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SPECIAL REPORT
December 1997
Abstract: This project was conducted to assist in predicting the effects of freezethaw cycling on stabilized
hazardous waste material during the 199697 freezing season. The Raymark Superfund site in Stratford,
Connecticut, is under remediation with the intent of
using the area for commercial development. The site
was classified as a Superfund site in 1995. The onsite soil contains asbestos, lead, PCBs, volatile organic
compounds (VOCs), semi-VOCs, and solvents. These
contaminants are by-products of the manufacturing
process for heat-resistant automotive parts. The stabi-
Prepared for
December 1997
PREFACE
This report was prepared by Dr. Vincent C. Janoo, Research Civil Engineer, Lynette A.
Barna, Civil Engineer, and Sherri A. Orchino, Civil Engineering Technician, Civil Engineering Research Division, Research and Engineering Directorate, U.S. Army Cold Regions
Research and Engineering Laboratory, Hanover, New Hampshire. Funding was provided
by the U.S. Environmental Protection Agency (EPA) through the U.S. Army Corps of Engineers, New England District (NED).
The authors wish to acknowledge the efforts and assistance of the EPA, NEDs Geotechnical Engineering Section, Foster Wheeler Environmental Corporation, and the Stratford
Resident Office for making this project possible. The authors thank Anthony Firicano of
NED and Jeffrey Stark of CRREL for technically reviewing the manuscript of this report.
Field work is labor intensive and requires the assistance and cooperation of a team. The
authors thank the CRREL field crew who aided in gathering data during the trips to Stratford: Troy Arnold, Charles Smith, Jeffrey Stark and Anthony Wood. They also thank Kurt
Knuth, who aided in installing and monitoring the electronic collection systems.
The contents of this report are not to be used for advertising or promotional purposes.
Citation of brand names does not constitute an official endorsement or approval of the use
of such commercial products.
ii
CONTENTS
Preface ..........................................................................................................................................
Introduction .................................................................................................................................
Stabilized soil testing .................................................................................................................
Clegg impact hammer ...........................................................................................................
Dual-mass dynamic cone penetrometer .............................................................................
Temperature data and analysis .................................................................................................
Field testing data analysis .........................................................................................................
Clegg impact hammer results ..............................................................................................
DCP results .............................................................................................................................
Conclusions .................................................................................................................................
Literature cited ............................................................................................................................
Appendix A: Thermocouple temperature data ......................................................................
Appendix B: Clegg impact hammer data ................................................................................
Appendix C: DCP data ..............................................................................................................
Abstract ........................................................................................................................................
ii
1
1
3
4
5
9
9
10
10
11
13
17
23
25
ILLUSTRATIONS
Figure
1. Raymark Superfund site map ......................................................................................... 2
2. Test site grid layout ........................................................................................................... 2
3. Clegg impact hammer testing ......................................................................................... 3
4. Clegg impact values plotted against compressive strength for all soils tested ....... 3
5. Clegg impact values plotted against compressive strength and showing 95%
confidence bars ........................................................................................................... 4
6. DCP testing ........................................................................................................................ 4
7. Correlation plot of CBR vs. DCP index .......................................................................... 5
8. Example of completed DCP data sheet for the Remark Superfund site ................... 5
9. Thermocouple configuration ........................................................................................... 6
10. Datalogger installation ..................................................................................................... 6
11. Estimated frost depth ....................................................................................................... 7
12. Variability of unconfined compressive strength for December and March Clegg
data ............................................................................................................................... 8
13. Histograms showing shift in unconfined compressive strength ............................... 9
14. Comparison of mean CBR values with depth for December and March ................. 11
TABLES
Table
1. Summary of temperature data recorded at thermocouple sites ................................. 6
2. Summary of maximum frost penetration at all thermocouple sites .......................... 9
3. Summary of Clegg hammer results for unconfined compressive strength .............. 10
iii
INTRODUCTION
CRREL was approached by the Geotechnical
Engineering Division of the New England District (NED), U.S. Army Corps of Engineers, to
assist in predicting the effects of freezethaw
cycling on stabilized hazardous waste material.
