Professional Documents
Culture Documents
Product Identifier
Product
ACETIC ACID GLACIAL
name
Chemical
acetic acid glacial
Name
Synonyms 65580, Ashland J.T.Baker Chem-Supply, C2-H4-O2, CH3COOH, Fisher Scientific, ROA30, acetic acid > 80%, acetic acid vapour, anhydrous acetic acid, ethanoic acid, ethylic acid, glacial ac
Proper
shipping ACETIC ACID, GLACIAL or ACETIC ACID SOLUTION, more than 80% acid, by mass
name
Chemical
C2H4O2
formula
Other means
of 189|20104265|20104334|20108230|32|36373|36374|36375|36376|36377|36378|36379|36380|36381|36382|36383|36384|36385|36386|36387|36388|36389|36390|36391|36392|36393|3639
identification
CAS number 64-19-7
Relevant identified uses of the substance or mixture and uses advised against
Manufacturer of various acetates, acetyl compounds, acetate rayon, plastics and rubber; in tanning, printing calico and dyeing silk. As an acidulant and
Relevant identified uses preservative in foods. Solvent for many organic substances; also dissolves phosphorus, sulphur and halogen acids. Widely used in commercial organic
syntheses.
HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the Model WHS Regulations and the ADG Code.
Poisons Schedule S6
[2] Flammable Liquid Category 2, Metal Corrosion Category 1, Skin Corrosion/Irritation Category 1A
GHS Classification
Legend: 1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex VI
Label elements
Continued...
Chemwatch: 2789-3 Page 2 of 8 Issue Date: 01/01/2013
Version No: 8.1.1.1 Print Date: 05/08/2015
ACETIC ACID GLACIAL
Hazard statement(s)
H225 Highly flammable liquid and vapour
H290 May be corrosive to metals
H314 Causes severe skin burns and eye damage
Substances
CAS No %[weight] Name
64-19-7 >98 acetic acid glacial
Mixtures
See section above for composition of Substances
Continued...
Chemwatch: 2789-3 Page 3 of 8 Issue Date: 01/01/2013
Version No: 8.1.1.1 Print Date: 05/08/2015
ACETIC ACID GLACIAL
Extinguishing media
Water spray or fog.
Foam.
Dry chemical powder.
BCF (where regulations permit).
Continued...
Chemwatch: 2789-3 Page 4 of 8 Issue Date: 01/01/2013
Version No: 8.1.1.1 Print Date: 05/08/2015
ACETIC ACID GLACIAL
Control parameters
EMERGENCY LIMITS
Ingredient Material name TEEL-1 TEEL-2 TEEL-3
acetic acid glacial Acetic acid Not Available Not Available Not Available
Exposure controls
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly
effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.
The basic types of engineering controls are:
Appropriate engineering Process controls which involve changing the way a job activity or process is done to reduce the risk.
controls Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and
"removes" air in the work environment.
|In confined spaces or at elevated temperatures, where concentrated mist or fumes are present, an impervious suit ventilated by a supply of clean, cooled air
may be required.
Personal protection
Safety glasses with unperforated side shields may be used where continuous eye protection is desirable, as in laboratories; spectacles are not sufficient
where complete eye protection is needed such as when handling bulk-quantities, where there is a danger of splashing, or if the material may be under
pressure.
Eye and face protection
Chemical goggles.whenever there is a danger of the material coming in contact with the eyes; goggles must be properly fitted.
Full face shield (20 cm, 8 in minimum) may be required for supplementary but never for primary protection of eyes; these afford face protection.
Alternatively a gas mask may replace splash goggles and face shields.
Skin protection See Hand protection below
Elbow length PVC gloves
When handling corrosive liquids, wear trousers or overalls outside of boots, to avoid spills entering boots.
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to manufacturer. Where
the chemical is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior
Hands/feet protection
to the application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and.has to be observed when making a final
choice.
|Do not use polyethylene gloves.
Body protection See Other protection below
Overalls.
PVC Apron.
