Series ONS SET-2

·¤æðÇU Ù´.
Code No. 56/2/N
ÚUæðÜ Ù´. ÂÚUèÿææÍèü ·¤æðÇU ·¤æ𠩞æÚU-ÂéçSÌ·¤æ ·ð¤ ×é¹-ÂëcÆU
Roll No. ÂÚU ¥ßàØ çܹð´Ð
Candidates must write the Code on the
title page of the answer-book.

· ·ë¤ÂØæ Áæ¡¿ ·¤ÚU Üð´ ç·¤ §â ÂýàÙ-˜æ ×ð´ ×éçÎýÌ ÂëcÆU 15 ãñ´Ð
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10.15 ÕÁð ç·¤Øæ Áæ°»æÐ 10.15 ÕÁð âð 10.30 ÕÁð Ì·¤ ÀUæ˜æ ·ð¤ßÜ ÂýàÙ-Â˜æ ·¤æð Âɸð´»ð ¥æñÚU §â
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· Please check that this question paper contains 15 printed pages.
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· Please check that this question paper contains 26 questions.
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it.
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ÚUâæØÙ çߙææÙ (âñhæç‹Ì·¤)

CHEMISTRY (Theory)

çÙÏæüçÚUÌ â×Ø Ñ 3 ƒæ‡ÅðU ¥çÏ·¤Ì× ¥´·¤ Ñ 70

Time allowed : 3 hours Maximum Marks : 70

56/2/N 1 P.T.O.
âæ×æ‹Ø çÙÎðüàæ Ñ

(i) âÖè ÂýàÙ ¥çÙßæØü ãñ´Ð

(ii) Âýà٠ⴁØæ 1 âð 5 Ì·¤ ¥çÌ Üƒæé-©žæÚUèØ ÂýàÙ ãñ´ ¥æñÚU ÂýˆØð·¤ ÂýàÙ ·ð¤ çÜ° 1 ¥´·¤ ãñÐ

(iii) Âýà٠ⴁØæ 6 âð 10 Ì·¤ ܃æé-©žæÚUèØ ÂýàÙ ãñ´ ¥æñÚU ÂýˆØð·¤ ÂýàÙ ·ð¤ çÜ° 2 ¥´·¤ ãñ´Ð

(iv) Âýà٠ⴁØæ 11 âð 22 Ì·¤ Öè ܃æé-©žæÚUèØ ÂýàÙ ãñ´ ¥æñÚU ÂýˆØð·¤ ÂýàÙ ·ð¤ çÜ° 3 ¥´·¤ ãñ´Ð

(v) Âýà٠ⴁØæ 23 ×êËØæÏæçÚUÌ ÂýàÙ ãñ ¥æñÚU §â·ð¤ çÜ° 4 ¥´·¤ ãñ´Ð

(vi) Âýà٠ⴁØæ 24 âð 26 Ì·¤ Îèƒæü-©žæÚUèØ ÂýàÙ ãñ´ ¥æñÚU ÂýˆØð·¤ ÂýàÙ ·ð¤ çÜ° 5 ¥´·¤ ãñ´Ð

(vii) ØçÎ ¥æßàØ·¤Ìæ ãæð, Ìæð Üæò» ÅðUÕÜæð´ ·¤æ ÂýØæð» ·¤Úð´UÐ ·ñ¤Ë·é¤ÜðÅUÚUæ𴠷𤠩ÂØæð» ·¤è ¥Ùé×çÌ Ùãè´ ãñÐ

General Instructions :

(i) All questions are compulsory.

(ii) Questions number 1 to 5 are very short answer questions and carry 1 mark each.

(iii) Questions number 6 to 10 are short answer questions and carry 2 marks each.

(iv) Questions number 11 to 22 are also short answer questions and carry 3 marks each.

(v) Question number 23 is a value based question and carry 4 marks.

(vi) Questions number 24 to 26 are long answer questions and carry 5 marks each.