The stabilized waste material is being used as a
fill material below the pavement structure at the
Raymark Superfund site in Stratford, Connecticut. This report focuses on the testing methods
and results obtained from the field work.
The Raymark Superfund site is currently
under remediation with the intention of using the
reclaimed land for commercial development.
A portion of the site is planned to be used as a
parking area, and the pavement structure of the
proposed parking area will consist of a layer of
bituminous concrete over a graded gravel base.
The total pavement structure thickness will be
559 mm. The pavement structure will be either 76
mm of asphalt concrete over 483 mm of gravel
base for standard duty traffic, or 102 mm of
asphalt concrete over 457 mm of gravel base for
heavy duty traffic loads. Below the pavement layer
will be 203 mm of a common granular fill material followed by a 152-mm layer of Tilcon common granular fill.
Geosynthetic liner materials, approximately
25 mm thick, will be placed below the Tilcon material. A minimum thickness of 914 mm of materials will be placed above the geosynthetic liner
materials. Below the geosynthetic liner materials
is a 203-mm sand gas collection layer. The undermost layer is the waste material, which is a mixture of on-site soil combined with hazardous
waste that was produced on site. Asbestos, lead,
PCBs, volatile organic compounds (VOCs), semiVOCs, and solvents have been detected in the onsite soil. This mixture was treated with 3.5%
13+00
13+00
12+00
11+00
Area
1N
Area 3
N
10+00
9+00
Site 30
Area 6
8+00
Area 1W
Area 4E
7+00
Area 2A
Area 4W
Site 20
Area 7
6+00
Site 10
5+00
Area
2S
Area 8
4+00
Field Test
Site 3
Area 10A
Area
5A
Site 40
3+00
Area
1S
Area 6E
Field Test
Site 1 Field Test Site 2
2+00
Area 9
1+00
Thermocouples
0+00
A
1.5 m
0.3 m
15 m
1.5 m
3m
( )
7000
(psi)
1200
Soil 1 A-1-b
Soil 2 A-3
Soil 3 A-1-b
Soil 4 A-2-4
Soil 5 A-1-b
Soil 6 A-1-a
Regression
1000
6000
800
5000
4000
3000
600
400
2000
200
1000
0
0
0
50
100
Clegg-Hammer Impact Value
150
Figure 4. Clegg impact values plotted against compressive strength for all
soils tested.
3
(1)
0
0
Figure 5. Clegg impact values plotted against compressive strength and showing 95% confidence bars.
where fc is unconfined compressive strength
and CIV is the Clegg impact value.
The CIV may also be correlated to California
bearing ratio (CBR) (Yoder et al. 1991) using eq 2:
CBR = CIV 2 0.07 .
(2)
10
1
1
10
Date
Date
March 12,
12, 1997
1997
March
Soil Type(s)
Type(s)
Soil
stabilized
stabilized waste
wastematerial
material
No.
Accumulative Penetration
Penetration Penetration
Penetration Hammer
Hammer
No.
of ofAccumulative
blows penetration
penetration per
perblow
blowset
set per
perblow
blow
blow
blows
blow
(mm)
(mm)
(mm)
factor
(mm)
(mm)
(mm)
factor
(3)
(4)
(5)
(1)(1)
(2)(2)
(3)
(4)
(5)
(1)
(1)(2)
(2)(3)
(3)(4)
(4)(5)
(5)(6)
(6)(7)
(7)(8)
(8)
200
Raymark
Superfund
Raymark
SuperfundSite
Site
00
2525
5555
80
80
110
110
150
150
190
190
230
230
270
270
330
330
390
390
435
435
480
480
100
Site
3 North0+00
0+00
3 North
Location Site
Location
0 0
3 3
1010
10
10
10
10
15
15
10
1010
1010
1010
1010
10 8
8 8
8
292
DCP 1.12
CBR =
CBR (%)
CBR = 292/DCP1.12.
