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)-JEE(Advanced)/19
FIITJEE JEE(Advanced)-2019
OPEN TEST
PAPER-2
1. C 24. A 47. B
2. C 25. C 48. B
3. B 26. C 49. B
4. AD 27. D 50. BC
5. AC 28. B 51. ACD
9. C 32. B 55. A
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AIITS-OT (Paper-2)-PCM (Sol.)-JEE(Advanced)/19 2
Physics PART – I
SECTION – A
1. C
k
Sol. F
v
dv k k
m ; vdv dt
dt v m
2
mv
= kt
2
Work done by force = change in kinetic energy.
2. C
L L J
Sol. J x I w Vcm =
2 2 m
LL
J x
L J 2 2 J
Vcm ; L
2 M I m x 2
ML2 J
I=
12
3. B
Sol. vA x
dx dx
a x ; adt ; x t2
dt x
4. AD
Sol. fmax = 0.4 110 = 44 N 40N
40 + f = 60 N
f
f = 20 N
a=0
30N
60N 80N
5. AC
P(dV)
Sol. C Cv …(i)
n(dT)
dT
To ev …(ii)
dV
From (i) and (ii)
R
C Cv
V
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3 AIITS-OT (Paper-2)-PCM (Sol.)-JEE(Advanced)/19
6. ABCD
dy
Sol. Particle velocity vp = –v
dx
v is the wave velocity.
dy
is the slope.
dx
At point S, slope is zero, there force Vp at S is zero.
At point T, slope is (+)ve, there fore Vp will be along –ve x direction
dy
Excess pressure dP = –B.
dx
At point S, slope is zero
dP = 0.
At point R, slope is –ve
dP is (+) ve i.e., particles located near C are under compression.
7. BC
1
2 10 30º
2usin 2 1s .
Sol. T 30º
g 10
30º 30º
8. BD
4
25t 50
Sol. V dt
2 10
9. C
Po V
Sol. P 5Po
Vo
1 Po V 2
T 5P
o V
nR Vo
dT 1 2Po V
5Po =0
dV nR Vo
5V
V o at maximum temperature.
2
25
Tmax To
16
10. D
dQ P dV
Sol. Cv 0
ndT n dT
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AIITS-OT (Paper-2)-PCM (Sol.)-JEE(Advanced)/19 4
Po V
5Po
Vo nR
CV 0
n 2Po V
5Po
Vo
V
5
Vo 3
2V 2
5
Vo
25
V= Vo
8
SECTION – C
11. 2
V v
Sol. =
r
V
r
12. 3
Sol. Let v0 be the velocity required to send a particle to infinity from point A. A 30°
1 GMm
mv 20 =0
2 2R R
GM
v0 =
R R
velocity of projection at A
1 GM
vp = v0 =
2 2R
vp
30°
A
B
R r v
Let v be the velocity at the highest point and r be its distance from
the center of the plant A.
1 GMm GM
mv 20 =0 v0
2 2R R
velocity of projection at A
1 GM
vp = v0 =
2 2R
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5 AIITS-OT (Paper-2)-PCM (Sol.)-JEE(Advanced)/19
Let v be the velocity at the highest point and r be its distance from the
center of the planet. Using Conservation of angular momentum.
m vp 2 Rcos30° = m vr
3R GM 3GMR
v= …(1)
r R 2r 2
From conservation on the mechanical energy at A and B
GMm 1 GM GMm 1
– m. =– mv2
2R 2 2R r 2
replacing the value of v from (1) in the above eqn.
GM GM 1 3 GMR
– =– r2 – 4Rr + 3R2= 0
4R r 2 2 r2
(r – 3R)(r – R)= 0 r = R, r = 3R
13. 2
1
Sol. m V 2 Pdt
2
t3
V2 = 4
2
V=2
14. 6
Sol. For equilibrium of block rod
Mg sin = (N) m = 0.5
= (Mg cos + mg cos )
M
370
15. 2
Sol. Velocity of efflux = 16 × 0.25 = 4 m/s2
2h
Time of fall of the liquid = = 0.25 sec.
g
Thus, range on horizontal surface = velocity of efflux × time of fall = 2 m.
