Board Exam

Periodic assesment for board exam 2017
EXAM ON P-BLOCK ELEMENTS

F.M. 30 TIME : 1 HR
CLASS 12- (1)
_______________________________________________________________________________________________
Answer the following questions :
1. MCQ : ( any five ) 5X1
(i) The number of P-O-P bonds in cyclic metaphosphoric acid is
(a) 0 (b) 2 (c) 3 (d) 4
(ii) Which of the following substances has highest proton affinity ?
(a) H2S (b) NH3 (c) (NH4)2SO4 (d) H2O
(iii)Which of the following is strongest acid ?
(a) HF (b) HCl (c) HBr (d) HI
(iv) An example of neutral oxide is
(a) NO (b) CaO (c) CO2 (d) ZnO
(v)Nitrogen di oxide is prepared by heating
(a) lead nitrate (b) potassium nitrate (c) sodium nitrite (d) Ammonium nitrate
(vi)There is no S-S bond in
(a) S2O42- (b) S2O52- (c) S2O32-
(d) S2O72-
2.Account for the following ( any five ) 5X2

(i) R3P=O is known but R3N=O is unknown.
(ii) All the halogens are coloured
(iii) Interhalogen compounds are more reactive than the halogens which it is
formed
(iv) PCl5 can acts as chlorinating agent
(v)Xenon forms compounds with oxygen and fluorine
(vi)Reducing character of gr 15 hydrides increasing down the gr.
3. Draw the structures of ( any two ) : 2X1
(i) XeOF4 (ii) N2O4 (iii) O3
4. Answer the following : ( any ten ) 10X1
(i) what do you mean by pseudo halogen ?
(ii) write down the use of iodine
pentoxide (iii) Write down the catalyst used in Ostwald process (iv) Write down
the formula of galena (v) Write down the basicity of phosphoric and phosphorus
acid (vi) Write the structure of IF 5
(vii) Give the structure of PCl 5 in solid state
(viii) Prepare chlorine at ordinary temperature (ix) An orange coloured compound
on heating produces nitrogen . Identify the compound (x) Arrange the increasing
N-O-N bond angle : NO2 , NO2+ , NO2- (xi) Write one difference between red and
white phosphorus. (xii) Arrange the hydrides of gr 16 in the increasing order of
acidic character.
5. Write only balanced chemical reactions : 3
Subhasish 9830523086
Page 1

(a) Reaction of copper sulphate with PH3
(b) Reaction of excess ammonia with
chlorine (c) Reaction of SO2 with Cl2 in dried condition.
F.M. 30 TIME : 1 HR
CLASS 12- (1)
_______________________________________________________________________________________________
(i) The weakest acid
(a) HI (b) HBr (c) HCl (d) HF
(ii) Which of the following is linear in shape
(a) H2S (b) NH3 (c) N2O (d) H2O
(a) HOCl (b) HClO2 (c) HClO3 (d) HClO4
(iv) Lead nitrate on heating produces
(a) NO (b) NO2 (c) N2O3 (d) N2O5
(v)Nitrogen is prepared by heating
(a) lead nitrate
(b) potassium nitrate (c) Ammonium nitrite (d) Ammonium
nitrate
(vi)Which of the following acid is per acid
(a) H2SO2 (b) H2SO3 (c) H2SO4 (d) H2SO5
2.Account for the following ( any five ) 5X2
(i) Which one is stronger oxidising agent and why ?
Bi(V) and Sb(V)
(ii) SF6 is known but SH6 is nonexistent. Explain

