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Antonio Bonomi. "ETHANOL QUALITY REGULATION", p.801-812. In Luis Augusto Barbosa Cortez (Coord.).

Sugarcane bioethanol R&D for Productivity and Sustainability, So Paulo: Editora Edgard Blcher, 2014.

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http://dx.doi.org/10.5151/BlucherOA-Sugarcane-SUGARCANEBIOETHANOL_67

ETHANOL QUALITY REGULATION


Antonio Bonomi

INTRODUCTION quality of the biofuels, will also be evaluated. The


requirement for the harmonization of the Brazil-
Historically, a new configuration of the sug- ian fuel ethanol specification with that of other
arcane agro industrial system, that supports the countries will be discussed. This is because ethanol
most important biofuel fuel ethanol, started in will be commercialized in a highly competitive and
Brazil with the deregulation of the sector, the com- globalised market, in which quality and price are
mercial globalization of the Brazilian economy and the major differentials. Besides discussing ethanol
the perspective of increasing international demand specification, the present chapter presents major
for ethanol. aspects related to the quality and control and sug-
The deregulation process of the sugar-alcohol gests mechanisms, that can be implemented by the
industry during the 1990s was due to the Brazilian State of So Paulo.
State withdrawing control caused by the stagna-
tion of the sector at that moment. Nevertheless, THE REGULATORY FRAMEWORK
the state departure was only partial, because of its
importance in the dynamics of the sector. The regulatory framework that exists today
In order to maintain the leading position in in Brazil provides support to the production and
the production and commercialization of biofu- commercialization of ethanol, seen as a global com-
els, it was very important for the Brazilian biofuel modity. Three federal entities are the basis for this
sector to have official support. Law n. 11097 of regulatory framework:
January 13, 2005 formally introduced biofuels in ANP Brazilian Petroleum, Natural Gas
the Brazilian Energy Matrix and the Brazilian Pe- and Biofuels Agency, set up by Decree n.
troleum, Natural Gas and Biofuels Agency ANP 2455, of January 14, 1998. It is the regula-
was responsible for the regulation of the sector. tory organism for activities related to oil,
In this context, there is a regulatory and meth- natural gas and biofuels industries in Bra-
odological framework that maintains the Brazilian zil (ANP, 2008a); and responsible for the
leading position in the biofuel area. definitions and specifications of biofuels
In this chapter, the fundamental aspects re- (ethanol in this case) and for quality con-
quired to guarantee the ethanol quality will be trol, in all the stages of the production and
presented in detail essential for internal market commercialization chain.
consumption and to facilitate its commercializa- INMETRO Brazils National Institute of
tion in the international market. In addition, dif- Metrology, Standardization and Industrial
ferent fuel ethanol specifications that exist today Quality, created by Law n. 5966 of Decem-
in the world, strategies and mechanisms to be ber 11, 1973. It is responsible for metrology
implemented in a bioenergy policy, to ensure the field, formulation, coordination and super-
802 A New Model for Industrial Production and Final Uses of Ethanol

