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Marking scheme 2017

CHEMISTRY (043)/ CLASS XII

Chemistry 56 (B)

1 Because the electrons occupying the anionic vacant sites are unpaired 1
2 HClO, HClO2, HClO3, HClO4 (ANY TWO) 1
3 NO2 1
4 Pentaamminenitrito-N-cobalt(III) nitrate 1
5 p-nitroanilne < Anilne < p-methylaniline 1
6 Because of addition of non-volatile solute, vapour pressure of the solution lowers 1
down.
Because it depends on molaltiy / numbers of solute particles / Tb m 1
7 i) Rate increases by 4 times 1
ii) Second order 1
8 i) Xe F4 + SbF5 [Xe F3]+ [SbF6]- 1
ii) 2XeF2 + 2H2O(l) 2Xe(g) + 4 HF(aq) +O2 (g) 1
OR
8 i) All electrons in xenon are paired. By promoting one,two or three elecrons from filled 1
p-orbitals to vaccant d-orbitals we get 2, 4 and 6 unpaired electrons.
ii) The I.E of xenon is low to favour the formation of compounds. 1
9 i) Vitamin E 1
ii) Glucose and Fructose 1
10 i) Globular proteins unfolds and lose biological activity/Denaturation of protein takes 1
places
ii)Starch is polymer of --glucose and cellulose is polymer of - glucose 1
11
d=
3 1
7.2 3 30010 10 3 6.0210 23
z= 56 1

z = 2.08 2
1
Iron has bcc structure.
12 Tf = i Kf m
Here , m = w2x 1000/ M2XM1
1.62= i 1.86 K kg /mol 3.9 g x1000 / 122 g/mol x49 1
1.62 122 49
i=1.86 3.91000 = 1.33

As i > 1 , so the solute particles gets dissociated .


Note: This value of i is abnormal as per the Kf value given in the question paper . 1
(or any other correct method)
13 2.303 []
= log
[]

2.303 100
t99% =
1
= 2.303 2 / k - (i)

2.303 100
t90% = = 2.303 1 / k -(ii)
10
Divide (i) equation by (ii)
2.303
99% 2

90%
= 2.303 =2
1

t99% = 2 t90% 1
OR
13
2 21
Log 1 = 2.303 [ 1 2
]

24 102 50
Log = [ ] 1
4 102 2.303 8.314 300 350

0.000476
Log 6 =
19.147

0.7782 19.147
Ea= 0.000476
= 3.130 104 J mol-1
= 31.30 k J mol -1 1
14 a) Zinc being low boiling metal will distill first leaving behind impurities/ on 1
electrolysis the pure zinc metal gets deposited on cathode from anode.
b) i)Because its easier to reduce the oxide of a metal than its sulphide. 1
ii)Reduction of ZnO by carbon is spontaneous but that of Cr2O3 is non 1
spontaneous /

ZnO + C- Zn + CO , G= -ve ; Cr2O3 + 3C - 2Cr + 3CO , G= +ve


15 i) X-X bond in interhalogens is weaker than X-X bond in halogen. 1
ii) High bond dissociation energy/ due to presence of triple covalent bond. 1
iii) Because bond dissociation enthalpy decreases from NH3 to BiH3 1
16 a) sp3d2 , 1
paramagnetic
high spin
b) As (en) is bidentate chelating ligand while F- is monodentate ligand. 1
17 a) i)
1

b)
ii)

(or any other correct method)


c) Alkyl halides cannot form hydrogen bonds with water molecules. 1
18
a.

b.

c.

