SMK TASEK UTARA

UJIAN PRA PENTAKSIRAN SEM 2 - PERTAMA TAHUN 2017

Section A - Answer Sheets

1. A 2. C 3. C 4. D 5. C
6. D 7. B 8. C 9. B 10. D
11. D 12. C 13. B 14. D 15. C

16.(a) i. enthalpy change of atomisation [1] 19. m1 - m2 : a) Re-write equation according to the amount
ii. electron affinity [1] required to form ethene [2]
iii. enthalpy change of hydration [1] 2 C (s) + 2 O2 (g)
2 CO2 (g) H = -787.4 kJ
2 H2 (g) + O2 (g)
2 H2O (l) H = -571.8 kJ
b) i. -heat change during a chemical reaction is the same [1]
2CO2 (g) + 2 H2O (l)
C2H4 (g) + 3O2 (g) H = +1411.0 kJ
- independent of the route of the chemical change occur [1]
m3 : 2 C(s) + 2 H2 (g)
C2H4 (g) [1]
ii. H4 = H1 + H2 + H3 [1]
m4 : Answer :- 51.8 kJ mol-1 (ins " - " kJ mol-1) [1]
iii. All correct [2] each wrong (-1 m) [2]
m5 - m6 : b) Labeling [1] Arrow [1] [2]
Chlorine Bromine Iodine
Energy / kJ
H4 = - 624 H4 = - 332 H4 = - 138
Fe (s) + 3/2 Cl2 (g)
17. (a) i. B : saturated potassium chloride / potassium nitrate /
ammonium nitrate [1] - 48.5
C : hydrochloric acid (or any strong acid) at 1.0 mol dm-3. [1] -399.5 3+
Fe (aq) + 3/2 Cl2 (g)
ii. (draw from hydrogen half cell to copper half cell on the wire
and from copper half cell to hydrogen half cell on salt bridge [1]
b) i. Use platinum as electrode [1] FeCl3 (s) - 167.2 x 3
concentration of Fe3+ and Fe2+ at 1.0 mol dm-3 [1] -150.6
ii. express the 1/2 equation oxidation and reduction [1]
Fe3+ (aq) + e-
Fe2+ (aq) E0 = + 0.77V Fe3+ (aq) + 3 Cl- (aq) Fe
Cu (s)
2 e- + Cu2+ (aq) E0 = - 0.34 V m8 : H = [- 48.5 + 3(-167.2)] - [ - 399.5] [1]
2Fe (aq) + Cu
2 Fe (aq) + Cu2+
3+ 2+
[1] = - 151 @ -150.6 kJ mol-1. [1]
Ecell = + 0.43 V [1] b) m9 : Finding both half equations [1]
Section C H2O2 + 2 H+ + 2 e- 2 H2O E0 = +1.77 V
18. m1-m6 : a) Each steps and enthalpy change is [1] x 6 Sn2+ Sn4+ + 2 e- E0 = 0.15 V
K+ (g) + Cl (g) + e- m10 : H2O2 + 2 H + Sn Sn2+ + 2 H2O
+ 4+
[1]
Hatom of Cl [1] EA of Cl [1] m11: Ecell = + 1.61 V [1]
+ - m12 : Since E0cell is positive, reaction is spontaneous [1]
K (g) + Cl2 (g) + e
ii. m13 : Find both half equations [1]
HIE of K [1] K+ (g) + Cl- (g) Cr2O72- +14H+ + 6e- 2Cr3+ + 7H2O E0 = +1.33 V
K (g) + Cl2 (g) Cl2 + 2H2O 2 HOCl + 2H+ + 2e- E0 = - 1.63 V
Hatom of K [1] LE [1] m14:Cr2O72- + 3Cl2 +8H+ 6HOCl + H2O + 2Cr3+ [1]
K (s) + Cl2 (g) m15 : Ecell = - 0.30 V [1]
Hf [1] m16 : E0cell is negative, reaction is non- spontaneous [1]
KCl (s) 20. (a) Using Hess Law
4 C (s) + 3 H2 (g) C4H6 (g) H = +112.0 kJ / mol [1]
m7 : Hf = (-701) + [(90) + (121) + (418) + (-364)] [1] H2 (g) + O2 (g) H2O (l) H = -286.0 kJ / mol [1]
m8 : = - 436 kJ mol-1 [1]
C (s) + O2 (g) CO2 (g) H = -394.0 kJ / mol [1]
b) m9 : -Pb(NO3)2 contain Pb2+, NO3, and H2O while Mg(NO3)2
C4H10(l) + 13/2O2 (g) 4CO2(g) + 5H2O(l)H = -2877 kJ mol-1
contain Mg2+, NO3, and H2O [1]
m10 : - Electrolysis Pb(NO3)2 produce Pb (cathode) and O2 C4H6 (g) 4 C (s) + 3 H2 (g) H = -112.0 kJ / mol
(anode) [1] 5 H2 (g) + 5/2 O2 (g) 5 H2O (l) H = -1430 kJ / mol [2]
m11 : lead deposited at cathode since Eo (-0.13 V) is less 4 C (s) + 4 O2 (g) 4 CO2 (g) H = -1576 kJ / mol
negative than EoH2O (-0.83V) [1] 4 CO2(g) + 5 H2O(l) C4H10 (l) + 13/2 O2(g)H = +2877 kJ
m12 : Cathode : Pb2+ + 2e
Pb [1]
C4H6 (g) + 2 H2 (g) C4H10 (l)H = - 241.0 kJ / mol [1]
m13 : Electrolysis of Al(NO3)3 produce hydrogen (cathode) and (b) (i) Cu2+ + Pb Cu + Pb2+ [1]
oxygen (anode) [1] (ii) E0cell = E0cat - E0ano [1] E0cell = (+ 0.34) - (-0.13) [1]
m14 : Hydrogen deposited at cathode since EoH2O (-0.83V) is 0
E cell = + 0.47 V [1]
more positive than EoAl3+/Al (-1.66 V) [1]
0.059 [Pb2+ ] [1] 0.059 [Pb2+ ] [1]
m15 : Cathode : 2 H2O + 2e
H2 + 2OH [1] (iii) E
cell
0
= Ecell lg 2+
+ 0.70 = + 0.47 lg
m16 : At anode, O2 produce since EoH2O (+1.23V) is 2 [Cu ] 2 1.0
more negative than EoNO3- @ [Pb2+] = 1.6 x 10-8 mol dm-3 [1]
Anode : 2 H2O
O2 + 4H+ + 4e- [1]