(iii) ICl is more reactive than I2. Why ?
(iv) Iodine is insoluble in water but soluble in KI solution. Explain
(v)Most of the inert gas compounds are formed by xenon. Why ?
(vi)Hydrogen sulphide is more acidic than water. Why?
3. Draw the structures of ( any two ) : 2X1
(i) XeF4 (ii) HClO4 (iii)N2O5
(i) Arrange the halogens in the decreasing order of electron gain enthalpy (ii)
write down the formula of brown ring compound (iii) Write down the name of gas
obtained by heating ammonium nitrate (iv) Write down the use of helium gas (v)
Arrange the hydrides of group 15 in the increasing order of basic property (vi)
Write the structure of ClF3
(vii) Which one is better complexing agent ? NH 3 and
PH3 (viii) Which compound is considered as first prepared inert gas compound (ix)
A basic gas on reaction with copper sulphate produces black ppt. Identify the gas
(x) Arrange the following hydrides in increasing bond angle : H 2S , H2O , H2Te ,
H2Se (xi) Write one distinction test between ammonia and phosphine . (xii)
Arrange the hydrides of gr 15 in the increasing order of reducing character.
5. Write only balanced chemical reactions : 3
(a) Reaction of chlorine with hot conc NaOH (b) Reaction of ammonia with excess
chlorine (c) Reaction of KMnO4 with conc HCl.
Page 2

F.M. 45 TIME : 1.5 HR
CLASS 12- set : P/12/03
`
_______________________________________________________________________________________________
(i) The number of P-O-P bonds in cyclic metaphosphoric acid is
(a) 0 (b) 2 (c) 3 (d) 4
(ii) Which of the following substances has highest proton affinity ?
(a) H2S (b) NH3 (c) (NH4)2SO4 (d) H2O
(a) HF (b) HCl (c) HBr (d) HI
(iv) An example of neutral oxide is
(a) NO (b) CaO (c) CO2 (d) ZnO
(v)Nitrogen di oxide is prepared by heating
(a) lead nitrate (b) potassium nitrate (c) sodium nitrite (d) Ammonium nitrate
(vi)There is no S-S bond in
(a) S2O42- (b) S2O52- (c) S2O32-
(d) S2O72-
2.Account for the following ( any ten ) 10X2

(i) R3P=O is known but R3N=O is unknown.
(ii) All the halogens are coloured
(iii) Interhalogen compounds are more reactive than the halogens which it is
formed
(iv) PCl5 can acts as chlorinating agent
(v)Xenon forms compounds with oxygen and fluorine
(vi)Reducing character of gr 15 hydrides increasing down the gr.
(vii) Which one is stronger oxidising agent and why ?
Bi(V) and Sb(V)
(viii) SF6 is known but SH6 is nonexistent.

(ix) Iodine is insoluble in water but soluble in KI solution.
(x)Most of the inert gas compounds are formed by xenon.
(xi)Hydrogen sulphide is more acidic than water. Why?
(xii)Hydrogen fluoride can not be kept in glass bottles. Explain
Page 3
3. Draw the structures of ( any five ) : 5X1

(i) XeOF4
(ii) N2O4
(iii) O3 (iv) XeF4
(v) HClO4 (vi)N2O5

(i) what do you mean by pseudo halogen ?
(ii) write down the use of iodine pentoxide
(iii) Write down the catalyst used in Ostwald process
(iv) Write down the formula of galena
(v) Write down the basicity of phosphoric and phosphorus acid
(vi) Write the structure of IF5
(vii) Give the structure of PCl5 in solid state
(viii) Prepare chlorine at ordinary temperature
(ix) An orange coloured compound on heating produces nitrogen . Identify the
compound
(x) Arrange the increasing N-O-N bond angle : NO2 , NO2+ , NO2(xi) Write one difference between red and white phosphorus.
(xii) Arrange the hydrides of gr 16 in the increasing order of reducing character.
5. Write only balanced chemical reactions : 5X1
(a) Reaction of copper sulphate with PH3
(b) Reaction of excess ammonia with chlorine
(c) Reaction of SO2 with Cl2 in dried condition.
(d) Reaction of chlorine with hot conc NaOH
(e) Reaction of KMnO4 with conc HCl.
Page 4

