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Simple Dew Point Control HYSYS v8.6

Steps to set up a simulation in HYSYS v8.6 to model a simple dew point control system consisting of:
Gas chiller
Flash separator
Liquid stabilizer with gas recycle & compression
Product gas compression
Simple propane refrigeration loop

When the simulation is set up the overall PFD should look like the following figure.

Basis
A gas plant is processing 100 MMscfd (dry basis) to produce a spec pipeline gas as well as a pipeline
raw mix liquid product. The following are known conditions for the feedstock and specification for
the products:
The composition of the feed gas is shown in the following table.
The gas enters the plant at 400 psia & 120F.
The gas has a small amount of water, 2 lb water per MMscf dry gas.
The produced pipeline gas should have a gross heating value between 905 to 1050 Btu/scf 1
& a hydrocarbon dew point no higher than 15F.
The produced pipeline gas should be delivered to the pipeline at 1000 psia and no higher
than 120F.
The produced liquids shall be exported via pipeline & stabilized to have a TVP (true vapor
pressure) @ 100F no greater than 103 psia.
A simple propane loop will be used to provide the chilling duty. The condenser will operate
at 120F. The minimum approach temperature within the chiller will be 10F.

1 If the gross heating value spec cannot be achieved set the chilled separator to the lowest reasonable
temperature when using a simple propane chilling loop, -30F.

Rev 1.2 -1- March 13, 2016

 Air coolers will be used to cool gases & liquids to 120F.

Component Mol%
N2 0.357
CO2 0.194
C1 80.980
C2 13.238
C3 3.438
i-C4 0.431
n-C4 0.742
i-C5 0.199
n-C5 0.156
n-C6 0.163
n-C7 0.065
n-C8 0.026
n-C9 0.010

Create new simulation file

Start the program from Start, All Programs, Aspen Tech, Process Modeling V8.6, Aspen HYSYS, Aspen
HYSYS V8.6. When the program opens choose the New button.

Define the Components & the Property Models

Specify components, fluid property packages, & crude oil assays

The first step is to add a set of pure chemical species to represent the gas & water phases. With
Component Lists highlighted click on the Add button. From the list of pure components pick: H2O,
Nitrogen, CO2, Methane, Ethane, Propane, i-Butane, n-Butane, i-Pentane, n-Pentane, n-Hexane,
n-Heptane, n-Octane, & n-Nonane.

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The next step is to pick a fluid property package. From the Fluid Packages screen click the Add
button. Choose the Peng-Robinson option and make sure it is associated with Component List 1.

It would be a good idea to save this file. Click the File tab & select Save As. Choose an appropriate
name & location.

Set up & Solve the Flowsheet

Gas Chilling & Separation
When you activate the Simulation & youll see a blank flowsheet. We will want to create a feed
stream & attach it to an LNG Exchanger. The outlet will be attached to a flash separator.

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Ensure that the model Palette is visible. If it is not, press the View tab & click Model Palette.

Place the following items on the flowsheet:

A Material Stream, Dry Feed
A Material Stream, Feed Water
A Mixer, Combine
An LNG Exchanger, Chiller
A 3-Phase Separator, DPC Separator.

Double-click on the Dry Feed stream to open up the entry forms for this stream. Enter the 100
MMscfd flowrate in the Molar Flow box. Note that once you enter the flowrate it changes the units to
lbmole/hr.

Now we need to specify the composition. Select Composition under Worksheet in the left-hand
column. Click the Edit button to bring up a form to enter the composition of this stream. Enter the
values from the table in the Basis section as Mole Fractions. Note that these add up to approximately
100, not 1. Select the Normalize button. Click OK. Now you should see that the form associated with
the stream is in green, meaning that all values for the stream have been calculated.

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We want to do the same thing for the water portion of the feed represented by the stream Feed
Water. Double-click on the Feed Water stream to open up the entry forms for this stream. Enter

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200 lb/hr in the Mass Flow box (to represent the 2 lb/MMscf water content). Enter the pressure but
do not enter the temperature.

