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T H E O R Y OF F E R R O M A G N E T I C H Y S T E R E S I S t
D.C. JILES
Ames Laboratory , Iowa State University, Ames, 1.4 50011, USA
and
D.L. A T H E R T O N
Physics Department, Queen's University, Kingston K7L 3N6, Ontario, Canada
A mathematical model of the hysteresis mechanism in ferromagnets is presented. This is based on existing ideas of domain
wall motion including both bending and translation. The anhysteretic magnetization curve is derived using a mean field
approach in which the magnetization of any domain is coupled to the magnetic field H and the bulk magnetization M. The
anhysteretic emerges as the magnetization which would be achieved in the absence of domain wall pinning. Hysteresis is then
included by considering the effects of pinning of magnetic domain walls on defect sites. This gives rise to a frictional force
opposing the movement of domain walls. The impedance to motion is expressed via a single parameter k, leading to a simple
model equation of state. This exhibits all of the main features of hysteresis such as the initial magnetization curve, saturation
of magnetization, coercivity, remanence, and hysteresis loss.
t Research supported under contract from the Canadian De- Early investigators in the field of m a g n e t i s m
partment of Energy, Mines and Resources (CANMET, considered several possible explanations for the
Physical Metallurgy Lab.,) and the National Research p h e n o m e n o n of ferromagnetic hystersis. These hy-
Council of Canada (Industrial Materials Research Institute).
potheses fell b r o a d l y into two categories, one of
Operated for the US Department of Energy by Iowa State
University, under contract no. W-7405-Eng-82,supported by which suggested that a frictional type force was
the Director of Energy Research, Office of Basic Energy responsible a n d the other which considered hyster-
Sciences. esis as due entirely to the strong m u t u a l interac-
tions between the individual magnetic moments. In the past there have been many attempts to
The original suggestion of a restoring force which fit equations to actual magnetization data, how-
tried to maintain the moments in their initial ever no single satisfactory equation has been de-
unmagnetized state was due to Weber [3]. How- veloped to describe the processes involved in this.
ever, although this would be able to explain the Consequently, attempts to describe the behavior
shape of the initial magnetization curve, it would of ferromagnets have always been handicapped by
be unable to explain residual magnetization once their restriction to only narrow ranges of field.
the applied field was removed. Wiedemann [4] According to the review by Cullity [7] in only
postulated the existence of a frictional resistance three instances have algebraic expressions been
to rotation of the "magnetic molecules", as he obtained for the curves. These are, high field
called them, an idea which lends quite well to magnetization curves of single crystals, as in the
account for the most obvious effects of magnetic work of Williams [8], high field magnetization
hysteresis. curves of polycrystals which are governed by the
Maxwell [5] appears to have been the first to law of approach to saturation as indicated by
suggest that hysteresis could be explained in terms Chikazumi [9] and low field magnetization curves
of the mutual interactions of an array of magnetic and hysteresis loops of polycrystalline specimens
moments. This idea was pursued further by Ewing which exhibit Rayleigh loops [10].
[6] who believed that the mutual magnetic interac- The recurring problem in previous attempts to
tions could entirely account for the phenomenon. obtain a hysteresis function has been that either
Ewing's concept was supported by some simple an extremely comphcated mathematical function
calculations which showed that the essential fea- could be used to describe the behavior to an
tures of hysteresis would be obtained from a small arbitrary level of accuracy but with little or no
number of strongly interacting moments. Ewing's theoretical basis, or alternatively, a simple func-
influence was such that the concept of mutual tion, obtained from first principles, could be used
interactions being totally responsible for hysteresis which, although it has a good theoretical founda-
50 D.C. Jiles, D.L. A therton / Theory of ferromagnetic hysteresis
tion did not characterize real materials with suffi- is too restricted a concept. Domain walls are also
cient accuracy. pinned by inhomogeneities within a grain, for
The usual approach to the empirical curve fit- example tangles of dislocations, regions of inho-
ting method has been the use of power series as in mogeneous strain and any precipitates or nonmag-
the work of Brauer [11] or the use of rational netic inclusions within a grain. In addition the
polynominals as in the work of Fischer and Moser locations at which the domain walls are planar we
[12], Trutt [13] and Widget [14]. A more recent believe are on the anhysteretic magnetization
application of the rational function method has curve, not at remanence as suggsted by Globus.
been made by Rivas, Zamarro, Martin and Pereira For materials with high anhysteretic susceptibility,
[15] in which families of major hysteresis loops of course, these locations will be very close to the
have been generated and the results have shown remanence point on the M , H plane.
