You are on page 1of 12

IIT JAM

Chemistry (CY)
Model Paper with Answer Key
Based on Exam Pattern

Eduncle.com
Mpa 44, 2nd Floor, Above Bank Of India, Rangbari Main Road,
Toll Free: 1800-120-1021
Mahaveer Nagar 2nd, Near Amber Dairy, Kota, Rajasthan, 324005
Website: www.eduncle.com | Email: Info@Eduncle.com
Chemistry-CY (MQP)

Chemistry (CY)
Model Paper with Answer Key

Duration : 180 minutes Maximum Marks : 100

Read the following instructions carefully.

1. This test paper has a total of 60 questions carrying 100 marks. The entire question paper
is divided into Three Sections A, B and C. All sections are compulsory. Questions in
each section are of different types.

2. Section A contains Multiple Choice Questions (MCQ). Each MCQ type question has
four choices out of which only one choice is the correct answer. This section has 30
Questions and carry a total of 50 marks. Q.1 Q.10 carry 1 mark each and Questions
Q.11 Q.30 carry 2 marks each.

3. Section B contains Multiple Select Questions (MSQ). Each MSQ type question is
similar to MCQ but with a difference that there may be one or more than one choice(s)
that are correct out of the four given choices. The candidate gets full credit if he/she
selects all the correct choices only and no wrong choices. This section has 10 Questions
and carry 2 marks each with a total of 20 marks.

4. Section C contains Numerical Answer Type Questions (NAT). For these NAT type
questions, the answer is a real number which needs to be entered using the virtual
numerical keypad on the monitor. No choices will be shown for these type of questions.
This section has 20 Questions and carry a total of 30 marks. Q.1 Q.10 carry 1 mark
each and Questions Q.11 Q.20 carry 2 marks each.

Contact Us : Website : www.eduncle.com | Email : support@eduncle.com | Call Toll Free : 1800-120-1021 1


Chemistry-CY (MQP)

SECTION-(A) MULTIPLE CHOICE QUESTIONS (MCQ)

1. Which of the following are non-polar ?


(1) SiF4 (2) Xef4
(3) SF4 (4) BF3
(5) NF3
Select the correct answer using the codes below :
(A) 1, 2, 3 and 4 (B) 2, 3, and 5
(C) 3, 4, and 5 (D) 1, 2 and 4

2. The decreasing order of the first ionization energy of the following elements is
(A) Xe > Be > As > Al (B) Xe > As > Al > Be
(C) Xe > As > Be > Al (D) Xe > Be > Al > As

3. Which of these compounds are aromatic in character ?

(A) C (B)
CN CN

(C) (D) All of these


CH2

4. R-alanine is represented by______

2 COOH 1 NH
2
3 4
4 1
(A) H NH2 (B) H3 C H
3 CH R 2 COOH S
3

H COOH

(C) HOOC NH2 (D) H3C NH2

CH3 H

5. Toluene when refluxed with bromine in the Presence of light gives mainly______
(A) O-bromotoluene (B) M-bromotoluene
(C) O and p-bromotoluene (D) Benzyl bromide

6. Tertiary alcohol can be converted into primary amine by the use of______
(A) NH3 / Al2O3 / B (B) HCN
(C) RCN /H
(D) CH3NH2 / P2O5

Contact Us : Website : www.eduncle.com | Email : support@eduncle.com | Call Toll Free : 1800-120-1021 2


Chemistry-CY (MQP)


7. If a Particle has linear momentum p 2i j k , at position r 3i j k , then its angular
momentum is ________

(A) i 2k (B) 2 i 5 j k

(C) 5 i 2j (D) 2i 5 j k

G
8. =
p T
(A) U (B) S
(C) S (D) V

9. An electron is found in an orbital with one radial node and two angular nodes. Which orbital
electron is in ?
(A) 15 (B) 2p
(C) 3d (D) 4d

10. n-simple molecule of solute A associate in solution as nA (A)n The degree of association is
x. what is the number of particles at equilibrium ?
(A) 1 + x + (x/n) (B) 1 - x (x/n)
(C) 1 + (2x/n) (D) None of above

