Professional Documents
Culture Documents
APRIL 2011
RELEASE AGENTS
Chemistry to help create perfect tires,
with increased productivity and profit
TIRE/ROAD INTERACTION
Tire engineers and road
engineers must collaborate
THE SECRETS OF SUCCESS
Meet the winners of the 2011
Tire Technology International Awards
2011s
hottest
technology
This years most innovative
tire developments revealed
PEOPLE
Chuck Yurkovich vice president of global technology, Cooper Tires Osamu Mikami president, Yokohama Europe
Marc Junio general director, Goodyear Innovation Center Luxembourg Hee-Se Ahn vice president of sales,
Hankook Europe Dr Alan Gent University of Akron Jonas Lundberg Reosense Wolfgang Schffl Oerlikon Saurer
A P R I L 2 0 1 1 IN THIS ISSUE
COVER STORY
12 Tire Technology Expo 2011
Discover the cutting-edge innovations, machinery, and
services that will be driving the tire industry forward this year
44
26
RELEASE AGENTS RELEASE AGENTS
REGULARS
Free 4 Update
time
Release agents and mold-cleaning products play a vital role
in the tire production process and are key to reducing defect
The latest tire news, including massive R&D center
levels, overcoming specific molding concerns, and achieving
higher productivity and efficiency
by Adam Gavine
54 Tire legends
technology is Chem-Trend, headquartered which helps reduce the build-up of
in Michigan, USA. The companys mold fouling.
Doug Butcher explains that their R&D However, this is becoming an
department aims to develop products that increasingly difficult task as molds
do more than act as mold release agents. become more complex.
They also overcome specific molding The advances we observe are largely
issues, such as keeping molds in service in the mold manufacturing process,
for longer, and improving tire appearance. helping to improve manufacturing
These products are better described efficiency; these types of advance
as mold treatments, he says. The latest clearly have no bearing on our industry.
developments include products created to However, these mold manufacturing
64 Tire tail
Dr Alan Gent, winner of our inaugural Lifetime
Achievement Award, discusses his past and future
There has never been a greater need for cooperation
and collaboration between road and tire engineers,
but there are challenges in forming such a coalition
by Roger Williams, and Peter Roe, research fellow, TRL
I
t was in the late 1960s that the
tire industry in Europe achieved
significant improvements in wet
grip through the introduction of
the radial tire, improved tread pattern
designs, and the introduction of high-
friction synthetic polymers.
evaluate polymer and tread compound
wet friction. The fine-textured asphalt
was used in evaluating tread pattern
design in terms of water clearance.
The problem then was that neither
proving ground surface was a true
reflection of a real road surface. Also, road
COLUMNS
6 Williams: Rounded thinking
During that period, most tire industry textures of the day had little relationship
evaluations were conducted on proving to the needs of tires and vehicles in terms
grounds using two types of test surface: of optimizing friction, improving ride
smooth gravel pebbles, and fine-textured and comfort, reducing noise, and, as has
asphalt. The gravel was obtained from become required more recently, reducing
Chesil Beach near Bridport, Dorset, the effect on tire rolling resistance.
UK, and the particles were embedded At the same time, the Road Research
in concrete or bitumen macadam. The Laboratory, now TRL, the UKs Transport
material proved popular as a test surface Research Laboratory, was a world leader
and was exported worldwide to the extent in developing an understanding of the
that its widespread use was banned to important road surface characteristics
avoid lasting damage to a geographical that affected skid resistance (the roads
M have reported
the enhancement
of properties by
as a strain sweep test in dynamic mode.
A rubber processing analyzer (RPA)
can test the strength of the filler networks
rewarded.
on the formed interactions between to ascertain the strain dependency
rubber and filler. That can be studied and elasticity of different nano-filled
Published by Head of production & logistics Tire Technology International is published The views expressed in the articles and
Ian Donovan quarterly together with an Annual Review. technical papers are those of the authors
Production team Printed by William Gibbons, Willenhall, and are not necessarily endorsed by the
Carole Doran, Lewis Hopkins, West Midlands, WV13 3XT, UK, and publisher. While every care has been
Cassie Inns, Robyn Skalsky distributed by US Mail Agent, Clevett taken during production, the publisher
Worldwide Mailers LLC, 7 Sherwood Ct, does not accept any liability for errors
Art director Craig Marshall
Randolph, NJ 07869. that may have occurred.
Editor Adam Gavine Art editor Andy Bass
Subscriptions 50/US$90 per year for Contact: Tire Technology International,
Associate editor Roger Williams Design team Abinger House, Church Street, Dorking,
four issues plus Annual Review
Technical consultant Joe Walter Louise Adams, Anna Davie, Surrey, RH4 1DF, UK
Andrew Locke, James Sutcliffe, Periodicals postage paid at Dover, NJ
tel: +44 1306 743744
Nicola Turner, Julie Welby, Ben White 07801, USA. Postmaster: Send address
Contributors fax: +44 1306 742525
changes to: Tire Technology International,
Brian Cowan, Keith Read, Satnam Singh Sales director Colin Scott editorial fax: +44 1306 875824
19 Route 10 East, Bldg 2 Unit 24,
Chief sub editor Alex Bradley Circulation Adam Frost email: tire@ukipme.com
Succasunna, NJ 07876, USA.
Sub editor William Baker CEO Tony Robinson ISSN 1462-4729 Tire Technology Member of the Audit
Managing director Graham Johnson International. This publication is
Proofreaders Bureau of Circulations
Editorial director Anthony James protected by copyright 2011
Aubrey Jacobs-Tyson, Frank Millard
Average net circulation per issue for the period
January 1, 2010 to December 31, 2010: 5,430 copies
e-mail: cm@conti.de
Web: www.conti-cm.com
INDUSTRY
WHATS NEW
FOCUS
n the 1940s, Pierre Marcel Bourdon of Michelin patented It was when considering how the runflat tire of the early
I the steel radial tire and changed tire design forever (date
of application in France: June 4, 1946; patent approval
date: June 3, 1950; patent number: 2,493,614).
