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Chemistry (CY)
Model Paper with Answer Key
Based on Exam Pattern
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Chemistry-CY (MQP)
Chemistry (CY)
Model Paper with Answer Key
1. This test paper has a total of 60 questions carrying 100 marks. The entire question paper
is divided into Three Sections A, B and C. All sections are compulsory. Questions in
each section are of different types.
2. Section A contains Multiple Choice Questions (MCQ). Each MCQ type question has
four choices out of which only one choice is the correct answer. This section has 30
Questions and carry a total of 50 marks. Q.1 Q.10 carry 1 mark each and Questions
Q.11 Q.30 carry 2 marks each.
3. Section B contains Multiple Select Questions (MSQ). Each MSQ type question is
similar to MCQ but with a difference that there may be one or more than one choice(s)
that are correct out of the four given choices. The candidate gets full credit if he/she
selects all the correct choices only and no wrong choices. This section has 10 Questions
and carry 2 marks each with a total of 20 marks.
4. Section C contains Numerical Answer Type Questions (NAT). For these NAT type
questions, the answer is a real number which needs to be entered using the virtual
numerical keypad on the monitor. No choices will be shown for these type of questions.
This section has 20 Questions and carry a total of 30 marks. Q.1 Q.10 carry 1 mark
each and Questions Q.11 Q.20 carry 2 marks each.
2. The decreasing order of the first ionization energy of the following elements is
(A) Xe > Be > As > Al (B) Xe > As > Al > Be
(C) Xe > As > Be > Al (D) Xe > Be > Al > As
(A) C (B)
CN CN
2 COOH 1 NH
2
3 4
4 1
(A) H NH2 (B) H3 C H
3 CH R 2 COOH S
3
H COOH
CH3 H
5. Toluene when refluxed with bromine in the Presence of light gives mainly______
(A) O-bromotoluene (B) M-bromotoluene
(C) O and p-bromotoluene (D) Benzyl bromide
6. Tertiary alcohol can be converted into primary amine by the use of______
(A) NH3 / Al2O3 / B (B) HCN
(C) RCN /H
(D) CH3NH2 / P2O5
7. If a Particle has linear momentum p 2i j k , at position r 3i j k , then its angular
momentum is ________
(A) i 2k (B) 2 i 5 j k
(C) 5 i 2j (D) 2i 5 j k
G
8. =
p T
(A) U (B) S
(C) S (D) V
9. An electron is found in an orbital with one radial node and two angular nodes. Which orbital
electron is in ?
(A) 15 (B) 2p
(C) 3d (D) 4d
10. n-simple molecule of solute A associate in solution as nA (A)n The degree of association is
x. what is the number of particles at equilibrium ?
(A) 1 + x + (x/n) (B) 1 - x (x/n)
(C) 1 + (2x/n) (D) None of above
O CHOH
3
h
Hu
coome
(A) (B)
coome
coome
(C) (D)
coome
ClCo CoCl
(C) (D) All of these
Dmf
(A) Cl C Cl (B) Cl C O CH 3
CHCOOCH5
CH 22COOC22H5
+
H
14. [ x]
CHOH
2
[ x ] is :
CH2COOH CH2COOH
(A) (B)
CH2
O O
CH2 C CH2 C
(C) (D)
CH2 O CH2 O O
H C OH TsCl / pyridine
[x]
H C OH
CH3
[ x ] will be _______
CH3 CH3
H C O Ts H C OTs
(A) (B)
H C OH H C OTs
CH3 CH3
CH3
HC
(C) O (D) No reaction
HC
CH3
17. When sulphanilic acid is treated with excess of bromine water, it gives _____
Br
SO 3H
(A) (B)
Br Br
Br Br NH2
SO 3H SO 3H
Br Br
(C) (D)
Br Br NH2
NH2 Br
Br
C CH 2 CH 3 Br
(A) (B)
C6H5 CH CH3
Br
Br
(C) (D) CH2 CH C CH 3
CH2 CH CH CH3
CH3
19. +
The shape of which one of the orbitals corresponds to the angular wave function in the figure
given above ?
(A) dx2-y2 (B) dxy
(C) py (D) px
20. The ground stable energy of hydrogen atom is -13.6 ev what is the ground state energy of life?
(A) 3.4 ev (B) 13.6 ev
(C) 40.8 ev (D) 122.4 ev
21. Taking into account the isoelectronic Principle and VSEPR Theory, predict in which one of the
following pairs, both molecular species have Pyramidal geometry ?
22. XeF3+ belongs to which one of the following AXnEm nomenclature (A = Central, X = singly bonded
liquid and E = an unshared electron pair) ?