vision of the national metrology, standard- isms responsible for emissions control, trying al-
ization and industrial quality policy (DIAS, ways to satisfy the consumers requirements. Such
1998). INMETRO is therefore, responsible specifications are periodically revised to meet
for the metrology standards of the country the new engine technologies, the environmental
and is the leading Brazilian technical organ- requirements and, finally, the supply of products
ism in ensuring that biofuels meet the met- to society.
rological requirements in Brazil, European As an example of the continuous improvement
Unit and United States of America tripartite of the specifications, a revision of the Brazilian
task force (WHITE PAPER..., 2007). ethanol specification (ANP Decree n. 2/2002)
ABNT Brazilian Association for Technical was performed in December 2005, regulating
Norms, founded in 1940, is the organism the addition of dye to anhydrous ethanol ANP
responsible for the technical standardiza- Resolution n. 36/2005 (ANP, 2005), that started to
tion in the country. It supplies the required be commercialized with an orange color, without
basis for the Brazilian technological devel- interfering in the physicochemical characteristics
opment (ABNT, 2008a) and is therefore of the product. The addition of dye was best alter-
responsible for up to date technical norms native to solve the problem of addition of water to
tuned to effective national specifications anhydrous ethanol (used only in the mixture with
and regulations. gasoline) commercialized as hydrated ethanol.
The specification of a product, besides insur-
The supply of biofuels (as well as other fuels) ing its quality, is also a reference standard for the
is considered of public interest and deserves some consumer market. For ethanol, the international
state intervention which in the case of the fuel market points to a growing demand, stimulated
ethanol including production, commercialization, by public policies through the use of renewable
distribution, sale and quality control. It is the re- energies that will lead to a reduction of CO2 net
sponsibility of the State of So Paulo, the country emissions.
leader of ethanol production, to give technical Brazil and the United States of America (USA)
support and to create institutional conditions for are discussing ways to increase ethanol utilization
the three federal regulatory entities to operate in in the world. The idea is to transform ethanol in a
a coordinated and effective way. world commodity such as petroleum, corn or and
coffee. The US is planning to increase internal
FUEL ETHANOL SPECIFICATION ethanol consumption by more than six fold in the
next few years for environmental and social rea-
The fuel specification is defined through a set sons, and is looking for greater cooperation with
of characteristics required for a good performance Brazil in this area.
of the engine, evaluated through internationally Presently, there are important differences
standardized agreed methods. ANP, as well as all between Brazilian and international specifications
the international organisms responsible for fuel for biofuels, in general, and for fuel ethanol, in
specifications, do not regulate the chemical com- particular. For international trade of these fuels
position of the fuels, but establish, through Reso- their harmonization is essential.
lutions and Technical Regulations, specifications In 2007, a Tripartite Task Force was created,
that define the minimum quality requirements for comprising specialists from the European Union,
the proposed utilization. The proposals of the fuels Brazil and the USA, aiming at harmonizing ethanol
specifications elaborated by specialized techni- and biodiesel specifications. On the Brazilian side,
cians are consolidated by the regulatory organ- the group of specialists is coordinated by Itamaraty
ism based on discussions, looking for a consensus (Brazilian Ministry of External Affairs), with the
among the agents responsible for the production participation of ANP, Petrobras, INMETRO, ABNT
and use of the fuels and the environmental organ- and UNICA (WHITE PAPER..., 2007).
Ethanol Quality Regulation 803
Table 1 compares the ethanol specifications The three current specifications are very simi-
(characteristics and limitations) adopted in Bra- lar, mainly because all of them were derived from
zil ANP Resolution n. 36/2005 (ANP, 2005), The a unique specification (the Brazilian one). Differ-
European Union prEN 15376/2007 (CEN, 2007) ences reflect different markets, climate conditions
and USA D4806-07a (ASTM, 2008). in each country and region, and variations in raw
Table 2 (WHITE PAPER..., 2007) classifies materials used for production. A significant differ-
the differences found in fuel ethanol specifica- ence among the three sets of standards is water
tions in 3 categories: (A) similar characteris- content, which is set at different levels, primarily
tics, (B) characteristics with significant differ- due to the varying ethanol concentrations allowed
ences and (C) characteristics with fundamental in gasoline mixture and also to gasoline distribu-
differences. tion differences (WHITE PAPER..., 2007).

TABLE 1 Brazilian, European and North American specifications for fuel anhydrous ethanol.

ANP n. 36/2005 prEN 15376/2007 ASTM D 4806 07a


Property
(ANP, 2005) (CEN, 2007) (ASTM, 2008)

Appearance Clear & no impurities Clear & bright Clear & bright

Color Colorlessa

Acidityb max 30 mg/l 0.007% m 56 mg/l

Electrical Conductivity max 500 S/m

Residue by Evaporation max 10 mg/100 ml

Density at 20C max 791.5 kg/m3

Ethanol content min. 99.3 INPMc 98.7%m 92.1%v

Ethanol content min.d 99.6%v


C3-C5 sat. alcohols max. 2%m
Methanol content max 1%m 0.5%v

Hydrocarbons content max 3%v


Denaturant min-max 1.96% a 5%v

Water content max 0.3%m 1%v

Copper content max 0.07 mg/kg 0.1 mg/kg 0.1 mg/kg

Sulfur content max 10 mg/kg 30 ppm

Sulfate content max 4 ppm

Phosphorus content max 0.5% mg/kg


Inorganic Chloride content max 20 mg/l 32 mg/l

Washed Gum content max 5 mg/100 ml

pHe 6.5 a 9

a
Colorless before dye addition; a 15 mg/l dye content should be added, giving the product an orange color.
b
Defined as acetic acid.
c
INPM = %m.
d
Limit only applies to ethanol not produced by fermentation from sugarcane or ethanol contaminated by other types of alcohol.
Source: ANP, 2005; CEN, 2007; ASTM, 2007.
804 A New Model for Industrial Production and Final Uses of Ethanol