16. 3
I
Sol. We know that Loudness = 10 log10
I0
I
According to the problems A 10log10
I0
2I
B 10log10 3dB
I0
17. 3
q
Sol. T (R)
t
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AIITS-OT (Paper-2)-PCM (Sol.)-JEE(Advanced)/19 6
18. 2
fR R
Sol. Cv =
2 1
2
f=
( 1)
19. 4
m A 2
Sol. 3
mB 2
mA mB
3 ; x CM .
mB m A mB 4
20. 6
338 5
Sol. f f 1 6
338 5
SECTION – D
21. 00001.40
Sol. VmM 4iˆ 3 ˆj
m
V u ˆi 3 ˆj
m M
VM Viˆ
Here, along horizontal direction mVm MVM 0
um 4
V u and u V 4 u
M 1
To move one meter w.r.t. ground
4
2 3
1 24 14
1 1 or 1.40
g g 10
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7 AIITS-OT (Paper-2)-PCM (Sol.)-JEE(Advanced)/19
22. 00005.18 Hz
m 2
Sol. Tsp = –K2 =
3
3K
m
m 1
T 2 f .
3K T
23. 00002.72 J
Sol. Loss in KE = Kf – Ki
1 2 1
K f mv cm Icm 2
2 2
1 1
Ki (0.08) (10)2 (0.08) (6)2
2 2
Apply conservation of momentum and angular momentum to get Vcm and .
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AIITS-OT (Paper-2)-PCM (Sol.)-JEE(Advanced)/19 8
Chemistry PART – II
SECTION – A
24. A
NA no of electron will be removed by
6.023 1023
16 gm of metal M
2.25 1023
= 42.83 gm of metal M
equiv. wt. of metal is 42.83
25. C
Sol. Higher electronegativity, higher bond length
26. C
Sol. Pequm = 1 atm
K1 pCO2 1atm
K 2 pNH3 pH2S = 0.5 0.5 = 2.5 10–2 atm2 = 0.25 atm2
2
2 2 1
K 3 pNH3 pCO2
3 3
4 1 4
0.148 atm3
9 3 27
The order is K1 > K2 > K3
27. D
Sol. It is dumbbell along Z axis
28. B
Sol. Fact Based.
29. AC
Sol. Addition of inert gas at constant pressure shift the reaction towards greater number of
moles.
30. ABCD
moles Mass of one litre H2O 1000
Sol. (A) H2O = 55.55 mol L–1 = 55.55 mol dm–3
Vol. in L Molar mass 18
1L
(B) Kw = [H+] [OH–] = 10–7 10–7 = 1 10–14
(C) Degree of dissociation =
[H+] = C
H 107
or, 1.8 109
C 55.55
H OH
(D) Ionization constant(Kionization) =
H2O
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9 AIITS-OT (Paper-2)-PCM (Sol.)-JEE(Advanced)/19
C C 2C
= 2C ( is very small)
C 1 1
= (1.8 10–9)2 55.5 = 1.8 10–16 mol dm–3
31. A
Sol. O O O(-)
(-) (-)
32. B
Sol. At 770 k, Cl2 2C l
(i)CH3 CH CH2 2C l CH2 CH CH2 HCl
(ii)CH2 CH CH2 C l Cl CH2 CH CH2
33. B
Sol. Addition takes place.
SECTION – C
34. 4
Sol. OH OH OH OH
COOH NO 2 Cl
, ,
,
Cl
35. 3
Sol.
Br, (CH3)3CBr, CH2Br
36. 4
Sol. Fact calculated from MOT
37. 1
Sol. Highest energetic orbital is p-orbital
38. 4
Sol. N2 O2
2NO
Initial a (100–a) 0
Final (a – x) (100 – a – x) 2x
2x 1.8
Given x = 0.9
100 100
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AIITS-OT (Paper-2)-PCM (Sol.)-JEE(Advanced)/19 10
[NO]2
Also K P = Kc =
[N2 ][O 2 ]
(2x)2
=
(a – x)(100 – a – x)
= 2.1 × 10–3
a= 79% ; 100 – a = 21%
39. 1
Sol.
PCl5
PCl3 Cl2
Mole before
dissociation 1 0 0
mole after 1-x x x
n
nPCl3 nCl2
P
Kp = ......(i)
nPCl5 n
At P = 0.1x = 4 atm,
By equation (i)
1
0.1 0.1 4
Kp =
0.9 1.1
= 0.0404 atm
At = 0.2
1
0.2 0.2 P
0.0404 = :
0.8 1.2
P = 0.969 atm
40. 4
Sol.
N2O4
2NO2
Mole before equillibrium 1 0
Mole at equilibrium (1 – x 2x
n
4x 2 P
Kp =
(1 – x) n
4x 2 160
640 =
(1– x) (1 x)
4x 2
4=
1 – x2
or 1 – x2 = x2
2x2 = 1
1
x2 =
2
or x = 0.707 = 70.7%
When x = 0.5, let pressure be P.