F.M. 45 TIME : 1.5 HR
CLASS 12- set : P/12/04
`
_______________________________________________________________________________________________
A. MCQ : ( any five ) 5X1
1.When Cl2 gas reacts with hot and concentrated sodium hydroxide solution, the oxidation
number of chlorine changes from
A Zero to 1 and zero to +3
B Zero to + 1 and zero to 3
C Zero to + 1 and zero to 5
D Zero to 1 and zero to +5
2.In which of the following compounds, nitrogen exhibits highest oxidation state?
A N3H
B NH2OH
C N2H4
D NH3
3.Three reactions involving H2PO4- are given below
(i) H3PO4 + H2O = H3O+ + H2PO4(ii) H2PO4- + H2O = HPO42- + H3O+
(iii) H2PO4- + OH- = H3PO4 + O2In which of the above does H2PO4- act as an acid?
A (i) only
B (ii) only
C (iii) only
D (i) and (ii)
4.The correct order of increasing bond angles in the following species is
A Cl2O < ClO2 < ClO2B ClO2- < Cl2O < ClO2
C Cl2O < ClO2- < ClO2
D ClO2 < Cl2O < ClO25.The tendency of BF3, BCl3 and BBr3 to behave as Lewis acid decreases in the sequence:
A BCl3 > BF3 > BBr3
B BF3 > BCl3 > BBr3
C BBr3 > BF3 > BCl3
D BBR3 > BCl3 > BF3
6.P4O10 is the anhydride of
A H3PO2
B H3PO3
C H3PO4
D H4P2O7
7.Which of the following statements regarding ozone is not correct?
The oxygen-oxygen bond length in ozone is identical with that of molecular
A
oxygen
B The ozone is response hybrid of two structures
Page 5

C
D
The ozone molecule is angular in shape

Ozone is used as a germicide and disinfectant for the purification of air.
8.Which of the following contains P - O - P bond?

A Hypophosphorous acid
B Phosphorous acid
C Pyrophosphoric acid
D Orthophosphoric acid
B.Account for the following ( any ten ) 10X2
1) Oxygen almost invariably exhibits an oxidation state of -2 but the other members
of the family exhibit negative as well as positive oxidation states of +2, +4 & +6.
Why?
2) H2S is a gas whereas H2O is a liquid, why?
3) Why bond angle of H2O is less than NH3?
4) Boiling point of Gr-16 elements increases from H2S to H2Po, why?
5) HF is kept in wax bottles but not in glass bottles, why?
6) HF has a greater electronegativity difference and more ionic character than HCl,
HBr and HI but it is the weakest acid, why?
7) Halogens are strong oxidizing agents, why?
8) Anhydrous HCl is a bad conductor of electricity while aqueous HCl is a good
conductor, why?
9) Bleaching action of chlorine is permanent but that of sulphur dioxide is
temporary, why?
10) XeF2 has a straight linear structure and not easily hydrolyzed, why ?
11) Deep sea divers use a mixture of He and O2 instead of air for breathing, why?
12) Though E.A. of fluorine is less than that of chlorine but fluorine is a better
oxidizing agent, why?
13) Most of the reactions of fluorine are exothermic, why?
3. Draw the structures of ( any five ) : 5X1
(i) XeO3
(ii) H2SO5
(iii) ClF
(iv) SO2
(v) HClO4 (vi)H3PO4

(i) what do you mean by interhalogen
(ii) write down the use of argon gas
(iii) Write down a compound of chlorine having +7 oxidation state
(iv) Write down the formula of Fremys salt
(v) Write down the structure of I3(vi) Write the structure of XeF2
(vii) Give the structure of PCl5 in gaseous state state
(viii) Prepare chlorine at ordinary temperature
(ix) An white coloured compound on heating produces nitrogen . Identify the
compound
(x) Arrange the increasing N-O-N bond angle : NO2 , NO2+ , NO2(xi) Write one difference between ammonia and phosphine
(xii) Arrange the hydrides of gr 17 in the increasing order of reducing character.
5. Write only balanced chemical reactions : 5X1
Page 6