TABLE 2 Classification of the differences of the various bio- country has one or more entities equivalent to
ethanol specifications. ABNT and these entities discuss and harmonize
related matters through the International Organi-
Category (A) Category (B) Category (C) zation for Standardization ISO. ABNT was given
Appearance Ethanol content Water content the responsibility to the secretary of the ISOs
Color Acidity Normalization Committee for the biofuels (WHITE
PAPER..., 2007).
Phosphorus
Density The national ethanol normalization is cur-
content
rently make up from 18 Brazilian norms for the
Sulfate content pHe
characteristics of ethanol and water mixtures, 6 for
Gum/Evaporation
Slfur content
residue
the distribution logistics, 3 for the characteristics
of superior alcohols; 2 for the characteristics of
Copper content
ethanol for industrial use, 9 for the use in engines
Iron content and 2 for the production of fuel ethanol. Table 3
Sodium content presents a complete list of the Brazilian ethanol
norms currently in use. In the context, besides
Source: WHITE PAPER..., 2007.
the national norms, the US norms produced by the
American Society for Testing Materials ASTM
are also largely used (ANP, 2005; ABNT, 2008b).
For bioethanol, the Task Force concluded that The application of technical norms is strongly
there is no technical specification characteristic connected to the technology and regulatory frame-
that constitutes a barrier to trade given the current work. For this reason, it is necessary to update
situation. However, it is recognized that additional regularly in order to make them compatible with
drying and testing will be required by Brazil and the present technological changes of the country.
USA exporters willing to supply the EU market. Therefore, the organizations responsible for nor-
The impact and costs associated with these ad- malization set up technical committees with the
ditional processes have not been evaluated by the objective to keep up with technical changes specifi-
Task Force (WHITE PAPER..., 2007). It is also im- cations and regulations. An example is PROCONVE
portant to know the composition of the anhydrous the national program for the control of the air
ethanol before denaturation in different countries, pollution by automotive industry, coordinated by
in order to establish the quality limits, considering Ibama/MMA (Ministry of Environment), that re-
the different raw-materials (sugarcane, corn, sugar quires a continuous update of the norms for mea-
beet and others) and the processes employed in suring the sulfur content in gasoline and diesel oil.
production. In relation to ethanol norms, there is an ABNT
commission, named ABNT/CEET-00:001.61 A
TECHNICAL NORMS FOR FUEL Temporary Special Commission on Fuel Ethanol,
ETHANOL that revises old norms as well as develops new
ones (ABNT, 2008c).
The technical norms are documents produced
by nationally and internationally recognized orga-
CERTIFIED REFERENCE MATERIALS
nizations that establish guidelines and restrictions
FOR FUEL ETHANOL
for the execution of an activity, service or product.
In general, technical norms are required for the There is a strong need to guarantee and con-
standardization or to make uniform the procedures trol the quality of the chemical analysis, reducing
and actions of the different interested parties. costs, avoidance of analysis duplication, use of
In Brazil, the official organization in charge of Certified Reference Materials CRMs. The CRMs
technical norms for emission is the ABNT. Each are specific materials produced in a certain amount
Ethanol Quality Regulation 805
TABLE 3 Brazilian ethanol norms in use.

Code Title Publication Reference

Ethyl alcohol Determination of acetal, acetaldehyde, ethyl acetate,


NBR10260 acetone, methyl alcohol, superior alcohols and benzene contents by 01.04.1988 Quality
gas chromatography

NBR10266 Alcohols Determination of the brome number 01.04.1988 Quality

Ethyl alcohol Determination of the sodium concentration


NBR10422 30.04.2007 Quality
Methodof flame photometry

Distribution
NBR10425 Alcohols (establish characteristics required for alcohol reception) 01.08.1988
Logistics

Superior
NBR10429 Superior alcohols Determination of total alcohol content 30.08.1988
Alcohols

Superior
NBR10430 Superior alcohols Color stability assay with sulfuric acid 01.08.1988
Alcohols

Corrosion inhibitor additive for fuel hydrated ethyl alcohol Distribution


NBR10517 01.10.1988
Efficiency evaluation as a function of the storage period Logistics

NBR10547 Ethyl alcohol Determination of the electrical conductivity 11.12.2006 Quality

Ethyl alcohol Determination of benzene by ultraviolet


NBR10649 30.04.1989 Quality
spectrophotometry

Hydrated ethyl alcohol Determination of the pH


NBR10891 11.12.2006 Quality
Potentiometricmethod

NBR10892 Hydrated ethyl alcohol for the alcohol chemistry industry 01.01.1990 Industrial Use