(A) AX3E0 (B) AX3E1
(C) AX3E2 (D) AX3E3
25. Haemoglobin a complex containing iron is a constituent of blood. The oxidation state of iron of
the complex is ________
(A) zero (B) +1
(C) +2 (D) +3
26. Match list-I (The metallozymes) with list-II (The metal present in the enzyme) and select the
correct answer using the codes given below the lists:
List - I List - II
A. Carboxy peptidase 1. Fe
B. Cytochrome 2. Cu
C. Nitrogenose 3. Zn
D. Ascarbate oxidase 4. Mo
Codes :
A B C D
(A) 3 2 1 4
(B) 1 3 4 2
(C) 4 2 3 1
(D) 3 1 4 2
27. The isomerism that are possible in the w(III) complexes [Co(NH3)3 (NO2/3)] and [Co(NH3)3 NO2]Cl2
respectively, are _______
(A) Coordination and position (B) Optical and linkage
(C) Geometrical and linkage (D) None of these
Where the symbol have their usual meaning, using the steady state approximation for [ES]. The
overall rate equation workout to be
k 2 [E0 ][S] k 1 k 2
(A) r (B) r
km [S] k1
k1[E][S] k 2 [E][S]
(C) r (D) r
km [S] km(k 1 k1 ) [S]
30. The standard oxidation potential of copper and silver electrodes are-
cu
cu E = 0.84V
and Ag
Ag E = 0.79V
Respectively, an electrochemical cell containing a copper electrode dipping in a 0.1m CuSO4
solution and a silver electrode dipping in a 0.1m AgNO3 solution is formed using a salt bridge
when current is drawn from the cell.
(A) Cu will be deposited and Ag will pass into solution as ions.
(B) Both Cu and Ag will be deposited from their respective ionic states respectively.
(C) Both Cu and Ag will pass into solution as ions.
(D) Cu will pass into solution as ions and Ag will be deposited.
(A) (B) +
(C) (D)
(A) H C OH (B) H C NH 2
CH2OH COOH
COOH
CHO
H C OH
HO C H
(C) H C OH (D)
H C OH
HO C H
CH2OH
CH2OH
O
OCH3
OH O
3.
O O O
OH
I II III IV
Which among these can exist tautomerism ?
(A) I (B) II
(C) III (D) IV
6. The angular momentum of electron can have the value (s) ___
h h
(A) (B)
2
2h 5h
(C) (D)
22
7. The correct starting material and product of different disintegration series are______
(A) 232Th, 208pb (B) 235U, 206pb
(C) 238U, 207pb (D) 237Np, 209Bi
8. In which of the following set, both the species are isoelectronic and and isostructural?
(A) CO32, NO3 (B) SO42, ClO3
(C) SO42, PO43 (D) ClO3, CO32
10. In which of these compounds does the carbon atom (underlined) nor use Sp3 hybridization for
bond formation.
(A) CH 3 COOH (B) OC (NH2)2
(C) (CH3)3 COH (D) C2H5 CHO
1
1. How many d-electrons in Cu+ (At. No. = 29) can have the spin quantum number ?
2
226 226
2. One gram of Rq has an activity of nearly 1 Ci. The half life of Ra is ____ years.
3. The non-compressive volume of a gas is ____ times than the actual volume of gas molecules.
4. Density of lithium atom is 0.53 g/cm3. The edge length of Li is 3.5 A. Find out the number of
lithium atoms is a unit cell. (N0= 6.022 x1023/mol& M= 6.94)
7. For the hopothetical reactions, the equilibrium constant (k) values are given below:
A B, K1 = 2 ;
B C, K2 = 4 ;
C D, K3 = 3 ;
The equilibrium constant (k) for the reaction A D is _____
8. What current strength in ampere will be required to liberate 10g of chlorine from sodium chloride
solution in one hour?
11.
What value of n in Huckel's rule applies to the aromatic compound shown above?
12. When methyl glucopyranoside reacts with periodic acid, how many moles of the oxidising agent
are consumed per mole of sugar ?
13. How many isomeric aldehydes are possible with formula C5H10O ?
14. The ionic radius of the fluoride ion is ____ using only the following interionic distance and the
radius of the iodide ion 2.19A.
RbI = 3.67Ao KCl = 3.14Ao RbBr = 3.44Ao
NaCl = 2.79Ao KBr = 3.29Ao NaF = 2.31Ao
15. How many nearest, neighbours are there in an atom or ions for an octahedral hole of a closed
packed structure ?
16. In hydrogen atom, energy of first excited state is -3.4ev, then the K.E. of same orbital of hydrogen
atom is ____ev.
17. The molecular MLx is planar with 7 pairs of electrons around M in the valence shell, the value
of x is ______.
18. In the electronic structure of H2SO4, the total number of unshared electrons is ____.
19. The dissociation constant of a substituted benzoic acid at 25C is 1.0 104. The pH of a 0.01
M solution of its sodium salt is _______.
20. How many moles of AgCl would be obtained, when 100ml of 0.1m CO(NH3)5Cl3 is treated with
excess of AgNO3 ?
ANSWER KEY
1 2 3 4 5 6 7 8 9 10
D C D A D C B A D B
11 12 13 14 15 16 17 18 19 20
C D C C C D B A B D
21 22 23 24 25 26 27 28 29 30
C C C D C D C B A D
1 2 3 4 5 6 7 8 9 10
B,D B,C A,B,C B,C,D A,D A,B,C A,D A,C A,B,C,D A,B,D
1 2 3 4 5 6 7 8 9 10
5 1582 4 2 -30 1.5 24 7.55 2 84
11 12 13 14 15 16 17 18 19 20
4 2 4 1.33 6 3.4 5 16 8 0.02