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0.

145 Porcentaje de error Experimental vs Teorico


T [°C] Presion Experimental [Psi] Presion teorica [Psi]
70.9 1.42 4.717
78.7 2.84 6.543
87.2 5.68 9.177
92.4 8.52 11.181
97.8 10 13.633
102.7 12 16.230
110.6 14 21.239
115.1 16 24.617
117.8 20 26.926
121.1 22 29.878
124.3 24 32.991
127.3 26 36.211
129.5 28 38.639
131.5 30 41.058
133.2 32 43.175
134.7 34 45.043
136.5 36 47.518
138.3 38 50.040
139 40 51.021
140 42 60.274
Porcentaje de error promedio

T [°C] vs P vapor Experimental [Psi]


45

40 f(x) = 0.0001418562x^3 - 0.0377634368x^2 + 3.6442535724x - 118.3017260549


R² = 0.9970880341
35
P vap experimental [Psi]

30

25

20

15

10

0
70 74 78 82 86 90 94 98 102 106 110 114 118 122 126 130

T [°C]
Antoine
% Error T [°C] T [K]
69.898 70.9 344.05
56.594 78.7 351.85
38.103 87.2 360.35
23.796 92.4 365.55
26.646 97.8 370.95
26.063 102.7 375.85
34.084 110.6 383.75
35.003 115.1 388.25
25.721 117.8 390.95
26.367 121.1 394.25
27.252 124.3 397.45
28.199 127.3 400.45
27.534 129.5 402.65
26.934 131.5 404.65
25.884 133.2 406.35
24.517 134.7 407.85
24.240 136.5 409.65
24.061 138.3 411.45
21.601 139 412.15
30.318 140 413.15
31.141
Intervalo de temperaturas [°C] 70,9 - 140
P bar
T °C
Constantes de antoine (experimentales)
l [Psi] a 2.93151
b 457.199
c 45.1189

3.5
3
P vapor [bar]

2.5
2
1.5
1
114 118 122 126 130 134 138 142 0.5
0
325 337 34
0.5
0
325 337 34
Antoine
Presion Experimental [Psi] Presion Experimental [Bar] T [°C]
1.42 0.0979055494 70.9
2.84 0.1958110988 78.7
5.68 0.3916221976 87.2
8.52 0.5874332964 92.4
10 0.6894757 97.8
12 0.82737084 102.7
14 0.96526598 110.6
16 1.10316112 115.1
20 1.3789514 117.8
22 1.51684654 121.1
24 1.65474168 124.3
26 1.79263682 127.3
28 1.93053196 129.5
30 2.0684271 131.5
32 2.20632224 133.2
34 2.34421738 134.7
36 2.48211252 136.5
38 2.62000766 138.3
40 2.7579028 139
42 2.89579794 140

Constantes de antoine (teoricas) %Error


a 5.11564 42.6951466
b 1687.537 72.90732
c 230.17 80.3975757

Antoine -- > T [K] vs P vapor [bar]

f(x) = 0.0400139544x - 14.0633092552


R² = 0.9332218594

337 349 361 373 385 397 409

T [K]
337 349 361 373 385 397 409

T [K]

Proceso dinamico
% Error datos teoricos vs experimentales 31.14
% Error datos constantes de antoine 65.33
% Error entalpia de vaporizacion 33.09
Clausius - Clapeyron
Presion Experimental [Psi] 1/T Ln P [Psia]
1.42 0.0029 0.3507
2.84 0.0028 1.0438
5.68 0.0028 1.7370
8.52 0.0027 2.1424
10 0.0027 2.3026
12 0.0027 2.4849
14 0.0026 2.6391
16 0.0026 2.7726
20 0.0026 2.9957
22 0.0025 3.0910
24 0.0025 3.1781
26 0.0025 3.2581
28 0.0025 3.3322
30 0.0025 3.4012
32 0.0025 3.4657
34 0.0025 3.5264
36 0.0024 3.5835
38 0.0024 3.6376
40 0.0024 3.6889
42 0.0024 3.7377

Calor latente de vaporizacion (experimental) Calor latente de vaporizacion (teorico)


Pendiente -6512.2 Entalpia de vaporizacion [Kj/Kg]
R [Kj/Kmol*K] 8.314
Entalpia de vaporizacion [Kj/kg] 3007.912822

1/ T [K] vs Ln P vap
4.0000

3.5000 f(x) = - 6152.2356515507x + 18.6576171282


R² = 0.972588833
3.0000
Ln P vap [Psi]

2.5000

2.0000

1.5000

1.0000
7 409 421 0.5000

0.0000
0.0024 0.0025 0.0025 0.0025 0.0026 0.0026 0.0027 0.0027 0.0027 0.0028 0.

