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Group members:
Muhammad Syahmi Bin Shafidin (161312086)
Ashrul Afiq Bin Azman (161312074)
Ahmad Afzarullah Shah Bin Ab Razak (161312072)
Nik Muhamad Haziq Shahirin Bin Nik Hassan Basri (161312432)
Table of Content
Introduction to Composite Materials..........................................................................................2
Various types of Composites Materials...................................................................................3
Classification of composites...................................................................................................5
Reinforced Plastics......................................................................................................................6
Properties of Reinforced Plastics.........................................................................................10
Application of Reinforced Plastics.......................................................................................13
Metal Matrix Composites.........................................................................................................13
Mechanical Properties of Metal matrix composites............................................................15
Ceramic-Matrix Composite......................................................................................................16
Common ceramic matrix composites in industrial application............................................19
Applications of ceramic matrix composite..........................................................................23
In contrast to metallic alloys, each material retains its separate chemical, physical, and
mechanical properties. the two constituents are a reinforcement and a matrix.
In most cases, the reinforcement is harder, stronger, and stiffer than the matrix.
in all directions. they may be spherical, platelets, or any other regular or irregular
geometry.
Particulate composites tend to be much weaker and less stiff than continuous
Matrices
Polymer
Ceramic
Metal
Thermosets
Alloys
Aluminiums)
(Epoxy,
,Polyester)_))(Steels,
,
Carbon
and
Graphite
Glass
Ceramics
(Semi
conductors,
Cermets)
Thermoplastics
(Polystyrene,Nylons)ns
Cements
Reinforcements
Fibres
WhiskersLaminar
Particulates
FlakesFilled
Microspheres
Short
Singlecrystals
Long
Plies
Threads
Organic
Inorganic
The arrangement of the reinforcement (distribution, size, shape, and orientation matters).
and
arrangement of the reinforcement will determine the properties of the composites material and
its anisotropy.
Classification of composites
Matrices:
o
Organic Matrix Composites (OMCs)
Polymer Matrix Composites (PMCs)
o
Carboncarbon Composites
Metal Matrix Composites (MMCs)
o
Ceramic Matrix Composites (CMCs)
o
Reinforcements:
o
Fibres reinforced composites
o
Laminates composites
o
Particulate composites
Advantages
Disadvantages
Reinforced Plastics
STRUCTURE OF REINFORCED PLASTICS
Known as polymer matrix composites (PMC) and fiber reinforced plastics (FRP) it has
fiber in polymer matrix. The fiber are strong and stiff, it has specific strength (knows as
strength to weight ratio) and specific stiffness(stiffness to weight ratio).Reinforced plastics
structure have increase gradually from fatigue resistance, and higher toughness and creep
resistance than those made of unreinforced plastics. Fibers in reinforced plastics, have little
structural value, they are stiff in their longitudinal direction but have no transverse stiffness or
strength. Although polymer matrix less strong and less stiffness then fiber, but it is tougher
and inert to any chemically reactions. Therefore reinforced plastic are combination of this two
advantages in the compound, fiber percentage in reinforced plastic usually ranged between
10% to 60%.
REINFORCING FIBERS
Glass, carbon, ceramics, aramids and boron are the most common reinforcing fibers.
Glass are high strength, low stiffness, high density, low cost and commonly use. Carbon are
highly in modulus or high in strength, low cost,less density than glass. Aramids is very high in
strength to weight ratio of all fibers mostly use to make bullet proof kevlar.
MATRIX MATERIALS
Thermosets such as epoxy and polyester with the former most commonly used.
Thermoplastics such as polyetheretherketone are tougher than thermosets, but lower
resistance to the temperature.
GLASS FIBERS
It is widely use, due to low cost material from others fibers. Called as glass fiber reinforce
plastics (GFRP) contain between 30% to 60% glass fibers. It is produce by drawing the
molten glass into the small opening of platinum die. Then it is elongated, cooled and wound
on a roll. The glass fibers then treated with silane (known as silicon hydride).