Ethyl alcohol Determination of chloride and sulfate concentration


NBR10894 27.08.2007 Quality
Ions chromatography method

NBR10896 Anhydrous ethyl alcohol for the alcohol chemistry industry 01.01.1990 Industrial Use

Ethyl alcohol Determination of iron and cupper concentration


NBR11331 27.08.2007 Quality
Atomic absorption spectrophotometry method

Light road automobile vehicles Measurement of


NBR11481 01.11.2002 Engines Use
evaporativeemissions

NBR11483 Alcohols Determination of the relative density 01.06.1990 Quality

Light road automobile vehicles Determination of emissions of


NBR12026 aldehydes and acetone in the exhaust gas by liquid chromatography 30.03.2002 Engines Use
DNPH method

Distribution
NBR12781 Wagon tank Degasification 01.02.1993
Logistics

Distribution
NBR12782 Wagon tank Tank cleaning 01.01.1993
Logistics

Automotive gasoline Determination of the fuel anhydrous ethyl


NBR13992 01.10.1997 Quality
alcohol content

NBR13993 Fuel ethyl alcohol Determination of the gasoline content 01.02.2002 Quality

Superior
NBR14052 Sugarcane spirit Determination of superior alcohols 01.04.1998
Alcohols

NBR14525 Fuels Determination of gum by evaporation 24.07.2006 Engines Use

NBR14752 Auto motor road vehicles Fuel electric pump Maintenance assays 01.10.2001 Engines Use

continues
806 A New Model for Industrial Production and Final Uses of Ethanol

Code Title Publication Reference

NBR14753 Auto motor road vehicles Injection valve Maintenance assays 01.10.2001 Engines Use

Ethyl alcohol Determination of water content Karl Fischer


NBR15531 08.10.2007 Quality
volumetric method

Ethyl alcohol Determination of non-volatile material content by


NBR15559 28.01.2008 Quality
evaporation

Acetone, ethyl and methyl alcohols Determination


NBR5824 01.07.1986 Quality
ofpermanganate reduction time Barbet Method

Distribution
NBR5991 Plastic packages for alcohol Requirements and assay methods 30.07.1997
Logistics

Determination of density and alcohol content of ethyl alcohol and its


NBR5992 01.03.1980 Quality
mixtures with water

Color use for piping identification in sugar plants and refineries and Alcohol
NBR7485 02.10.1994
alcohol distilleries Production

Alcohol
Safety on installations for production, storage, handling and Production/
NBR7820 01.04.1983
transport of ethanol (ethyl alcohol) Distribution
Logistic

NBR8644 Fuel ethyl alcohol Determination of evaporation residue 17.03.2008 Quality

Corrosion inhibitor additives for fuel hydrated ethyl alcohol


NBR8645 30.10.1984 Engines Use
Efficiency evaluation in carburetors without coating

NBR8689 Light road automobile vehicles Fuels for test Requirements 30.04.2006 Engines Use

NBR9184 Gasoline and alcohol filter Determination of characteristics 01.12.1985 Engines Use

Alternative internal combustion engines for vehicles using fuel


NBR9297 01.03.1986 Engines Use
hydrated ethyl alcohol Verification of calibration requirements

NBR9866 Ethyl alcohol Determination of acidity 11.12.2006 Quality

NBR9868 Ethyl alcohol Determination of formaldehyde content 30.05.1987 Quality

Source: ABNT, 2008b.