(a) Reaction of ozone gas with potassium iodide
(b) Reaction of sulphur dioxide with potassium dichromate
(c) Reaction of SO2 with Cl2 in aq solution
(d) Reaction of white phosphorus with conc NaOH
(e) Reaction of phophine with HCl
1(d)
2(a) 3(b)
4(b) 5(d)
6(c)
7(a)
Page 7
8(c)
EXAM ON d/f-BLOCK ELEMENTS

F.M. 32 TIME : 1 HR
CLASS 12- (2)
_______________________________________________________________________________________________
A. Answer the following questions : 8X1
1.Which of the following arrangements does not represent the correct order of the
property stated against it?
A V2+ < Cr2+ < Mn2+ < Fe2+ : paramagnetic behaviour
B Ni2+ < Co2+ < Fe2+ < Mn2+ : ionic size
C Co3+ < Fe3+ < Cr3+ < Sc3+ : stability in aqueous solution
D Sc < Ti < Cr < Mn : number of oxidation states
2.Which of the following lanthanoid ions is diamagnetic?
(At. nos. Ce = 58, Sm = 62, Eu = 63, Yb = 70)
A Ce2+
B Sm2+
C Eu2+
D Yb2+
3.KMnO4 can be prepared from K2MnO4 as per the reaction:
3MnO42 2H2O
2MnO4 + MnO2 + 4OH
The reaction can go to completion by removing OH ions by adding
A KOH
B CO2
C SO2
D HCl
4.Which of the following statements about the interstitial compounds is incorrect?
A They retain metallic conductivity
B They are chemically reactive
C They are much harder than the pure metal
D They have higher melting points than the pure metal
5.(NH4)2Cr2O7 On heating gives a gas which is also given by
A heating NH4NO2
B heating NH4NO3
C Mg3N2 + H2O
D Na (comp.) + H2O2
6.A red solid is insoluble in water. However, it becomes soluble if some KI is added
to water. Heating the red solid in a test tube results in liberation of some violet
coloured fumes and droplets of a metal appear on the cooler parts of the test tube.
The red solid is
A (NH4)2Cr2O7
Page 8

B
C
D
HgI2
HgO
Pb3O4
7.All the metals form oxides of the type MO except

A Copper
B Barium
C Silver
D Lead
8.Among the following, the coloured compound is
A CuCl
B K3 [Cu(CN)4]
C CuF2
D [Cu(CH3CN)4]BF4
2. Account for the following : 8X2
(a)Actinoid contaraction is more than lanthanoid contraction.
(b) The Standard electrode potential of Ni+2 / Ni is high negative
(c) Zr and Hf have similar size.
(d) Transition metals form complex compounds very easily .
(e) Cr+2 is stronger reducing agent than Fe+2
(f) Zn has lowest enthalpy of atomisation.
(g) Cu+2 in aqueous state is more stable than Cu+1
(h) The third ionisation enthalpy of La and Ga are abnormally low .
3. Write balanced chemical reaction : 4X1
(a) potassium dichromate reacts with Fe+2 solution (b) potassium permanganate
reacts with thiosulphate solution
(c) potassium dichromate reacts with KI solution (d) potassium permanganate
reacts with oxalic acid solution
4. Give the structure :
2X1
(a) permanganate ion (b) dichromate ion
EXAM ON d , f BLOAK AND COORDINATION COMPOUNDS

F.M 30 TIME 1 HR
A. Answer the following questions ( any five ): 5X1
Page 9

(At. nos. Ce = 58, Sm = 62, Eu = 63, Yb = 70)
A Ce2+
B Sm2+
C Eu2+
D Yb2+
3MnO42 2H2O
2MnO4 + MnO2 + 4OH
A KOH
B CO2
C SO2
D HCl
A heating NH4NO2
B heating NH4NO3
C Mg3N2 + H2O
D Na (comp.) + H2O2
The red solid is
A (NH4)2Cr2O7
B HgI2
C HgO
D Pb3O4
A Copper
B Barium
C Silver
D Lead
A CuCl
B K3 [Cu(CN)4]
C CuF2
D [Cu(CH3CN)4]BF4
Page 10
2. Account for the following ( any five ) : 5X2