CARBON FIBERS
Carbon fibers are much more expensive than glass fibers.It has a combination of low
density,high strength and high stiffness.The composite is called carbon-fiber reinforced
plastics (CFRP).Te difference between carbon and graphite is Carbon fiber are 90% carbon
while graphite are more than 99% carbon.Carbon fibers contain amorphous carbon and
graphite. Which are amorphous carbon (non-crystalline) and graphite (crystalline).These fiber
are classifies by their elastic modulus,which ranges from 35 to 800 GPa, as
low,intermediate,high and very high modulus.All carbon fibers are made by pyrolysis of
organic precursors,commonly (polyacrylonitrile) due to it low in cost.Also Rayon and Pitch
that are residue from petroleum refining of catalytic crackers.Pyrolysis process which are
inducing chemical changes by heat for instance, by burning a length of yarn and causing the
material to carbonize and become black in color.With polyacrylonitrile the fiber are partially
cross linked at the moderate temperature to prevent melting,and are simultaneously
elongated.At the stage,the fibers are carburized and exposed to elevated the temperature to
expel the hydrogen and nitrogen from polyacrylonitrile.The temperature for carbonizing range
up to 1500 degree celcius, for graphitizing the temperature up to 3000 degree celcius.
meter on a 7 micro meter diameter of graphite fiber core with the process known as
continuous electroplating .This kind of product are mostly use for electromagnetic and radio
frequency shielding and lightning-strike protection.
CERAMIC FIBERS
This material are really useful for high-temperature applications and in metal matrix
composites.These kind of fibers have low elongation,low thermal conductivity but it is a good
chemical resistance or inert chemically.This compound are made up of alumina,silica, and
boric oxide to produce ceramics fibers known as nextel.
POLYMER FIBERS
Polymer fibers may be made of nylon, rayon, acrylics, or aramids; the most common are
aramid fibers. Aramids such as Kevlar, are among the toughest fibers and have very high
specific strength. Aramids can undergo some plastic deformation prior to fracture and, hence,
have higher toughness than brittle fibers. However, aramids absorb moisture (hygroscopic),
thus degrading their properties and complicating their application. Another high-performance
polyethylene fiber is Spectra. It has an ultra-high molecular weight and high molecular-chain
orientation. Spectra, a bright white polyethylene, has better abrasion resistance and flexuralfatigue resistance than aramid fibers at a similar cost. In addition, because of its lower density
(970 kg/m3), it has a higher specific strength and specific stiffness than aramid fibers.
However, a low melting point and poor adhesion characteristics as compared to other
polymers are its major limitations to applications. Polymer fibers are made by two processes:
melt spinning and dry spinning. Melt spinning involves extruding a liquid polymer through
small holes in a die (spinnerets). The fibers are then cooled before being gathered and wound
onto bobbins. The fibers may be stretched to further orient and strengthen the polymer. In dry
spinning, the polymer is dissolved in a liquid solution to form a partially oriented liquidcrystal form. As the polymer passes through the spinnerette, it is oriented further, and at this
point, the fibers are washed, dried, and wound. Aramids are oriented in solution and are
oriented fully when they pass through the spinnerette and therefore, do not need to be drawn
any further.
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BORON FIBERS
These fibers consist of boron deposited (by chemical vapor-deposition techniques) onto
tungsten fibers. Boron also can be deposited onto carbon fibers. Boron fibers have desirable
properties, such as high strength and stiffness, both in tension and in compression, and
resistance to high temperatures. However, because of the high density of tungsten, they are
heavy and also are expensive.
OTHER FIBERS
Other fibers used in composites are silicon carbide, silicon nitride, aluminum oxide,
sapphire, steel, tungsten, molybdenum, boron carbide, boron nitride, and tantalum carbide.
Whiskers also are used as reinforcing fibers. Whiskers are tiny needle-like single crystals that
grow to 1 to 10 m in diameter, with high aspect ratios (the ratio of fiber length to its
diameter) ranging from 100 to 15,000. Because of their small size, either whiskers are free of
imperfections, or the imperfections they contain do not significantly affect their strength,
which approaches the theoretical strength of the material (size effect). The elastic moduli of
whiskers range between 400 and 700 GPa, and their tensile strength is on the order of 15 to 20
GPa, although this varies with the material.
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continuous rotving (slightly twisted strands) fibers, woven fabric (similar to cloth), yarn
(twisted strands), and mats of various combinations. Various hybrid yarns also are available
Matrix Materials
The matrix in reinforced plastics has three principal functions:
Support the fibers in place and transfer the stresses to them so that the fibers can carry
most of the load.
Protect the fibers against physical damage and the environment.
Reduce the propagation of cracks in the composite by virtue of the greater ductility and
toughness of the plastic matrix.