Select Composition under Worksheet in the left-hand column. Click the Edit button to bring up a
form to enter the composition of this stream. Enter a 1 for the H2O mole fraction. Select the
Normalize button. Click OK. Now you should see that the form associated with the stream is still
yellow because the temperature has not been specified. That is OK, were going to back-calculate
the final condition so that the total feed gas is 120F.

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For most of the unit operations well define connections & create new streams using the operations
Design form. Double-click on Mixer. Define the 2 Inlets as Dry Feed & Feed Water. Define a new
Outlet stream as Total Feed.

Select the Worksheet tab. Note that the flowrate & pressure of the Total Feed stream are calculated.
But we still have to specify some type of temperature information to fully calculate Total Feed.
Specify the temperature as 120F. Note that not only have all properties been calculated for Total
Feed but also the final conditions for Feed Water have been determined. A Mixer is an isenthalpic
operation, so the enthalpy for Feed Water (and hence its temperature & quality) became specified
once we fully specified Total Feed.

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We now want to model the gas side of the Chiller. We could use a Cooler operation, but since well
ultimately want to calculate approach temperatures between the gas & the propane in the chilling
loop an LNG Exchanger is more appropriate. Double-click on Chiller. Specify the 1st Inlet Stream as
Total Feed & define the Outlet Stream as Chilled Gas. For now specify the Pressure Drop as 0. Make
sure that specification for Hot/Cold is Hot.

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We now want to specify the cold separator & determine the properties of the produced gas. Double-
click on DPC Separator. Specify the Inlet as Chilled Gas. Create new streams, Cold Vapor, Cold
Liquid, & Cold Water as the Vapour, Light Liquid, & Heavy Liquid, respectively.

Lets estimate the needed temperature for the cold separator Click on the Worksheet tab &
specify -10F for the temperature of Chilled Gas. Notice that all values are calculated for Chilled
Gas, Cold Liquid, & Cold Vapor.

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Is this temperature for the cold separator appropriate to make spec pipeline gas? The primary
variable that we can control with the temperature is the dew point of the produced gas at the
pipeline conditions. Well look at the P-T diagram for Cold Vapor to get an indication of whether
weve come close to the dew point spec. Up in the ribbon under the Home tab, click on Stream
Analysis & choose Envelope. In the pop-up form choose Cold Vapor as the Object & click OK.

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The results in the Design tab show that the Cricondentherm is -2.953F, much colder than it needs to
be to meet the 15F pipeline dew point spec. We could reduce Chiller duty (and ultimately power
required for the propane cooling loop) by allowing this temperature to be higher. Note from the PT
diagram that the dew point at the pipeline inlet pressure, 1000 psia, is about -10F, less than the
cricondentherm. However, since the gas in the pipeline will experience pressures lower than the
inlets 1000 psia, it is more appropriate to use the cricondentherm as the controlling value for this
spec.

For now well use trial-and-error to determine an appropriate temperature for the cold separator.
Note that if we specify the temperature of Chilled Gas as 9.5F we get a cricondentherm of Cold
Vapor of just over 15F.

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Rev 1.2 - 12 - March 13, 2016
Have we met the heating value spec? We can determine this from additional properties calculated
for Cold Vapor. Double-click on Cold Vapor & select Properties under the Worksheet in the left-
hand column. Notice that an HHV has been calculated of 1,175 Btu/scf. This is too high & will
require more heavy hydrocarbons be removed.

But before we modify the cold separators operation we will add the liquid stabilizer section.

Liquid Stabilization
The next step is to determine if the produced liquid will make the TVP spec of 103 psia. Double-
click on Cold Liquid & select Properties under the Worksheet heading in the left-hand column. At the
bottom of the list there is an item for True VP at 37.8 C [psia]. The value is 654.9 psia, much higher
than our spec. We can look at the composition to see the problem it has 16% methane. This is
much too high to try to have in a raw mix NGL.