4 (0.5)2 P
Then Kp = 640 =
0.5 1.5
P = 480 mm
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11 AIITS-OT (Paper-2)-PCM (Sol.)-JEE(Advanced)/19
41. 2
Sol.
ClF3 :
This is the electronic structure of chlorine atom in the excited state.
In ClF3 sp2d hybridisation occurs, 3 unpaired electrons form bounds with fluorine atoms,
and 2 lone pairs occupying 2 corners of a distorted trigonal bipyramidal structure.
42. 3
Sol. Fact based
43. 4
Sol.
PCl5
PCl3 Cl2
Mole before
dissociation 0.1 0 0
mole after (0.1 – x) x x
dissociation
Given volume of container = 8 litre
x x
.
[PCl3 ][Cl2 ] x2
Now Kc = = 8 8 = ....... (i)
[PCl5 ] (0.1– x) 8(0.1– x)
8
Also, PV = nRT for the equilibrium mixture at 540 K.
1 × 8 = (0.1 + x) × 0.082 0 × 540
x = 0.08 ...... (ii)
0.08 0.08
Kc =
8(0.1 – 0.08)
= 4 × 10–2 mole litre–1
SECTION – D
44. 00000.66
Sol.
PCl5
PCl3 Cl2
P
P(1 - 0.5) 0.5P 0.5P
= 0.5 P
4
0.5 P + 0.5 P + 0.5 P = 2 P =
3
4
KP = 0.5 P = 0.5 = 0.66 atm
3
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AIITS-OT (Paper-2)-PCM (Sol.)-JEE(Advanced)/19 12
45. 00016.40
nRT 2 0.082 300
Sol. P 16.40 atm
V 3
46. 00001.53
Sol. O O
CHBr3 R COONa
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13 AIITS-OT (Paper-2)-PCM (Sol.)-JEE(Advanced)/19
SECTION – A
47. B
Sol. The total numbers of required ways = the total number of factors of n.
180 22 32 5 . Therefore the total number of factors of 180 is 3 3 2 18 .
48. B
Sol. AB AO BO a AOB 60 P(x, y)
A
PA
3
r a
B
x 2 y 2 a2 3a2 a
x 2 y 2 4a2 O a
a
49. B
Sol. 2 sin x 1 2 cos y 1 0
1
either sin x
2
11 7
x ,
6 6
Or
1
cos y ,
2
2 4
y ,
3 3
4 11 19
maximum value of x y .
3 6 6
50. BC
4
Sol. x 4 y4 x y
2xy 2x 2 3xy 2y 2 0
two real and two complex roots
51. ACD
1
Sol. Given, sin x sin y cos z .............(1)
2 2
sin2 x sin3 y 1
................(2)
cos z 4 2
sin x sin4 y 1
..................(3)
cos2 z 8
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AIITS-OT (Paper-2)-PCM (Sol.)-JEE(Advanced)/19 14
cos2 z
½ 2..............(4)
sin xxin2 y
1
(3) x(4) sin y .............. (5)
2
1
(1) x (2) sin3 x sin4 y
16
sin3 x 1
sin x 1 (6)
1
cos z (7)
2
1 3
Now sin x sin y 1
2 2
tan x y z tan165 tan15 3 2
3 1
cos y z
2 2
sec y z 6 2
optionsA,C,D
52. AB
x y 1 2x y 0
Sol.
All the lines pass through 1,2
PA 2
PB and PC make angle with the line
6 P 1,2 C
PA : x y 1 0
Slope of PB and PC are given by
1 A
1 B
3 2 3,2 3 xy5
1
1
3
The equation are y 2 2 3 x 1
and y 2 2 3 x 1
53. ACD
Sol.
2t 2 ,t lies out-side of x y 2 2y 3 .
54. ABD
Sol. Let p ,q d, r 2d, s 3d (where d > 0)
then d 2 (i),
d a (ii)
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15 AIITS-OT (Paper-2)-PCM (Sol.)-JEE(Advanced)/19
56. B
SECTION – C
57. 2
Sol. 1 x
3n
3nC0 3nC1x 3nC2 x 2 ....... 3nC3n x 3n …………(i)
Put x 1, , 2
23n 3nC0 3nC1 3nC2 ....... 3nC3n ………..(ii)
1
3n
3nC0 3nC1 3nC2 2 ....... 3nC3n3n …………….(iii)
2 3n …………..(iv)
1 3nC0 3nC12 3nC24 ....... 3nC3n 6n
Equation (ii) gives Sn 23n 8n
(ii) + (ii) + (iv) we get
3n 3n
8n 1
1 2 3 3n
C0 3nC3 ........... 3nC3n
2 3n 3n
Sn 3 Tn
n
Sn 1 2 3Tn
n
Sn 3Tn 2 1
58. 2
Sol. circle ‘C’ is x2 + y2 + y 16 = 0, it intersects the circle x2 + y2 6x 10y + 9 = 0,
7
orthogonally then .