The advantages of improved mileage and roadholding met
the needs of the vehicle industry at a time when road structural
1990s vintage could be redesigned to create a tire with runflat
performance but with the weight of a conventional tire that
Dunlop Tyres UK brought together the expertise of its very
different tire design functions, particularly those of the
motorcycle race tire team and research group. The resulting
improvements and increased networks encouraged greater concept became known internally, appropriately, as the CTT
distances to be traveled at faster speeds. Progressively the world tire (Combined Technology Tyre), a name retained today.
road network has enabled the radial concept to prove its worth. At the time, there was the perceived rule that lower aspect
The 1970s marked the start of design modifications to enable ratio car tires had to have a flat profile, but motorcycle tires have
runflat performance, but in general these tires embraced material a rounded profile. The results of the first experiment, in which
development changes rather than fundamental design changes to a large rear motorcycle tire was fitted to a family car, created
the radial concept, with the exception of sidewall strengthening much food for thought. The runflat performance, without any
and bead-lock systems. However, the scene began to change design modification or lubricant, was considerable. Studies of
with the introduction of electric and hybrid vehicles, increased the way the contact patch geometry changed shape with camber,
and tightening tire performance regulations, and the potential cornering or braking suggested the idea of an adaptive contact
of intelligent tires, not to mention the green issue. Is the patch. Force and moment testing suggested some deficiencies
conventional steel radial tire the design for the future? in cornering, but because of the way the adaptive contact patch
There is the need for ever-lower tire rolling resistance, worked, the levels were fairly close to a standard radial tire.
reduced noise, higher wet roadhold, runflat capability, and As a rear motorcycle tire the radial element of its construction
adaptability toward TPMS and intelligent tire concepts. If the was formed by a 0 wrapped textile cord in three layers. It was
tire materials were of a renewable or sustainable category and known that the cut edges of conventional steel breakers can
compounds were totally green, then this would be ideal. initiate breaker edge looseness and tire failure, yet no instances
We are aware that very low aspect ratio tires are not preferred of breaker edge looseness were found in motorcycle tires with
for minimum rolling resistance. It has been shown that for zero-degree breaker construction. This suggested that if adequate
EVs, every 3% reduction in rolling resistance obtains a 2% cornering power can be generated and cords and material of
improvement in range at 60km/h (37mph). Additionally, suitable stiffness found, this could be a viable car tire construction.
any form of spare tire carried around is added weight. The challenges of optimizing and constructing the tread and
Increasing the tire aspect ratio and reducing the cross-section breaker profiles for wear, structural, and dynamic performance
results in a weight saving. Wheel diameter reduction would also were significant, not least due to the tire building methodology.
help to reduce tire weight, but the challenge will be to make These were met knowing the advantages of weight reduction
a small tire acceptable from a marketing point of view and due to the rounded profile design and an inherently good runflat
to ensure that it is of sufficient durability to carry the vehicle performance. Other advantages sought and since achieved
load, even if this is reduced through vehicle design. were enhanced wet roadholding and lower tire-to-road noise
associated directly with the shape of the contact patch.
But perhaps another aspect of the concept and of even greater
importance was the potential to produce a radial tire to a greatly
simplified construction, so easing automated manufacturing.
Patents were filed (ref. Williams, Clarke, and Nock, European
Patent 94309359-1, filed December 14, 1994), and the concept
is now in production incorporated within the third and fourth
generation runflat tires manufactured in Japan by SRI Dunlop
and referred to as CTT tires.
The gap between the conventional tire weight and stiffness
characteristics can be matched by a tire also capable of runflat
ability. Given the specific demands of tire size and shape changes
demanded for EVs, it is becoming apparent that the conventional
tire design may well be replaced. tire
www.tiretechnology-expo.com
JOE WALTER
Several countries that had higher fatality
rates than the USA 20 years ago are now
below the US rate
ighway fatalities continue to decline in many NHTSA studies indicate that all vehicle issues combined
www.tiretechnology-expo.com
THE MOST
SIGNIFICANT
DATES
FOR 2012
www.tiretechnology-expo.com
To book exhibition space
contact: Colin Scott,
KOELNMESSE,
GERMANY
www.tiretechnology-expo.com
REVIEW
The state
of the art
2011s biggest advances
in tire development and
production technology
have just been revealed,
courtesy of Tire
Technology Expo
At Ichimaru-Giken an innovative new Our concept is to circulate the gas inside The Expo was a resounding success for
system to aid curing was on show . the bladder to make an even temperature. the company, with many visitors wanting
The concept of our gas recirculation If we maintain an even temperature inside to trial the technology at their facilities.
system is quite new, said the companys the bladder it will naturally improve the All the big companies and experts are
Shinichiro Fukada. It is being used by quality of the tire. If you have different here. Only experts come here who know
one Japanese tire manufacturer that temperatures, you will have inconsistent about the curing process, so we dont have
we cant name, which is reporting good quality. Our goal, and our customers goal, to explain how our idea works. However,
performance. But now we have completed is to make the temperature even. there are many different types of curing
development, it is time to promote it The technology took almost 10 years press, depending on the customer and the
to other people. to develop, partly because confidentiality materials they use, so we ask them to try the
Fukada explained that many curing meant that customers couldnt provide device and decide if their quality improves.
systems struggle with temperature Ichimaru-Giken with the data they needed. Even though one customer in Japan
differentials between the upper and Instead, Fukada and his team had to visit doesnt give us data because its secret, we
lower parts inside the bladder, as an even, customers to use their curing presses know the system works well because we
constant temperature is what is required. and gather their own data. have received repeat orders, stated Fukada.
3D wheel force
sensors
Visitors interested in wheel force
sensors were intrigued by Expo newcomer
A&D Technologys range. A reason for the
interest was the companys bold claims
of accuracy.
The leaders in wheel force sensors
in Europe are Kistler and MTS, but we
want to enter the market, said managing
director of A&D Europe, Jurgen Brettenbeck.
And we are getting a very positive
response.
The Wheel Force Sensor (WFS) measures
the three directional components of forces
and three components of torque associated
with each directional force while a car is
on the move. The WFS has an accuracy
of 0.1%, and allows for detection of the
effects of rolling friction of the tire on the
road, which in turn makes the analysis of
the effect on a tire in relation to the energy
being transferred from the tire to the Combined with its hardware range, Langs LTire Design software can create intricate designs
car possible.
A&D states that the 0.1% accuracy
is essential to analyze the effects of a tire
or energy loss through a tire a device with
Linear friction testing machine
only 1% accuracy cannot observe these An interesting launch from Altracon was be applied to cover the full operating range
effects because the effects of rolling friction its high-speed linear friction testing (HSLFT) of passenger car and truck tires.
are in the order of 1%. machine, which enables users to determine Test conditions such as asphalt, concrete,
What is unique is that we have a model- friction coefficients of rubber samples on snow, ice, and aquaplaning can all be
based sensor approach where we dont different surfaces and under various simulated. For greater accuracy, the machine
use a strain gauge and amplifier, continued, operating conditions to predict compound can be installed in a climate chamber,
Brettenbeck. We thought about the best and pattern influences on grip and traction allowing a temperature range from -15C
design for the sensor element, making it performance. to +40C. Optional integrated equipment
as linear as possible, and so we feed all The machine can simulate all relevant is available, including an integrated high-
the signals directly into a digital signal tire-testing conditions, with a unique linear speed camera for evaluation of slip and
processing system. We make a model of induction motor with peak performance block bending, a thermograph to measure
the sensor in real time that calculates the of 7,000N to enable sliding velocities up stress facts, or a high-resolution surface
real forces. This approach gives us better to 10m/s, generating accelerations up to scanner for a topographic characterization
accuracy and cross-talk behavior. 100m/s2. Vertical forces up to 3,500N can of applied surfaces.