3. Write balanced chemical reaction( any three ) : 3X1
2X1
2
6. Give structure : (i) sodium hexafluorosilicate ( IV)
Potassiumhexacyanoferrate(II)
2
(ii)
7. Explain ( any two ) 2X2

(i) NiCl4]2 is paramagnetic while [Ni(CO)4] is diamagnetic though both are
tetrahedral. Why?
(ii) The hexaquo manganese(II) ion contains five unpaired electrons, while the
hexacyanoion contains only one unpaired electron. Explain using Crystal Field
Theory.(iii) Explain perfect and imperfect complex using example
8. Give example : Homoleptic complex , coordination isomerism
Page 11
1(a)
2(d) 3(b) 4(b)
5(a) 6(b) 7(c) 8(c)

EXAM ON COORDINATION COMPOUNDS
F.M 30 TIME 1 HR
1.MCQ QUESTIONS : 5x1

(i) .How many ions are produced from the complex Co(NH 3)6Cl2 in solution?
(a) 6 (b) 4 (c) 3 (d) 2
(ii).The oxidation number of cobalt in K[Co(CO)4] is
(a) +1 (b) +3 (c) 1 (d) 3
(iii).Amongst the following, the most stable complex is
(i) [Fe(H2O)6]3+ (ii) [Fe(NH3)6]3+ (iii) [Fe(C2O4)3]3 (iv) [FeCl6]3
(iv) .What will be the maxium wavelengths of absorption in the visible region for the following:
(a) [Ni(NO2)6]4, (b) [Ni(NH3)6]2+, (c) [Ni(H2O)6]2+ (d) [Ni(CN)4]2(v) .Amongst the following ions which one has the highest magnetic moment value?
(a) [Cr(H2O)6]3+ (b) [Fe(H2O)6]2+ (c) [Zn(H2O)6]2+
2. .Using IUPAC norms write the systematic names of the following: (any five )
5X1
(i) [Co(NH3)6]Cl3 (ii) [Pt(NH3)2Cl(NH2CH3)]Cl (iii) [Ti(H2O)6]3+ (iv) [Co(NH3)4Cl(NO2)]Cl (v) [Mn(H2O)6]2+
(vi) [NiCl4]2 (vii) [Ni(NH3)6]Cl2 (viii) [Co(en)3]3+(ix) [Ni(CO)4]
3. Using IUPAC norms write the formulas for the following: (any five ) 5X1
(i) Tetrahydroxozincate(II)
(ii) Potassium tetrachloridopalladate(II)
(iii) Diamminedichloridoplatinum(II)
(iv) Potassium tetracyanonickelate(II)
(v) Pentaamminenitrito-O-cobalt(III)
(vi) Hexaamminecobalt(III) sulphate
(vii) Potassium tri(oxalato)chromate(III)
(viii) Hexaammineplatinum(IV)
4.Draw the structures of optical isomers of:
2X3
(i) [Cr(C2O4)3]3
(ii) [PtCl2(en)2]2+
(iii) [Cr(NH3)2Cl2(en)]+
5. Explain on the basis of valence bond theory that [Ni(CN) 4]2 ion with square planar structure is diamagnetic and
the [NiCl4]2 ion with tetrahedral geometry is paramagnetic.
2
6.[NiCl4]2 is paramagnetic while [Ni(CO)4] is diamagnetic though both are tetrahedral. Why?
7.[Fe(H2O)6]3+ is strongly paramagnetic whereas [Fe(CN)6]3 is weakly paramagnetic. Explain.
2
2
8.Explain [Co(NH3)6]3+ is an inner orbital complex whereas [Ni(NH3)6]2+ is an outer orbital complex.
9.Predict the number of unpaired electrons in the square planar [Pt(CN) 4]2 ion.
Page 12
EXAM ON d/f-BLOCK ELEMENTS