100
------25
25
30
30
25
25
30
30
40
40
40
40
40
40
40
40
60
60
60
60
45
45
45
45
------8.3
8.3
3.0
3.0
2.5
2.5
3.0
3.0
2.7
2.7
4.0
4.0
4.0
4.0
4.0
4.0
6.0
6.0
6.0
6.0
5.6
5.6
5.6
5.6
11
11
11
1
1
1
1
1
1
1
11
11
11
11
11
11
1
DCP
index
index
CBR
CBR
(%)
(%)
Depth
Depth
(in)
(in)
(6)
(6)
(7)
(7)
(8)
(8)
------8.3
8.3
3.0
3.0
2.5
2.5
3.0
3.0
2.7
2.7
4.0
4.0
4.0
4.0
4.0
4.0
6.0
6.0
6.0
6.0
5.6
5.6
5.6
5.6
------27
27
85
85
105
105
85
85
97
97
62
62
62
62
62
62
39
39
39
39
42
42
42
42
00
1.0
1.0
2.2
2.2
3.1
3.1
4.3
4.3
5.9
5.9
7.5
7.5
9.1
9.1
10.6
10.6
13.0
13.0
15.4
15.4
17.1
17.1
18.9
18.9
Figure 8. Example of completed DCP data sheet for the Raymark Superfund site.
in January. The data gathered from the thermocouples were used to determine whether 910 mm
of material was a sufficient thickness to prevent
frost penetration into the stabilized waste material.
At sites 10 and 20, the thermocouple strings
were installed into the Tilcon common granular
fill material. Site 30 was located in another sub-
Solar
Panel
PVC pipe
for mounting
Datalogger
3 meters
Thermocouple cables
Subbase soil or
sand material
Thermocouple rod
Thermocouple sensors
set at 230 mm intervals
Material
Date started
Tilcon
19 December 1996
Tilcon
19 December 1996
J.J. Brennan 19 December 1996
Sand
8 January 1997
Data collected up to
Total days
19 February 1997
19 February 1997
19 February 1997
19 February 1997
83
83
74*
62
230
460
690
920
Dec 18 Dec 27
Jan 6
Jan 16
Jan 26
Feb 5
Feb 15
Feb 25
230
460
690
920
Dec 18
Mar 7
Dec 27
Jan 6
Jan 16
Feb 15
Feb 25
Mar 7
Feb 5
b. Thermocouple site 20
230
460
690
920
Dec 18
Jan 26
Time (days)
Time (days)
Dec 27
Jan 6
Jan 16
Jan 26
Feb 5
Feb 15
Feb 25
230
460
690
920
Jan 8
Mar 7
Jan 16
Jan 26
Feb 5
Feb 15
Time (days)
Time (days)
Feb 25
Mar 7
kPa
1200
psi
180
December
March
160
1000
800
140
120
100
600
400
80
60
40
30 psi
limit
200
20
0
0
0
10
15
20
25
30
35
40
45
50
40
45
50
40
45
50
a. Site 1.
kPa
psi
700
4500
4000
3500
December
March
600
500
3000
400
2500
2000
1500
300
200
1000
500
0
100
0
0
10
15
20
25
30
35
2000
b. Site 2.
psi
300
December
March
250
1500
200
1000
150
100
500
50
0
0
10
15
20
25
30
35
c. Site 3.
Figure 12. Variability of unconfined compressive strength for December and March Clegg data.
8
80
December:
Mean = 71
Standard Deviation = 37
March:
Mean = 33
Standard Deviation = 16
70
60
Thermocouple
site
Frequency
50
40
10
20
30
40
30
20
10
25
172
50
345
75
517
100
689
125
861
150
1033
175
1206
psi
kPa
200
1378
a. Site 1.
45
December:
Mean = 307
Standard Deviation = 133
March:
Mean = 170
Standard Deviation = 138
40
35
30
Frequency
230
510
460
460
230
500
460
460
25
20
15
10
5
0
50
345
100 150 200 250 300 350 400 450 500 550 600
689 1034 1378 1723 2067 2412 2756 3101 3445 3790 4134
psi
kPa
b. Site 2.
