MODEL SOLUTIONS TO IIT JEE ADVANCED 2016

Paper I Code 0
PART I

1 2 3 4 5
A B D D D

6 7 8 9 10 11 12 13

A, D B, C A, B, D B, D B, C, D A, C, D A, B, C, D D

14 15 16 17 18
6 9 3 8 9

Section I 4.
N cos60 N
60
1. For = 45 = i N sin60 l
r = 30. When ray graces PR after separation 30
c = 45
ext. L = 45 + 30 = 75
l/2
= 180 (75 + 90) = 15 h
W N
hc 60
2. eV0 =
f P
hc h 3
e(2) = cos30 = =
0.3 10 6 l' 2
hc 2h
e(1) = l =
0.4 10 6 3
1 1 3N 32
e = hc 106 N=
.4
N cos60 + N = 16 =
0 . 3 0 2 3
0 .1 N sin60 = f
e = hc 106
0 . 3 0 .4 2 3 16 3
19
16 =ff = newton
1.6 10 0 .3 0 .4 3 2 3
h=
3 108 0.1 106 Taking torque about P,
= 0.64 1033 l
N l = W cos 60
= 6.4 10 2
34

32 2h l 1 h 3 3
mc 120 4200 (30 10 ) = 16 =
3. = 3 3 2 2 l 16
t 3 60 60
= 933 W
P = 3 kW + 933 W
= 3933 W
5. v = 3t 2 i + 2t j
+
a = 6t i + 2 j
+
+ + + 10
v = 3 12 i + 2 1 5 j
+ + + 3
+ + +
= 10 i + 10 j (A) correct
+ 10
+ + F = m a = 0.1 6 1 i + 2 5 j
+ + + 3
+ + + ( )
= 2 i + j (C) Wrong
+ + + ( ) (
L = r p = i + j 0.1 3 i + 2 j )
= 0.1[2 k 3 k ]
+ + +

= 0.1 ( k )
+

5( k ) = k
It is a case of discharging of a capacitor in the 10 5
= 0.1
resistor. 3 3
Q = Q0et/RC (B) correct
Dividing by l,
Q Q0 t / RC
( )(
= r F = i + j 2 i + j )
= e 10
l l = k 2k = 2 5 k
= e t/RC 3
' e t / RC =
20
k
j = E = = (at a point) 3
2r 2r
Hence (D) correct

j coulomb coulomb 2
9. E = farad/m = =
volt m Jm
kBT = energy = joule
coloumb 2 1
A. = WRONG
coulomb 2 m
t m3 J
Jm
Section II coloumb 2 J
B. = =m
Jm 1
1 1 1 coulomb 2
= ( 1)
1 1
6. = m3
v u R1 f CORRECT
1 1 1 1 60 + 30
= = coloumb 2
60 30 f f 60 30 C. = m3 / 2
2 2/3
f = 20 cm coulomb 1
(D) correct 3 J
Jm m
1 1 1
+ = f = 15 cm WRONG
+ 10 30 f '
Since convex mirror, (c) wrong coloumb 2
D. =m
Radius of curvature R1 = 2f = 30 cm coulomb 2 1
1/ 3
(B) wrong 3 J
Jm m