F.M. 40 TIME : 1.5 HR
CLASS 12- (2)
_______________________________________________________________________________________________
A. Answer the following questions : 8X1
(At. nos. Ce = 58, Sm = 62, Eu = 63, Yb = 70)
A Ce2+
B Sm2+
C Eu2+
D Yb2+
3MnO42 2H2O
2MnO4 + MnO2 + 4OH
A KOH
B CO2
C SO2
D HCl
A heating NH4NO2
B heating NH4NO3
C Mg3N2 + H2O
D Na (comp.) + H2O2
The red solid is
A (NH4)2Cr2O7
B HgI2
C HgO
D Pb3O4
Page 13

A Copper
B Barium
C Silver
D Lead
A CuCl
B K3 [Cu(CN)4]
C CuF2
D [Cu(CH3CN)4]BF4
2. Account for the following : 8X2
3. Write balanced chemical reaction : 4X1
2X1
2
6. Give structure : (i) sodium hexafluorosilicate ( IV)
Potassiumhexacyanoferrate(II)
2
(ii)
7. Explain ( any two ) 2X2

(i) NiCl4]2 is paramagnetic while [Ni(CO)4] is diamagnetic though both are
tetrahedral. Why?
(ii) The hexaquo manganese(II) ion contains five unpaired electrons, while the
hexacyanoion contains only one unpaired electron. Explain using Crystal Field
Theory.(iii) Explain perfect and imperfect complex using example
8. Give example : Homoleptic complex , coordination isomerism
Page 14
EXAM ON POLYMER AND CHEMISTRY IN EVERY DAY LIFE

F.M. 30 TIME : 1 HR
CLASS 12- (3)
_______________________________________________________________________________________________
1. MCQ ( answer any five ) : 5X1
(i) Which one of the following polymers is prepared by condensation polymerization?
A
Teflon B. Rubber C. Styrene D . Nylon 6,6
(ii) [NH(CH2)NHCO(CH2)4CO]n is a
A
addition polymer B thermosetting polymer C. Homopolymer D.Co-polymer
Page 15
(iii) Which of the following is a fully fluorinated polymer?

A
Neoprene B Teflon C. Thiokol
D. PVC
(iv) Which of the following is a polyamide?

A
Teflon B. Nylon 6,6 C. Terylene D. Bakelite
(v) Arsenic containing medicine used for the treatment of syphilis, is

A
Tetracycline B Ofloxacin C Erythromycin D Salvarsan
(vi)The artificial sweetener containing chlorine that has the appearance and taste as that of sugar and is stable
at cooking temperature is
A
Aspartame B Saccharin C Sucralose
D Alitame
(vii) The class of drugs used for the treatment of stress is

A
Analgesics B Antiseptic C Antihistamine D Tranquilizers
2. Write down the difference between : 2X3

(a) Addition polymer & condensation polymer
(b) Thermoplastic & thermosetting polymer
(c) Natural rubber and vulcanised rubber.
3. Give the structure of monomer of following polymers : 4X1
(a) Buna N (b) Nylon 6 (c) Dacron (d) PTFE
4.What do you mean by antiseptic and disinfectant ? Give example of a compound
which can be used both as antiseptic and disinfectant.
2
5. What are the advantages of using sucralose as artificial sweetner ? Why
aspartame is limited to cold food and drinks ?
2
6. Mention the constituents of dettol and tincture iodine .
Page 16