60
December:
Mean = 116
Standard Deviation = 57
March:
Mean = 62
Standard Deviation = 27
50
40
Frequency
Maximum frost
penetration depth
(mm)
String A
String B
30
20
10
0
25
172
50
345
75
517
100
689
psi
kPa
a. Site 3.
Figure 13. Histograms showing shift in unconfined compressive
strength.
490
2117
800
Coefficient of
Standard deviation
variation
(kPa)
(%)
December March December March
228
1172
428
255
917
393
110
952
186
52
43
49
48
81
43
DCP results
Using previously discussed eq 1 and 2, we
determined that the unconfined compressive
strength of 30 psi is approximately equivalent to a
CBR of 10. This finding was used to determine
the lower limit of CBR 10 for the DCP data, since
DCP values are expressed in CBR. This analysis
concentrated on four depths below the surface
of the material, 150 mm, 230 mm, 305 mm, and
460 mm, to coincide with the depth of frost penetration measured at the site. For each site, a mean
CBR value was calculated at each depth. The CBR
values obtained at each sampling point were then
compared to the mean. The testing in March was
performed approximately 150 mm from the loca-
10
100
80
60
40
20
CBR 10 Limit
0
0
50
100
150
200
250
300
350
400
450
500
Depth (mm)
120
100
80
60
40
20
CBR 10 Limit
0
0
50
100
150
200
250
300
350
400
450
500
Depth (mm)
11
13
14
15
16
DECEMBER
17
Site 1
MARCH
Site 1
18
DECEMBER
19
Site 2
MARCH Site 2
20
DECEMBER
21
Site 3
MARCH
22
Site 3
Mean
Standard Error
Median
Mode
Standard Deviation
Sample Variance
Kurtosis
Skewness
Range
Minimum
Maximum
Sum
Count
Confidence Level(95.000%)
Mean
Standard Error
Median
Mode
Standard Deviation
Sample Variance
Kurtosis
Skewness
Range
Minimum
Maximum
Sum
Count
Confidence Level(95.000%)
44.15
4.50461078
39.25
39.25
25.87701888
669.6201062
0.853964902
1.041687556
109.39
3.650000001
113.04
1456.95
33
8.82886183
Mean
Standard Error
Median
Mode
Standard Deviation
Sample Variance
Kurtosis
Skewness
Range
Minimum
Maximum
Sum
Count
Confidence Level(95.0%)
9.240303031
1.101501943
6.47
6.47
6.32764691
40.03911553
3.770051247
1.819055542
28.98
1.58999999
30.5699999
304.93
33
2.158900941
57.09393939
6.125933663
48.1
48.1
35.1908097
1238.393087
0.901098603
1.106429616
146.7
9.3
156
1884.1
33
12.47810797
47.390625
5.4883847
38.4
27.2
31.046992
963.91572
7.4120506
2.61998
142.1
20.4
162.5
1516.5
32
11.193641
Mean
Standard Error
Median
Mode
Standard Deviation
Sample Variance
Kurtosis
Skewness
Range
Minimum
Maximum
Sum
Count
Confidence Level(95.000%)
23
43.05090909
4.042469626
37.5
22.15
23.22222001
539.2715023
0.034615909
0.803195649
92.8
11.84
104.64
1420.68
33
7.923083144
85.875862
12.607044
71.8
71.8
67.891009
4609.189
6.49938
307.6
23.9
331.5
2490.4
29
25.824388
Mean
Standard Error
Median
Mode
Standard Deviation
Sample Variance
Kurtosis
Range
Minimum
Maximum
Sum
Count
Confidence Level(95.000%)
Mean
Standard Error
Median
Mode
Standard Deviation
Sample Variance
Kurtosis
Skewness
Range
Minimum
Maximum
Sum
Count
Confidence Level(95.000%)
21.04757576
2.21469896
18.64
27.17
12.72247692
161.8614189
0.193894639
0.822932227
48.72
5.45
54.17
694.57
33
4.34072376
89.848485
10.720748
61.8
48.1
61.586008
3792.8363
-0.3042073
1.0689974
210.9
16.5
227.4
2965
33
21.83743
Mean
Standard Error
Median
Mode
Standard Deviation
Sample Variance