Following its acquisition by Bosch Rexroth in 2008, drive and control specialist Jurgen Brettenbeck, MD, A&D: We
Hgglunds Drives was keen to demonstrate the advantages to its customers at are new to the expo so we hired a girl to
Tire Technology Expo 2011: greater resources with regard to experience, technological give out advertisements, which really worked.
expertise, solutions, and local and global service throughout their combined international People have been very interested in our
network. The companys range of drive and control products will continue to be sold technology. This show is worth coming
under the Hgglunds name. to, and we will come back next year.
Tire identification
technology
SICK was showing visitors how tires could be identified using the
OPS890 barcode reading system. The system comprises eight CLV490
line scanners arranged to reliably detect the barcode on the tire bead.
The reading system is triggered by two WL18 (A) photoelectric
reflex sensors that are arranged in an X-shape in the reading zone
to reliably detect the tire. Two further WL18 (B) photoelectric reflex
sensors, arranged one over the other, provide fast pre-adjustment
of the code readers focus position. The large depth of field of the
devices does not require any further adjustment.
Paints and
coatings
Chemicals specialist Chem-Trend was
demonstrating its MonoLube inside tire
paints. Doug Butcher was on hand to
explain, Runflats have special requirements,
as air can get trapped between the curing
bladder and the innerliner during curing.
With these coatings, we allow the user to
use a lower coating weight so the inside of
the tire gets a good appearance, but still get
enough air bleed to get low-profile difficult
sections out of the mold without any
trapped air. Thats attractive because these
tires are costly to make and sell at a premium.
The company was also showing its
MonoCoat bladder coating, a room-
temperature curing coating, which,
according to Butcher, is somewhat unique
because most other coatings need to be
baked on to the bladder. It is a very tough,
high abrasion-resistant film, which provides
protection to the bladder surface against
chemical and abrasive attack to make
sure that this area, especially the bead, is
protected. Our customers are recording
a bladder life increase of anywhere between
15 and 40%. That sounds a big range, but
if the bladder is a good fit to the inside of MonoCoat can be applied
the tire then there is less room to improve at room temperature, which
bladder life. is kinder to the bladder
7RXU6WRS1R
Efficient tire testing machine $XWRPRWLYH,QGXVWU\ 6XSSOLHUV
Alfamation was showing its new X-Raptor passenger car radial (PCR) tire testing machine,
which, the company claims, brings next-generation technology to the inspection and
quantitative control of tires. +RZFDQ\RXSURWHFW
The X-Raptor features specially developed software that produces test results that WKHHQWU\SRLQWVIRU
can be easily understood by users and enables simple, reliable, and accurate controls.
The X-Raptors footprint is 35% smaller than other machines, stated president of
FDUERGLHVH[LEO\
Alfamation, Mauro Arigossi. This means that manufacturers can easily install the machine DQGZLWKVFRSHIRU
in plants with less available space. In creating the innovative design of the X-Raptor and
our advanced Automated Defect Recognition (ADR) software, we achieved cost reductions
IXWXUHH[SDQVLRQ"
that we pass on to our customers, ultimately offering a more cost-effective product than
others on the market.
Though only introduced at the expo, the X-Raptor is already in use by a major tire
manufacturer for Formula 1 cars. Other major tire manufacturers are also are looking at 'HWDLOVRQWKHVHQVRUVROXWLRQDW
installing the machine at their tire production plants, according to the company. In addition
to a reduced footprint, the X-Raptors volume and weight are at least 50% less than tire
testers. This compact form-factor makes it ideal for integration in manufacturing lines
or for moving to offsite locations to test tires in batch mode.
With in-line operation, each tire coming from the line is automatically centered and
measured using high-precision light sensors. In offline use, the X-Raptor can be paired
with a manual tire loader in which the tire is loaded and unloaded on the same side of the
machine. With the ADR software installed, each tire image is automatically analyzed and any
flaws are shown to the operator. It can detect faults including belt centering, belt width, cord
angle, cord spacing, and foreign bodies. Engineers can configure the software for use with
a human operator, or in a fully automated mode in which the software makes the pass/fail
ZZZVLFNVROXWLRQVWRXUFRP
decision. The cycle time is up to 15 seconds per tire in its basic working mode..
CO2 mold
cleaning
LKYs mobile CO2 mold-cleaning machine
has been designed to enable removal of
residue from inside the tire mold within 30
minutes, without removing the mold from
the curing press. The machine uses pure CO2
pellets at a temperature of -78C, which are
then propelled into the hot tire mold by
a stream of compressed air, via a nozzle.
Once the pellets hit the residual layer
inside the mold, all remaining grime turns
brittle as a result of the extreme difference
in temperature, and is removed from the Being non-nuclear and
mold surface by the impact of the pellet non-ionizing, the SME
blast. During this process, the CO2 system is safe for humans
becomes gaseous.
A specially designed soundproof feature
inside the machine restricts noise emission Non-nuclear scanning
at close range to as little as 84dB(A). FACTS Inc was showing the latest in its array of measurement technology, the Shadow
Measurement Eddy (SME) Gauge System, which can measure the true total thickness
for both calendered rubber such as innerliners, and textile calendered fabric. The
radiated signal is non-nuclear, and non-ionizing so it is safe for humans and requires
SHOW HIGHLIGHT no special licensing.
One of the highlights of the Expo The system incorporates non-nuclear scanning technology and measures from one
was the Gala Dinner, during which side of the moving web. This technology can be used alone or in conjunction with the
the winners of the Tire Technology companys On-Cal 3 gauges to provide an overall, high-performance calender gauge
International Awards for Innovation control solution. This system scans the overall fabric and compensates for shrinkage.
and Excellence were announced. Because compound has no effect on the measurement, and due to its non-nuclear,
The awards are growing in stature non-ionizing nature, the measurement capabilities of this system are claimed to be easy
every year, and the 2011 event had to implement, and easy to live with. The cost of ownership is minimized since wipe tests,
some particularly strong candidates. field surveys, and a radiation safety officer associated with radiation gauges are eliminated.
Turn to page 35 to find out who The SME Gauge is ideal for applications such as roller head and profile calendars where
won, why, and what they have to say. it is not practical to place gauges on the calender rolls.
Agile
m nd
Cooper Tires develops tires with the very latest features
and agility. Its vice president of global technology,
Chuck Yurkovich, talks frankly about the companys
strategy and vision, and life without OE contracts
by Mike Magda
Cooper debuted in the 2010 Dakar Rally and where Cooper showed off four new
will take part again in 2011 on Discoverer products, including the Zeon RS3-S.
STT tires, Coopers flagship off-road rubber, A low-profile, UHP summer tire, the RS3
which is also designed for wet handling was originally developed with NASCAR
legend Jack Roush for his tuner line
of supercharged Mustangs.
We applied racing technology
developed in Europe and the USA, as
well as some exciting new compounds
and polymers specifically developed to
enhance performance, says Yurkovich.