11. The final product of the reaction is:

O CHOH
3

h
Hu

coome
(A) (B)

coome

coome
(C) (D)

coome

12. In the given reaction -


O O
reagent
R C OH R C Cl
reagent may be:
(A) PCl5 (B) SoCl2

ClCo CoCl
(C) (D) All of these
Dmf

Contact Us : Website : www.eduncle.com | Email : support@eduncle.com | Call Toll Free : 1800-120-1021 3


Chemistry-CY (MQP)

13. In the given reaction sequence


h CH3 OH
CHCl3 (A)
(excess)
(B)
(B) is _______
O O

(A) Cl C Cl (B) Cl C O CH 3

(C) CH3O C O CH3 (D) CO2 + HCl

CHCOOCH5
CH 22COOC22H5
+
H
14. [ x]
CHOH
2

[ x ] is :

CH2COOH CH2COOH

(A) (B)
CH2

O O

CH2 C CH2 C

(C) (D)
CH2 O CH2 O O

15. In the given reaction


CH3

H C OH TsCl / pyridine
[x]
H C OH

CH3
[ x ] will be _______
CH3 CH3

H C O Ts H C OTs
(A) (B)
H C OH H C OTs

CH3 CH3
CH3
HC
(C) O (D) No reaction
HC

CH3

Contact Us : Website : www.eduncle.com | Email : support@eduncle.com | Call Toll Free : 1800-120-1021 4


Chemistry-CY (MQP)

16. In the given reaction


OH
COOH
HNO 3 / H2SO 4
[x]
[x] is :
(A) 2-hydroxy-3-nitrobenzoic acid (B) 2-hydroxy-2-nitrobenzoic acid
(C) 2-hydroxy-5-nitrobenzoic acid (D) 2, 4, 6-trinitrophenol

17. When sulphanilic acid is treated with excess of bromine water, it gives _____
Br
SO 3H

(A) (B)
Br Br
Br Br NH2
SO 3H SO 3H
Br Br
(C) (D)

Br Br NH2
NH2 Br

18. Which of the following will be more reactive for E1 reaction?

Br

C CH 2 CH 3 Br
(A) (B)
C6H5 CH CH3

Br
Br
(C) (D) CH2 CH C CH 3
CH2 CH CH CH3
CH3

19. +

The shape of which one of the orbitals corresponds to the angular wave function in the figure
given above ?
(A) dx2-y2 (B) dxy
(C) py (D) px

Contact Us : Website : www.eduncle.com | Email : support@eduncle.com | Call Toll Free : 1800-120-1021 5


Chemistry-CY (MQP)

20. The ground stable energy of hydrogen atom is -13.6 ev what is the ground state energy of life?
(A) 3.4 ev (B) 13.6 ev
(C) 40.8 ev (D) 122.4 ev

21. Taking into account the isoelectronic Principle and VSEPR Theory, predict in which one of the
following pairs, both molecular species have Pyramidal geometry ?

(A) BO33 and SO32 (B) CO32 and NO3

(C) SO23 and ClO3 (D) SO3 and ClO3

22. XeF3+ belongs to which one of the following AXnEm nomenclature (A = Central, X = singly bonded
liquid and E = an unshared electron pair) ?
(A) AX3E0 (B) AX3E1
(C) AX3E2 (D) AX3E3

23. Consider the 0.1N aqueous solutions of the following electrolytes:


1. NaOH 2. NH4OH
3. CH3 COOH 4. HCl
h
The correct sequence of their increasing p is
(A) 2, 1, 3, 4 (B) 3, 4, 2, 1
(C) 4, 3, 2, 1 (D) 4, 3, 1, 2

24. The molecule N (Sime3)3 has a


(A) pyramidal shape and is a lewis base
(B) pyramidal shape and lewis acid
(C) T-shaped geometry and is a lewis and
(D) Trigonal planar geometry and has no lewis base character

25. Haemoglobin a complex containing iron is a constituent of blood. The oxidation state of iron of
the complex is ________
(A) zero (B) +1
(C) +2 (D) +3

26. Match list-I (The metallozymes) with list-II (The metal present in the enzyme) and select the
correct answer using the codes given below the lists:
List - I List - II
A. Carboxy peptidase 1. Fe
B. Cytochrome 2. Cu
C. Nitrogenose 3. Zn
D. Ascarbate oxidase 4. Mo

