Kanoria Chemicals & Industries Limited

P.O. Ankleshwar 393 002, Bharuch, (Gujarat)

SODIUM FORMATE

General Information
CAS Number 141 - 53 - 7
EINECS Number 205 - 488 - 0
Chemical Name Sodium Formate.
Chemical Classification Sodium salt of mono carboxylic acid.
Synonyms Sodium salt of formic acid.
Formula CHO2Na
Molecular weight 68.02
Shipping Name Sodium Formate.
Codes / Label Not applicable.
Hazardous Waste ID No. Not applicable.
Hazchem Code Not applicable.
UN Number No number assigned. This product is not regulated under this code.
Description White crystalline powder with slight odor of Formic acid.
Product uses For dyeing, Printing fabrics, Leather tanning and chrome electroplating process;
as an antioxidant in paper industry; for manufacturing Formic acid, oxalic acid,
sodium hydrosulphite and metal formates.

Product Specifications
Specifications Limits
Sodium Formate, % w/w min. 98.00
Moisture, % w/w max. 0.50
Other organic matters, %w/w max.(
1.50
as pentaerythritol )
Iron , ppm max. 5.00
In dyeing & printing fabric; leather tanning and chrome electroplating
Application process; in paper industry as an antioxidant; in the manufacturing process of
Formic acid; sodium hydro sulphite & metal formtes.
25 Kg. HDPE bags with loose polythene liner inside.500/1000 Kg. HDPE Jumbo
Packaging
bags.

This information is based on our present state of knowledge and is intended to provide general notes on our products
and their uses. It should therefore, not be construed as guaranteeing specific properties of the products described or
their suitability for a particular application. Any existing industrial property rights must be observed. The quality of our
product is guaranteed under our General Conditions of Sale.

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 Kanoria Chemicals & Industries Limited
P.O. Ankleshwar 393 002, Bharuch, (Gujarat)

MATERIAL SAFETY DATA SHEET

(According to 91/155 EC)

1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING

Product details:

Trade name SODIUM FORMATE

Chemical name/ formula SODIUM FORMATE, CHO2Na

Manufacturer / Supplier

Kanoria Chemicals & Industries Ltd. Kanoria Chemicals & Industries Ltd.

3407 GIDC Industrial Estate, A304/305/306, Universal Business Park,

ANKLESHWAR 393 002 (Gujarat), Chandivali Farm Road, Off.Saki Vihar Road,
India Tel:+91 2646 668801-04 Near Kamani Oil Mills, Saki Naka, Andheri(East),
Fax: +91 2646 251816 Mumbai 400 072 (Maharashtra) I n d i a.
Email: ank@kanoriachem.com Tel: +91 22 28470216, 28470217
www.kanoriachem.com Fax: +91 22 28470235
Email: kcil@bom3.vsnl.net.in

Safety Department
Further information obtainable from in case of emergency
+91 2646 668869

2. HAZARD IDENTIFICATION

2.1 Classification of the substance or mixture:

Classification according to Regulation (EC) No 1272/2008 [CLP]

Health hazard Serious Eye Damage/Eye irritation Category 2

Physical hazard Material may burn, but does not ignite readily. Avoid temperature.

2.2 Label elements:

Pictogram

H319: Causes serious eye irritation.

Hazard statement
H315: Causes skin irritation.

P280: Wear protective glove/protective clothing/eye protection/face protection

Precautionary statement P264: Wash hands thoroughly after handling.

Single exposure to vapors or mist is not likely to be hazardous. Continued or

prolonged
Other hazard Contact may irritate the skin and cause a skin rash (dermatitis). Contact with eyes
may cause slight irritation.

3. COMPOSITION/ INFORMATION ON INGREDIENTS

Description CAS Number EINECS Number Concentration (%) Risk Phrases

Sodium Formate 141-53-7 205-488-0 98.0 R36/38

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4. FIRST-AID MEASURES

After inhalation Remove to fresh air, restore breathing. Get medical attention.

After skin contact Remove contaminated clothing, wash with soap and water. Get medical attention if
irritation persists. Wash thoroughly clothing before reuse.

After eye contact Flushed opened eye for several minutes under running water.

After swallowing Induce vomiting of conscious patient immediately by giving plenty of water to drink.
Consult physician immediately in case of an unconscious victim.

Most important symptoms and Single exposure to vapors or mist is not likely to be hazardous. Continued or
effects, both acute and prolonged
delayed Contact may irritate the skin and cause a skin rash (dermatitis). Contact with eyes
may cause slight irritation. Single dose oral toxicity low.

Indication of any immediate None.

medical attention and special
treatment needed

5. FIRE-FIGHTING MEASURES

5.1 Extinguishing media.

Suitable extinguishing media CO2, dry chemical powder for small fire. Water spray, foam for large fire.