Coopers racing interests spread
across more than 150 racing series, from
open-wheel events such as Formula 3
and the Atlantic Championship series,
to SCSA series, off-roading, drifting,
and NMRA/NMCA and many other
drag racing series, under the brands
of Cooper Tires, Avon Tyres, and
Mickey Thompson Tires.
Clockwise from top: The Cooper Tire & Vehicle Test Center in Texas has had its track surfaces updated. This can also benefit external users of the
facility; the last few months have seen Cooper invest heavily in manufacturing plants in Mexico and China; the CAFE-complaint GFE; the Zeon RS3
capabilities but would like to see more Alternatives) project, a collaboration really helps you to evaluate real-world wear
defined tools for the dynamics and of agriculture companies, rubber rate or irregular wear, says Yurkovich.
mechanisms of tread wear. He would manufacturers, and universities to develop Cooper is also paying closer attention
also like to see more harmony with auto new sources of raw materials that could, to product field performance assessments
makers modeling. Yurkovich says, someday, maybe in 10 through magazine tire tests, consumer
Typically, youll see tire manufacturers to 15 years, offset 25-40% of the natural reviews that appear on retail sites, and
have very complex tire models and rubber we have to import to the USA. tire discussions in social media on
very simplistic suspension system and Two sources of green materials are being the internet.
vehicle models. Vehicle manufacturers studied, including the Russian dandelion, We also get a lot of unsolicited
have very complex vehicle models which could be compatible with the North feedback through our website, adds
and simplified tire models, says American climate. Yurkovich. In Europe, some of the
Yurkovich. When you get those Tire testing, field performance, and magazine tire tests have a much bigger
to the same state of technology, consumer feedback are priorities for impact on consumer preferences than
then thats a good place to be. Yurkovich as well. The company recently we see in the North American market.
added new surfaces at the San Antonio Typically, these test results demonstrate
Rubber alternatives test track to expand test routines, and our philosophy of not overemphasizing
Given the volatility of oil prices and capabilities, and new options in the lab one particular performance parameter
troublesome shortages of natural rubber, are also being developed. at the expense of overall tire performance,
Cooper is part of the PENRA (Program One of the challenges is to develop but rather our ability to stretch the
of Excellence in Natural Rubber a controlled environment wheel test that overall tire performance envelope. tire
For over 100 years Rhein Chemie has been keeping the rubber industry in motion with innovative solutions. By acquiring
Darmex, we have become a global leader in the manufacture of release agents and are now able to offer tire makers even
greater value. High performance Rhenoshape bladders enable premium quality of the nal products, and thus are the
perfect addition to such innovative products as polymer-bound chemicals, processing promoters, vulcanization and ller
activators, release agents and tire paints.
Free
time
Release agents and mold-cleaning products play a vital role
in the tire production process and are key to reducing defect
levels, overcoming specific molding concerns, and achieving
higher productivity and efficiency
by Adam Gavine
Even the most advanced of curing presses, such as these models from Harburg Freudenberger,
require release agents in order to ensure the finished tire is as good as it can possibly be
Cleaning by laser
No matter how effective the release
agent, the mold surface will require
periodic cleaning. Clean-Lasersysteme
GmbH, which was shortlisted for a Tire
Technology International Award for
Innovation and Excellence, has created
the cleanLASER system to clean tire
mold surfaces using bundled light.
a tire, but the basic challenges of The next steps in Chem-Trends This type of laser cleaning uses no
ensuring optimum rubber flow, good tire release agent technology will, therefore abrasives, chemicals or liquids. Unlike
appearance, and ease of removal from the be driven by the direction in which grit blasting or chemical cleaning, the
mold always exist. One could argue that our partners tire compounds and laser process uses no media so there
these challenges become greater as tire mold designs evolve. Likely short-term is no secondary waste. The method
mold design becomes ever more complex evolution will include better resistance vaporizes and immediately vacuum-
and tire compounds more challenging to mold fouling from stickier high- captures removed coatings and dirt,
to mold. performance summer and winter ensuring a reduction in waste disposal
tire treads, as well as improved- and environmental pollutants compared
Next steps performance sidewall compounds. with conventional ways of cleaning and
So what will the next steps be in release Of course, optimizing rubber flow de-coating. At Tire Technology Expo 2011
agent technologies? Companies, such as across an array of ever-evolving specialist the company also presented its newly
Chem-Trend, work closely with the tire compounds and enhancing release developed sideWALL optic for semi-
industry to develop products that help for increasingly complex tire designs automated cleaning of sidewall molds
them reduce defect levels and overcome will be ongoing technological challenges and engravings a very gentle, efficient,
specific molding concerns to help them for our dedicated development chemists, and fast method.
improve their efficiency. says Butcher.
DREAM
FACTORY
6. Warehousing
5. Palletizing
4. Testing
3. Curing
www.cimcorp.com
CIMCORP IN A NUTSHELL
Automation technology company Cimcorp supplies robotic solutions for managing material ows
in production and distribution environments. Cimcorps purpose-built systems, software and
services improve the protability and competitiveness of its customers businesses.
The Cimcorp group which consists of Cimcorp Oy in Finland and RMT Robotics Ltd in Canada
has become a leading supplier worldwide to the tire industry, and is also regionally strong as
a supplier to the food & beverage and postal services sectors. The group has around 220 employees
and has delivered almost 2.000 robotic systems across ve continents.
CIMCORP OY
Satakunnantie 5, FI-28400 Ulvila, FINLAND
phone +358 2 6775 111
fax +358 2 6775 200
info@cimcorp.com
www.cimcorp.com
North America
RMT Robotics Ltd. (a Cimcorp Oy company)
BENEFIT FROM 635 South Service Road
Grimsby, Ontario, Canada L3M 4E8
phone +1 905.643.9700
OUR AUTOMATION SALES RMTROBOTICSCOM s WWWRMTROBOTICSCOM
Brazil, Parana
EXPERTISE
M2 Concepts Solucoes Empresariais LTDA
phone + 55 41 32052937
murilo@m2concepts.com.br
4
Award winners
secrets of success
The leading lights of the worlds tire industry have been announced at the Tire Technology
International Awards for Innovation and Excellence 2011. These are the stories behind
the headlines
Runners-up:
APOLLO
Apollos remarkable rate of expansion is showing no signs of abating. Following its acquisition of Vredestein Banden in 2009, the Indian
company is entering Europe with an initial range of passenger car tires with speed ratings from T to Y, 4x4, and summer and winter tires,
primarily comprising the top 50 sizes by volume. Also, the companys latest plant, in Chennai, India, shows the companys drive toward
being a Top 10 manufacturer, having been fitted with extensive automated technologies for tire building and inspection. Apollo now
exports to more than 70 countries across the world, and has manufacturing facilities in three continents, with four plants in India, another
four in Southern Africa, and another in the Netherlands. We have a feeling this companys time will come in the awards.