(vii) Use log tables, if necessary. Use of calculators is not allowed.

56/2/N 2
1. ·¤æðÜæ§ÇUè âæòÜ ·¤è çSÍÚUÌæ ·ð¤ çÜØð ·¤æÚU‡æ çÜç¹°Ð

Write the reason for the stability of colloidal sols.

2. »×ü ·¤ÚUÙð ÂÚU ZnO ÂèÜð Ú´U» ·¤è ãæð ÁæÌè ãñÐ €Øæð´?

ZnO turns yellow on heating. Why ?

3. Pb(NO3)2 ·¤æð »×ü ·¤ÚUÙð ÂÚU °·¤ ÖêÚðU Ú´U» ·¤è »ñâ çÙ·¤ÜÌè ãñ çÁâ·¤æ Æ´UÇðU ãæðÙð ÂÚU
çmÜ·¤è·¤ÚU‡æ ãæð ÁæÌæ ãñÐ »ñâ ·¤è Âã¿æÙ ·¤èçÁ°Ð

On heating Pb(NO3)2 a brown gas is evolved which undergoes dimerization

on cooling. Identify the gas.

4. çِ٠Øæñç»·¤ ·¤æ ¥æ§ü.Øê.Âè.°.âè. Ùæ× çÜç¹°Ð

Write the IUPAC name of the given compound :

56/2/N 3 P.T.O.
5. çِÙçÜç¹Ì Îæð ¥çÖç·ý¤Øæ¥æð´ ×ð´ âð ·¤æñÙ SN2 ãñ ¥æñÚU €Øæð´?

(i)

(ii)

Which of the following two reactions is SN2 and why ?

(i)

(ii)

6. çِ٠¥çÖç·ý¤Øæ¥æð´ âð â´Õç‹ÏÌ ÚUæâæØçÙ·¤ â×è·¤ÚU‡ææð´ ·¤æð çÜç¹° Ñ

(i) ·¤æðËÕð ¥çÖç·ý¤Øæ
(ii) °ðçÙâæðÜ ·¤è Èý¤æ§ÇðUÜ-·ýñ¤ÅU °ðâèçÅUÜè·¤ÚU‡æ ¥çÖç·ý¤Øæ
¥Íßæ
¥æ ·ñ¤âð M¤Âæ´ÌÚU‡æ ·¤ÚUÌð ãñ´ Ñ
(i) ȤèÙæòÜ ·¤æ ÅUæ©ÜèÙ ×ð´
(ii) Ȥæò×ðüçËÇUãæ§ÇU ·¤æ °ÍñÙæòÜ ×ð´

56/2/N 4
 Write the chemical equations involved in the following reactions :
(i) Kolbe’s reaction
(ii) Friedal - Crafts acetylation of anisole
OR
How do you convert :
(i) Phenol to toluene
(ii) Formaldehyde to Ethanol

Pt → N (g) 1 3H (g)
7. °·¤ ¥çÖç·ý¤Øæ 2NH3 (g)  2 2

ÎÚU 5 k
(i) §â ¥çÖç·ý¤Øæ ·¤è ·¤æðçÅU ¥æñÚU ¥‡æéÌæ çÜç¹°Ð
(ii) k ·¤è ØêçÙÅU çÜç¹°Ð
Pt → N (g) 1 3H (g)
For a reaction : 2NH3 (g)  2 2
Rate 5 k
(i) Write the order and molecularity of this reaction.
(ii) Write the unit of k.

8. (i) ©â ¥‡æéâ´Ø »é‡æÏ×ü ·¤æð çÜç¹° Áæð »éL¤ ¥‡æé¥æ𴠷𤠥æ‡æçß·¤ ÎýÃØ×æÙ ·¤æð ™ææÌ ·¤ÚUÙð
×ð´ ÂýØæð» ×ð´ ¥æÌæ ãñÐ
(ii) ¥ÙæÎàæü çßÜØÙ ×ð´ çß¿ÜÙ ·¤æ ·¤æñÙ âæ Âý·¤æÚU ‹ØêÙÌ× €ßÍÙ °çÁØæðÅþUæ ·ð¤ çÙ×æü‡æ ·¤æð
ÎàææüÌæ ãñ?
(i) Write the colligative property which is used to find the molecular mass
of macromolecules.
(ii) In non-ideal solution, what type of deviation shows the formation of
minimum boiling azeotropes ?

