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Calculate Kc for
2 HI(g) H2(g) + I2 .
2. Phosgene (COCl2) is a poisonous gas that dissociates at high temperature into two other
poisonous gases, carbon monoxide and chlorine. The equilibrium constant
Kp = 0.0041 at 600K. Find the equilibrium composition of the system after 0.124 atm of
COCl2 is allowed to reach equilibrium at this temperature.
What will be the partial pressures of all three components if 0.200 mole of PCl 5and 3.00 moles of
PCl3 are combined and brought to equilibrium at this temperature and at a total pressure of 1.00
atm?
4. Consider the equilibrium: 2SO2(g) + O2(g) 2SO3(g) Kc = 4.36 M-1 . Calculate the value of Q
for a situation in which the concentrations are [SO2]= 2.00M, [O2]= 1.50M, and [SO3] = 1.25M.
5. Consider the equilibrium: 2N2O(g) + O2(g) 4NO(g) . 3.00 moles of NO(g) are introduced into a
1.00-Liter evacuated flask. When the system comes to equilibrium, 1.00 mole of N 2O(g) has
formed. Determine the equilibrium concentrations of each substance. Calculate the K c for the
reaction based on these data.
6. An NH3 solution has a pH of 11.00. Calculate the analytical molarity of NH 3 in the solution?
7. 2.00 mL of 0.0150M HCl solution is added to 10.00 mL of 0.150M HOAc solution. Calculate pH
of the resulting mixture. Ka = 1.75x10-5
8. Calculate the pH of a 0.36 M CH3COONa solution given the pKa of acetic acid is 4.745.
9. Calculate the hydronium and hydroxide ion concentration of pure water at 25C (K w=1.01x10-14)
and 100C (Kw=49x10-14).
10. Calculate the hydronium and hydroxide ion concentrations and the pH and pOH of 0.200 M
aqueous NaOH at 25C.
11. The pKa of acetic acid is 4.75. Find the pH of acetic acid solutions of labeled concentrations of
1.0 M, 0.010 M, and 0.00010 M.
12. 3.0 mL of 0.150 M HCl solution is added to 10.0 mL of 0.150 M HOAc solution. Calculate the
pH of the mixture. (Ka = 1.75 x 10-5)
10
13. Determine the pH of 0.10M HCN (aq). For HC, Ka = 4.9 10 .
14. 2.00mL of 0.0150M HCL solution is added to 10.00mL of 0.150 HOAC solution. Calculate the
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pH of the resulting mixture. Ka of HOAC is 1.75 10 .
15. Calculate the pH of a buffer solution that initially consists of 0.0500 M NH 3 and 0.0350 M NH4+.
(Note: Ka for NH4+ is 5.6 x 10-10). The equation for the reaction is as follows:
NH4+ <-> H+ + NH3
16. A saturated solution of Mg(OH) 2 is prepared. The pH of the solution is 10.17. What is the K sp for
this compound?
HC2H3O2 H+ + C2H3O2
23. The Kw value that we normally use is for room temperature (25C). Calculate the equilibrium H+
concentration and pH of pure, neutral water at 0.0C (Kw = 1.14 x 10 15 at 0.0C)
24. Methylamine (CH3NH2) is a derivative of the weak base ammonia. Write the equation for the
ionization of methylamine in water, and use the I.C.E. method to find the pH of a 3.75 M CH 3NH2
solution. (Kb = 4.37 x 104 at 25C)
25. Find the pH of a 0.325 M acetic acid solution, Ka = 1.8 x 10-5
Calculate all three equilibrium concentrations when [H2] = [I2] = 0.200 M and K = 64.0.
Calculate K for 2 HI H2 + I2 .
31. Benzoic acid (C6H3COOH) has a Ka of 6.3x10-5. Calculate the pH of a 0.120 M sodium benzoate
(NaC6H3COO).
32. An NH3 solution has a pH of 11.00. Calculate the analytical molarity of NH 3 in the solution. Kb =
1.8 x 105
33. Calculate the concentrations for each species present in a 0.1000 M aqueous solution of ammonia
(Kb = 1.8 x 10-5).
NH3(aq) + H2O(l) NH4+(aq) + OH-(aq)
34. Calculate the pH of the buffer solution that is 0.15 M HF and 0.15 M F-. (Ka = 6.8 x 10-4)
37. Find the equilibrium concentration of HC 7H5O2 from a 0.43 M solution of Benzoic Acid,
HC7H5O2. Ka of HC7H5O2= 6.4 x 10-5
38. 2.00mL of 0.015M HCl solution is added to 10.00mL of 0.150M HOAc, calculate the pH of the
resulting mixture. Ka=1.75x10-5
41. Calculate the pH of a solution that is 0.200 M in NH3 and 0.300 M in NH4Cl.
+
++ H 2 O NH 3 + H 3 O
NH 4
Ka = 5.70 10-10
Calculate all three equilibrium concentrations when [H2] = [I2] = 0.200 M initially and
Kc = 64.0
43. Calculate the pH of 0.30M solution of Sodium Benzoate, C6 H 5 COONa . The
is 1.55 1010
k b for C6 H 5 CO O .
44. Find the pH of a 0.20M solution of sodium propionate, C2 H 5 COONa , where the
5
K a o f propionic acid is1.34 10 .
2 NO ( g )+ 2 H 2 ( g ) N 2 ( g)+ 2 H 2 O(g)
Determine the value of the equilibrium constant, Kc, for the reaction. Initially, a mixture of 0.100
M NO, 0.050 M H2, 0.100 M H2O was allowed to reach equilibrium (initially there was no N2).
At equilibrium the concentration of NO was found to be 0.062 M.
46. Consider the following reaction
C2 H 4 ( g ) + H 2 ( g ) C2 H 6 (g) K c =0.99
What is the concentration for each substance at equilibrium if the initial concentration of ethene,
C2H4 (g) , is 0.335 M and that of hydrogen is 0.526 M?
47. What mass (in grams) of Ba(IO3)2 (487 g/mol) can be dissolved in 500 mL of water at 25oC?
48. Calculate the solubility of Ba(IO3)2 in a solution prepared by mmixing 200 mL of 0.100 M
Ba(NO3)2 with 100 mL of 0.100 M NaIO3.
49. What is the Kb for the equilibrium:
+ H 2 O HCN +OH
CN
Ka= 6.2 x 10-10
50. Calculate the hydroxide ion concentration in a 0.0100 M sodium hypochlorite solution.
++ NO 2
HNO2+ H 2 O H 3 O
Ka = 7.1 x 10-4