( 1) 1 = 1 CORRECT
R1 f

( 1)
1
=
1 10. P

30 20
3
1 = = 1.5 = 2.5
2 1800 m
(A) correct

7. B, C
M 10 m 10 m N

8. r = t 3 i + t 2 j

1800 m
R
 The component of the cars velocity along PM l
and PN are to be considered. R = , A decreases with evaporation R
A
c + v0 ' c + v0 ' increases (B) WRONG.
f1 = f1 f2 ' = f2 c
c V2
Since the distances PQ and RQ are large, the (D) P = , R increases with time (D)
R
component velocity is nearly equal to the cars
correct.
velocity.
(C) As it consumes less power, lesser heating
c + v0 ' and lesser temperature. Hence by Wiens law
vP = f1 f2 = (f1 f2) (approaching)
c corresponding to maximum intensity increases.
c v0 ' That is, frequency decreases (C) wrong.
vR = f1 f2 = (f1 f2) (Receding)
c
Section III
vQ = (f1 f2) since motion is perpendicular to MN
c + v0 c v0 '
vP + VR = (f1 f2) + 6.6 10 34 3 108
c
hc
c 14. E = =
970 10 10 1.6 10 19
= vQ 2 (c) correct
= 12 eV
E = 13.6 12 = 1.6
(D) Correct since component velocity is nearly
13.6
the same as cars velocity. Hence beat frequency = 1.6 n = 3
is nearly constant. n2
Transitions = 6
(B) correct since approaching car suddenly
becomes receding car.
15. 12
5 B 12 6 C+e

11. Snells law 12.014u 12u

n1 sini = n2 sinf (C) correct Energy released due to mass defect of
f depends on n2, but l is independent of n2 0.014u = 931.5 0.014 = 13.041 MeV
(D) correct. Energy of e
(A) correct as shift depends on R.I of slab. = 13.041 MeV excitation energy of 4.041 MeV
(B) wrong since if n1 = n2, n1sini = 0 which need = 9 MeV
not be the case
2 [ ]ga2
16. v =
2
n 9
2 [8 0.8]g 1
12. rn = r0
Z
vP =
rn +1 rn (n + 1)2 n2 9 3
=
2 [8 1.6]g (0.5 )2
independent of Z
rn n2 vQ =
(A) correct 9 2
2n + 1 VP 7.2 1 2
= =
n3 VQ 6.4 (0.5 )2 3
2n 1 14.4
2 (B) correct = =3
n n 4 .8
Z2
En = Rhc 5
n2 17. min =
12
1 1
+ 2 1 1 1 1
En +1 En (n + 1)2
n n2 + (n + 1)2 = + +
= = Reff 3 4 12
En 1 n2 (n + 1)2
12
n 2 Reff = = 1.5
8
2n + 1 2n 1
= 2 2 3 (C) correct 5
2
(
n n +1 )2
n n n max =
1.5
nh Ln+1 Ln (n + 1) n 1 max 12
Ln = = = So = =8
2 Ln n n min 1.5
(D) correct
18. P T4
13. Due to non-uniform evaporation, the resistance 4
of the filament is not uniform along its length. P 760
log2 1 = 1 = log2

Hence heating is not uniform (A) WRONG P
0 T0
 4 4 4 4
P 3040 2 760 1 1
log2 2 = x = log2 = = = 2
P 2x 3040 4 2
0 T0
4 2 2 1
760 = =
2 =
2x 2.2x 1 28
T0 2 x 1 = 28
3040
4 x1=8
2x =
x=9
T0

PART II

19 20 21 22 23
B B A A C

24 25 26 27 28 29 30 31
B, C B, C B B, C, D A, C, D A A, B, C B, D

32 33 34 35 36
4 5 9 4 6

Section I 23. qrev = Pext .V

= 3 1 L atm
19. Atomic radii increases in the order = 3 101.3 J
Ga < Al < n < Tl q
Ssurr = rev
T
20. [NiCl4]2, Na3[CoF6] and CsO2 are paramagnetic 3 101.3
Compounds. =
300
= 1.013 J K1
H2
21. H2CC=CHCH2
catalyst Section II
CH3
n

natur al r ubber CH3

CH3CCH
H2CCHCH2CH2
OH

CH3 ( i) O2 ( i) CHCl3 / NaOH

n 24.
+

+
( ii) H 3O ( ii) H 3O

22. The plot of radial probability function (4r2dr2) Cumene (P )

against distance from the nucleus (r) for 1s
orbital is OH OH
CHO
+

4 r2dr2 (Q )
CHO
(R)

OH OCH2Ph
CHO CHO
NaOH
0 r
P hCH 2Br
25. BrF5 sp3d2 hybridisation Section III
5 bp and 1 lp
ClF3 sp3d hybridisation