9. çِ٠·¤è â´ÚU¿Ùæ°¡ çÜç¹° Ñ

(i) (HPO3)3 (ii) XeF4
Write the structures of the following :
(i) (HPO3)3 (ii) XeF4

56/2/N 5 P.T.O.
10. ÁÕ ©Ââãâ´ØæðÁ·¤ Øæñç»·¤ NiCl2.6H2O ·¤æð AgNO3 ·ð¤ âæÍ ç×ÜæØæ ÁæÌæ ãñ ÌÕ Øæñç»·¤
·ð¤ ÂýçÌ ×æðÜ ÂÚU AgCl ·ð¤ Îæð ×æðÜ ¥ßÿæðçÂÌ ãæðÌð ãñ´Ð çÜç¹°
(i) ·¤æòŒÜð€â ·¤æ â´ÚU¿Ùæ âê˜æ
(ii) ·¤æòŒÜð€â ·¤æ ¥æ§ü.Øê.Âè.°.âè. Ùæ×
When a coordination compound NiCl2.6H2O is mixed with AgNO3, 2 moles of
AgCl are precipitated per mole of the compound. Write
(i) Structural formula of the complex
(ii) IUPAC name of the complex

11. çِ٠·ð¤ çÜØð ·¤æÚU‡æ ÎèçÁ° Ñ

(a) ȤèÙæòÜ ·¤æ ÂýæðÅUæðÙè·¤ÚU‡æ ·¤çÆUÙ ãñ ÁÕç·¤ °ÍñÙæòÜ ·¤æ ÂýæðÅUæðÙè·¤ÚU‡æ ¥æâæÙè âð ç·¤Øæ
ÁæÌæ ãñÐ
(b) ÇUæ§ü×ðçÍÜ §üÍÚU ·¤è ¥Âðÿææ °ÍñÙæòÜ ·¤æ €ßÍÙæ´·¤ ©‘¿ÌÚU ãæðÌæ ãñÐ
(c) HI ·ð¤ âæÍ ¥çÖç·ý¤Øæ ·¤ÚUÙð ÂÚU °ðçÙâæðÜ È¤èÙæòÜ ¥æñÚU CH32I ×éØ ©ˆÂæÎ ÎðÌæ ãñ Ù
ç·¤ ¥æØÇUæðÕð‹ÁèÙ ¥æñÚU CH3OH.
Give reasons for the following :
(a) Protonation of Phenols is difficult whereas ethanol easily undergoes
protonation.
(b) Boiling point of ethanol is higher than that of dimethyl ether.
(c) Anisole on reaction with HI gives phenol and CH32I as main products
and not iodobenzene and CH3OH.

12. (a) ·¤æòŒÜð€â [Fe(CN)6]42 ·ð¤ çÜØð â´·¤ÚU‡æ, ¿éÕ·¤èØ ÃØßãæÚU ¥æñÚU çSÂÙ Âý·¤æÚU ·¤æð
çÜç¹° (Â.â´. Fe526)
(b) ·¤æòŒÜð€â [Co(en)2Cl2]1 ·ð¤ °·¤ ’Øæç×ÌèØ °·¤Ü·¤ ·¤æð çÜç¹° Áæð Âý·¤æàæ·¤èØ
âç·ý¤Ø ãæðÌæ ãñÐ
(a) For the complex [Fe(CN)6]42, write the hybridization, magnetic character
and spin type of the complex. (At. number : Fe526)
(b) Draw one of the geometrical isomers of the complex [Co(en)2Cl2]1 which
is optically active.