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We can process the high-pressure liquid in a low pressure stripping column to remove these light
ends. Lets add two more units:
A Control Valve, VLV-001
A Reboiled Absorber, Stabilizer.

Double-click on VLV-100. Specify the Inlet as Cold Liquid and define a new stream Flashed Liquid
as the Outlet.

Lets define the stabilizing column as a 10-stage column with a kettle reboiler. Double-click on
Stabilizer. Set the Top Stage Inlet feed as Flashed Liquid. Define new streams Recovered Gas for
the Ovhd Vapour Outlet and Stabilized Liquid for the Bottoms Liquid Outlet. Define the stream
Q-Reboiler for the Reboiler Energy Stream. Set the # Stages as 10. Press the Next> button to
continue the definition for this tower.

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Accept the default Once-Through reboiler configuration. This will model a kettle reboiler. Press the
Next > button to continue the towers definition.

Lets look running the tower at 200 psia. Specify 200 for both Top Stage Pressure & the Reboiler
Pressure. Press the Next > button to continue the towers definition.

Were able to specify temperatures on this next form. Ultimately we will want to run the reboiler in
such as way as to produce a liquid with a 103 psia vapor pressure at 100F. If we were running the
tower at 103 psia then we could set the reboiler temperature as 100F. However, since were
running the tower at a higher pressure the reboiler temperature must be higher; for now lets set an
estimate of 200F. Press the Next > button to continue the towers definition.

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We will not have to specify a boil-up ratio since were going to use a TVP spec on the reboiler. Leave
this blank & press Done

The tower does not run automatically because the specifications have not been fully defined. Select
Specs Summary item in the left-hand column. Notice that the default spec on the column is to
produce an overhead product rate (whose value has not been specified). But this is not how we
want to run this column. Before we enter the true spec click on the Active box for Ovhd Prod Rate to
turn it off.

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Lets add the reboiler temperature as the operating spec. Select Specs item in the left-hand column.
Press the Add button for column specifications. On the list select Column Temperature & press Add
Spec(s) Select Reboiler as the Stage & enter 200 for the Spec Value. Close this form.

Even though we have fully specified the tower the feed coming from VLV-100 has not been fully
specified, so the tower will not run. Go to the Worksheet tab and enter 200 for the pressure of
Flashed Liquid. Now that this feed is fully specified the tower will quickly calculate & converge.

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How close are we to creating a stabilized liquid with the correct TVP? Lets create a new spec for
this but dont make it active; we can then see how close we are. Select the Design tab and then the
Specs item in the left-hand column. Press the Add button for column specifications. On the list select
Column Stream Property Spec near the bottom of the list & press Add Spec(s) Select the Stabilized
Liquid @COL1. Youll have to go to another form to actually pick the type of stream property. Click
the Select Property button. On the next form select the tree structure under Standard & choose True
VP @ 37.8 C; press Select. Enter the value 103. Close this form.

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Now lets go back to the Design tab & Specs selection. Highlight the Stream Property Spec & you can
see that the calculated TVP is actually 67.85 psia, lower than the desired 103 psia. Well have to
decrease the temperature in the reboiler.

Select the Active check box; now the tower becomes unconverged (because we have overspecified
the unit with both the TVP spec & the reboiler temperature spec). Select the Temperature column
specification & uncheck its Active checkbox. Now the tower will converge again, now with a reboiler
temperature of 166.4F.

Rev 1.2 - 19 - March 13, 2016

What does the stabilized liquid look like? Double-click on Stabilized Liquid & select Composition
under the Worksheet tab. Note that there is essentially no methane & very little ethane all of this
material has been stripped out into the overhead vapor stream.

Lets look at how much has been stripped out. Double-click on Recovered Gas. Select Composition
under the Worksheet tab. Notice that this gas has very high concentrations of methane & ethane. But
could this be directly produced as pipeline gas? Select Properties. Note that the HHV is too high,
1449 Btu/scf.