good agreement with experimental data. It is More recently the problem of modelling mag-
noticeable that Rivas et al. used two generating netization curves of ferromagnets has received at-
functions which were added to give the correct tention from Porteseil and Vergne [27] who studied
behavior. These functions bear a marked resemb- the magnetization process from consideration of
lance to the two terms of the equation derived on Bloch wall motion in polycrystalline ferromagnets
the basis of the present model, the anhysteretic and the interactions of these walls with structural
function and its derivative. Although Rivas et al. defects. They then calculated the magnetization
[15] had no theoretical justification for summing curves. However this model only took into account
two such functions, the present work indicates irreversible domain wall motion in the low field
why such an approach is correct. region, it did not fully consider reversible domain
The theoretical approach to the problem of wall motion. Further experimental investigations
hysteresis has involved generally one of two meth- were undertaken by Astie, Degauque, Porteseil
ods. Calculations based on the Preisach-N6el and Vergne [28], Degauque and Astie [29] and
model [16-18], two of the most recent of which Astie, Degauque, Porteseil and Vergne [30]. In one
have been by Del Vecchio [19] and by Rahman, of these papers [29] the authors state that in low
Poloujadoff, Jackson, Perrard and G o w d a [20]. magnetic fields the magnetization is due to the
However a serious drawback of the Preisach model displacement of the magnetic domain walls. Al-
is its aribitrary nature. The other method, which is though it is true that at low fields domain wall
theoretically sounder, is based on the micromag- motion dominates the magnetization process com-
netics theory of Brown [21] and Aharoni [22]. pared with domain rotation, we consider, in accor-
However this method does not yield a simple dance with Globus, that domain wall bulging (a
equation of state for a ferromagnet which was the reversible process) and domain wall displacement
objective of the present work and consequently (an irreversible process) are both important in this
this method will not be considered further. region and that an irreversible mechanism alone is
Globus [23] and Globus and Duplex [24-26] unrealistic.
developed a model of domain wall motion which The present paper describes a model of hyster-
was able to explain qualitatively the general shape esis which generates the familiar sigmoid-shaped
of hysteresis curves of ferromagnetic and ferri- hysteresis loops by considering impedences to do-
magnetic materials. Their model assumed that do- main wall motion caused by pinning sites encoun-
main walls were pinned only on grain boundaries tered by the domain walls as they move. The
by a type of frictional force. Under the action of a existence of such pinning sites was first suggested
field the domain walls underwent first a reversible by Kersten [31,32] and by Becker and D~ring [33].
motion due to domain wall bulging and later an For the purposes of the model no distinction has
irreversible motion due to domain wall displace- been made between the different types of pinning
ment. These ideas are very much in accord with sites. A mean pinning energy per site is used and
the model presented here, except that we believe the pinning sites are assumed to be uniformly
pinning of domain walls on grain boundaries only distributed throughout the solid. Such assump-
D.C. Jiles, D.L. A therton / Theory of ferromagnetic hysteresis 51
3. Normal magnetization
Fig. 2. Elementary form of hysteresis loop with switching from
extreme magnetization states. The curves were obtained as the Although the Langevin equation works quite
solution of eq. (6) with the following values of the parameters:
Ms=l.6x106A/m, a =1100 A/m, a= 410 -3 . well for describing the magnetization of a para-
magnet, the modified Langevin equation does not
give such a good description of the normal dc
magnetization of a ferromagnet because the model
ignores the possibility of the change of magnetiza-
tion being impeded, as for example when the
M/MS 1.2
1.0
MS= I . 6 NA/M
o - I i 0 0 A/M
k= 0
o l p h a = I . 6E-03 ///7
z
]E
0.8
/
7
(-87. 50~ 0.4
1 I
5 10
H (kA/rn]
Fig. 3. Solution of the anhysteretic magnetization eq. (6) with Fig. 4. Experimental initial and anyhysteretic magnetization
the following values of the parameters: M~ = 1.6 x 106 A / m , curves for a sample of iron containing 0.1 wt% carbon mainly
a=ll00A/m, ~ = 1 . 6 1 0 3. as Fe3C precipitates.
D.C. Jiles, D.L. A therton / Theory of ferromagnetic hysteresis 53
<~pin> = (%)(1 - cos 0). (12) and - 1 when H increases in the negative direc-
tion, d H / d t < 0, ensuring that the pinning oppo-
The total energy dissipated through pinning ses changes in magnetization.
when a domain wall of area A is moved through a This equation of state for a ferromagnet under
distance x between domains whose moments lie at the given conditions has been given previously
an angle 0, Epin ( x ) is given by [37]. The coefficient k is not constrained to be
constant and may vary as a function of M and H.