Contact Us : Website : www.eduncle.com | Email : support@eduncle.com | Call Toll Free : 1800-120-1021 6


Chemistry-CY (MQP)

Codes :
A B C D
(A) 3 2 1 4
(B) 1 3 4 2
(C) 4 2 3 1
(D) 3 1 4 2

27. The isomerism that are possible in the w(III) complexes [Co(NH3)3 (NO2/3)] and [Co(NH3)3 NO2]Cl2
respectively, are _______
(A) Coordination and position (B) Optical and linkage
(C) Geometrical and linkage (D) None of these

28. For the reaction :


2Cl(g) Cl2 (g)
the thermodynamic properties
(A) G, H, and S are positive.
(B) G, H, and S are negative.
(C) G and H are negative and S is positive.
(D) G is negative and H and S are positive.

29. For an enzyme catalysed reaction


E1
E+S
ES
E2 E+P
E 1

Where the symbol have their usual meaning, using the steady state approximation for [ES]. The
overall rate equation workout to be
k 2 [E0 ][S] k 1 k 2
(A) r (B) r
km [S] k1
k1[E][S] k 2 [E][S]
(C) r (D) r
km [S] km(k 1 k1 ) [S]

30. The standard oxidation potential of copper and silver electrodes are-

cu
cu E = 0.84V

and Ag
Ag E = 0.79V
Respectively, an electrochemical cell containing a copper electrode dipping in a 0.1m CuSO4
solution and a silver electrode dipping in a 0.1m AgNO3 solution is formed using a salt bridge
when current is drawn from the cell.
(A) Cu will be deposited and Ag will pass into solution as ions.
(B) Both Cu and Ag will be deposited from their respective ionic states respectively.
(C) Both Cu and Ag will pass into solution as ions.
(D) Cu will pass into solution as ions and Ag will be deposited.

Contact Us : Website : www.eduncle.com | Email : support@eduncle.com | Call Toll Free : 1800-120-1021 7


Chemistry-CY (MQP)

SECTION-(B) MULTIPLE SELECT QUESTIONS (MSQ)

1. Which of the following are aromatic ?

(A) (B) +


(C) (D)

2. Which of the following compounds has (L) configuration ?


CHO CH3

(A) H C OH (B) H C NH 2

CH2OH COOH
COOH
CHO
H C OH
HO C H
(C) H C OH (D)
H C OH
HO C H
CH2OH
CH2OH

O
OCH3
OH O
3.
O O O
OH

I II III IV
Which among these can exist tautomerism ?
(A) I (B) II
(C) III (D) IV

4. Lysione is not used as :


(A) Disinfectant (B) Germ killer
(C) Treating eye disease (D) Anti-cancer drug

5. Which of the following is correct about G ?


(A) G = H TS (B) At equilibrium G = 0
(C) At equilibrium G = RT logk (D) G = G + RT logk

Contact Us : Website : www.eduncle.com | Email : support@eduncle.com | Call Toll Free : 1800-120-1021 8


Chemistry-CY (MQP)

6. The angular momentum of electron can have the value (s) ___
h h
(A) (B)
2
2h 5h
(C) (D)
22

7. The correct starting material and product of different disintegration series are______
(A) 232Th, 208pb (B) 235U, 206pb
(C) 238U, 207pb (D) 237Np, 209Bi

8. In which of the following set, both the species are isoelectronic and and isostructural?
(A) CO32, NO3 (B) SO42, ClO3
(C) SO42, PO43 (D) ClO3, CO32

9. Which of the following statement is/are correct


(A) In CCl4, only dispersive forces exist
(B) In CHCl3 molecule, both dipole forces as well as dispersive forces exist.
(C) In H2O molecule, both hydrogen bonds as well as dispersive forces are present.
(D) In cyanogen, the number of sigma and pi-bonds are 3 and 4 respectively

10. In which of these compounds does the carbon atom (underlined) nor use Sp3 hybridization for
bond formation.
(A) CH 3 COOH (B) OC (NH2)2
(C) (CH3)3 COH (D) C2H5 CHO

SECTION-(C) NUMERICAL ANSWER TYPE QUESTIONS (NAT)

1
1. How many d-electrons in Cu+ (At. No. = 29) can have the spin quantum number ?
2

226 226
2. One gram of Rq has an activity of nearly 1 Ci. The half life of Ra is ____ years.