56/2/N 6
13. H2O2 ·ð¤ ÂýÍ× ·¤æðçÅU ç߃æÅUÙ ·ð¤ ÎÚU çSÍÚUæ´·¤ ·ð¤ çÜØð çِ٠â×è·¤ÚU‡æ çÎØæ ÁæÌæ ãñ Ñ

1.0 3 104 K
log k 5 14.2 2
T

§â ¥çÖç·ý¤Øæ ·ð¤ çÜØð Ea ¥æñÚU ÎÚU çSÍÚUæ´·¤ k ·¤æð ÂçÚU·¤çÜÌ ·¤èçÁ° ¥»ÚU §â·¤è ¥Ïü-¥æØé
200 ç×ÙÅU ãæðÐ (çÎØæ »Øæ Ñ R58.314 JK21 mol21)

The rate constant for the first order decomposition of H2O2 is given by the
following equation :

1.0 3 104 K
log k 5 14.2 2
T

Calculate Ea for this reaction and rate constant k if its half-life period be
200 minutes. (Given : R58.314 JK21 mol21)

14. çِ٠ÂÎæð´ ·¤æð ÂçÚUÖæçáÌ Ñ

(i) O/W §×ËàæÙ

(ii) ÁèÅUæ ÂæðÅð´UçàæØÜ

(iii) ÕãéÜè¥æ‡æçß·¤ ·¤æðÜæò§ÇU
Define the following terms :
(i) O/W Emulsion
(ii) Zeta potential
(iii) Multimolecular colloids

15. °·¤ Ìˆß 400 pm ·¤æðçàæ·¤æ ·ð¤ ç·¤ÙæÚðU ·ð¤ âæÍ f.c.c. ×ð´ ç·ý¤SÅUçÜÌ ãæðÌæ ãñÐ Ìˆß ·¤æ ƒæوß
7 g cm23 ãñÐ Ìˆß ·ð¤ 280 g ×ð´ ç·¤ÌÙð ÂÚU×æ‡æé ßÌü×æÙ ãñ´?

An element crystallizes in a f.c.c. lattice with cell edge of 400 pm. The density
of the element is 7 g cm23. How many atoms are present in 280 g of the
element ?

56/2/N 7 P.T.O.
16. (i) D-‚Üê·¤æðâ ·¤è °·¤ ¥çÖç·ý¤Øæ çÜç¹° çÁâ·¤è ÃØæØæ §â·¤è ¹éÜè oë´¹Üæ â´ÚU¿Ùæ ·ð¤
mæÚUæ Ùãè´ ·¤è Áæ â·¤Ìè ãñÐ
(ii) ‹Øêç€Ü·¤ ¥Ü ×ð´ ç·¤â Âý·¤æÚU ·¤è çÜ´·ð¤Á ãæðÌè ãñ?
(iii) ÁÜ-ƒæéÜÙàæèÜ ¥æñÚU Èñ¤ÅU-ƒæéÜÙàæèÜ ÂýˆØð·¤ ·ð¤ °·¤ °·¤ ©ÎæãÚU‡æ ÎèçÁ°Ð
(i) Write one reaction of D-Glucose which cannot be explained by its open
chain structure.
(ii) What type of linkage is present in Nucleic acids ?
(iii) Give one example each for water-soluble vitamins and fat-soluble
vitamins ?

