Professional Documents
Culture Documents
Poonyapa Phansokk
597 02497 21
Narita Chanthon
597 14644 21
Thanawat Anantamongkolchai
597 01851 21
1
Process
Catalyst
Introduction
PTA
5%
Fiber
30%
PET
65%
Film
PTA
Process
Overall Process
Oxidation
Hydrogenation
PTACTA
TA
4-CBA
P-TA
Purification Process
http://eiadoc.onep.go.th/eialibrary/cd-001325-1.pdf/Figure/F232.pdf
Catalyst
Reaction
Hydrogenation of 4-CBA
Condition
CTA is puried by
hydrogenation in water at
270280 C under hydrogen
(5 bar) over a granular 0.5
wt.% Pd/C catalyst in a
trickle-bed reactor. Life of
PTA catalysts in industrial
Hydrogenation is a chemical reaction between plants is relatively short
molecular hydrogen (H2) and another compound short (6-18 months,
or element, usually in the presence of a catalyst depending on plant
such as nickel, palladium or platinum.
operation and catalyst
properties)
10
Reaction
0.5 % Pd/C Catalyst for PTA have been investigated by
Activity tests
Physical Techniques
-
SEM-EDS
CO chemisorption
XRD (X-ray powder diffraction)
OR
12
TEM images of
Pd/C catalyst.
Size distribution of
Pd particles obtained
from Pd/C catalyst.
13
Conclusion
The results show that The conversion rate of 4-CBA nearly reaches 100% under
reaction temperature of 278 C, H2 partial pressure of 0.5 MPa and reaction time
of 1 h. The catalyst remains nearly stable after five consecutive hydropurification
tests. The concentration of ternary surfactants (Brij 35-Tween 80-CTAB) at 0.67 g/L
provides the highest catalyst performance.
14