7.Give example (a) antacid (b) broad spectrum antibiotic (c) antifertility drug
(d) anionic detergent (e) antipyretic drug (f) food preservative
6
8.What do you mean by tranquilizers ?
give two examples .
9.Write down the harmful effect of aspirin as analgesic .
EXAM ON METALLURGY
F.M. 26 TIME : 45 min
CLASS 12- (3)
_______________________________________________________________________________________________
1.Answer the following questions : 10X1
(a) What is the role of depressant in froth floatation process ?
(b) Differentiate between mineral and ore (c) What do you mean by smelting ? Give
reaction
(d) Define the terms gangue and flux
(e) What is the role of silica in copper extraction
(f) Why is pine oil used in froth floatation process ?
(g) How is cast iron different from pig iron ?
(h) Write the principle of zone refining method
(i) What is the role of cryolite in the extraction of aluminium ?
(j) What is the role of graphite rod in the electrometallurgy of aluminium ?
2. Copper can be extracted by hydrometallurgy but not zinc. Explain.
3. Why is the extraction of copper from pyrite difficult than that from its oxide
through reduction? 2
4. Giving examples, differentiate between roasting and calcination.
5. Write chemical reactions taking place in the extraction of zinc from zinc blende.
2
6. How can you separate alumina from bauxite ore associated with
silica? Give equations. 2
7. What is hydrometallurgy? Explain with an example
8. What is leaching process? How is it used for the concentration of silver and gold
ores? 2
9. Free energies of formation Gf of MgO(s) and CO(g) at 1273K and 2273 K are
given below:
2
Gf [MgO(s)] = 941 KJ mol1 at 1273 K.
Gf [CO(g)] = 439 KJ mol1 at 1273 K.
Page 17

Gf [MgO(s)] = 314 KJ mol1 at 2273 K.
Gf [CO(g)] = 628 KJ mol1 at 2273 K.
On the basis of above data, predict the temperature at which carbon can be used
as a reducing agent for MgO(s).
EXAM ON METALLURGY AND BIOMOLECULES

F.M. 30 TIME : 60 min
CLASS 12- (4)
_______________________________________________________________________________________________
1.Answer the following questions : 10X1
(a) What is the role of depressant in froth floatation process ?
(b) Differentiate between mineral and ore
(c) Give example of one reducing and one nonreducing sugar
(d) Define the terms gangue and flux
(e) What is the role of silica in copper extraction
(f) Why is pine oil used in froth floatation process ?
(g) How is cast iron different from pig iron ?
(h) What do you mean by Zwitterion ?
(i) What is the role of cryolite in the extraction of aluminium ?
(j) What are the hydrolysis product of sucrose ?
2. Copper can be extracted by hydrometallurgy but not zinc. Explain.
3. What is mutarotation ? 2
4. Giving examples, differentiate between roasting and calcination.
5. Write chemical reactions taking place in the extraction of zinc from zinc blende.
2
6. How can you separate alumina from bauxite ore associated with
7. What is hydrometallurgy? Explain with an example
8. What is leaching process? How is it used for the concentration of silver and gold
ores? 2
Page 18

9. Free energies of formation Gf of MgO(s) and CO(g) at 1273K and 2273 K are
given below:
2
Gf [MgO(s)] = 941 KJ mol1 at 1273 K.
Gf [CO(g)] = 439 KJ mol1 at 1273 K.
Gf [MgO(s)] = 314 KJ mol1 at 2273 K.
Gf [CO(g)] = 628 KJ mol1 at 2273 K.
10.Write three differences between DNA and RNA .
11.What do you mean by inversion of sucrose ? Give reaction
EXAM ON POLYMER,EVERYDAY CHEMISTRY,BIOMOLECULES , METALLURGY

F.M. 40 TIME : 1.15 HR
CLASS 12- (4) `
_______________________________________________________________________________________________
1. SAQ ( any ten ) 10X1
(a) ______________ is a drug which is used both as analgesic and antipyretic
(b)_____________ is an example of a sulpha drug
(c) ____________ is used in the treatment of mental disorders
(d)Chemical name oh natural rubber is __________
(e) _______________ is the monomer of nylon 6
(f) An example of polyester is _________________
(g) ____________ vitamin contains cobalt atom .
(h) ______________ is non reducing sugar.
(i) Valine is ______________ amino acid.
(j)_____________ is used as a flux to remove SiO2
(k) The reducing agent used in the thermite process is ___________
(l) The most pure iron is ______________
2. Short answer type questions : 15X2
(a). Giving examples, differentiate between roasting and calcination.
2
(b). Write chemical reactions taking place in the extraction of zinc from zinc
blende. 2
(c). How can you separate alumina from bauxite ore associated with
(d). What is mutarotation ? 2
(e).Write three differences between DNA and RNA . 2
(f).What do you mean by inversion of sucrose ? Give reaction 2
(g) . Free energies of formation Gf of MgO(s) and CO(g) at 1273K and 2273 K are
given below:
2
Gf [MgO(s)] = 941 KJ mol1 at 1273 K.
Gf [CO(g)] = 439 KJ mol1 at 1273 K.
Gf [MgO(s)] = 314 KJ mol1 at 2273 K.
Page 19