3 bp and 2 lp 32. D . c
XeF4 sp3d2 hybridisation T
But
4 bp and 2 lp P
SF4 sp3d hybridisation

4 bp and 1 lp and c T
3
T2
NH2 NHCOCH3 D
P
3
acetylatio n KBrO3 / HBr D 2 ( 22 ) 2
= =4
D1 2
26.
NHCOCH3 NH2 33. The geometrical isomers are
H 2 Cl
H 3O+ NaNO2 / HCl
N O
he at 27 3-278 K Co

O N
Br Br Cl H2
N2Cl Br
H2 Cl H2
Cu / HBr N N

Co
O O
Br Br Cl

H2 Cl
27. Higher the activation energy, slower the reaction.
Rate constant increases with increase in N Cl
temperature as the rate of collision increases Co
which in turn increases the number of activated
O NH2
molecules.
O
Larger the activation energy, greater the
influence of change in temperature on rate
constant. H2 Cl
The pre-exponentitial factor (A) is a measure of N Cl
the number of collisions. Co

2-
O O
NH2
OH

B Cl

O O O Cl
28. HO B B OH Co
O
N O
O O H2 NH2
B

OH n2 1
34. =
n1 9
1 1000
29. Only CuS is precipitated selectively. m=
9 M1
30. Ketones containing OH group on -carbon and 1 2 1000
all aldehydes answer Tollens test. M=
1 M2 + 9 M1
1000 2000
31. Nuclides that lie below the band of stability have Given, =
too few neutrons for stability and decay by 9M1 M2 + 9M1
positron-emission or electron capture. n either M2
case the number of neutrons increases and =9
M1
decreases the number of protons.
35. Possible chiral products are H H
CH3C*CH2C*CH3
H
BrCH2C*CH2CH2CH3
Br Br
Br
H
CH3C*CH2CH2CH2Br
H H
CH3C* C*CH 2CH3
Br
Br Br 36. 8MnO 4 + 3S2O32 MnO2 + 6SO24
(n = 3 ) (n = 8 )

PART I

37 38 39 40 41
C A D D C

42 43 44 45 46 47 48 49
A, D B, C, D A, B, C B, C B, C A, C A, D A, B, C, D

50 51 52 53 54
5 3 1 2 0

Section I 80 39

= 100 40
20 3 80 39
+
37. P(T1) = P(T2 ) =
20 80
D Defective 100 4 100 40
100 100
78
=
Let P D = x P D = 10 x 93
T2 T1
P(D) = 0.07 38. 6G 4B atmost one boy
P(D) = P(T1) P D + P(T2 ) P D (i) Boy + 3G 4C1 6C3
T1 T2 (ii) 4G 6C4
20 80 Total ways of selection of team
.07 = 10 x + x
100 100 = 4 20 + 15 = 95
7 = 200x + 80x From each team the captain may be chosen in
4
C1 ways
7 1
x= = (Team + Captain) = 95 4 = 380
280 40
P D = P D' =
1 39 39. x2 2x sec + 1 = 0
T2 40 T2 40
x=
(2 sec )
4 sec 2 4
P D = P D' =
1 3
2
T1 4 T1 4
= sec tan
Required Probability = P T2
<<