1/ T [K]
Ln
1.0000
7 409 421 0.5000

0.0000
0.0024 0.0025 0.0025 0.0025 0.0026 0.0026 0.0027 0.0027 0.0027 0.0028 0.

1/ T [K]
izacion (teorico) % Error
2260 33.0934877

1/ T [K] vs Ln P vap

.6576171282

0.0026 0.0027 0.0027 0.0027 0.0028 0.0028 0.0029 0.0029 0.0029 0.0030

1/ T [K]
0.0026 0.0027 0.0027 0.0027 0.0028 0.0028 0.0029 0.0029 0.0029 0.0030

1/ T [K]
0.145 Porcentaje de error Experimental vs Teorico
T [°C] Presion [Psi] Presion teorica [Psi]
70 1.42 4.524
80 2.84 6.875
90 7.1 10.177
100 11 14.706
110 15 20.790
120 21 28.807
130 29 39.205
140 42 52.422
Porcentaje de error promedio

T [K] vs P vapor Experimental [Psi]


45
40 f(x) = 0.0001110101x^3 - 0.0277372294x^2 + 2.5987604618x - 83.2012121212
P vap experimental [Psi]

35 R² = 0.9978049886
30
25
20
15
10
5
0
68 72 76 80 84 88 92 96 100 104 108 112 116 120 124 128 132 136 140

T [K]
Antoine
% Error T [°C] T [K]
68.614 70 343.15
58.693 80 353.15
30.232 90 363.15
25.200 100 373.15
27.850 110 383.15
27.101 120 393.15
26.030 130 403.15
19.881 140 413.15
37.164
Intervalo de temperaturas [°C] 70 - 140
P bar
T °C
Constantes de antoine (experimentales)
a 1.87966
b 194.926
c 42.1354

Antoine -- > T [K] vs P vapor [bar


3.5
124 128 132 136 140
3
P vapor [bar]

2.5 f(x) = 0.0004985566x^2 - 0.3392553855x + 57.8502558916


R² = 0.9924255614
2

1.5

0.5

0
340 344 348 352 356 360 364 368 372 376 380 384 388 392

T [K]

Proceso cuasiestatico
% Error datos teoricos vs experimentales 35.45
% Error datos constantes de antoine 77.80
% Error entalpia de vaporizacion 35.45
Antoine Clau
Presion Experimental [Psi] Presion Experimental [Bar] T [°C]
1.42 0.0979055494 70
2.84 0.1958110988 80
7.1 0.489527747 90
11 0.75842327 100
15 1.03421355 110
21 1.44789897 120
29 1.99947953 130
42 2.89579794 140

Constantes de antoine (teoricas) %Error


a 5.11564 63.2566013
b 1687.537 88.4490829
c 230.17 81.6937915

vs P vapor [bar]

916

380 384 388 392 396 400 404 408 412 416 420

T [K]
Clausius - Clapeyron
Presion Experimental [Psi] 1/T Ln P [Psia]
1.42 0.0029 0.3507
2.84 0.0028 1.0438
7.1 0.0028 1.9601
11 0.0027 2.3979
15 0.0026 2.7081
21 0.0025 3.0445
29 0.0025 3.3673
42 0.0024 3.7377

Calor latente de vaporizacion (experimental) Calor latente de vaporizacion (teorico)


Pendiente -6627.5 Entalpia de vaporizacion [Kj/Kg]
R [Kj/Kmol*K] 8.314
Entalpia de vaporizacion [Kj/kg] 3061.168611

1/ T [K] vs Ln P vap
4.0000
f(x) = - 6627.5196979812x + 19.9171795667
3.5000 R² = 0.9725367205

3.0000
Ln P vap [Psi]

2.5000

2.0000

1.5000

1.0000

0.5000

0.0000
0.0024 0.0025 0.0025 0.0025 0.0026 0.0026 0.0027 0.0027 0.0027 0.0028 0.0028 0.0029 0.0029 0.0029 0.0030

1/ T [K]
izacion (teorico) % Error
2260 35.4499385

0.0029 0.0029 0.0029 0.0030

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