3. The non-compressive volume of a gas is ____ times than the actual volume of gas molecules.

4. Density of lithium atom is 0.53 g/cm3. The edge length of Li is 3.5 A. Find out the number of
lithium atoms is a unit cell. (N0= 6.022 x1023/mol& M= 6.94)

5. Calculate the enthalpy of the following reaction :

H2C = CH2(g) + H2(g)


CH3 CH3(g)
The bond energies of C-H, C-C, C=C and H-H are 99, 83, 147 and 104 kcal respectively.

Contact Us : Website : www.eduncle.com | Email : support@eduncle.com | Call Toll Free : 1800-120-1021 9


Chemistry-CY (MQP)

6. For a reaction A+B


C+D. If the concentration of A is doubled without altering the concentration
of B, the rate gets doubled, if the concentration of B is increased by nine times without altering
the concentration of A, the rate gets tripled. The order of reaction is _____

7. For the hopothetical reactions, the equilibrium constant (k) values are given below:
A B, K1 = 2 ;
B C, K2 = 4 ;
C D, K3 = 3 ;
The equilibrium constant (k) for the reaction A D is _____

8. What current strength in ampere will be required to liberate 10g of chlorine from sodium chloride
solution in one hour?

9. How many stereoisomers exist with the following basic connectivity?


Br CH2 CH (CH3). CH2 CH3

10. Use the following data to answer the question below:


H2
H = 28.6 kcal/mol
Ni
excess H2
(Ni) H = 116.2 kcal/mol
(Anthracene)
The resonance energy of anthracene is _____

11.

What value of n in Huckel's rule applies to the aromatic compound shown above?

12. When methyl glucopyranoside reacts with periodic acid, how many moles of the oxidising agent
are consumed per mole of sugar ?

13. How many isomeric aldehydes are possible with formula C5H10O ?

14. The ionic radius of the fluoride ion is ____ using only the following interionic distance and the
radius of the iodide ion 2.19A.
RbI = 3.67Ao KCl = 3.14Ao RbBr = 3.44Ao
NaCl = 2.79Ao KBr = 3.29Ao NaF = 2.31Ao

15. How many nearest, neighbours are there in an atom or ions for an octahedral hole of a closed
packed structure ?

Contact Us : Website : www.eduncle.com | Email : support@eduncle.com | Call Toll Free : 1800-120-1021 10


Chemistry-CY (MQP)

16. In hydrogen atom, energy of first excited state is -3.4ev, then the K.E. of same orbital of hydrogen
atom is ____ev.

17. The molecular MLx is planar with 7 pairs of electrons around M in the valence shell, the value
of x is ______.

18. In the electronic structure of H2SO4, the total number of unshared electrons is ____.

19. The dissociation constant of a substituted benzoic acid at 25C is 1.0 104. The pH of a 0.01
M solution of its sodium salt is _______.

20. How many moles of AgCl would be obtained, when 100ml of 0.1m CO(NH3)5Cl3 is treated with
excess of AgNO3 ?

ANSWER KEY

SECTION-(A) MULTIPLE CHOICE QUESTIONS (MCQ)

1 2 3 4 5 6 7 8 9 10
D C D A D C B A D B
11 12 13 14 15 16 17 18 19 20
C D C C C D B A B D
21 22 23 24 25 26 27 28 29 30
C C C D C D C B A D

SECTION-(B) MULTIPLE SELECT QUESTIONS (MSQ)

1 2 3 4 5 6 7 8 9 10
B,D B,C A,B,C B,C,D A,D A,B,C A,D A,C A,B,C,D A,B,D

SECTION-(C) NUMERICAL ANSWER TYPE QUESTIONS (NAT)

1 2 3 4 5 6 7 8 9 10
5 1582 4 2 -30 1.5 24 7.55 2 84
11 12 13 14 15 16 17 18 19 20
4 2 4 1.33 6 3.4 5 16 8 0.02

Contact Us : Website : www.eduncle.com | Email : support@eduncle.com | Call Toll Free : 1800-120-1021 11

You might also like