Epin(X)
= f-10
xn<% ) (1-cosO)Adx.
2 "-
(13) Nevertheless, the form of the solution remains the
same whether k is constant or not, only the shape
The net change in magnetization of the ferro- is modified by variable k.
magnet (remembering that by symmetry there will It should be noticed then that the form of eq.
be a number of domains at an angle 0 to the field (18) is free from any limitations which may be
direction such that the component of magnetiza- imposed on its generality by a choise of a specific
tion perpendicular to the field due to these do- function to model the anhysteretic. In order to
main will be zero) will be make use of it, however, some assumptions have
to be made as to the form of Ma. as a function of
d M = m(1 - cos O)A dx, (14)
field. We have found that an empirical form of
substituting into equation (13) leads to Langevin function models most forms of anhys-
teretic curve very well.
Epin(M) _ n(%) t'MdM" (15) The differential eq. (18) may be rewritten in a
Fm Jo more convenient form as
Replacing k = n ( c , ~ ) / 2 m therefore gives
dM 1
(man--m) (19)
Epi. ( M ) = k f M d M. (16) dH 8k/tto - or(Man - M )
J0
which shows that apart from the perturbation due
3.3. The irreversible magnetization process to the coupling of magnetization, expressed
through the coefficient a, the rate of change of
Hence under the assumptions of a uniform magnetization M with field is proportional to the
distribution of pinning sites, and treating each one displacement from the anhysteretic, M a , - M,
as having the mean pinning energy, the total work which is a useful result.
done against pinning is proportional to the change
in magnetization. The magnetization energy 3.4. Domain wall motion of flexible domain walls
f M d B e from equation (8) is now the difference
between the energy which would be obtained in One of the central assumptions of the models
the ideal or lossless case fMa,(He)dB e minus the of Becker and DSring [33], Kersten [32] and
loss due to hysteresis, k f d M Kondorsky [40] is that the domain walls are planar
and rigid. Among other features of these models
the hypothesis of planar walls was criticized by
fMdSe= fMan(ne) dBe-kf(~-~8~)d~o (17) Nrel [41] who noted that the domain walls should
be flexible in order that the walls could be dis-
and consequently, differentiating with respect to placed without ever being completely unattached
Be. from pinning sites. Later Kersten [42] published a
revised theory which included the expansion, or
M = Man - - 8k(dM/dBe). (18)
bending, of domain walls under the action of a
This is the model differential equation of hys- magnetic field.
teresis. The parameter 8 takes the value + 1 when When the domain walls bend while being held
H increases in the positive direction, d H / d t > 0, for example on two pinning sites as shown in fig. 5
D. C. Jiles, D.L. A therton / Theory of ferromagnetic hysteresis 55
the linear displacement, r is the radius of curva- It is now necessary to make some assumptions
ture and 2 y is the distance between pinning sites. concerning the dependence of Mre v upon x. It is
By simple geometry not possible to take into account every possible
x=r-~/(r2-y 2) (21) situation and geometry. Naturally there will be an
almost infinite number of possible configurations
and if E is the surface energy of the domain wall in which domain walls interact with defects, be
and P is the excess pressure caused by application they regions of inhomogeneous strain, point de-
of the field, fects, dislocations, nonmagnetic inclusions or grain
boundaries.
P = 2E/r, (22) Therefore consider the situation in fig. 5 and
so that suppose, like Globus and Duplex [42] that a do-
x = 2E/P - ~/(2E/P) 2 _y2 (23) main wall bisects a spherical grain and is pinned
at the grain boundary. Under the action of a field
and using a binominal expansion on the square the domain wall is deformed reversibly through a
root term, distance x. The volume swept out by the domain
wall is AV('rr/6)x(3y2+x 2) and the change in
x- p ~- ~ + .... (24) magnetization will be Mrev = 2AVm if the mo-
ments in the two domains are parallel and anti-
x -~ y 2 p / Z E , (25) parallel to the field.
for small displacements this expression relating x Consequently, substituting from eq. (29)
to the excess pressure P becomes exact. m~y4C' (Man - M )
Now consider the actual form of the pressure P Mrev - 4E
on the domain wall. The fundamental idea of the ~r(y2 )3
model presented so far is that the force experi- +m- 5 -4-~C'(Man- M) (30)
enced by the domain walls is not simply due to the
applied field, but is due to the applied field minus and as in the Globus analysis [42] neglecting terms
a contribution due to the tendency of a ferromag- of order greater than x2 leaves
net towards a random orientation of its domain
configuration. Mrev = C( Man - M ) , (31)
It is implicit in the model presented so far that where now the coefficient of proportionality is
the effective magnetostatic energy is given to c = ( m ~ y a / 4 E ) C '. The value of the coefficient c
within a coefficient of proportionality by, is determined experimentally by the ratio of the
initial differential susceptibilities of the normal
E = ( M - Ma,) 2, (26)
and anhysteretic magnetization curves, c =
and that the force on the domain walls is X0 . . . . /X0anhys" Consequently the amount by which
the domain walls bulge before breaking away from
F = (Man - M ) . (27) their pinning sites, and hence the reversible com-
The pressure on the domain walls will then be ponent of magnetization, is for small displacement
simply linearly dependent on Man - M.