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Recycle of Recovered Gas
One might ask we didnt include a condenser on the stabilizer column. We can effectively get this
effect by reconfiguring the process to recycle the recovered gas from the stabilizing column
upstream of the chiller & cold separator. However, since the recovered gas is produced at a lower
pressure it must be compressed to a higher pressure consistent with the original feed gas.

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Lets add three units:
A Compressor, Recycle Gas Compressor
A Mixer, Recycle Mixer.
A Recycle, RCY-1.

Note that some of the items have been flipped on the PFD shown above. This was done by selecting
the item on the Flowsheet, selecting Flowsheet/Modify in the ribbon, & then selecting Flip
Horizontal.

Double-click Recycle Gas Compressor. Set the Inlet as the Recovered Gas stream. Create an Outlet
stream HP Recycle Gas & a work Energy stream W-Recycle Compressor. Select the Worksheet tab.
Set the outlet pressure of the HP Recycle Gas to 400 psia. Note the calculations are completed using
the default adiabatic efficiency, 75%, and gives an outlet temperature of 225F.

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Now lets combine the HP Recycle Gas with the Total Feed & introduce it into the Chiller. Double-
click on Chiller & delete Total Feed as an Inlet Stream. Instead, create a new stream, Process Feed,
as the Inlet Stream.

Double-click on RCY-1. Select HP Recycle Gas as the Inlet. Create a stream Recycled Gas as the
Outlet.

Double-click on the Mixer Recycle Mixer. Select Process Feed as the Outlet. For now, only select
Total Feed as the Inlet.

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At this point the simulation has converged but without the Recycled Gas being mixed with the fresh
feed. But the stream has been initialized and the recycle calculation can proceed. Now, double-click
on Recycle Mixer & add Recycled Gas as the second Inlet stream. Now the simulation should
converge including this recycle back to the fresh feed.

How has adding the recycle gas affected the final results? There is not a great deal of Recycled Gas
being mixed with the fresh feed so the composition of the Cold Vapor does not change by much. The
cricondentherm increases only slightly to 15.07F.

The produced gas also still has a higher heating value that is too high, 1176 Btu/scf. We can try to
decrease the HHV by reducing the temperature of the Chilled Gas. Lets lower this temperature to
the lowest limit reasonable for a simple propane chilling loop, -30F. Reducing this temperature
does shift more of the heavy ends out of the produced gas & the HHV is lower. However, the HHV of
Chilled Gas is still too high, 1145 Btu/scf. Unfortunately this is pretty much the best we can do when
using a chilled single-stage flash separation unit.

Prevention of Freezing in DPC Separator

Even though there is not a great deal of water in the fresh feed there will still be water drop-out &
potential freezing in the DPC Separator. The typical technique is to inject a high concentration of
ethylene glycol (EG) upstream of the Chiller to prevent ice or hydrate formation.

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Return to the Properties section. Select Component List -1 to view the active component list. Use the
search term glycol. Select EGlycol from the databank list & press Add. The component EGlycol will
be placed at the bottom of the list.

Return to the Simulation section. Lets add a stream for the ethylene glycol, EG, into the Recycle
Mixer. Double-click on the stream EG. Select Composition & set it to 85 wt% ethylene glycol & 15
wt% water. Select Conditions; set the pressure to 400 psia & its temperature to 120F (typical for
air cooling after regenerating in a small packed column). For now set the mass flow rate to 370
lb/hr (this should make the Cold Water stream about 55 wt% glycol).

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Nearly all of the glycol will be part of the Cold Water stream. This stream will be about 55 wt%
glycol. Is this enough to protect from freezing? We can check the hydrate formation temperature for
the Cold Water stream to determine if weve added enough glycol (the hydrate calculation will also
determine ice conditions, too). Right-click on the Cold Water stream & choose Create Stream
Analysis, Hydrate Formation. Click on the Design tab & select Connections. Note that solids will
form at these conditions. You can get more information form the Performance tab. The freezing
point temperature for this stream is -8.2F. So, we do not have enough glycol added to provide
protection from solid formation.