Matrix materials are usually therrnoplastics or thermosets and commonly consist of epoxy,
polyester, phenolic, fluorocarbon, polyethersulfone, or silicon. The most commonly used are
the epoxies (80% of all reinforced plastics) and the polyesters (less expensive than the
epoxies). Polyimides, which resist exposure to temperatures in excess of 300C, continue to
be developed for use as a matrix with carbon fibers.
better adhesion between them improves the overall strength of the composite. Generally, the
highest stiffness and strength in reinforced plastics are obtained when the fibers are aligned in
the direction of the tension force. The composite is then highly anisotropic. It has properties,
such as strength and stiffness, that depend on direction. As a result, other properties, such as
stiffness, creep resistance, thermal and electrical conductivity, and thermal expansion, also are
anisotropic. The transverse properties of such a unidirectionally reinforced structure are much
lower than the longitudinal properties. For example, note how strong fiber-reinforced
packaging tape is when pulled in tension, yet how easily it can split when pulling in the width
direction. Because it is an engineered material, a reinforced plastic part can be given an
optimal configuration for a specific service condition. Also, a composite flywheel rotor has
been produced using a special weaving technique in which the reinforcing fibers (Eglass) are
aligned in the radial direction as well as in the hoop direction. Designed for mechanicalenergy storage systems in low-emission electric and hybrid vehicles, the flywheel can operate
at speeds up to 50,000 rpm.
Strength and Elastic Modulus of Reinforced Plastics
The strength and elastic modulus of a reinforced plastic with unidirectional fibers can be
determined in terms of the strengths and moduli of the fibers and matrix and in terms of the
volume fraction of fibers in the composite. In the following equations, c refers to the
composite, f to the fiber, and fn to the matrix. The total load, Pc, on the composite is shared
by the fiber (Pf) and the matrix (Pm). Thus,
(9.1)
which can be written as
(9.2)
where Ac, Af, and Am are the cross-sectional areas of the composite, the fiber, and the matrix,
respectively; thus, Ac = Af + Am. Lets now denote x as the area fraction of the fibers in the
composite. Then Equation can be written as follows because the x also represents the volume
fraction and the fibers are uniformly longitudinal in the matrix
(9.3)
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The fraction of the total load carried by the fibers now can be calculated. First, note that in the
composite under a tensile load, the strains sustained by the fibers and the matrix are the same
(that is, ec = ef = em).
Consequently,
(9.4)
Since the relevant quantities for a specific situation are known, by using Eq. (9.1),the fraction
Pf/PC can be found. Then, using the foregoing relationships, the elastic modulus, Ec, of the
composite can be calculated by replacing 0 in Eq. (9.3) with E.
Thus,
(9.5)
( The figure above shows the tensile strength of glass-reinforced polyester as a function of
fiber contentand fiber direction in the matrix. )
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And the A380 jumbo jet with 700 passengers capacity, has horizontal
stabilizers,ailerons,wing boxes and leading edges,secondary mounting brackets of the
fuselage,and a deck structure made of composites with carbon fibers,thermosetting resins, and
thermoplastics,the upper fuselage is made of alternating layers of aluminum and glass fiber
reinforced so most of the part are compositely build part.
Also a very famous cold war stealth bomber aircraft is made of composites, consist of
carbon and glass fiber,epoxy resins matrices, high temperature polyimides, and other
advanced materials.Mostly the military advanced weapon are using the composite in order to
enhanced the mobility and other advantages on the weapon to make it reliable.Such as
development of U.S Navy for small,all composite ship or attack boat capable of speeds up to
93KM/H
Metal matrix composite (MMC) is composite material with at least two constituent
parts, one being a metal necessarily, the other material may be a different metal or
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Example of MMC
BRAKE CALIPERS :
Traditional brake calipers are made from iron and can weigh around 3kg in a small car
very constrained.
Now, new brake calipers were designed using an aluminium alloy reinforced with
precast composite inserts using continuous ceramic fiber.
Property Aluminium
fiber
Tensile Strength 3.1 GPa
Elastic Modulus 380 GPa
Density 3.9 g/cm3
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Mechanical Properties of
Metal matrix composites
Higher elastic modulus
Higher strength
Higher ductility
Higher resistance to elevated
temperatures
ADVANTAGES
Higher temperature capability
Fire resistance
Higher transverse stiffness and
DISADVANTAGES
Higher cost of some material systems
Relatively immature technology
Complex systems
strength
No moisture absorption
Higher electrical and thermal
conductivity
Better radiation resistance
Ceramic-Matrix Composite
Introduction To Ceramic
Ceramic is an inorganic, nonmetallic solid material comprising metal, nonmetal or
metalloid atoms primarily held in ionic and covalent bonds. Large number of possible
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combinations of elements makes a wide variety of ceramics available for a broad range of
consumer and industrial applications.