Kurtosis
Skewness
Range
Minimum
Maximum
Sum
Count
Confidence Level(95.000%)
85.72878788
11.03500524
66.45
85.31
63.39127891
4018.454242
10.02494028
336
22.15
358.15
2829.05
33
21.62818082
70.46575758
7.454179897
59.05
48.14
42.82100339
1833.638331
1.47852653
1.410152504
160.5
24.92
185.42
2325.37
33
14.6099025
Mean
Standard Error
Median
Mode
Standard Deviation
Sample Variance
Kurtosis
Skewness
Range
Minimum
Maximum
Sum
Count
Confidence Level(95.0%)
24
71.57272727
9.633989578
59
48.1
55.34305666
3062.85392
23.87339084
4.580572038
320.7
37.5
358.2
2361.9
33
19.62377799
118.265
15.259899
107.35
185.4
80.747798
6520.2069
0.9343503
0.9649896
329.5
19.9
349.4
3311.42
28
29.908809
Mean
Standard Error
Median
Mode
Standard Deviation
Sample Variance
Kurtosis
Skewness
Range
Minimum
Maximum
Sum
Count
Confidence Level(95.000%)
74.79969697
11.27557378
61.81
61.81
64.77323996
4195.572616
12.74844194
3.442423925
333.23
24.92
358.15
2468.39
33
22.09968579
101.27917
15.354489
80.55
59
75.221325
5658.2478
3.9727061
1.9148318
312.7
17.3
330
2430.7
24
31.763137
Mean
Standard Error
Median
Mode
Standard Deviation
Sample Variance
Kurtosis
Skewness
Range
Minimum
Maximum
Sum
Count
Confidence Level(95.000%)
25
92.53548387
11.37722444
71.78
104.64
63.34570477
4012.678312
2.29775190
1.453996854
264.829999
27.17
292
2868.6
31
22.29891712
Form Approved
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2. REPORT DATE
December 1997
4. TITLE AND SUBTITLE
5. FUNDING NUMBERS
8. PERFORMING ORGANIZATION
REPORT NUMBER
10. SPONSORING/MONITORING
AGENCY REPORT NUMBER
For conversion of SI units to non-SI units of measurement consult Standard Practice for Use of the
International System of Units (SI), ASTM Standard E380-93, published by the American Society for Testing and Materials,
1916 Race St., Philadelphia, Pa. 19103.
This project was conducted to assist in predicting the effects of freezethaw cycling on stabilized hazardous
waste material during the 199697 freezing season. The Raymark Superfund site in Stratford, Connecticut, is
under remediation with the intent of using the area for commercial development. The site was classified as a
Superfund site in 1995. The on-site soil contains asbestos, lead, PCBs, volatile organic compounds (VOCs), semiVOCs, and solvents. These contaminants are by-products of the manufacturing process for heat-resistant automotive parts. The stabilized waste material is being used as the subgrade material in the pavement structure.
Field testing was conducted to determine the unconfined compressive strength of the stabilized material before
and after the freezing season. Testing was completed using the Clegg impact soil tester and dynamic cone penetrometer. Additionally, thermocouples were installed to estimate the depth of frost penetration that could be
expected, and to ensure that the overlying layers in the pavement structure would be adequate to prevent frost
penetration into the stabilized layer.
Cement-stabilized materials
Flexible pavement design
17. SECURITY CLASSIFICATION
OF REPORT
UNCLASSIFIED
NSN 7540-01-280-5500
Freezethaw cycling
Pavement
UNCLASSIFIED
Subgrade
19. SECURITY CLASSIFICATION
OF ABSTRACT
UNCLASSIFIED
29
UL
Standard Form 298 (Rev. 2-89)
Prescribed by ANSI Std. Z39-18
298-102