and certified afterwards. They are prepared with nol and that the federal government has adopted
the highest metrological quality and focus on three many actions to implement a biodiesel produc-
major functions: tion program, there are only 4 CRMs available in
to help develop better analytical methods Brazil. They are for bioethanol (water content,
(reference methods); density, pH and ethanol content for anhydrous
to calibrate measuring systems used to and hydrated fuel ethanol) and none for biodiesel
improve the commerce of goods, to es- (INMETRO, 2008).
tablish a quality control and to determine
performance characteristics or properties
measurement; QUALITY CONTROL OF FUEL
to insure the adequacy and integrity of ETHANOL
the quality control programs in long-term
Nowadays, in order to guarantee the quality
measurements.
of fuels commercialized in the State of So Paulo,
Despite the fact that Brazil has been, for a long there are monitoring and sample inspection pro-
time, one of the largest world producers of etha- grams, promoted by ANP and the So Paulo Finance
Ethanol Quality Regulation 807
Secretariat, as well as some verifications/controls EXISTENT BARRIERS TO BIOFUELS
performed by the Public Ministry and the Public COMMERCE
Safety Commission generally based on complaints.
Since 1999 the ANP, through agreements Although Brazil is the world largest exporter
established with research institutes and universi- of ethanol, markets suffer from large bottlenecks.
ties, has evaluated the quality of the fuels com- Despite the fact that the US and the EU Commu-
mercialized in Brazil, including the State of So nity have established ambitious targets for ethanol
Paulo, mapping the and directing the enforcement use, the alignment of the Brazilian specification
actions of the agency. with the ones practiced in these countries is ex-
The quality of ethanol (anhydrous and hydrat- tremely important.
ed) produced in the country is presently directly Worldwide, the technical specifications of fuel
controlled by ANP through Quality Certificates ethanol are not centralized in any international
provided by the producers. normalizing organization, with each country adopt-
Through these monitoring and enforcing ac- ing a different specification. Thus, the require-
tions, a reduction was observed (Figure 1) in the ments vary depending on the importing country; in
non-conformity index of the fuels commercialized the Brazilian case the ANP is the national organism
all over Brazil (ANP, 2008b). responsible for setting the specifications of the
Since 2004, the Finance Secretariat of the ethanol produced and commercialized internally.
State of So Paulo, together with ANP, is control- Nowadays, the Brazilian norms not always
ling the quality of gasoline and hydrated ethanol present experimental methods similar or equiva-
commercialized in the state, as well as the fiscal lent to the tests defined by the majority of the
situation of the gas (petrol) stations in several international countries that, in the future, can
urban areas. This action has improved the gasoline represent large commercial partners, importing
station enforcement in the State of So Paulo. Brazilian biofuels.
In order to inhibit fuel adulteration and also Many of the available ethanol norms have
to guarantee their quality, besides the monitoring been effective for more than 5 years and some of
and enforcing programs, there is a Fuel Tracing them have been used for 20 years as mentioned
Program. ANPs Regulation n. 274/2001 establishes (Table3), violating ABNTs own recommendation.
the requirement of adding a tracer to solvents and This situation, alone, increases the probability of
petroleum derivatives selected by the Agency, as having its validity questioned by buyers.
well as the prohibition of the presence of the tracer On the other hand, some of the Brazilian
in gasoline. norms recently updated define quite simple and

20

15 12.6
9.6
10
%

7.3 7.4
6.8 6.5
5.9 4.9 4.9
5 3.8 3.6 3.4 3.9 3.8 3.7
2.6 2.8 3.1
1.9 1.9 1.9

0
2002 2003 2004 2005 2006 2007 March 2008

Gasoline Diesel oil Hydrated ethanol

FIGURE 1 Non-conformity index of fuels in Brazil.