17. (i) °ÍèÙ ·ð¤ ÕãéÜ·¤è·¤ÚU‡æ ×ð´ Õð‹ÁæðØÜ ÂÚU¥æò€âæ§ÇU ·¤è €Øæ Öêç×·¤æ ãæðÌè ãñ?
(ii) çِ٠ÕãéÜ·¤ ×ð´ °·¤Ü·¤ ·¤è Âã¿æÙ ·¤èçÁ°Ð

(iii) ©Ù·ð¤ ¥´Ì¥æü‡æçß·¤ ÕÜ ·ð¤ ¥æÏæÚU ÂÚU ÕɸÌð ·ý¤× ×ð´ çِ٠·¤æð ÃØßçSÍÌ ·¤èçÁ°Ð
ÙæØÜæòÙ-6, 6, ÂæòÜèÍèÙ, ÕêÙæ-S
¥Íßæ
°ÍèÙ ·ð¤ Èý¤è ÚñUçÇU·¤Ü ÕãéÜ·¤è·¤ÚU‡æ ·¤è ç·ý¤ØæçßçÏ ·¤æð çÜç¹°Ð
(i) What is the role of benzoyl peroxide in the polymerization of ethene ?
(ii) Identify the monomers in the following polymer :

(iii) Arrange the following polymers in the increasing order of their

intermolecular forces :
Nylon-6, 6 Polythene, Buna-S
OR
Write the mechanism of free radical polymerization of ethene.

56/2/N 8
18. ÁÕ 50 g ÁÜ ×ð´ Na2SO4 (M5142 g mol21) ·¤æ 2 g ƒæéÜæØæ ÁæÌæ ãñ ÌÕ ÂýæŒÌ çßÜØÙ
·ð¤ €ßÍÙæ´·¤ ·¤æ ÂçÚU·¤ÜÙ ·¤èçÁ°Ð Øã ×æÙ·¤ÚU ¿çÜØð ç·¤ Na2SO4 ·¤æ ÂêÚUèU ÌÚUã ¥æØÙè·¤ÚU‡æ
ãæð ÁæÌæ ãñÐ
(ÁÜ ·ð¤ çÜØð Kb 50.52 K kg mol21)
Calculate the boiling point of solution when 2 g of Na2SO4 (M5142 g mol21)
was dissolved in 50 g of water, assuming Na 2SO 4 undergoes complete
ionization.
(Kb for water50.52 K kg mol21)

19. çِ٠¥çÖç·ý¤Øæ¥æð´ ×ð´ ÂýˆØð·¤ ·ð¤ ×éØ ãñ ×æðÙæðãñÜæ𠩈ÂæÎ ·¤æð çÜç¹° Ñ

(i)

(ii)

(iii)

Write the major monohalo product(s) in each of the following reactions :

(i)

(ii)

(iii)

56/2/N 9 P.T.O.
20. çِ٠·ð¤ ·¤æÚU‡æ çÙÏæüçÚUÌ ·¤èçÁ° Ñ
(i) H3PO4 ·¤è ¥Âðÿææ H3PO2 ÂýÕÜÌÚU ¥Â¿æØ·¤ ãñÐ
(ii) ¥æò€âèÁÙ ·¤è ¥Âðÿææ âËȤÚU ×ð´ oë´¹ÜÙ ·¤è Âýßëçžæ ¥çÏ·¤ ãñÐ
(iii) ¥Â¿æØ·¤è ÃØßãæÚU HF âð HI ·¤è ¥æðÚU ÕɸÌæ ãñÐ
Assign reason for the following :

(i) H3PO2 is a stronger reducing agent than H3PO4.

(ii) Sulphur shows more tendency for catenation than Oxygen.
(iii) Reducing character increases from HF to HI.

21. (i) °·¤ ÂçÚUc·¤ÚU‡æ çßçÏ ·¤æ Ùæ× çÜç¹° Áæð ¥çÏàææðá‡æ ·ð¤ çâhæ‹Ì ÂÚU ¥æÏæçÚUÌ ãæðÌæ ãñÐ
(ii) Ûææ» ŒÜßÙ çßçÏ ×ð´ ¥ßÙ×·¤ ·¤è €Øæ Öêç×·¤æ ãæðÌè ãñ?
(iii) ¥æò€âæ§ÇU ¥ØS·¤ âð ¥æØÚUÙ ·ð¤ çÙc·¤áü‡æ ×ð´ ¿êÙð ·ð¤ ˆÍÚU ·¤è €Øæ Öêç×·¤æ ãæðÌè ãñ?
(i) Name the method of refining which is based on the principle of adsorption.