Gf [CO(g)] = 628 KJ mol1 at 2273 K.
(h). Copper can be extracted by hydrometallurgy but not zinc. Explain. 2
(i). Why is the extraction of copper from pyrite difficult than that from its oxide
through reduction? 2
(j). Giving examples, differentiate between slag and gangue.
2
(k) Write down the monomers of (i) PET (ii) glyptal
2
(l) What are the advantages of vulcanization ?
(m) What is the significance of 6,6 in nylon 6 6 ?
(n) Give example of one preservative , one oxidant and two artificial sweetner. 2
(o) Write the reactions related to extraction of Zn from zinc blende. 2
Page 20

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Periodic assesment for board exam 2017

EXAM ON P-BLOCK ELEMENTS

2.Account for the following ( any five ) 5X2

Periodic assesment for board exam 2017

Bi(V) and Sb(V)

(ii) SF6 is known but SH6 is nonexistent. Explain

Periodic assesment for board exam 2017

EXAM ON P-BLOCK ELEMENTS

2.Account for the following ( any ten ) 10X2

Bi(V) and Sb(V)

(viii) SF6 is known but SH6 is nonexistent.

Periodic assesment for board exam 2017

3. Draw the structures of ( any five ) : 5X1

(iii) O3 (iv) XeF4

(v) HClO4 (vi)N2O5

4. Answer the following : ( any ten ) 10X1

Periodic assesment for board exam 2017

Periodic assesment for board exam 2017

The ozone molecule is angular in shape

8.Which of the following contains P - O - P bond?

(v) HClO4 (vi)H3PO4

4. Answer the following : ( any ten ) 10X1

Periodic assesment for board exam 2017

Periodic assesment for board exam 2017

EXAM ON d/f-BLOCK ELEMENTS

Periodic assesment for board exam 2017

7.All the metals form oxides of the type MO except

EXAM ON d , f BLOAK AND COORDINATION COMPOUNDS

Periodic assesment for board exam 2017

Periodic assesment for board exam 2017

2. Account for the following ( any five ) : 5X2

7. Explain ( any two ) 2X2

Periodic assesment for board exam 2017

2(d) 3(b) 4(b)

5(a) 6(b) 7(c) 8(c)

1.MCQ QUESTIONS : 5x1

Periodic assesment for board exam 2017

EXAM ON d/f-BLOCK ELEMENTS

Periodic assesment for board exam 2017

7. Explain ( any two ) 2X2

Periodic assesment for board exam 2017

EXAM ON POLYMER AND CHEMISTRY IN EVERY DAY LIFE

Periodic assesment for board exam 2017

(iii) Which of the following is a fully fluorinated polymer?

(iv) Which of the following is a polyamide?

(v) Arsenic containing medicine used for the treatment of syphilis, is

(vii) The class of drugs used for the treatment of stress is

2. Write down the difference between : 2X3

Periodic assesment for board exam 2017

give two examples .

9.Write down the harmful effect of aspirin as analgesic .

Periodic assesment for board exam 2017

EXAM ON METALLURGY AND BIOMOLECULES

Periodic assesment for board exam 2017

11.What do you mean by inversion of sucrose ? Give reaction

EXAM ON POLYMER,EVERYDAY CHEMISTRY,BIOMOLECULES , METALLURGY

Periodic assesment for board exam 2017

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