808 A New Model for Industrial Production and Final Uses of Ethanol

low cost methods. This, from one side, facilitates In the case of ethanol, Brazil can be notified re-
the operation of laboratories in the production garding the production process, due to the burning
units, as they do not require additional investment, operation used in sugarcane harvesting, besides
but, on the other side, they do not consider more problems with labor relations. Since these are
sophisticated methodologies indicated in several aspects not regulated by WCO, Brazil should give
international specifications, reducing its accep- special attention to solve them, mainly because
tance by the importers. biofuels commerce is associated to environment
It is true that one of the major bottleneck to preservation.
be overcome related to the technical norms is the Recently, the new attack of the international
reduced availability of specialists working in the community against biofuels has focused the follow-
technical committees. This fact is due to several ing claim: biofuels are using land that should be
reasons, such as the reduced dissemination of the used to produce food. In Brazil, food production
normalization culture among the administration of increased 6.8% in the last harvesting season in
the enterprises, the traditional overload of profes- spite of the ethanol production growth. Still this
sionals in their activities, the cost represented by year, the Federal Government informs, that the
an effective participation and, sometimes, the lack sugarcane zoning will be complited. This document
of appropriate technical committees. will tell where it is possible to plant sugarcane
As already mentioned, these technical barri- and where should be avoided and even forbidden
ers to the commerce of biofuels, in general, and (SELO..., 2008).
specially of fuel ethanol are been analyzed and dis-
cussed by an international Working Group, that is CONTRIBUTIONS TO POLICIES
trying to eliminate them (WHITE PAPER..., 2007). PROPOSITION
In the context of the international market,
Specification and normalization of biofuels
countries are aware against the creation of tech-
nical barriers based on biased regulations that In this quality context, the major demand is
hamper free commerce. The World Commerce the requirement of technical support of the exist-
Organization WCO keeps a notification panel ing Working Groups including the regulatory or-
of cases of technical barriers sent by the interna- ganizations (ANP, INMETRO, ABNT), producers,
tional community, aiming at a fair handling of the automakers, research institutes and universities.
disputes (PERINA; MACHADO; MIRANDA, 2003). These groups aim at specifying the quality required
Besides the technical barriers on the biofuels by the biofuels in order to meet the national and
quality, there are several other barriers that can international demands, looking for harmonization
be created. Presently, it is clear that there is a with the different world specifications. In spite the
tendency to create new barriers related to aspects fact that specification regulation is an ANP assign-
of biofuels production, associated to the require- ment, the State of So Paulo can contribute to the
ment of demonstration of good labor relations process as an inductor, reinforced by the position
in the production units and lack of environment of the largest ethanol producer and consumer.
damage. These aspects will be fundamental to The evolution of the sector normalization has
make business in biofuels international trade vi- not started naturally with this focus, but the pres-
able. The problem related to these requirements ent context makes it more critical that the national
is the fact that a position has not been negotiated norms include, without prejudice of the methods
at WCO. Brazil has tried, through its regulation traditionally employed, the modern methods,
organisms, biofuels producers associations and which are used in the developed countries that are
researchers working in the area, to demonstrate potential importers of biofuels.
the sustainability of the fuel ethanol produc- As a general conclusion, the requirement will
tion from sugarcane (GOLDEMBERG; COELHO; be to stimulate and support an effort to elaborate
GUARDABASSI,2008). Brazilian norms with analytical methods compa-
Ethanol Quality Regulation 809
rable with their equivalents reported in the inter- controlling the quality of the fuels commercial-
national specifications. It is obvious that there will ized in the State, being responsible for the logistic
be questions related to the cost of implementing aspects.
these new methodologies, since some of the old An additional aspect of the biofuels quality
Brazilian norms include low cost methods, that control policy is the incentive to strengthen a na-
did not require high investments by the producers, tional production chain in the State of So Paulo
mainly in training and instrumentation operation. of the required instrumentation for the analysis
A policy of the state of So Paulo should fore- of biofuels, decreasing the dependence of the
see, in a first stage, the support for the instrumen- traditional foreign producers, as well as creating
tation update of the laboratories of the Research new labor posts.
Institutes that support the producers and, in a Considering the aspect of using tracers to
second stage, a policy of incentives to the labora- control the quality of biofuels, it is strategic that
tories of the producers that envision exporting the the Government of the State of So Paulo supports
biofuels. A way to support this industrial sector in the development of new tracers that will allow the
monitoring laboratories to identify possible frauds
updating their infrastructure would be by opening
practiced in the production and distribution of the
special lines of credit in State Banks.
biofuels. Still in this area, the Government of the
Another favorable action in this context would
State of So Paulo should, through organisms that
be the promotion of a Training Program, including
deal with legal matters, discuss with ANP a techni-
updating courses and conferences, for Brazilian
cal alternative to answer the legal questioning of
personnel responsible for the tests and analysis
the impossibility of a complete defense of those
of the biofuels, covering up to date normalization,
accused of fraud, due to the secrecy involved in
if possible with the participation of members of
the use of tracers.
the international normalization committees and
specialists of the major biofuels testing centers.
Quality certificate
The certified reference materials for the bio-
fuels could be prepared from the moment that the The creation of a state quality certificate for
specifications and the norms are consolidated, that the sector or the active participation of the state in
some national primary standards are available and a national certification scheme, being constructed
that the required specific specialized knowledge by Inmetro (INMETRO, 2008b) would be impor-
is defined and available in the academic and tech- tant policies to indicate the quality of the biofuels
nical sector. The Government of the State of So produced in the State of So Paulo. The introduc-
Paulo would be responsible to create incentives for tion of a quality certificate implies not only the
the utilization of the certified reference materials adoption of standards for the product, but also the
by the biofuels producers, including their use as implementation of a tracking procedure in order
an evaluation item for receiving a state quality to make the control of the production links that
certificate. are to be certified viable. In this way, in the case
that some portion of the product does not meet
Quality control the required specifications for commercialization,
it would be easy to identify and analyze the source
It seems important to increase the invest- of the problem and work it out in order to minimize
ment in the present working model (fuels quality its effects.
monitoring, aiming at directing the enforcement The tracking of the chain can be total or par-
actions), since it has produced positive results, tial, considering the economic cost of a tracking
improving even the quality of the new biofuels. system compared with the benefits. Nevertheless,
The Government of the State of So Paulo in the case of compulsory tracking, the scope of the
should establish a policy to create and keep up to process covered is defined by the quality standards
date reference laboratories, for monitoring and that should be reached (MACHADO, 2000).
810 A New Model for Industrial Production and Final Uses of Ethanol

