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Antifoams / Defoamers

TEGO Antifoam

Member Company of
Fongs Industries Group
About Us
Evonik is the creative industrial group from The Business Line Interface & Performance
Germany which operates in three business of Evonik has its base in all kinds of organic
areas: Chemicals, Energy and Real Estate. specialty surfactants and organomodified
Evonik is a global leader in specialty chem- siloxanes. We hold strong positions with
icals, an expert in power generation from antifoams, emulsifiers, corrosion inhibitors,
hard coal and renewable energies, and one dispersing aids, hydrophobing and wetting
of the largest private residential real estate agents, softeners and radiation curable
companies in Ger-many. Our strengths are release coatings. Our broad product range,
creativity, spe-cialization, continuous self- technological background and application
renewal, and reliability. Evonik is active in know-how addresses several industries like
over 100 countries around the world. plastics, rubber, label, tape and release liner
manufacturing, construction, lubricants,
agro, textile and tissue industry.

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Product Range
The textile industry is facing many conflicting challenges, such
as the need for higher efficiency, reducing cost through shorter
product cycles while maintaining a high quality standard and
continuously providing innovation.

Aside from the beneficial characteristics Our antifoam/defoamer product range


of surfactants (leveling agents, scouring comprises:
agents, wetting agents etc.), they are also
responsible for the formation of foam Concentrates
during almost all stages of production. Emulsion concentrates
For instance, the jet fills with foam and Ready to use emulsions
the production cannot proceed at opti-
mum speed. Care has to be taken that Depending on the antifoam/defoamer,
the applied antifoam does not negatively it can be either added as an internal anti-
impact the fabric quality by staining the foam thus being incorporated into the
fabric, or does not disturb the machine textile auxiliary to prevent foam forma-
runnability. tion, or added as an external antifoam,
whereby being added at the occurrence
of the foam to destroy it.

rupture
spreading
entering escaping gas

1 2 3 4 5

Figure 1. Mechanism of defoaming = defoamer

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Key Application Properties
Evonik offers antifoams/defoamers based on organo-modified siloxanes. High stability as well
as high efficiency during various textile application processes merge the advantanges of both
organic and silicone antifoams. In addition, we offer silica and silicone oil free defoamers.

The following table summarizes the relevant property profiles of our antifoams/defoamers:

Ionic Physical Conc.


Product Composition Type Form wt % Advantages and Application Suggestions

Water dispersable, no silicone spotting, no reverse


Concentrate based effect on printability, excellent stability as concent-
TEGO on organo-modified rate. Pre-defoaming of surfactant concentrates
Antifoam 793 siloxanes Non-ionic Liquid 100 with less than 30 % water content.

No silicone spotting, no reverse effect on printabi-


Concentrate based lity, excellent stability as concentrate. Pre-defoa-
TEGO on organo-modified ming of surfactant concentrates with less than 20
Antifoam 3062 siloxanes Non-ionic Liquid 100 % water content.

Excellent stability in alkaline conditions, even at


elevated temperatures. Jet-stable. Pre-defoaming
of surfactant concentrates. In aqueous media, the
Emulsion concentrate use of pre-dilutions (1:3 to 1:10 in water) is re-
TEGO based on organo- commended. Ready to use predilutions are availa-
Antifoam MR 1015 modified siloxanes Non-ionic Liquid 70 ble on request.

Emulsion concentrate with excellent jet stability


and good electrolyte tolerance. Easy to dilute. Sui-
TEGO Jet stable antifoam table for the production of ready to use dilutions.
Antifoam 7001 concentrate Non-ionic Liquid 40 Recommended for jet dyeing of polyamide.

Silica and silicone oil Easy to handle as on line defoamer, e.g. for white
TEGO free defoamer concent- water in nonwoven production using water entan-
Antifoam 2290 rate Non-ionic Liquid 100 glement.

Emulsion based on
TEGO organo-modified Antifoam for jet dyeing. No silicone spotting. Pre-
Antifoam PS 10 siloxanes and other dilutions have to be used immediately after prepa-
(Europe) ingredients Non-ionic Liquid 10 ration.

Emulsion based on
TEGO organo-modified Antifoam for jet dyeing. No silicone spotting. Pre-
Antifoam 32 H 10 siloxanes and other dilutions have to be used immediately after prepa-
(Asia) ingredients Non-ionic Liquid 16-17 ration.