BRIDGESTONE
It has been an impressive year for Bridgestone. In addition to significant research and production advances, the company has taken
a global view of the environmental impact of tires the so-called cradle to grave approach covering the whole product life cycle, from
raw materials, production and distribution, to tire usage and end-of-life disposal. To aid further research, Bridgestone has also commenced
work on a US$100 million state-of-the-art Technical Center in Akron, Ohio. The investment will keep hundreds of jobs in the community.
Meanwhile Bridgestone Europe is expanding steel cord and tire production around the world, and continuing environmental initiatives.
T manufacturing efficiency
has been answered by
Reosense, and rewarded
in this category, which recognizes
scientific and technological excellence
Jonas Lundbergs birthday: what
better present could he receive?
The technology
The technology uses an ultrasound
transducer which sends out ultrasound
waves into the rubber, which reflect and
come back again. It then measures the
echo time, which can vary during curing
because there are variations in curing
time from blend to blend, explains Jonas
Lundberg, managing director of Reosense.
We can compare the cure times from one
production line to another. Humidity, air
temperature, and the properties of the
compound all have variations. Especially
with natural rubber, there is a lot of rubber. These tests showed cure time
variation as it is a natural product. A big reductions of 25-30%. I wouldnt say
factor of cure time is how long it takes to thats representative of tires though
heat up the rubber, so heat conductivity is they are between 10 and 20%. But if
important. This system picks up variations you can reduce your production time by
and adjusts cure time accordingly. even 10% that represents a lot of money,
The system sends a signal to the press because you also increase capacity and
so it opens when curing is complete, productivity, and reduce energy costs.
instead of opening after a fixed cure The first system has been delivered to
time containing a safety margin. This ABB in Sweden, which has reduced the
is no mere theory, as the company has The CureSense system is designed to save cure time on one of its rubber products
completed three case studies on technical energy and time by 20%. CureSense has also been used
on a tire mold with promising results.
Runners-up We are continuing testing, now with
COLLMANN agricultural tires, and we have detected
Collmann was nominated for its VerTiX Tire X-Ray machine with Coll-Tech X-Ray ADR. variation between batches. It looks
This tire handling equipment allows for automatic feeding of any tire size, with the promising and we are open to doing
newest x-ray sensors rapidly producing sharp images. The x-ray image is inputted to an tests with different clients.
Automatic Defect Recognition product that uses data mining and analysis techniques to
qualify tire cord integrity. These techniques are able to input and analyze pixel-to-pixel The way forward
differences in an x-ray of a complete tire that is megapixels in size. This inspection can Having the technology recognized by
occur in seconds, and can distinguish up to four different cord layers within one tire x-ray. the jury has been an important boost
for Lundberg, who states, We have
LMI GOCATOR done a lot of work on technical rubber,
With the Gocator 3D line-based measurement sensor, LMI has emphasized ease of use and getting this award really helps and
through a built-in web browser, measurement tools, and I/O for a complete solution encourages us in the tire industry. Were
in a sensor. The Gocator can be used as a single sensor, dual buddy configuration, very pleased and we look forward to
or up to 24 sensors in a synchronized system. The system is standalone, and a flexible working in the tire industry. There are
configuration means that users can define field of view, MR, exposure, and trigger rate. many different companies interested
in testing CureSense.
W unprecedented levels
of public interest, so it
is fitting that our Tire
Technology of the Year is the Goodyear
UltraGrip Ice+ studless ice tire.
enjoyed so much interest,
and Junio is at the forefront
of the technology
Osamu Mikami
We at Yokohama are very pleased to
receive such an honorable award, states
President of Yokohama Europe GmbH,
Osamu Mikami. We have been actively
achieving our environmental projects
based on our companys mid-term
GD100 strategy. We are delighted that our
attitude toward the environment has been
recognized for example, the Forever
Forest tree planting project, zero emission
goals for our production sites, solar power Further initiatives include solar
and co-generation schemes, and also power. At Hangzhou Yokohama Tire,
our environmental products, such as the companys Chinese subsidiary and
the BluEarth series. factory, 729 solar panels of 100W each
The Forever Forest Project aims to have been installed, supplying about
plant 500,000 seedlings at seven domestic 67,000kWh of electricity annually, about
and 11 overseas production sites. The 0.3% of the facilitys requirement, cutting
past 12 months have seen Yokohama CO2 emissions by about 94 tons per
hold tree-planting ceremonies at all of its year. Yokohama has also installed solar
18 sites. Overall, approximately 183,000 power at the R&D Integrated Center at
trees 36.7% of the goal of 500,000 cleanLASER is an impressive technology which its Hiratsuka factory in Japan, where 120
have already been planted. is proving a success in tire manufacturing plants panels of 87W each will supply about
8,000kWh of electricity annually, cutting
Runners-up: CO2 emissions by about three tons per
CLEAN-LASERSYSTEME GMBH year. Photovoltaic systems have also been
This companys cleanLASER system was developed to clean tire mold surfaces using introduced at the companys Mishima
bundled light, a technology which impressed the jury. This type of laser cleaning uses and Shinshiro-Minami plants in Japan.
no abrasives, chemicals or liquids, and unlike grit blasting or chemical cleaning, the In addition, Yokohamas manufacturing
laser process uses no media so there is no secondary waste. The method vaporizes plants in Thailand and the Philippines
and immediately captures by vacuum any removed coatings and dirt, ensuring have achieved complete zero emissions
a reduction in waste disposal and environmental pollutants compared to conventional status that is, no waste subject to direct
ways of cleaning and de-coating. landfill disposal and Yokohamas Salem
plant in the USA has been recognized
CONTINENTAL CARBON COMPANY as an Extraordinary Environmental
Continental Carbon Company was nominated for the real-time performance monitoring Enterprise in the Virginia Environmental
system it has implemented at its carbon black manufacturing plant in Ponca City, Excellence Program. Looking forward,
Oklahoma, USA. This system provides a level of production efficiency that can only Yokohama has announced a target of
be attained through continuous monitoring of key performance indicators and reducing greenhouse gas emissions by
improving every aspect of the manufacturing process. 25% by 2020 through the use of natural
energies and efficient equipment. tire
For over 100 years Rhein Chemie has been keeping the rubber industry in motion with innovative solutions. By acquiring
Darmex, we have become a global leader in the manufacture of release agents and are now able to offer tire makers even
greater value. High performance Rhenoshape bladders enable premium quality of the nal products, and thus are the
perfect addition to such innovative products as polymer-bound chemicals, processing promoters, vulcanization and ller
activators, release agents and tire paints.