M/MS
The irreversible c o m p o n e n t of magnetization is 1.0 Q:
Solutions m a y be obtained either by solving eq. Fig. 6. Theoretical anhysteretic magnetization curves obtained
as solutions of eq. (6) with the following values of the parame-
(34) directly or alternatively b y solving eq. (19) ters: M s = ] . 6 1 0 6 A/m, k = 0 , a = 1 . 6 X 1 0 - 3 . Values of a
a n d then adding Mre v using eq. (31). are given on the figure.
M/MS
the a l t e r n a t i n g field a m p l i t u d e reaches zero. A n
1.0 e x a m p l e of an e x p e r i m e n t a l anhysteretic curve for
a s a m p l e of steel used in the present work is given
in fig. 8. This is c o m p a r e d in the figure with
theoretical anhysteretic curve d a t a o b t a i n e d by
using a curve fitting r o u t i n e to d e t e r m i n e the
values of the p a r a m e t e r s M s, a a n d a in eq. (6). A
a
large n u m b e r of anhysteretic curves have been
d e t e r m i n e d e x p e r i m e n t a l l y b o t h for different sam-
ples of steel a n d u n d e r different c o n s t a n t a p p l i e d
u n i a x i a l stress. In all cases, the solutions of eq. (6)
0"5 with different values of the three p a r a m e t e r s , gave
an excellent fit to the curve.
M/MS M/MS
l.O
1-0 MS= i. 6 MA/M
a= llOO A/M
k= 400
o l p h o - i. 6E-03
H kA/M
i i i 1 ~ 1 1 i ~ i i i i i
5 5
0.5
o Fe-C O - 0 6 W t % f r o m f i g . 11
Theoretical
H (kA/m)
Fig. 10. Comparison of experimental and theoretical initial
4. 3. Major hysteresis loops
magnetization curves. The experimental results were obtained
on a specimen of F e - C 0.06 wt%. The theoretical results were Major hysteresis loops are obtained by cycling
obtained with the following values of parameters: M s = 1 . 6 the H field at progressively increasing amplitudes
106A/m, a = l l 0 0 A/m, k=400, a = l . 6 x 1 0 3, c = 0 . 2 .
starting from the demagnetized state. These are
M {MA/m)
used widely to define the magnetic properties of a
ferromagnet and their general shape is well known.
1.6 A family of experimental major hysteresis loops
for a sample of steel is shown in fig. 11.
Fe-C O 0 6 W t % Theoretical major hysteresis loops are obtained
from solutions of eq. (34) also with progressively
increasing HmaX starting from the demagnetized
state Hm,x = 0. From this the theoretical major
hysteresis loops of fig. 12 were obtained.
r
N (kA/m) 5. Conclusions
significance of the anhysteretic curve, which is the [5] J.C. Maxwell, Electricity and Magnetism (Oxford, Univ.
locus of global equilibrium states, emerges. An Press, Oxford, 1873).
equation for the anhysteretic curve, which is par- [6] J.A. Ewing, Phil. Mag. 5 (1890) 205.
[7] B.D. Cullity, Introduction to Magnetic Materials, (Ad-
ticularly simple is also given.
dison-Wesley, New York, 1972).
The model is based on a mean field approxima- [8] H.J. Williams, Phys. Rev. 52 (1937) 747.
tion in which each domain is assumed to interact [9] S. Chikazumi, Physics of Magnetism (Wiley, New York,
with the field H and a weighted mean of the bulk 1964).
magnetization. The impedance to the changes in [10] L. Rayleigh, Phil. Mag. 23 (1887) 225.
[11] J.R. Brauer, IEEE Trans. Magn. MAG-11 (1975) 81.
magnetization, the equivalent of Wiedemann's
[12] J. Fischer and H. Moser, Archiv. fur Electrotechnik 42
"frictional type" force is provided by pinning sites (1956) 286.
inside the solid in the form of imperfections, in- [13] F.C. Trutt, E.A. Erdelyi and R.E. Hopkins, IEEE Trans.
clusions and regions of inhomogeneous strain, Power App. Sys. PAS-87 (1968) 665.
which oppose the motion of domain walls. This is [14] G.F.T. Widger, Proc. Inst. Elect. Engg. 116 (1969) 156.
