u'-
(1) 4, 4, 4
(3) 0, 1, 2
5s, 5p, 5d

(2) 5, 4, 3
(4) 5, 5, 5

147. Be and Al exhibit many properties which are similar. But the two elements differ in

tx -u-' v-Jz'h-o. F ' -' N-'


N-Ch-'
Be, Al

(1) Exhibiting maximum covalency in the compounds

't--x Je
---' v-Jz N'
(2) Formation of covalent halides

'---F' j--'
p-J N-'
(3) Formation of Polymeric hydrides

--M'-Jjwj--'pJN-'
(4) Exhibiting amphoteric nature in their oxides

j q'x Cyy-Eo v-Jz N-'


148. During the formation of N2+ from N2 , the electron to be removed from the
orbital is
N2 '* N2+ p--p',

Js'*-

ZE-T--
(1)

(3)

(2)*

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49

(4)*

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Code E 2014 A

149. In an octahedral structure, the pair of d - orbitals involved in d2sp3 hybridisation


is

d--&' uN'A o Et-


d2sp3 K---
_
d- Jsx

(1) dxy, dyz

(2) dx2 - y2, dz2

(3) dzx, dz2

(4) dxy, dx2 - y2

150. Disproportionation reaction is given by

-'-
u' aC
(1) H2O2
(2) P4 in alkaline medium

~---

P4

(3) S8 in alkaline medium

~--

S8

(4) All the above

jFo

a
151. Z = 1 - represents compressibility factor
RTV
a
Z
=
1
-

J-n-'x'-'Eo *-'h-

RTV

(1) at very low pressure

up'-

uC
g-v l (3) at moderate pressure

CJ ' l
(4) at high pressure
C
' l
(2) at very high temperature

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Code E 2014 A

152. For a 0.24 m aqueous solution of a weak acid HX (The degree of dissociation =
0.6), the freezing point is (Kf = 1.85 K mol-1 kg)
HX 0.24m -' 'x v

\ N'- Bv 0.6

, v 'F
-1
n (Kf = 1.85 K
.v.)
(1) -0.71 C

(2) +0.71 C

(3) -0.84 C

(4) +0.84 C

153. An aqueous solution of Cupreous chloride is electrolysed between Copper anode


and Platinum cathode. The products formed at anode and cathode are respectively

uv xj -v--Eo ,
x - 'u N'u-Cy-x- C'.
, l p
p-o' '-
(1) Cu, Cl2

(2) Cl2, Cu

(3) Cu+2, Cu

(4) Cl2, H2

154. The types of hybridisation exhibited by the central metal atom or ion present in
[Co(NH3)6]+3, [CoF6]-3, [Ni(CO)4] and [Ni(CN)4]-2 are respectively
[Co(NH3)6]+3, [CoF6]-3, [Ni(CO)4], [Ni(CN)4]-

-'
v-Jz
-K-- ' '

(1) d2sp3, sp3d2, sp3, dsp2

(2) sp3d3, d2sp3, dsp2, sp3

(3) d2sp3, sp3d2, sp3, sp3

(4) sp3d2, d2sp3, dsp2, dsp2

155. The conductivity of a saturated solution of AgCl is 3.6 10-6 ohm-1 cm-1 and
its equivalent conductance is 1.8 ohm-1 cm2 equiv-1. The Ksp of AgCl is
AgCl %h v -y 3.6 101

,E 'u -y
-1
2
-1
1.8 ' .O'. 'u

' 1

.O'

AgCl Ksp
(1) 6 10-6

(2) 4 10-6

(3) 5 10-8

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51

(4) 4 10-8

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Code E 2014 A

156. Organic conducting polymer(s) among the following is/are

C -
s -M-'-(')
(1) Poly aniline

M-

EM
(2) Poly pyrrole
v

(3) Poly thiophene

-'
(4) All the above

jFo

157. In the cubic crystal of CsCl (d = 3.97 g/cm3) the 8 corners are occupied by
chloride ions, the centre of body is occupied by Caesium ion. The neighbouring
distance between Cs+ and Cl- ions in Ao units is
(Atomic mass of Cs = 139.91 & Cl = 35.45)
3

p- 8 -x (d = 3.97 v/ .O'.
xj 'x, "-' vEo
''v-N'-. _- o
Cs+, Cl- x 'u
CsCl '

(1) 7.14 Ao

(2) 3.57 Ao

(3) 4.13 Ao

(4) 8.26 Ao

158. A first order reaction is 50% complete in 30 minutes at 300 K and 10 minutes at
320 K. The energy of activation for the reaction is

v' v u 30 EN'-x 50]


h-C. u
320K l
10 EN'x -C.
u h-> h h
300K l

(1) 43.85 KJ mol-1

(2) 43.85 J mol-1

(3) 23.1 KJ mol-1

(4) 69.3 J mol-1

Space for rough work

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Code E 2014 A

159. When - D glucose is dissolved in water, 63.6% of glucose is converted into

- D glucose. Kc for the muta rotation is

-D x-E F L---p'

63.6]

-D x- JC.

Jhv' Kc
N'
(1) 3.64
(2) 0.572 (3)
1.747
(4) It is impossible to find Kc value
Kc N'-'

'-\-
u- '
160. Matchthefollowing:(CE --:)
List-1(d - 1)
List -2(d 2)
(A) BF3

(I) Conjugate acid of OHOH-

V-

'x
(B) NH3

(II) Conjugate base of OH-

V-
~
OH-

(C) H2O

(III) Lewis acid

'x
(D) O-2

(IV) Bronsted base & Lewis base

v-d~
&

~
(V) Lewis acid & Bronsted acid

'x

& v-

d'x
Correct match is

(1) III V
(3) III

II

(2) II

V IV

(4) III IV I
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III IV

D
II
II

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