Back then before 4000 B.C, ceramics used in pottery and bricks. The important of
ceramics rose due to time in various field such as in tool and die materials, heat engines, and
automotive components, such as exhaust-port liners, automotive spark plugs, coated pistons,
and cylinder lines.
Two general properties of ceramics :
o Traditional Ceramics
Whiteware, tiles, brick, sewer pipe, pottery, and abrasive wheels
o Industrial Ceramics ( engineering, high-tech, or fine ceramics )
Automotive, turbine, structural, and aerospace components, heat exchangers,
semiconductors, seals, prosthetics, and cutting tools
The structure of ceramic crystals, containing various atoms of different sizes, is among
the most complex of all material structures. Consequently, properties such as hardness and
thermal and electrical resistance are significantly higher in ceramics than in metals.
Ceramics are available in single-crystal or in polycrystalline form. Varying
crystallinity and electron consumption in the ionic and covalent bonds cause most ceramic
materials to be good thermal and electrical insulators. Ceramic provide strength at high
temperature well above and have considerable oxidation resistance.
The fact that ceramics exhibit limited plasticity makes it a major drawback in
applications. This low strain capability of ceramics is of major concern, as it, quite often,
leads to catastrophic failure. Therefore, ceramics are not considered dependable as structural
material. Such limitation can be prevented with ceramic matrix composites, as a suitable
reinforcements would help them to achieve desirable mechanical properties including
toughness.
Introduction to Ceramic-Matrix Composites (CMC)
Ceramic matrix composites (CMCs) are a subgroup of composite materials as well as a
subgroup of technical ceramics. Ceramic products made for technical application are called
technical ceramic. They consist of ceramic fibres embedded in a ceramic matrix, thus forming
a ceramic fibre reinforced ceramic material.
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The most popular trade mark of SiC fibers: Hi-Nicalon, Nicalon S, Sylramic, Tyranno.
The properties of carbon fibers:
Carbon fibres are also commonly known as graphite fibres, although there are some basic
differences between the two types. Graphitization takes place at a much higher temperature
compared to the temperature at which carbonization takes place. The carbon content in the
graphite fibre is also higher and is usually more than 99%.
Low oxidation resistance is the main drawback of carbon fibers, which oxidize when
exposed in air at temperatures exceeding 932F (500C).
The most popular trademarks of carbon fibers: BP Amoco, Conoco, Grafil, Granoc, Toho,
Toray, Zoltek.
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The main disadvantages of alumina fibers are relatively low creep resistance caused by grain
growth at high temperatures and relatively high density.
21
Mechanical properties of ceramic fibres are quite different from monolithic ceramics
when embedded in ceramic matrix composite due to act of reinforcement fibers, which act so
that the mechanical stress received by the matrix is transferred to the fiber, increasing the
flexural resistance and fracture toughness. For example, the fracture toughness and thermal
shock resistance of the composites are superior when compared to monolithic materials.
The properties of ceramic matrix composites (CMC) can easily be adapted, varying,
for example, the architecture of the fibers, fiber types, interface layers of materials and
thickness of composites. Due to the efficiency of the chemical vapor infiltration (CVI)
process to fill between the fibers, and the purity and crystallinity of the matrix material, it is
expected that the mechanical properties of composites obtained by CVI are better than those
of composites obtained by other techniques. The average flexural strength of SiC composite
with Nicalon fiber obtained by different methods is 300 MPa with a fracture toughness of 15
1
MPa.m 2 .
Physical and Chemical Properties
Silicon carbide reinforced silicon carbide have lower density, higher temperature capability,
and lower thermal expansion compare to metallic superalloys.
The composite also possess higher oxidative durability, more predictable life, and lower
permeability.
yarns)
multi-directional structure (3D, 4D, 5D, and so on)
Mechanical Properties
High toughness, elasticity and mechanical strength.
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C/C composites can be used safely, as the fractures do not propagate rapidly in
their composite due to high strength, flexural resistance, and resistance to
Figure 3 - The PFC Patented Continuous Fiber Carbon-Carbon Disc is specially made
by taking a continuous fibre that is wound into the disc shape
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Figure 4 - Metal turbine made of silicon carbide fibre reinforced silicon carbide matrix
Figure 5 - 3M Type 203 Nextel fibre-reinforced Silicon Carbide (SiC) matrix ceramic composite
candle filter
Figure 6 -Ceramic matrix composite rocket nozzle liner designed and fabricated at Teledyne
Scientific Company
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