(ii) What is the role of depressant in froth floatation process ?

(iii) What is the role of limestone in the extraction of iron from its oxides ?

22. çِ٠¥çÖç·ý¤Øæ¥æð´ ×ð´ A, B ¥æñÚU C ·¤è â´ÚU¿Ùæ°¡ çÜç¹° Ñ

D
(i) C6H5 2 COO2NH1
4 
Br2/KOH
→ A  →B

NaNO /Cu
Sn/HCl CHCl 1alc. KOH
(ii) C6 H5N1 2
2 BF4 
2 → A  → B →
3 C
D

Write the structures of A, B and C in the following reactions :

D
(i) C6H5 2 COO2NH1
4 
Br2/KOH
→ A 
CH3COCl/pyridine
→ B  →C

NaNO /Cu
Sn/HCl CHCl 1alc. KOH
(ii) C6 H5N1 2
2 BF4 
2 → A  → B →
3 C
D

56/2/N 10
23. ¥ˆØ‹Ì ÃØSÌÌæ ·ð¤ ·¤æÚU‡æ Ÿæè×æÙ÷ ¥ßSÍè Ùð ¥ÂÙæ ÁèßÙ ÌÙæßÂê‡æü ÕÙæ ÚU¹æ ÍæÐ ¥ßÙ×Ù
·¤æð ÎêÚU ·¤ÚUÙð ·ð¤ çÜØ𠩋ãæð´ðÙð çÕÙæ ÇUæò€ÅUÚU ·¤è âÜæã ·ð¤ Ùè´Î ·¤è »æðçÜØæ¡ ÜðÙæ àæéM¤ ·¤ÚU çÎØæÐ
Ÿæè×æÙ÷ ¥ßSÍè ·ð¤ °·¤ ÙÁÎè·¤è ç×˜æ Ÿæè×æÙ÷ ÚUæòØ Ù𠩋ã´ð Ùè´Î ·¤è »æðÜè Ù ÜðÙð ·¤è âÜæã
Îè âæÍ ãè ©‹ã´ð Øæð»æâÙ ·¤ÚUÙð ·¤æð ·¤ãæÐ ¥ßSÍè Áè ¥ÂÙð ç×˜æ ·¤è âÜæã ×æÙ·¤ÚU Øæð»æâÙ
¥æñÚU ·é¤ÀU ÃØæØæ× ·¤ÚUÙæ àæéM¤ ·¤ÚU çÎØæÐ ÍæðǸð ãè çÎÙ ×ð´ ¥ßSÍè ¥ÂÙð ·¤æð SßSÍ ×ãâêâ
·¤ÚUÙð Ü»ðÐ
©ÂÚUæð€Ì ÂñâðÁ ·¤æð Âɸ·¤ÚU çِ٠·ð¤ ©žæÚU çܹð´ Ñ
(i) Ÿæè×æÙ÷ ÚUæòØ ç·¤Ù ×êËØæð´ (·¤× âð ·¤× Îæð) ·¤æð ÂýÎçàæüÌ ç·¤Øæ?
(ii) çÕÙæ ÇUæò€ÅUÚU ·¤è âÜæã ·ð¤ Ùè´Î ·¤è »æðÜè €Øæð´ Ùãè´ ÜðÙè ¿æçãØð?
(iii) Ùè´Î·¤æÚUè »æðçÜØæ¡ €Øæ ãæðÌè ãñ´? Îæð ©ÎæãÚU‡æ ÎèçÁ°Ð
Due to hectic and busy schedule, Mr. Awasthi made his life full of tensions and
anxiety. He started taking sleeping pills to overcome the depression without
consulting the doctor. Mr. Roy, a close friend of Mr. Awasthi advised him to
stop taking sleeping pills and suggested to change his lifestyle by doing Yoga,
meditation and some physical exercise. Mr. Awasthi followed his friend’s advice
and after few days he started feeling better.
After reading the above passage, answer the following :
(i) What are the values (at least two) displayed by Mr. Roy ?
(ii) Why it is not advisable to take sleeping pills without consulting doctor ?
(iii) What are tanquilizers ? Give two examples.