D' 6 12
P(T2 ) P D'
= T2

P(T1) P D' + P(T2 ) P D'
T1 T1 12 6

1 = sec tan
1 = sec + tan
 x2 + 2xtan 1 = 0 dy
42. (x2 + xy + 4x + 2y + 4) y2 = 0
x=
(2 tan )
4 tan + 4 2 dx
dy
2 [(x + 2)2 + y(x + 2)] y2 = 0
= tan sec dx
2 = tan +sec X =x+2
2 = tan sec Y=y
1 + 2 = sec tan + tan sec dY dy
=
=0 dX dx
dY
(X2 +YX) Y2 = 0
3 1 sin x cos x dX
40. + + 2 =0
cos x sin x cos x sin x Y = VX
dY dV
=V+X
2 cos x + 2 cos 2x = 0 dX dX
6
dV
(X2 + X2V) V + X V 2 X2 = 0
cos x + cos 2x = 0 dX
6
dV
x 3x (1 + V) V + X V2 = 0
2 cos + cos =0 dX
12 2 12 2
dV dV
x 3x V+X + V + V
2
V2 = 0
+ = or = dX dV
12 2 2 12 2 2 dV
5 5 X(1 + V) +V =0
x= x= dX
6 18 (1 + V )dV + dX = 0
5 5
Required sum = V X
6 18 Integrating logV + V +logX = C
5 logY +V = C
=
9 y
logy + =C
x+2
1 Curve passes through (1, 3)
41. 4x 2 + 1
x 3
log 3 + = C
1 1 3
Since x >0, 4 +
x3 x2 C = 1+ log3
Solution curve is
1 1 1
2 3 y
4x x logy + = 1 + log 3
x+2
Minimum value of is the maximum value of y = x +2 intersects at (1, 3)
1 1 1 (A) true
f(x) = 2 3
4x x 2logx + 2 = 1 + log3 (x + 2)

( )
1 2 1 = log3 x 1
y y 3 , where y = x + logx2 = 3 + log3
4 x x + 2logx = log3 3
f=
1
4
(
2y 3 y 2 ) 2log(y + 3) +
(x + 3)2
= 1 + log 3
x+2
f = (2 6 y )
1
y = (x + 3) do not intersect
2

4 D is correct
f = 0 y = 0 or
2 A, D correct
3
1
But y = 0 43.
x z
2
y=
3
S
2
Also, f < 0 at y = M
3
R(0, 3, 0)
1
Maximum of f = O y
27 3 3
T , , 0
Section II P(3, 0, 0) 2 2
Q(3, 3, 0)
x
 Circle C3 : x2 + (y q)2 = 12 Q3 (0, q)
S 3 Tangent at P to C1 x 2 + y = 3 ) (x)
(A) OT =
2 (x) touches C2
3
ST = 3 p3
= 2 3
O 3 T Q tan = 2 2 +1
2 p=3=6
p = 9, 3
p=9
A is incorrect q = 3
(B) Equation of line OQ is x = y centres of C2 & C3
As S lies directly above T, equation of the
plane containing OQS is x y = 0 ( 2, 1)
(B) correct
(C) Length of the ar from P(3, 0, 0) to x y = 0
3
Is
2
(C) correct (0, 9) (0, 3)
(D) Q2Q3 = 12
O (0, 0, 0)
Circle C2 : x2 + y2 2py + p2 12 = 0 p = 9
x2 + y2 18y + 69 = 0
xx1 + yy1 9(y + y1) + 69 = 0
xx1 + (y1 9)y + 69 9y1 = 0
x 2+y =3
3 3 x1 y 9 9 y1 69
M , + 3, 3 = 1 =
2 2 2 1 3
3y1 27 = 9y1 69
Equation of the line joining R and S is
6y1 = 69 27
x0 y3 z0
= = = 42
3 3 3 y1 = 7
2 2 x1 7 9
M lies on this line = = 2
2 1
3 3
M is , + 3, 3 x1 = 2 2

( )
2 2
3 3 R2 is 2 2 , 7
D. r s of OM are , + 3, 3 Circle C3
2 2
x2 + y2 + 6y 3 = 0
3 3
D. rs of RS are , ,3 xx1 + yy1 + 3(y + y1) 3 = 0
2 2 xx1 + (y1 + 3) y + 3y1 3 = 0
Since OM RS, x 2+y =3
3 3 3 3
, + + 3 + 3 3 = 0 x1 y + 3 3 3 y1
2 2 2 2 = 1 =
2 1 3
1
= x1
3 = +2
2
1 5
M is , , 1 x1 = + 2 2
( )
2 2
R3 is 2 2 , 1
15
OM = 3y1 + 9 = 3 3y1
2 6y1 = 6
(D) correct y1 = 1