A global insight of tire and tire raw materials supply and demand
Energy reduction through the design of tires, vehicles and roads
The new world of tire manufacturing
Biotechnology and the development of raw materials for tires
Devulcanization technology and the use of recycled rubber materials in tires
Tire retreading, a new beginning
Raw materials for greener tires
Tire filler technology: Black, white and gray
Intelligent tires, the coming essential vehicle component
Sustaining the road infrastructure, a priority for tire and road engineers
Tire technology off the road
The changing science of rubber material chemical analysis
Tire regulations of the future, a global overview
Tire inspection and evaluation, greater speed and greater accuracy
Trends and developments in steel, non-steel cords, and hybrid cords
Natural rubber, a new science and new properties
New approaches and new techniques for tire mathematical modeling
Fundamental research into the performance of rubber compounds
DEADLINES
Title & speaker: 9th September 2011
Powerpoint presentation: 13th January 2012
Full paper not required
Visit www.tiretechnology-expo.com for details or email m.fenner@ukipme.com
TIRE/ROAD INTERACTION
t was in the late 1960s that the evaluate polymer and tread compound
It was also in the late 1960s that accident risk in different road situations.
Dunlop initiated a research program But what has happened since in terms
involving Dr Geoffrey Lees, then of the of road surface developments and what
University of Birmingham, designed will they mean to future tire technology?
to understand the role of road surface Over the years the development
texture levels and tire properties. This climate has changed, shifting from safety
initiative led to the design of a road- (in terms of skid resistance) as the top
wearing-course material designed to characteristic alongside durability in the
optimize tire performance, marketed 1970s and 1980s, toward environmental
as Delugrip Road Surfacing Material. issues, particularly road/tire noise,
throughout the 1990s. Today, with
Dunlop Delugrip greater emphasis on climate change,
Lees great contribution was the ability local pollution, and resource
to design aggregate gradings for the consumption, rolling resistance
asphalt material that took into account is also gaining in interest.
aggregate shape, size, and packing factor. When spray-reducing porous asphalt
This knowledge enabled the creation of materials were being developed it was
grading specifications that were dense observed that they generated much
and impermeable, but had a packing less road/tire noise. Engineers studying
discontinuity at the surface, thus enabling this phenomenon discovered that
the surface macrotexture to be controlled dense materials could be designed to
as required for the particular road have similar properties from a noise
condition. perspective, but with greater durability.
The knowledge gained led directly Such surfacings can be laid in thin layers
back to the tire with the development and have a negative texture form,
of the Shell/Dunlop polymer (SSCP901), with voids below a generally level
the first to be specifically designed to surface rather than the positive form
optimize wet friction and minimize of traditional dense asphalt surfaces
tire rolling resistance. or the use of applied chippings, in
The road surface, Delugrip RMS, was which peaks occur above a mean level.
laid on roads and on race tracks in the
UK and a number of other countries; Macro and mega textures
it was a remarkable achievement for There is also a growing realization of the
a tire company to be in a position to important role of road macro and mega
advise road construction companies texture on tire rolling resistance, and
on road-wearing-course design. Some energy losses in the vehicle suspension.
of the concepts developed then are now The road surface properties that once were
incorporated in modern proprietary regarded as beneficially contributing to
road surface course materials. the reduction in a vehicles kinetic energy
At the time Dunlop acquired when interacting with a tire skidding
a valuable fund of knowledge regarding on a wet road are now seen as leading
road surface properties, which was of to undesirable energy losses in a rolling
considerable use in tire design. The one. This illustrates one aspect of the
work at TRL during this period led on to many balances that now need to be
suggestions for levels of skid resistance on struck between safety and environment.
roads, eventually resulting in the UKs first Emphasis on low-noise surfacings has
nationally applied standards for in-service led to the widespread introduction in
skid resistance, with criteria related to many European countries of proprietary
Textured highways?
One of the UKs leading transport design companies has come up with an ingenious
and simple solution to slow motorists speed and ease congestion on motorways
and dual carriageways.
Paul Priestman of Priestmangoode, the company which worked on designs for the Virgin
Pendolino train, Chinas high-speed trains and numerous leading airlines like Lufthansa
and Swiss, believes a simple solution could be found by laying a textured surface on each
motorway lane, varying in roughness from smooth on the inside slower lane to rough
on the outside overtaking lanes.
Driving for long periods in the overtaking lanes would, it is claimed, present motorists
with a less comfortable (and noisier) ride, subconsciously prompting them to move across
to the slower lanes for the smoothest ride, reducing congestion, reducing speeds overall,
and improving both road safety and fuel efficiency.
Money pits
The question of maintaining the road
infrastructure was brought into focus
after some harsh winters. Following the
2009/2010 winter, the UK reported some
1.6 million potholes, each being capable
of damaging tires and suspensions. It
was stated that it costs UK motorists
1 million (US$1.6 million) per day. It is
estimated that the cost of treating each
pothole was 70 (US$112). Such damage
to roads, initiated by the last winter,
has been exacerbated by years of poor
maintenance. The tire industry needs to support an education program to ensure
that drivers and tire fitters are aware of the safety implications of damaged tires.
There is also the question of chemical and particulate emissions from bituminous
surfaces. Those in the tire industry are well aware of the need to replace some oils in
rubber compounds. Then there is the concern over bitumen supply and what may replace
it as a binder. Concrete road surfaces have advantages and disadvantages. Clearly more
work will be needed if they are to match the best bituminous surfaces in terms of
desirable tire and vehicle performance.
APRIL 2011
2011s
hottest
technology
This years most
tire development innovative
s revealed
PEOPLE
Chuck Yurkovich
vice president of
Marc Junio genera global technology,
l director, Goody Cooper Tires
Hankook Europ ear Innovation Cente Osamu Mikam
e Dr Alan Gent r Luxembourg i president, Yokoh
University of Akron Hee-Se Ahn vice ama Europe
Jonas Lundb president of sales,
erg Reosense
Wolfgang Schf
fl Oerlikon Saurer
:<):*90), -9,,
(5+9,(+;/,
3(;,:;0::<,
65305,
qCZlhZmXajh^kZhq
Hjeea^ZgY^gZXidgnq
GZXgj^ibZci
q>cYjhignde^c^dchq>bV\Z\VaaZgn
mmm$j_h[j[Y^debe]o_dj[hdWj_edWb$Yec
VULCANIZATION
Slow
motion Benny George from the Rubber Research Institute of India
claims he has made an important discovery, with a new way
to control scorch time in peroxide vulcanization
by Satnam Singh
S peed
- wet track - surface structure scan
Endurance - High speed - Rolling resistance - Flat track - hot track
L inear
0,1 - 10000 mm/s
100 m/s
F riction
T esting
Fz 3500 N
Fx 7000N peak
Measurement - Hydraulic - Control unit replacement Check video at www.youtube > HSLFT
Endurance low- and highspeed machine Radial- and linear measurement
Footprint and pressure map scanner High - Low speed linear friction testing
High resolution surface scanner High speed video and thermo picture analysis
GPS repositioning track wear scanner High power LED light systems
56, rue de la gare L-6440 Echternach / Luxembourg Phone:+352 267 207 29 info@altracon.com www.altracon.com
)!$+)(+%'(&+"('*+'*+#+$'
&$ (&"'$')*+#'*'+)*!(+)(+%(&#!+ #%%&(*
*++ '&"&+)(+(#!'#+")*$%("%')* (&#!+ #%%&(*+ ()!"%')*++&*(#'*+'*+++
)!+")$'*+$$%&$ ) &%&+ ()!"%')*+ ()"&$$++ ++&' &*%
+)*%#'*&(+$$%&$+
+
#"'*&$+)(+)!+ ()!"%')*
)%(%)&, " * ',((#,,)(#! " &)(
Quiet visionary
In an era when the art of tire technology was well in advance of
its science, Hanns Peter Zoeppritz (1908-1985) was responsible
for visionary and innovative tire engineering accomplishments
T
Zoeppritz had analyzed more than
vehicle performance were first briefly serving on the Aachen faculty, 50 designs featuring convoluted metal
investigated and understood in he entered Kamms Automotive Research springs in arrangements that would
the 1930s. During this period, Institute in 1936. Thereafter, Zoeppritz provide runflat, highway speed capability
Maurice Olley in the USA introduced joined Phoenix AG in Hamburg in 1946, for military vehicles. Although some
the concepts of oversteer and understeer retiring in 1977 as director of engineering prototypes were massive, these ersatz
and the dependence of same on tire and testing. At Phoenix, his publications truck tires were designed to have load-
cornering stiffness. Olley also quantified focused on skid prevention and road-tire- deflection characteristics comparable
the ride modes of motor cars in terms of vehicle interactions. to pneumatics. Many of the airless tire
vehicle geometry, inertia, and suspension His most memorable achievement concepts evaluated by NASA for the
properties. Vehicle engineering studies while at Stuttgart was the development Lunar Rover vehicle of the 1970s were
were also underway at the Automotive in 1942 of the worlds first high-speed, motivated by his concepts.