24. (a) çِ٠·¤æð ·¤æÚU‡æ âçãÌ SÂcÅU ·¤èçÁ° Ñ

(i) ¥æò€âèÁÙ ·ð¤ âæÍ Mn ©‘¿Ì× ©Â¿ØÙ ¥ßSÍæ 17 ÎàææüÌæ ãñ Üðç·¤Ù Üé¥æðçÚUÙ
·ð¤ âæÍ §â·¤è ©‘¿Ì× ©Â¿ØÙ ¥ßSÍæ 14 ãè ÚUãÌè ãñÐ
(ii) çÁ·¤æðüçÙØ× ¥æñÚU ãæȤçÙØ× ·ð¤ »é‡æÏ×ü ×ð´ â×æÙÌæ ãæðÌè ãñÐ
(iii) â´·ý¤×‡æ ÏæÌé°¡ ©ˆÂýðÚU·¤ ·¤æ ·¤æ× ·¤ÚUÌè ãñ´Ð
(b) çِ٠â×è·¤ÚU‡ææð´ ·¤æð ÂêÚUæ ·¤èçÁ° Ñ
(i) D
2MnO2 14KOH1O2  →

(ii) Cr2O722 114H116I2 

→

56/2/N 11 P.T.O.
 ¥Íßæ
3d â´·ý¤×‡æ Ÿæð‡æè ·ð¤ Ìˆß Ùè¿ð çÎØð ÁæÌð ãñ´ Ñ
Sc Ti V Cr Mn Fe Co Ni Cu Zn

çِ٠·ð¤ ©žæÚU ÎèçÁ° Ñ

(i) ©â Ìˆß ·¤æ Ùæ× çÜç¹° Áæð â´·ý¤×‡æ Ìˆß Ùãè´ ×æÙæ ÁæÌæ ãñÐ ·¤æÚU‡æ ÎèçÁ°Ð
(ii) ç·¤â Ìˆß ·¤æ ©‘¿Ì× »ÜÙæ´·¤ ãñ?
(iii) ©â Ìˆß ·¤æ Ùæ× çÜç¹° Áæð 11 ©Â¿ØÙ ¥ßSÍæ ÎàææüÌæ ãñÐ
(iv) ·¤æñÙ Ìˆß 13 ©Â¿ØÙ ¥ßSÍæ ×ð´ ÂýÕÜ ©Â¿æØ·¤ ãñ ¥æñÚU €Øæð´?
(a) Account for the following :
(i) Mn shows the highest oxidation state of 17 with oxygen but with
fluorine it shows the highest oxidation state of 14.
(ii) Zirconium and Hafnium exhibit similar properties.
(iii) Transition metals act as catalysts.
(b) Complete the following equations :

(i) D
2MnO2 14KOH1O2  →

(ii) Cr2O722 114H116I2 

→

OR
The elements of 3d transition series are given as :
Sc Ti V Cr Mn Fe Co Ni Cu Zn
Answer the following :
(i) Write the element which is not regarded as a transition element. Give
reason.
(ii) Which element has the highest m.p ?
(iii) Write the element which can show an oxidation state of 11.
(iv) Which element is a strong oxidizing agent in 13 oxidation state and
why ?