44. x2 + y2 = 3
(
= R1 is 2 2 , 7 )
x2 = 2y (
R2 is 2 2 , 1 )
y2 + 2y 3 = 0 R1R22 = 32 + 64 = 96
(y + 3) (y 1) = 0
y = 3, 1 R1R2 = 16 6 = 4 6
Since P is in the first quadrant, y = 1 OR2R3
x2 = 2 x = 2 (
(0, 0) 2 2 , 7 ) (2 )
2, 1
(
P is 2 , 1 )
Circle C2 : x2 + (y p)2 = 12 Q2 (0, p)
 1 2 2 ( 1) Tangent at S x = 1
Area of OR2R3 = ysin = 1 x cos
2 72 2
= 1 cos
1 1 cos
= 12 2 = 6 2 y=
2 sin
Q2 (0, 9) 1 cos
Q3 (0, 3) Q is 1,
(
P 2, 1 ) (0, 9) (0, 3)
sin
Equation of the line through Q parallel to RS is
1 cos
Area of PQ2Q3 y= (1)
sin
=
1
2
{ 2 (12)}= 6 2 Equation of the normal at P is
y = (tan)x (2)
1 cos
45. g(f(x) = x f(x) = g1(x) (1) xtan =
sin
Also, g (f(x)) f (x) = 1
g (x3 + 3x + 2) (3x2 + 3) = 1 1 cos cos
x=
Put x = 0 sin sin

Then g (2) =
1 cos cos2
3 =
sin2
(A) incorrect
cos cos2 1 cos
Now, h(g(g(x))) = x x= , y=
1 1 1
h(x) = [g(g(x))] = g (g (x)) = f(f(x)), by (1) sin 2 sin
h (x) = f (f(x)) f (x)
=
( ) (
cos 1 cos ) ,=
cos
h(1) = f (6) f (1) 1 cos2 1 + cos
= 111 6 = 666 xcos + x = cos
(B) correct
x
Also, h(x) = f(f(x)) h(0) = f(f(0)) cos = (1)
f(2) = 16 1 x
(C) correct ysin = 1 cos = 1
x
h(x) = f(f(x)) h(g(3)) = f[f(g(3))] 1 x
= f(3) [since f = g1] 1 2x
= 38 =
1 x
(D) incorrect
1 2x
sin = (2)
46. PQ = k Q = kP1 (1 x )y
Equate the (2, 3) element on both sides Locus of E is

k
= k
1
(3 + 4 ) (1 2x )2 + x2 =1
12 + 20
y 2 (1 x )2 (1 x )2
8
= 1. Then |P|= 8
(1 2x)2 + y2x2 = y2(1 x)2
Also, PQ = k |P| |Q| = k3 1
(1 2x)2 y2 [1+ x2 2x x2]
k2 = y2(1 2x)
8 = k3
2 1
x
k = 4 |Q| = 8 2
(B) correct and (A) incorrect y2 = 1 2x is the locus
|P adj Q| = |P| |Q|2 = 8 82 = 29 1 1 1
(C) correct x= y2 = , y =
3 3 3
|Q adj P| = |Q| |P|2 = 8 82 = 29
(D) incorrect
f (x)
48. f (x) + =2
47. x
General solution is
P(cos, sin) xf(x) = C + x2
C
Q f(x) = +x
E x

R O S(1, 0)
x 0 +
1
lim xf = lim+ Cx 2 + 1
x x 0
{ }
(1, 0)
=1 (B false)

