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Specific gravity
Solution gas-oil ratio
Density of oil
Bubble point pressure
Formation volume factor
Isothermal compressibility
Viscosity
Solution Gas-Oil Ratio, RSO
Definition: volume of gas per unit volume of
crude oil produced under standard conditions
Pressure path
in reservoir
Separator
Solution Gas-Oil Ratio, RSO
Solubility ~ f(T,P,composition of gas and
oil)
-T
-P
- Similarity between oil and gas
- infinitely soluble
A
Density of Oil Under Reservoir Conditions
(o)
Importance: Often required in various reservoir
related calculations.
Calculation of o:
- From composition, with only C3+ compounds
- From composition, with C1, C2, C3+ compounds
- If composition is unknow (from porperties
measured under surface conditions)
Ideal Solution Principles
Ideal liquid solution: A hypothetical mixture of
liquids in which there is no special force of attraction
between the components of the solution and for
which no change in internal energy occurs on
mixing.
Assumption: nothing happens during mixing except
dilution (no shrinkage, no expansion, no heat
generation, no reaction etc.)
Vt = V1+V2
Mt= M1+M2
= Mt / Vt
Ex. 2.7: Use ideal-solution principles to calculate
the density at 14.7 psia and 60 deg F of a
hydrocarbon liquid of the following composition.
Comp xi MWi xiMWi SC,i Liq V at sc
C3 0.2 44.09 8.82 31.66 0.2786
C4 0.3 58.12 17.43 35.78 0.4871
C5 0.5 72.15 36.1 38.51 0.9374
62.35 1.703
1. Calculate mass
2. Calculate V
3. sc= 62.35/1.703=36.61
Correction at high P (Compression)
d d= -sc
lb / cu ft =d + sc
sc (lb / cu ft)
Correction at high T (Thermal Expansion)
d d= sc-
lb / cu ft = sc- d
sc (lb / cu ft)
Ex. 2.8: what are the density of the oil in Ex. 2.7
under reservoir condition of 2000 psia and
180F.
Comp MF MW xiMWi SC Liq V at sc
C3 0.2 44.09 8.82 31.66 0.2786
C4 0.3 58.12 17.43 35.78 0.4871
C5 0.5 72.15 36.1 38.51 0.9374
62.35 1.703
1. sc= 62.35/1.703=36.61
d d= -sc
lb / cu ft =d + sc
Chart #15
sc (lb / cu ft)
Correction at high T (Thermal Expansion)
d d= sc-
lb / cu ft = sc- d
xM i
(122.1748 7.3897) lb/mole
i
2. Density of C
+
3
i 3
n
52.34 lb/cu ft
xi M i
2.193 cu ft/mole
i 3 i
x2 M 2 (1.9425) lb/mole(100)
3. wt% of C2 in C +
2 n
1.66%
xM
(122.1748-5.4472) lb/mole
i i
i 2
o ob exp[co ( p pb )]
o : oil density at desired pressure
ob : oil density at bubble pressure
co : a constant determined at the average
pressure of p and p b (bubble pressure)
Bubble Point Pressure
You need:
Gas-oil ratio
Gas gravity
Tank oil gravity
Temperature
Chart #21
Formation Volume Factor BO
Definition (FVF, BO):
Vr: Volume of oil at reservoir T and P
Vr Vsc: Volume of oil at standard condition
Bo (14.7 psia and 60F)
Vsc Units: barrels of oil at reservoir conditions
per barrel of stock-tank oil (res bbl/STB),
always at 60F
BO > 1
- temperature high in reservoir
- Gas is dissolved in oil under reservoir conditions.
Shrinkage factor: 1/Bo
Formation Volume Factor, Bo
Solution:
450 res cc
Bo 1.38
327 ST cc
Estimation of Bo Using Correlation
for p pb : where,
g .5
F Rso ( ) 1.25T
Bo 0.972 0.000147 F 1.175 o
141.5
o oil specific gravity =
131.5 o , API
T temperature, F
for p pb :
Bo Bob exp[co ( pb p )]