Research Institute established in 1930 flat-track tire test machine for quantifying Rubber-saving pneumatic tires
at the Technical University Stuttgart. the steady-state cornering force-slip angle were another Zoeppritz innovation.
The main thrusts of the German efforts response of tires. Such data is required The overall diameter and air volume
under the leadership of the Institutes to assess the ability of a proposed tire- of such tires were the same as that of
director, Wunibald Kamm, were in the vehicle system to effect lane change the original design, but with sidewalls
areas of engines and aerodynamics. maneuvers and negotiate curves, and halved and replaced by an extended rim.
Kamm built the first full-scale automotive to judge its over/understeer tendencies. Experiments were conducted at Stuttgart
wind tunnel facility and influenced the In the USA, Olley had pushed in 1943 on a 5.50-16 prototype tire built
design of the BMW 328 Kamm Coupe. Goodyear to make such measurements, by I.G. Farbenindustrie in Leverkusen.
Stuttgart remains the wellspring of and this was done in 1935 but Tire weight and rolling resistance were
pioneering vehicle manufacturing and on the industry-standard roadwheel reduced, while vertical stiffness and
technology. Robert Bosch established dynamometer (300 revolutions per mile). cornering forces were increased. This
his automotive supply company there To this day, various rules of thumb exist is todays marketing-driven plus-sizing
in 1886, and was active in funding many to convert roadwheel cornering force craze, but developed years ago for
university activities until the mid-1930s. data to flat surface results, with varying the purpose of conserving scarce raw
Gottlieb Daimler built the first motor car success. Zoeppritzs achievement obviated materials, not for styling reasons.
there in 1889, and Ferdinand Porsche the need for this approximation, but only Zoeppritz anticipated by decades
built his prototype peoples car in came to the fore when commercial flat- many aspects of tire design and testing
a Stuttgart garage in 1934. Also coming tracks were commercialized decades that we take for granted today. He also
from Stuttgart were the tire innovations later by Calspan (1973), MTS (1980), authored many prescient papers while
of Dr-Ing. H. P. Zoeppritz. and most recently, TMSI (2009). at Stuttgart dealing with irregular tread
Zoeppritz was educated at Dresden Zoeppritz also developed non-rubber wear, footprint pressure distribution, cord
and obtained his doctorate from Aachen tires during World War II. At that time, flex fatigue, and in-vehicle control of tire
(1935), specializing in textile mechanics with natural rubber in short supply, pressure (including the spare), among
as he was in line to inherit the familys many warring nations were steadfastly other topics accomplishing this in an
long-established wool operations. investigating artificial tires mechanical era when the art of tire technology was
However, the great global depression devices devoid of rubber. By 1943, well in advance of its science. tire
ONLINE
FREE
digital version!
mmm$j_h[j[Y^debe]o_dj[hdWj_edWb$Yec
READER
ENQUIRY
SERVICE
qCZlhVcYZmXajh^kZhqHjeea^ZgY^gZXidgnqGZXgj^ibZciq>cYjhignde^c^dchq>bV\Z\VaaZgnqGZVYi]ZaViZhi^hhjZdca^cZ
Find out further details about the advertisers in this issue online at: www.ukipme.com/recard/ttmcard.html
TEIJIN ARAMID
tires@teijinaramid.com
www.teijinaramid.com
SM
TIRES, WHEELS & VEHICLE COMPONENTS TOUGH ON TESTING
TRANSPORTATION TESTING
1845 Harsh Ave. S.E., P.O. Box 758 Massillon, Ohio 44648-0758 USA
TESTING SYSTEMS FOR INDUSTRY
Phone: 330.833.8548 1.800.833.8547 Fax: 330.833.7902 www.stllabs.com
UNIVERSITY FOCUS
Big
ideas
The effects of Black and clay nanoparticles on styrene-
butadiene rubber have been put under the microscope
at two of Irans foremost research institutes
by Mohammad Karrabi, Iran Polymer and Petrochemical Institute,
and Somayyeh Mohammadian-Gezaz, Islamic Azad University
M have reported
the enhancement
of properties by
incorporation of nanofillers into
polymers. Using different types and
as a strain sweep test in dynamic mode.
A rubber processing analyzer (RPA)
can test the strength of the filler networks
and the filler-rubber interactions in
the green compound, as well as in the
concentrations of nanofillers, the obtained vulcanizate, in a wide range of shear
nanocomposites can exhibit enhanced amplitudes. Using this instrument, the
properties relative to the virgin polymer, viscoelastic responses of the gum, master,
such as better mechanical properties, and final compound can be detected.
lower permeability against gases, higher As a response to increasing strain,
heat deflection temperature or higher rubber compounds show a non-linear
flame retardancy. viscoelastic behavior, which is detected
In addition, the concentration and as a drop in the elastic modulus versus
type of fillers significantly affect the strain. In addition, tan b (G/G) increases
viscoelastic behavior of the polymers. when the strain rises, recognizing that
Normally, filled rubber compounds have the energy of dynamic deformation is
an ability to dissipate the main part of dissipated. Fillers can affect this strain-
the mechanical energy applied during dependent trend in rubber compounds.