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Performance data and use recommendations
for TEGO Antifoam 7001 jet defoamer
Jet dyeing of polyamide fabric in a laboratory Jet Dyeing Machine
(Mathis)

Parameters: pump nozzle 50%, reel speed 17m/min

Fabric: PA elastic knitted fabric

Liquor ratio: 1:30

Recipe:

Nylosan Red E-BNL 0.3 % Dyestuff from Clariant

Dymatic TBW-951 1.0 g/l Leveling agent from Dymatic (Alkylsulfonate)

Acetic Acid 1.0 g/l Adjustment of pH ~5

Defoamer 0.5 g/l (based on solid)

Foam build-up during dyeing process

Add the chemicals at 40C, heat up to 100C (1.5 C/min) hold for 100C for 30 min,
cool down to 70 C (1.5 C/min).

100 C for 30 min


1.5 C/min
1.5 C/min

70 C
70 C
40 C

time / min
0 10 20 30 40 50 60 70 80 90
40

35

30
foam height / cm

25

20 TA 7001
Comp. 1
15 Comp. 2
Comp. 3
10 Comp. 4
5

TEGO Antifoam 7001 provides efficient foam knock down, while the competition products
do not suppress the foam sufficiently over the whole process.

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Recommendations for dilution
Guideline formulation for stable, ready to use diluted emulsions of Production (at room temperature):
TEGO Antifoam 7001:
Charge the water into the vessel. Add
10% active 20% active TEGO XP 2226 and stir for 1 min.
Demineralised water 69.68 parts 46.42 parts Add caustic soda and stir until dilution is
TEGO XP 2226

2.63 parts 1.75 parts homogenous and thick. Stop stirring and
add TEGO Antifoam 7001 and preserva-
Caustic Soda (5.6%) 2.59 parts 1.73 parts
tive. Start stirring at low shear rates until
TEGO Antifoam 7001 25.00 parts 50.00 parts mixture is homogenous (approx. 5 min).
Preservative 0.10 parts 0.10 parts Stop stirring and discharge.

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Dosage/Handling
TEGO Antifoam 7001 can be applied as predilution of antifoam in water (1 part in
it is or in a diluted version. Dosage level 4 parts of water) is recommended.
may vary in dependence of process condi- Dosage level for dyeing in jet machines
tions. For preliminary trials we recom- also depends on the kind and concentra-
mend a dosage of TEGO Antifoam 7001 tion of leveling agents and dyeing sys-
between 0.025 % and 0.25 % (as is). Fur- tems. The following table has to be seen
ther dilution in production process is pos- as an orientation guide and is based on
sible. For use in jet dyeing applications a the lab jet results (% is based on actives).

Dosage recommendation

fabric Surfactant(s) Dosage of TEGO Antifoam 7001

PA alkane sulfonate (0.05 %) < 0.05 %

alkane sulfonate (0.05%) /


CO alcohol ethoxylate (0.05 %) 0.02 %

PES alcohol ethoxylate (0.2 %) 0.01 %

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www.evonik.com/textile-auxiliaries This information and any recommendations, technical
or otherwise, are presented in good faith and
believed to be correct as of the date prepared.
Recipients of this information and recommendations
must make their own determination as to its suitabil-
ity for their purposes. In no event shall Evonik as-
sume liability for damages or losses of any kind or
nature that result from the use of or reliance upon
this information and recommendations. EVONIK
EXPRESSLY DISCLAIMS ANY REPRESENTATIONS
AND WARRANTIES OF ANY KIND, WHETHER
EXPRESS OR IMPLIED, AS TO THE ACCURACY,
COMPLETENESS, NON-INFRINGEMENT, MER-
CHANTABILITY AND/OR FITNESS FOR A PAR-
TICULAR PURPOSE (EVEN IF EVONIK IS AWARE
OF SUCH PURPOSE) WITH RESPECT TO ANY
INFORMATION AND RECOMMENDATIONS
PROVIDED. Reference to any trade names used by
other companies is neither a recommendation nor
an endorsement of the corresponding product,
and does not imply that similar products could not
be used. Evonik reserves the right to make any
changes to the information and/or recommendations
at any time, without prior or subsequent notice.

Europe | Middle East | Africa Asia | Pacific The Americas

Evonik Nutrition & Care GmbH Evonik Specialty Chemicals Evonik Corporation
Goldschmidtstrae 100 (Shanghai) Co., Ltd. 7801 Whitepine Road
45127 Essen 55, Chundong Road P.O. Box 34628
Germany Xinzhuang Industry Park Richmond, VA 23234
Phone +49 201 173-2665 Shanghai, 201108 USA
fax +49 201 173-1990 PR China Phone +1 804 727-0700
www.evonik.com Phone +86 21 6119-1125 fax +1 804 727-0855
fax +86 21 6119-1406
Inv.-Nr.: 64-15
07/2015

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