[15] J. Rivas, J.M. Zamarro, E. Martin and C. Pereira, IEEE
the fundamental cause of hysteresis behavior in Trans. Magn. MAG-17 (1981) 1498.
ferromagnets. [16] F. Preisach, Zeit. for Physik 94 (1935) 277.
The model at present applies to isotropic solids, [17] L. N6el, J. de Phys. Rad. 11 (1950) 49.
that is polycrystalline materials or single crystals [18] L. N~el, Advan. Phys. 4 (1955) 191.
with low anisotropy. However by modifying the [19] R.M. Del Vecchio, IEEE Trans. Magn. MAG-16 (1980)
809.
form of eq. (6) to account for anisotropy this [20] M.A. Rahman, M. Poloujadoff, R.D. Jackson, J. Perrard
could be included into the model as indicated by and S.D. Gowda, IEEE Trans. Magn. MAG-17 (1981)
Furlani [34]. The impedance to changes in magne- 3253.
tization is assumed to be uniform, that is a mean [21] W.F. Brown, J. Appl. Phys. 30 (1959) 62S.
pinning energy per site only has been used. In [22] A. Aharoni, J. Appl. Phys. 30 (1959) 70S.
[23] A. Globus, Comptes Rendus, Acad. Seances 255 (1962)
practice a distribution of pinning energies would 1709.
be more exact however the form of the solution is [24] A. Globus and P. Duplex, Phys. Stat. Sol. 31 (1969) 765.
likely to remain much the same. [25] A. Globus and P. Duplex, Phys. Stat. Sol. (a) 3 (1970) 53.
The model includes at present irreversible [26] A. Globus and P. Duplex, IEEE Trans. Magn. MAG-2
changes in magnetization due to displacement of (1966) 441.
[27] J.L. Porteseil and R. Vergne, J. de Phys. 40 (1979) 871.
domain walls and reversible changes in magnetiza- [28] B. Astie, J. Degauque, J.L. Porteseil and R. Vergne, IEEE
tion due to bending of domain walls. Although the Trans. Magn. MAG-17 (1981) 2929.
model does not yet take into account less signifi- [29] J. Degauque and B. Astie, Phys. Stat. Sol. (a) 74 (1982)
cant contributions such as rotational processes 201.
these can not be entirely excluded and must ulti- [30] B. Astie, J. Degauque, J.L. Porteseil and R. Vergne, J.
Magn. Magn. Mat. 28 (1982) 149.
mately be incorporated into a more realistic model. [31] M. Kersten, Problem der Technischer Magnetisierungs-
The results of the theory have been compared kurve (Springer-Verlag, Berlin, 1938).
with experimental results for ferromagnetic steel [32] M. Kersten, Grundlagen Theorie der Ferromagnetischer
by considering the various types of magnetization Hysterese und der Koerzitivkraft (Hirzel, 1943).
curves, the anhysteretic, initial magnetization [33] R. Becker and W. DiSring, Ferromagnetismus (Springer-
Verlag, Berlin, 1939).
curve, and families of major hysteresis loops. In [34] E. Furlani, private communication.
all cases the agreement is excellent. [35] E. Callen, Y.J. Liu and J.R. Cullen, Phys. Rev. B16 (1977)
263.
[36] M. Langevin, Ann. de Chem. et Phys. 5 (1905) 70.
[37] D.C. Jiles and D.L. Atherton, IEEE Trans. Magn. MAG-
References 19 (1983) 2183.
[38] R.M. Bozorth, Ferromagnetism (Van Nostrand, New York,
1951).
[1] D.C. Jiles and D.L. Atherton, J. Phys. D 17 (1984) 1265. [39] K. Hoselitz, Ferromagnetic Properties of Metals and Al-
[2] R.S. Tebble and D.J. Craik, Magnetic Materials (Wiley, loys (Oxford Univ. Press, Oxford, 1952).
New York, 1969). [40] E.I. Kondorsky, Physik. Zeit. Sow 11 (1937) 597.
[3] W. Weber, Abhandlungen der Kg. S~chs Gesellschaft der [41] L. N~el, Annales Univ. Grenoble 22 (1946) 321.
Wissens (1852) 572. [42] A. Globus, P. Duplex and M. Guyot, IEEE Trans. Magn.
[4] G. Wiedemann, Phil. Mag. (1886) 52. MAG-7 (1971) 617.