deformation by damping, which depends In this work, attempts have been made
on the formed interactions between to ascertain the strain dependency
rubber and filler. That can be studied and elasticity of different nano-filled
Scheme 1: Possible filler-rubber interactions for Black and nanoclay. Black particles can be found in Black networks or dispersed Black-rubber bonds
compounds. In this way, SBR compounds nanofillers have higher viscosity than net Nanoclay
having various amounts of clay (closite SBR. In the presence of filler, the modulus As seen in Scheme 1A, nanoclay (layered
10A) and Black (N550) nanoparticles increases and flowability declines so the silica) can be dispersed in three different
were prepared, and the effects of viscosity increases. As the Black amount forms of flocculated, intercalated, and
nanofillers type and content on the d* rises incrementally, the linear zone exfoliated. In the flocculated form, clay
viscoelastic behavior were studied of the strain domain becomes shorter. layers aggregate separately from the
during the strain sweep tests. By adding 70phr N550, the viscosity polymer phase, which happens with
growth is 10-times larger and the curve insufficient mixing conditions or very high
Methodology state changes to fully non-linear form. concentration. By applying a suitable shear
Table 1 depicts some information about Higher nanoclay content also made an force, especially at higher temperature,
the materials used in this study and increase in the viscosity, with less effect the clay layers move away from each
the formulations of samples. Based on on the linear zone than with Black. other; consequently, the intercalated and
previous work in evaluating the effect It is interesting that 9phr of nanoclay exfoliated form are achieved. In previous
of processing conditions and nanoclay is more effective than 30phr of N550 work, it was concluded that compounds
content on the properties of SBR/ on the viscosity value, with a less containing 3phr, 6phr and 9phr nanoclay
organoclay nanocomposites by response disturbing effect on the linear zone. prepared at the previously mentioned
surface methodology, mixing conditions Viscoelastic behavior of compounds is mixing conditions achieve the desired
were selected to ensure the best dispersion dependent on the inter-molecular bonds intercalated or exfoliated morphology.
of the filler in the SBR matrix. of rubber chains and filler particles. The filler-based interactions explained
An RPA 2000 from Alpha Scheme 1 illustrates possible filler-rubber in Scheme 1 are responsible for
Technologies UK was used to investigate interactions for Black and nanoclay differences in viscoelastic behavior of
the viscoelastic properties of filled schematically. Black particles can be filled and unfilled rubber. Zero shear rate
compounds and gum. Strain sweep tests found in the Black networks or dispersed viscosity (d*0) is larger for SBR filled
were done using RPA at the temperature Black-rubber bonds. Under the shear with nanoparticles, increasing with filler
of 100C (212F) and the frequency of forces, breakdown of Black aggregates by amount. This is because of the restrictive
1.68Hz in the 0.1-100% strain domain. applied strain is a viscous response while influence of filler on the flowability
Figure 1 shows the complex viscosity the stretching of Black-rubber bonds is an of rubber chains.
(d*) of compounds versus the applied elastic response, until abruption at higher
strain. As can be seen, samples containing strains produces viscous deformation. Critical strain
Another parameter obtained from the
strain sweep test is the strain at which
Table 1: Materials and formulations of samples the modulus or viscosity curve is
Material Content (phr) Grade Supplier deviated from the linear state, called the
critical strain. Critical strain is affected
SBR 100 SBR-1500 Bandar Imam Petrochemical
meaningfully by the type and loading of
Clay 3, 6, 9 Cloisite 10A Southern Clay Products, USA nanofillers. With increasing filler content,
CB 30, 50, 70 N550 Pars Co, Iran the non-linear region starts from the lower
Aromatic Oil 10 Behran Behran strain. This observation is probably due to
filler-based structures, which are sensitive
Scheme 1A: Possible filler-rubber interactions in Black-filled compounds. Nanoclay can be dispersed in flocculated, intercalated, or exfoliated forms
to the applied strain undergoing the non- in comparison with net SBR, hence prepared. The effects of the nanofillers
linear irreversible breakdown. At higher more elasticity. It results from the elastic type and content on the viscoelastic
Black loading, there are more networks to stretching of clay-rubber bonds, which behavior were studied, performing
break down and the shifting in the critical enhances the elasticity of the compound. the strain sweep tests. The following
strain is more obvious. In nanoclay- However, Black has two different effects conclusions were formed: the complex
filled compounds, considering only the on tan b. At lower strains, Black-filled viscosity of filled SBR was higher than
formation of intercalated or exfoliated SBR exhibits more elastic behavior than SBR unfilled, with higher loading and larger
structures, there is no filler agglomeration gum, while at higher strains, the reverse viscosity; 9phr of nanoclay had a greater
to break down so the linear zone is trend appears. The elastic stretching effect on the viscosity values than 30phr of
broader than that of Black-filled SBR. of Black-rubber bonds at lower strain Black; in the presence of both nanofillers,
The curves of damping factor (tan make the elasticity rise; and at higher the critical strain reduced, especially in
b) versus strain are plotted in Figure 2 strains, more energy is dissipated, due to the case of Black; with increasing filler
for SBR compounds filled with various the viscous breakdown of Black-based concentration, the non-linear region starts
nanoparticles. As known, smaller tan b interactions, which increases the elasticity. from the lower strains; and compounds
indicated a stronger elastic manner so the containing nanoclay had a more elastic
elasticity of samples can be investigated, Conclusions nature than gum. Finally, Black had two
paying particular attention to the In this work, SBR compounds, with effects on elastic behavior: at low strains
variations of tan b. In the presence various amounts of clay (closite 10A) it caused more elasticity, but the reverse
of nanoclay, lower tan b is observed and Black (N550) nanoparticles were trend was recognized at high strains. tire
Figure 1: Complex viscosity vs strain with different nano filler loadings Figure 2: tan b vs strain for compounds with different nano filler loadings
Erhardt+Leimer GmbH
Albert-Leimer-Platz 1
86391 Stadtbergen, Germany
Phone ++49 (0)821 24 35-531
Fax ++49 (0)821 24 35-320
info@erhardt-leimer.com
www.erhardt-leimer.com
Index to Advertisers
Altracon SA ....................................................................... 53 Erhardt & Leimer GmbH .................................................... 62 Standards Testing Labd (STL)............................................ 57
A-Z Formen- und Maschinenbau GmbH ............................ 53 Kiswire Ltd ......................................................................OBC Teijin Aramid BV ............................................................... 57
Bosch Rexroth................................................................... 19 Kontrukta-Industry AS...................................................... 55 Tire Technology Expo 2011 ........................................7, 9, 10
BST International GmbH .................................................... 55 Rhein Chemie Rheinau GmbH ........................................... 25 Tire Technology International Online Enquiry Service......... 49
Cimcorp Oy ............................................................31, 32, 34 Samson Machinery Inc...................................................... 49 VMI Holland BV..................................................................IFC
Continental Reifen Deutschland GmbH.................................3 SICK AG............................................................................. 17 www.TireTechnologyInternational.com.............................. 56
INDUSTRY PEOPLE
Dr Alan Gent, a revered name in the tire industry, and recipient of the
inaugural Tire Technology International Lifetime Achievement Award,
shares his memories of a career in rubber