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Alkenes react with lots of other substances to form useful products, but a
particularly important reaction occurs when they react with themselves in a
process called POLYMERISATION.
1. Poly(propene)
H CH3 H CH3
n C C ( C C
)n
H H H H
propene poly(propene)
(monomer, unsaturated) (polymer, saturated)
You will be familiar with many of the uses of addition polymers already. These
types of materials are used for plastic bags, packaging, food and drink
containers, non-stick coatings, flooring, replacement windows, ropes, crates,
clothing, disposable gloves, insulation etc.
Products from plant material (wood, paper, cotton etc.) are biodegradable.
When buried, bacteria and fungi break them down into useful nutrients for
further plant growth. Nature recycles its own products!
Many polymers can not be incinerated (burned) to dispose of them either. People
often die from the smoke produced by burning polymers in house fires, long
before the fire itself reaches them. Polymers produce toxic materials (poisons)
when they are burnt, in addition to the expected products of combustion of
hydrocarbons, which are water, carbon dioxide, carbon monoxide and carbon
(soot).
Those polymers that contain chlorine (PVC for example) also produce hydrogen
chloride on burning. Those polymers that contain nitrogen (nylon for example)
produce hydrogen cyanide when they are burnt. Hydrogen cyanide is extremely
poisonous.
Recycling.
Bio-Polymers
Condensation polymerisation
The product is therefore smaller than if the two molecules had added together
(hence the term condensation). This is often water from two different
monomers, an H from one monomer, and an OH from the other, the 'spare
bonds' then link up to form the polymer chain.
This is the same kind of 'ester linkage' (-COOC-) found in fats which are
combination of long chain fatty carboxylic acids and glycerol (alcohol with 3 -OH
groups, a 'triol').
Natural polymers
These polymers are all man made but nature produces many polymers of its own.
Starch is a polymer made by plants. Plants join glucose molecules together into
very long chains to make starch. Potatoes and bread are rich in starch.
Many of your body parts are made of natural polymers called proteins. Your body
makes these by joining together small molecules called amino acids. Your hair,
skin, muscles etc. are made this way.
These bonds can be broken down inside the body by hydrolysis (reaction with
water) to produce the sugars which your body needs for energy.
Proteins are formed by joining amino acid into long chains. The structure below
shows the amino acid molecules joined together via condensation polymerisation
in much the same way as the synthetic polymer nylon. The amide bond found in
nylon is exactly the same as the peptide bond in a protein. In the diagram R
represents different groups of atoms.
These peptide bonds can be broken down inside the body by hydrolysis to
produce amino acids which your body needs for growth and repair.
1
Which of the following molecules can be used to make an addition polymer?
2
Which of the following molecules can be used to make an addition polymer?