Professional Documents
Culture Documents
Water
Metal
Water droplets
Oil Phase
Prediction of Corrosion in an Oil
Transmission Pipeline
Emulsion
Liquid-liquid physical interaction
Wettability
Liquid-liquid-solid interaction
Corrosiveness of the Aqueous Phase
Liquid-liquid chemical interaction
Influence of oil phase on water
phase corrosivity
Water Droplets Emulsion
Oil Droplets
Inversion Point
Oil-Phase Water-Phase
Water-in-Oil Emulsion Oil-in-Water Emulsion
Emulsion Inversion Point Determination
Non-Standard Methods
Electrical
Microwave
Radiation Scattering
Spectroscopic
Ultrasonic
Density-based techniques
Viscosity-based techniques
Emulsion Inversion Point Determination
(Standard Method: ASTM G205)
Electrical method
Emulsion Inversion Point
250
Inversion Point
200
Resistance (K-Ohms)
0
1
150
2
3
100
4
5
50
0
0% 10% 20% 30% 40% 50% 60% 70%
Water cut
Wettability Contact Angle Method
(Standard Method: ASTM G205)
Wettability Contact Angle Method
(ASTM G205)
Metal surface
Wettability Spreading Method
(ASTM G205)
Wettability Spreading Method
(ASTM G205)
.001 mpy
1000 1
0 0
0 10 20 30 40 50 60 70
Crude Oil Number
Effect of Crude Oil on the
Corrosiveness of Aqueous Phase -
Standard methods
ASTM G170: Guide for evaluating and qualifying oilfield
and refinery corrosion inhibitors in the laboratory
ASTM G184: Practice for evaluating and qualifying oilfield
and refinery corrosion inhibitors using rotating cage
ASTM G185: Practice for evaluating and qualifying oilfield
and refinery corrosion inhibitors using rotating cylinder
electrode
ASTM G202: Test method for using atmospheric pressure
rotating cage
ASTM D665: Test method for rust-preventing
characteristics of inhibited mineral oil in the presence of
water
NACE TM0172: Standard Test Method of determining
corrosive properties of cargoes in petroleum product
pipelines
Hierarchy of ASTM Standards
Standard Guide
Provides general guide (ASTM G170)
Standard Practice
Rotating Cage
Prescribes procedure (ASTM
G184, G185, and G188)
Standard Test Method
Prescribes procedure and expected
results (ASTM G202)
Precision developed based on round
robin tests
Based on 225 data points produced by
10 different laboratories around the
world (Canada, India, USA, and
Venezuela)
Bench-mark aqueous phase corrosion
rate established by round robin tests:
23 + 2 mpy or 0.58 + 0.05 mm/y
Corrosivity of Aqueous Phase in the
Presence of Different Crude oils
30
Corrosive Crude Oil
25
23 + 2 mpy Neutral Crude Oil
Corrosion Rate (mpy)
20
15
0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21
Crude Oil Identification Number
ASTM G205: Standard Guide for Determining
Corrosivity of Crude Oils
W/O No Corrosion
Emulsion
O/W
Oil-Wet No Corrosion
Wettability Mixed-Wet
Water-Wet