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Lets manually add more EG to bring the hydrate formation temperature down to -40F (colder than
the actual DPC Separator conditions but will match what will be the coldest temperature of the
refrigerant in the Chiller). Making manual adjustments to the flowrate of EG shows that you need to
add 2285 lb/hr of the 85 wt% glycol solution to provide protection from solid formation down
to -40F. Note that the glycol concentration in Cold Water will be 78 wt%.

Rev 1.2 - 27 - March 13, 2016

Propane Refrigeration Loop
We need to add a refrigeration loop to be able to cool the feed & recycle gases to the DPC Separator
temperature. Add the following equipment to the flowsheet:
A Compressor, C3 Compressor
A Cooler, C3 Condenser.
A Control Valve, C3 Valve.

Lets create the streams for the refrigeration loop starting at the Chiller. Double-click on Chiller.
Create new inlet & outlet streams Refrig Liquid & Refrig Vapor, respectively. Make sure that these
streams are associated with the Cold side. Specify a zero pressure drop. Under the Worksheet tab
specify the conditions for the outlet stream Refrig Vapor (1 vapor fraction & -40F).

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Double-click on the stream Refrig Vapor. Set the composition to 100% propane. (The temperature
& the vapor fraction should already have been set to -40F & 1, respectively).

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Next lets connect the cold liquid to the let-down valve. Double-click on C3 Valve. Set the Outlet as
Refrig Liquid. Create a new stream Condensed Liquid as the Inlet. Select the Worksheet tab; set the
temperature of Condensed Liquid to 120F & the Vapour / Phase Fraction to 0 (i.e., saturated
liquid). Note that the flowrate can now be calculated (276,972 lb/hr) to ensure an energy balance in
Chiller.

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Now lets complete the refrigeration loop. Double-click on C3 Compressor. Select Refrig Vapor as
the Inlet & create HP Vapor as the Outlet; create W-C3 Compressor as the Energy stream.

Double-click on C3 Condenser. Select HP Vapor as the Inlet & Condensed Liquid as the Outlet;
create Q-C3 Condenser as the Energy stream. Under Parameters set the Delta P as 0. Now the
refrigeration loop calculations are completed.

Product Compression
The final step is to add compression for the final product gas. Add to the flowsheet the unit:
A Compressor, Product Gas Compressor

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Double-click on Product Gas Compressor. Select Cold Vapor as the Inlet & create HP Product Gas
as the Outlet; create W-Product Compressor as the Energy stream. Select the Worksheet tab; set
the outlet pressure as 1000 psia. Note that outlet temperature is less than 120F, so a final cooler is
not needed to be able to introduce this gas into the pipeline.

Optimizing Process
The basic process has now been set up. Note that there are three major power users:
Product Gas Compressor 4,027 hp
Recycle Gas Compressor 111 hp
Refrigeration Compressor 7,982 hp

In addition there are two major heat users:

Stabilizers reboiler 3.293 MMBtu/hr
Reboiler to regenerate the ethylene glycol (not included in this simulation).

The major step for optimization is to recover the refrigeration from the cold streams from the DPC
Separator. By doing so there would be less refrigeration duty needed, reducing the power
requirement for the C3 Compressor. Also, by warming the Cold Liquid before going to the
Stabilizer the amount of reboiler duty will also be reduced.

As an example, if we send the Cold Vapor to the Chiller to recover some its refrigeration (heating to
-14F so that the outlet of the Product Gas Compressor is limited to 120F) then we reduce the
power to the C3 Compressor (7,327 hp) but increase the power to the Product Gas Compressor
(4,275 hp). Overall the power needed for these two compressors decreases by 3.4%.

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