Tangent at P
1
(
lim f ' = lim Cx 2 + 1
x 0 + x x 0 +
)
xcos + ysin = 1
= 1 (A) is true)
 x 0 + x 0
(
lim x 2f ' (x ) = lim C + x 2 ) abc
==6 6
4R
f (1) 1 abc 567
R= =
= C 0 C + 1 1 46 6 46 6
C0
35
=
(C) is false 4 6
We have
x y z 6 6 2 6
C 4R sin sin sin = = =
f(x) = +x 2 2 2 s 9 3
x
Taking C = 1 x y z 2 6
sin sin sin =
|f(x)| 2 for x (0, 2) 2 2 2 3 4R
(D) is true
2 6 4 6
=
sx sy sz 12 35
49. = = 86 4
4 3 2 = =
3s 2s s 12 35 35
= = x+y
9 9 Sin2
9(s x) = 4s 2
5s 180o z
9x = 5s x =
9 sin2
2
sy s
=
z
3 9 = sin2 90o
3s 3y = s 2
2s
= (1 + cos z )
3y = 2s y = z 1
= cos2
3 2 2
sz s z2 = x2 + y2 2xycosZ
=
2 9 x y 49 = 25 + 36 2 5 6 cosZ
9s 9z = 2s 60cosZ = 49 61 = 12
9z = 7s 1
z cosZ =
7s 5
z=
9 Z 1 1 1 6 3
cos2 = 1 + = =
Area of XYZ = s(s x )(s y ) (s z ) 2 2 5 2 5 5

4s s 2s Section II
= s
9 3 9
50. Coefficient of x2
s2 2 2 = 1 + 3C2 + 4C2 + + 49C2 + 50C2(m2)
=
9 3 = 50C3 + (m2) 50C2,
As nCr 1 + nCr = n + 1Cr
2 8 50
C3 + m2 50C2 = (3n + 1)51C3
r= 2 = (given)
s s 3 51
C3 + (m2 1) 50C2 = (3n + 1)51C3

(m2 1) 50C2 = 3n 51C3
2
s 2
=
8
3
50 49 2
2
( )
m 1 = 3n
51 50 49
32
8s 4 8 m2 1 = 51n
= s2 = 81 m2 = 51n + 1 51 5 = 255
81 3s 2 3
m = 16 255 + 1 = 256
s=9 n=5
5
x= 9 = 5
9 x 2 sin(x )
2s 2 9 51. lim
y= = =6 x 0 x sin x
3 3 By L Hospital Rule
7s 7 9 1 1
z= = =7 6 = 1 = and =
9 9 6 3
2 2
Area of XYZ = 81
1 1
9 3 6( + ) = 6 +
( )
= 2 2 3 3 =6 6
6 3
 3 1 1 1
= 6 = 3
6 x 1 2 4 = 10
3

1 3 9
1 + 3i 3 6
2x + 6x (1) (1) (2) = 10
52. z =
2 2x3 + 12x6 = 10
( )r 2s ( )2 Let x3 = y
2s
P2 = 2s 2s 12y2 + 2y 10 = 0
r r (y + 12) (y 10) = 0
y = 12 ; y = 10
x3 = 12 or x3 = 10
( )2r + 45 ( )r 2s + 2sr = 1 0
= 2s 2 real roots
( ) + 1
r r 2s
+
4s 2r
0
()2r + 4s = 1 54. Given
x
2s((-)r + r) = 0 2s = 0(not possible) t2
() + = 0 r should be odd
r r
1 + t 4 dt = 2x 1
r = 1 or 3 0
+ = 0 2 + 2 = 0 Differentiating both sides with respect to x
r = 1 2 + 4S = 1 4s = 4 s = 1 x2
r = 3 1 + 4s = 1 Not possible =2
1+ x4
Only ordered pair is (1, 1) 4 2
2x x + 2 = 0
Roots of the above are complex
x x2 1 x x2 x3 Hence, there is no solution.
53. 2x (2x ) 2
1 + 2x (2x ) (2x )3
2
= 10 Number of distinct solutions in (0, 1) is therefore,
3x (3x )2 1 3x (3x )2 (3x )3 0

x x2 1 1 x x2
x 3x 2
0 + 6 x 1 2x
3
(2x )2 = 10
2x 8 x 2
0 1 3x (3x )2
(8x 6x ) + 6x
3 3 3