The Social Environmental Certification of the on which process it will focus (only final quality, or
Sugar-alcohol Sector, designed by Imaflora, Embra- production process, workers conditions, environ-
pa Meio Ambiente and Fase (FERRAZ; PRADA; ment respect, among others), is to coordinate the
PAIXO, 2000), establishes several standards for different agents, making the process homogeneous
evaluating and monitoring for the certificate grant: and the data available.
Conformity with the international legisla- Actually, even with the benefits of a qual-
tion and pacts and treaties. ity certificate scheme, reducing the risks in the
Right and responsibility of property and commercialization of the products, a resistance
use of land. towards its adoption can be observed, both from
Fair relationship with the workers. the entrepreneur sector and the technical teams.
Relationship with the community. In order to minimize this resistance, it is essential
Planning, monitoring and evaluation of the to disseminate the largest amount possible of infor-
agro industrial activity, considering technical, mation regarding the implementation procedure
economic, social and environmental aspects. and the benefits and risks in case it is not adopted
Ecosystems conservation and biodiversity
completely. In the case of the technical team, the
protection.
adoption of a training program is essential as a
Soil and hydro sources conservation.
way to support and motivate the implementation
Control of the use of agro-chemicals.
of quality certificates schemes.
Management and utilization of residues and
The implementation of a quality system, al-
other chemical substances.
though costly, will bring large benefits to the sector
Interaction with the landscape.
and its cost can be minimized if the benefits to be
Promotion of the optimization of the use
achieved are clear and there is a strong coordina-
of multiple sources and products of the
tion and cooperation among the agents involved.
agricultural production system, in order
to guarantee the economic sustainability
of the activity. AKNOWLEDGEMENTS
Accomplishment of the pertinent legisla-
The author aknowledges Eduardo L. Machado
tion and promotion of the natural sources
(IPT), Heloisa B. Antonoff (IPT) and Ricardo R.
conservation and workers and community
Zucchini (IPT) who made great contributions to
security in the industrial processing of the
this chapter by writing the Reference Document:
sugarcane.
Instrumentos de Normatizao e Qualidade de
In the case of the biofuels, the challenge, after Biocombustveis for the Bioenergy Special Comis-
the definition of the scope of the certificate, i.e., sion of the So Paulo state in 2007.