Other protection
PVC protective suit may be required if exposure severe.
Eyewash unit.
Thermal hazards Not Available
Continued...
Chemwatch: 2789-3 Page 5 of 8 Issue Date: 01/01/2013
Version No: 8.1.1.1 Print Date: 05/08/2015
ACETIC ACID GLACIAL
NEOPRENE A B-PAPR-AUS /
up to 10 x ES B-AUS -
Class 1
NITRILE+PVC A
up to 50 x ES - B-AUS / Class 1 -
PE A
up to 100 x ES - B-2 B-PAPR-2 ^
PE/EVAL/PE A
PVC A ^ - Full-face
A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogen
SARANEX-23 A cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur dioxide(SO2), G =
TEFLON A Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB =
Methyl bromide, AX = Low boiling point organic compounds(below 65 degC)
BUTYL/NEOPRENE B
NATURAL RUBBER B
NATURAL+NEOPRENE B
NITRILE B
NAT+NEOPR+NITRILE C
Continued...
Chemwatch: 2789-3 Page 6 of 8 Issue Date: 01/01/2013
Version No: 8.1.1.1 Print Date: 05/08/2015
ACETIC ACID GLACIAL
Hazardous decomposition
See section 5
products
TOXICITY IRRITATION
[2] Eye (rabbit): 0.05mg (open)-SEVERE
Dermal (rabbit) LD50: 1060 mg/kg
acetic acid glacial Inhalation (mammal) LC50: 11.4 mg/L/4H[2] Skin (human):50mg/24hr - mild
[2] Skin (rabbit):525mg (open)-SEVERE
Inhalation (mouse) LC50: 5620 ppm/1H
[2]
Oral (rat) LD50: 3310 mg/kgE
Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's msds. Unless otherwise specified data
extracted from RTECS - Register of Toxic Effect of chemical Substances
Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a non-allergenic condition known
as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high levels of highly irritating compound. Key criteria for the
ACETIC ACID GLACIAL diagnosis of RADS include the absence of preceding respiratory disease, in a non-atopic individual, with abrupt onset of persistent asthma-like symptoms
within minutes to hours of a documented exposure to the irritant. A reversible airflow pattern, on spirometry, with the presence of moderate to severe
bronchial hyperreactivity on methacholine challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia, have also been included
in the criteria for diagnosis of RADS.
Toxicity
Ecotoxicity:
The tolerance of water organisms towards pH margin and variation is diverse. Recommended pH values for test species listed in OECD guidelines are between 6.0 and almost 9. Acute testing
with fish showed 96h-LC50 at about pH 3.5
For Acetic Acid: Acetic acid and its salts (the acetates) can be grouped together because of their close structural relationships, their natural occurrence in plants and animals, and their
fundamental role in cell metabolism.
Atmospheric Fate: Acetic acid is degraded photochemically in the atmosphere to produce hydroxyl radicals (estimated typical half-life of 22 days).
Bioaccumulative potential
Continued...
Chemwatch: 2789-3 Page 7 of 8 Issue Date: 01/01/2013
Version No: 8.1.1.1 Print Date: 05/08/2015
ACETIC ACID GLACIAL
Ingredient Bioaccumulation
acetic acid glacial LOW (LogKOW = -0.17)
Mobility in soil
Ingredient Mobility
acetic acid glacial HIGH (KOC = 1)
Labels Required
Marine Pollutant NO
HAZCHEM 2P
Class 8
Transport hazard class(es)
Subrisk 3
ICAO/IATA Class 8
Transport hazard class(es) ICAO / IATA Subrisk 3
ERG Code 8F
Continued...
Chemwatch: 2789-3 Page 8 of 8 Issue Date: 01/01/2013
Version No: 8.1.1.1 Print Date: 05/08/2015
ACETIC ACID GLACIAL
IMDG Class 8
Transport hazard class(es)
IMDG Subrisk 3
Safety, health and environmental regulations / legislation specific for the substance or mixture
Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using
available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other
settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.
end of SDS