5.2 Special hazard arising from the substance or mixture.

Hazardous combustion None Known.

products

5.3 Advice for fire fighters.

Protection against fire Evacuate area and fight fire from a safe distance.
Wear self contained breathing apparatus.

6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedure.

Evacuation Procedure Isolate the hazard area and deny entry to unnecessary and unprotected personal.

Special precautions Remove all contaminated clothing to prevent further absorption.

For non-emergency personnel Do not breathe dust.

6.2 Environment precautions.

Environment precautions Keep away from drains, surface and ground water.

6.3 Methods and materials for containment and cleaning up.

Clean up methods Take up mechanically. Sweep up and containerize for reclamation or disposal.
Dispose contaminated material as waste according to item 13.

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7. HANDLING AND STORAGE

Handling

Information for safe handling Avoid breathing dust, avoid contact with eyes, skin and clothing. Decontaminate
soiled clothing thoroughly before reuse.

Information about fire and None specified.

explosion

Storage

Requirements to be met by Store in a cool, dry, ventilated area. Keep away from flame. While transferring follow
storerooms and receptacles proper grounding procedure. Avoid generation of excessive dust.

8. EXPOSURE CONTROLS / PROTECTION

141-53-7 Sodium Formate

OES Short term value * 15 mg/m3

Long term value * 10 mg, ** 5mg/m3

115-77-5 Pentaerythritol

OES Short term value * 20 mg/m3

Long term value * 10 mg/m3, ** 4 mg/m3

* Total inhalable dust ** Respirable dust.

Personal protective equipment

General protective and hygienic The usual precautionary measures for handling chemicals are to be followed.
measures:

Respiratory protection Suitable respiratory protective devise recommended.

Protection of hands Protective gloves of natural rubber.

9. PHYSICAL AND CHEMICAL PROPERTIES

General information:

Form Crystalline powder.

Colour White.

Odour Odourless.

Change in condition

Melting point / Melting range 253oC

Boiling Point Decomposes.

Flash point: --

Ignition temperature --
o
Density AT 20 C 1920 KG/m3
o
Bulk density at 20 C 1200-1400 kg/m3

Solubility in / Miscibility with 0.5 kg/lit.

water at 20oC

PH 7-9

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10. STABILITY & REACTIVITY

The produce is hygroscopic. Readily absorbs moisture from atmosphere - solutions are strong base.

Reactivity This material is not reactive under normal ambient condition.

Chemical stability Stable.

Possibility of hazardous reaction No known hazardous reaction.

Dangerous decomposition products At higher temperature, decomposes into Sodium Oxalate and Hydrogen, then
into Sodium Carbonate. CO2 and CO may form. Avoid flame and strong mineral
acids e.g. Sulfuric Acid.

11. TOXICOLOGICAL INFORMATION

Acute toxicity:

LD /LC50 values relevant for classification:

Oral/LD 50 / approx. 11200 mg/kg (rat)

Primary irritant effect

On the skin Frequently or prolonged contact with skin may cause dermal irritation.

On the eyes Mild irritating effect.

Summary of evaluation of the CMR Shall not be classified as germ cell mutagenic, carcinogenic nor as a
properties reproductive toxicant.

12. ECOLOGICAL INFORMATION

Environmental toxicity According to 1272/2008/EC shall not be classified to the aquatic environment.

Process of degradability The substance is readily biodegradable.

Bio accumulative potential Does not significantly accumulate in organisms.

Mobility in soil Data are not available.

Result of PBT and vPvB Data are not available.

Assessment

13. DISPOSAL CONDITIONS

Waste treatment methods Dispose of this material in accordance with standard practice for disposal of
potentially hazardous material as required by applicable international, national,
or local laws. Do not dump into any sewers, on the ground, or into body of
water.

Whatever cannot be recycled should be transferred to appropriate and approved waste disposal facility. Dispose waste
containers and unused contents in accordance with official regulations.

14. TRANSIT INFORMATION

Land transport ADR/RID (cross-border)

ADR/RID class Not regulated.

15. REGULATORY INFORMATION

Labeling according to EU guidelines:

N.A. Observe general safety regulations for handling chemicals.

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16. OTHER INFORMATION

Kanoria Chemicals & Industries Limited provides the information contained herein in good faith, but makes no
representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate
precautionary handling of the material by a properly trained person using this product. Individuals receiving the
information must exercise their independent judgement in determining its appropriateness for a particular purpose.
KANORIA CHEMICALS & INDUSTRIES LIMITED MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR
IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR
PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION
REFERS. ACCORDINGLY, KANORIA CHEMICALS & INDUSTRIES LIMITED WILL NOT BE RESPONSIBLE FOR DAMAGES
RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION.

Department issuing MSDS: Safety Department

Date of Issue: 01-07-2015 Date of Revision: 30-06-2018

This document is valid for 03 years from the date of issue, and is bound to be canceled, if not revised on or before the
date of revision.