19 i) Bacause of weaker intermolecular interactions in aldehydes and ketones / 1


strong hydrogen bonding in alcohols.
ii) Due to I effect of chlorine / greater stabilisation of chloro acetate ions 1
iii) Because it does not contain -hydrogen atom. 1
20 A: C6H5COOH , B: C6H5CONH2 , C: C6H5NH2 1,1,1
21

i) Caprolactum / / NH2(CH2)5-COOH
1
ii) Buna-S
1
iii) Fibres
1
22 i) Aspartame 1
ii) An ester formed from stearic acid and polyethylene glycol 1
iii) Morphine 1
23 i) Alum coagulates blood due to which blood stops. 1
ii) Alum coagulates the impurities present in water and water is purified 1
iii) Clouds are colloidal in nature and carry charge. Spray of silver iodide causes 1
coagulation resulting in artificial rain
iv) Caring, responsible, helpful, kindness (Any two) ,
24
0.059 1
Ecell = Eocell -

log [2+]
+ 2
o 0.059
=[E c - EA] - log [2+]+ 2 1
0.059 102
=[0.80- (-2.34)] - 2 log 2
104
6
= 3.14- 0.0295 log 10
= 3.14- 0.0295 6 = 2.96 V 1
G= -nF Ecell 1
= -2 96500 2.96= -571280 J mol-1 / -571.28 k J mol-1 1
OR
24 a) i)Zinc being more reactive will sacrifice itself for iron 1
ii)Zinc is more reactive than copper , so it replaces copper from its salt solution.
b) . 1
oHCOOH = o HCOO- + o H+
= 349.6 + 54.6 = 404.2 S cm2/mol
Now, = m /o m
= 46.1 / 404.2 = 0.114
Dissociation constant ( Kc)= c2/ 1- ( since is very small so (1-) =1)
= (0.025) (0.114)2 = 0.000325
Kc = 3.25 10 -4
25 a) Due to comparable energies of 5f, 6d and 7s orbitals 1
Both show contraction / main oxidation state of +3. 1
b) Both Cr+ and Cu+ have stable configuration of exactly half filled (3d5) and
fully filled (3d10) d orbitals , so the removal of an electron from those is quite
difficult due to which second I.E of Cr and Cu are quite high. 2
c) Due to completely filled d orbitals which lead to weak metallic bonding. 1
OR
25 a) i)Due to presence of unpaired electrons in d-orbitals. 1
ii) Due to comparable energies of ns and (n-1) d orbitals / incomplete filling of d- 1
orbitals.
iii) Due to lanthanoid contraction. 1
b) .

1+1
or

(If the student writes only statement then award 1 mark only)

26 a) i)

ii)

b) i)Heat both compounds with NaOH and I2 , ethanol gives yellow ppt of iodoform 1
ii)Add Lucas reagent(ZnCl2 +HCl) to both the compounds, 2-methylpropan-2-ol 1
gives turbidity immediately. (or any other correct chemical test)
c) 2-Methylpropan-2-ol 1
OR
26 a)

1
b)i)The C-O bond in phenol has partial double bond character due to resonance /
carbon in phenol is sp2 hybridised whereas in alcohols it is sp3 hybridised. 1
ii)Due to I/-R effect of NO2 group and +I/+R effect of methyl group/ nitrophenoxide
ion is more stable as compared to methyl phenoxide ion. 1

1 Dr. (Mrs.) Sangeeta Bhatia 12 Sh. S. Vallabhan

2 Dr. K.N. Uppadhya 13 Dr. Bhagyabati Nayak

3 Prof. R.D. Shukla 14 Ms. Anila Mechur


Jayachandran

4 Sh. S.K. Munjal 15 Mrs. Deepika Arora

5 Sh. D.A. Mishra 16 Ms. Seema Bhatnagar

6 Sh. Rakesh Dhawan 17 Mrs. Sushma Sachdeva

7 Dr. (Mrs.) Sunita Ramrakhiani 18 Dr. Azhar Aslam Khan

8 Mrs. Preeti Kiran 19 Mr. Roop Narain


Chauhan
9 Ms. Neeru Sofat 20 Mr. Mukesh Kumar
Kaushik

10 Sh. Pawan Singh Meena 21 Ms. Abha Chaudhary

11 Mrs. P. Nirupama Shankar 22 Ms. Garima Bhutani

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