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Filiform corrosion occurs on metallic surfaces coated with a thin organic lm that is typically 0.1 mm thick.
The pa ern of corrosion a ack is characterized by the appearance of ne laments emana ng from one or
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more sources in semi-random direc ons. The laments are ne tunnels composed of corrosion products
underneath the bulged and cracked coa ng.
Filiform corrosion can be visually recognized without using a microscopy. Filiform corrosion has been
observed on surfaces of coated steel, magnesium, and aluminum with thin coa ngs of n, silver, gold,
phosphate, enamel, and lacquer. Filiform corrosion has also been observed on paper-backed aluminum
foils.
Mechanisms
What causes liform corrosion? Filiform corrosion is a special case of crevice corrosion.
During propaga on, water is supplied to the head of the lament from the surrounding atmosphere by
osmo c ac on due to the high concentra on of dissolved ferrous ions on the surface of steel substrate.
Osmosis tends to remove water from the inac ve tail, because of the low concentra on of soluble salts
(iron has precipitated as ferric hydroxide).
Preven on
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How to prevent liform corrosion? Filiform corrosion or underlm corrosion can be prevented with the
following methods:
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