REFERENCES
ABNT Associao Brasileira de Normas Tcnicas. Infor- 2008c. Disponvel em: <http://www.abnt.org.br/imagens/
maes gerais da homepage. Rio de Janeiro: ABNT, comites_tecnicos/Relao%20de%20CEE.pdf>. Acesso
2008a. Disponvel em: <http://www.abnt.org.br>. Acesso em: 12 maio 2008.
em: 12 maio 2008. ANP Agncia Nacional de Petrleo, Gs Natural e Bio-
ABNT Associao Brasileira de Normas Tcnicas. Nor- combustveis. Informaes gerais da homepage. Rio de
mas tcnicas para lcool. Rio de Janeiro: ABNT, 2008b. Janeiro: ANP, 2008a. Disponvel em: <http://www.anp.
Disponvel em: <http://www.abntnet.com.br/default. gov.br>. Acesso em: 12 maio 2008.
aspx>. Acesso em: 12 maio 2008. ANP Agncia Nacional de Petrleo, Gs Natural e Bio-
ABNT Associao Brasileira de Normas Tcnicas. combustveis. Boletim da qualidade dos combustveis
Comisses de estudo especiais. Rio de Janeiro: ABNT, ndice das no-conformidades Brasil. Rio de Janeiro:
Ethanol Quality Regulation 811
ANP, 2008b. Disponvel em: <http://www.anp.gov.br/ DIAS, J. L. M. Medida normalizao e qualidade aspec-
doc/conheca/boletim_qualidade/brasil.pdf>. Acesso tos da histria da metrologia no Brasil. Rio de Janeiro:
em: 12 maio 2008. Inmetro/FGV, 1998. 292 p.
ANP Agncia Nacional de Petrleo, Gs Natural e Bio- FERRAZ, J. M. G.; PRADA, L. S.; PAIXO, M. Certificao
combustveis. Resoluo ANP n. 36, de 6 dezembro socioambiental do setor sucroalcooleiro. So Paulo:
de 2005. Ficam estabelecidas, atravs da presente Embrapa Meio Ambiente, 2000. 195 p.
Resoluo, as especificaes do lcool Etlico Anidro GOLDEMBERG, J.; COELHO, S. T.; GUARDABASSI, P. The
Combustvel (AEAC) e do lcool Etlico Hidratado Sustainability of Ethanol Production from Sugarcane.
Combustvel (AEHC) comercializados pelos diversos Energy Policy, Surrey, v. 36, n. 6, p. 2086-2097, jun. 2008.
agentes econmicos em todo o territrio nacional, con- INMETRO Instituto Nacional de Metrologia Normaliza-
soante as disposies contidas no Regulamento Tcnico o e Qualidade Industrial. Material de referncia de
ANP n. 7/2005... Dirio Oficial [da] Unio, Braslia, bioetanol. Rio de Janeiro: Inmetro, 2008a. Disponvel
DF, 7 dez. 2005. Disponvel em: <http://nxt.anp.gov.br/ em: <http://www.inmetro.gov.br/metcientifica/mrc.
NXT/gateway.dll/leg/resolucoes_anp/2005/dezembro/ asp>. Acesso em: 12 abr. 2008.
ranp%2036%20-%202005.xml?f=templates$fn=default. INMETRO Instituto Nacional de Metrologia Normalizao
htm&sync=1&vid=anp:10.1048/enu>. Acesso em: 12 e Qualidade Industrial. Programa brasileiro de certifi-
maio 2008. cao em biocombustveis. Rio de Janeiro: Inmetro,
ANP Agncia Nacional de Petrleo, Gs Natural e 2008b. Disponvel em: <http://www.inmetro.gov.br/pai-
Biocombustveis. Portaria ANP n 274, de 1 de novem- nelsetorial/biocombustveis/>. Acesso em: 12 abr. 2008.
bro de 2001. Estabelece a obrigatoriedade de adio de MACHADO, R. M. Rastreabilidade, tecnologia da informa-
marcador a solventes e a derivados de petrleo even- o e coordenao de sistemas agroindustriais. 2000.
tualmente indicados pela ANP bem como a proibio da 239 f. Tese (Doutorado em Administrao) Programa
presena de marcador na gasolina. Dirio Oficial [da] de Ps-Graduao em Administrao, Universidade de
Unio, Braslia, DF, 5 nov. 2001, Republicada no Dirio So Paulo, So Paulo, 2000.
Oficial da Unio, Braslia, 20 dez. 2002. Disponvel em: PERINA, M. A.; MACHADO, R. Q.; MIRANDA, S. H. G. As
<http://200.179.25.133/NXT/gateway.dll/leg/folder_por- notificaes do Brasil no acordo TBT e a importncia
tarias_anp/portarias_anp_tec/2001/novembro/panp%20 das normas tcnicas no comrcio internacional. In: Con-
274%20-%202001.xml?f=templates$fn=default. gresso Brasileiro de Economia e Sociologia Rural, 41.,
htm&sync=1&vid=anp:10.1048/enu>. Acesso em: 12 2003, Juiz de Fora, MG. Anais... Juiz de Fora: Embrapa
maio 2008. Gado de Leite, 2003.
ASTM American Society for Testing and Materials. Stan- SELO DO INMETRO ZONEAMENTO, LOBBY. o contra-
dard Specification for Denaturated Fuel Ethanol for ataque do Brasil. O Estado de So Paulo, So Paulo,
Blending with Gasolines for Use as Automotive Spark- 20 abr. 2008.
Ignition Engine Fuel: D 4806-07a. West Conshohocken: WHITE PAPER ON INTERNATIONALLY COMPATIBLE
ASTM, 2008. BIOFUEL STANDARDS Tripartite Task Force Brazil,
CEN Comit Europen de Normalisation. Automotive European Union & United States of America, 31 dez.
Fuels Etanol as a Blending Component for Petrol 2007. Disponvel em: <http://www.abnt.org.br/imagens/
Requirements and Test Methods: EN 15376, dez. 2007. destaques/Biocombustivel_WHITE_PAPER_ICBS.pdf>.
Brussels: CEN, 2007. Acesso em: 12 abr. 2008.

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