5
Now |r1r2|< C1C2 < r1 + r2.
59. 2
Sol. LHS 2
7
and RHS 2, x and .
8 8
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AIITS-OT (Paper-2)-PCM (Sol.)-JEE(Advanced)/19 16
60. 5
Sol. Suppose k 2 log2 a 3 log3 b log6 a b , then we have
1 1 ab 6k
a 2k 2 , b 3k 3 , a b 6k , and therefore, k 2 k 3 22 33 .
a b ab 2 3
61. 2
Sol. Let a ib and a ib
from 2 3 we here b 3
3
Since is real
2 2
3
We conclude that 3 is real, since a ib a a2 3b 2 ib 3a2 b 2
We have 3a 2 b2 0 a 1
Hence a 2 b 2 2
62. 2
Sol. Coordinates of A are (1,3), (using parametric equation of straight line)
Image of A(1,3) about x + y = 2 always lies on side BC (–1,1) h2 + k2 = 2
63. 1
Sol. Let A be , 0 and B be , 0 where and are roots of x 2 bx c 0
Slope (PA). slope (PB) = –1
f x0 f x0
1
x0 x0
f 2 x 0 x0 x0
f 2 x 0 f x 0 f x0 x0 x0
f x 0 0 or 1
f x0 1 f x 0
0
64. 8
6 3 2
Sol. Given n6 n2
Ck n3
C2 3n2 n2
Ck n3
C2
Since a3 b3 c 3 3abc and a, b, c are positive a b c
2
n2 n2
Ck n 3C2
2
Solving n2 n3C2 we get n 6 and solving n2 n 2
Ck we get k 2
n k 8
65. 5
Sol. Notice that we must have a 1, z 6 . Now, we can just list trying values for b, c
(1, 2, 3, 4, 5, 6), (1, 2, 4, 3, 5, 6), (1, 2, 5, 3, 4, 6), (1, 3, 4, 2, 5, 6), (1, 3, 5, 2, 4, 6).
Thus, our answer is 5
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17 AIITS-OT (Paper-2)-PCM (Sol.)-JEE(Advanced)/19
66. 8
Sol.
Since cos sin1 x 1 x 2 and sin cos1 y 1 y 2 , we can use the expressions for
the first equation.
5
1 x2 1 y2
2
1 x 1 y 49
2 2
5
1 x 1 y 2
2 2
1 x2 1 y2 4
2 5
2 x2 y2 5
3 4
If we use the positive square root, we get:
2 5
2 x2 y2 2
3 4
4 5
x2 y2 2
3 4
25
x2 y2
12
If we use the negative square root, we get:
2 5
2 x2 y2 2
3 4
4 5
x2 y2 2
3 4
7
x2 y2
12
25
Since the second value for x 2 y 2 is negative, x 2 y 2
12
a2 25
2
, so a,b 5, 3
b 3 12
SECTION – D
67. 00324.75
Sol. f(x0) = x03 = 1
x0 = 1
x+y=0
Also, x0 + y0 = 0 y0 = 1
x4 (x0, y0)
Now, y f(x) c
4
x4
Also, y 0 0 c
4
1 3
1 c c
4 4
x4 3
f(x)
4
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AIITS-OT (Paper-2)-PCM (Sol.)-JEE(Advanced)/19 18
68. 00037.33
Sol. The two lines are parallel and 6 units apart.
The point is 4 units from the first line. B
Instead of the given lines consider the lines y 0, y 6 and the
point 0,2 q
A
x0 y2 0, 2
Equation of AB: r
cos sin
x0 y2 C
Equation of AC: r
cos 60 sin 60
r cos ,2 r sin lies on y 6
r sin 4
r cos 60 ,2 r sin 60 lies on the line y 0
r sin 60 2
sin 60 1
sin 2
3 1 1 2
cot cot
2 2 2 3
3 2
sin ,cos
7 7
4 4 7 112
r r2 37.33
sin 3 3
69. 00400.00
Sol. sin t and cos t are roots of 50x 2 5mx 4m 41 0
Since sin2 t cos2 t 1
2
5m 4m 41
2 1
50 50
m2 16m 64 0
m8
25m2
400
4
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