56/2/N 12
25. (a) çِ٠¥çÖç·ý¤Øæ¥æð´ ×ð´ A, B, C ¥æñÚU D ·¤è â´ÚU¿Ùæ¥æð´ ·¤æð çÜç¹° Ñ

(b) çِ٠·ð¤ Õè¿ Âã¿æÙ ·¤èçÁ° Ñ

(i) C6H52CH5CH2COCH3 ¥æñÚU C6H52CH5CH2CO CH2CH3 ×ð´
(ii) CH3CH2COOH ¥æñÚU HCOOH ×ð´

(c) çِ٠·¤æð ©Ù·ð¤ ÕɸÌð €ßÍÙæ´·¤ ·ð¤ ·ý¤× ×ð´ çÜç¹° Ñ
CH3CH2OH, CH3COCH3, CH3COOH

¥Íßæ
(a) §üÅUæÇüU ¥çÖç·ý¤Øæ âð âÕç‹ÏÌ ÚUæâæØçÙ·¤ ¥çÖç·ý¤Øæ ·¤æð çÜç¹°Ð
(b) ‹Øêç€ÜØæðçȤçÜ·¤ Øæð»æˆ×·¤ ¥çÖç·ý¤Øæ ·ð¤ ÂýçÌ ©Ù·¤è ÕɸÌè âç·ý¤ØÌæ ·ð¤ ·ý¤× ×ð´ çِÙ
·¤æð ÃØßçSÍÌ ·¤èçÁ° Ñ
CH32CHO, C6H5COCH3, HCHO

(c) Cl2CH22COOH ·¤æ pKa CH3COOH ·ð¤ pKa âð ·¤× €Øæð´ ãñ?
(d) çِ٠¥çÖç·ý¤Øæ ×ð´ ©ˆÂæÎ ·¤æð çÜç¹° Ñ

2 1. (i-Bu) AlH
CH3CH 2CH5CH2CH2CN 
2.H O
→
2

(e) Øæñç»·¤ C3H6O ·ð¤ Îæð ç·ý¤Øæˆ×·¤ â×æßØßè A ¥æñÚU B ãñ´Ð NaOH ¥æñÚU I2 ·ð¤ âæÍ »×ü
·¤ÚUÙð ÂÚU â×æßØßè A ¥æØÇUæðȤæ×ü ·¤æ ÂèÜæ ¥ßÿæð ÎðÌæ ãñ ’æÕç·¤ â×æßØßè B ·¤æð§ü
¥ßÿæð Ùãè´ ÎðÌæ ãñÐ A ¥æñÚU B ·ð¤ ¥‡æéâê˜æ çÜç¹°Ð

56/2/N 13 P.T.O.
 (a) Write the structures of A, B, C and D in the following reactions :

(b) Distinguish between :

(i) C6H52CH5CH2COCH3 and C6H52CH5CH2CO CH2CH3
(ii) CH3CH2COOH and HCOOH
(c) Arrange the following in the increasing order of their boiling points :
CH3CH2OH, CH3COCH3, CH3COOH
OR
(a) Write the chemical reaction involved in Etard reaction.
(b) Arrange the following in the increasing order of their reactivity towards
nucleophilic addition reaction :
CH32CHO, C6H5COCH3, HCHO
(c) Why pKa of Cl2CH22COOH is lower than the pKa of CH3COOH ?
(d) Write the product in the following reaction.

2 1. (i-Bu) AlH
CH3CH 2CH5CH2CH2CN 
2.H O
→
2

(e) A and B are two functional isomers of compound C3H6O. On heating with
NaOH and I2, isomer A forms yellow precipitate of iodoform whereas
isomer B does not form any precipitate. Write the formulae of A and B.

26. (a) çِ٠¥çÖç·ý¤Øæ ·ð¤ çÜØð 298 K ÂÚU E8cell ·¤æ ÂçÚU·¤ÜÙ ·¤èçÁ° Ñ
2Cr(s)1 3Fe21(0.01M) ® 2Cr31(0.01M) 1 3Fe(s)
çÎØæ »Øæ ãñ : Ecell50.261 V
(b) A ¥æñÚU B ·ð¤ E8 ×æÙæð´ ·¤æ ©ÂØæð» ·¤ÚUÌð ãé° Âýæ»éç€Ì ·¤èçÁ° ç·¤ §Ù×ð´ ·¤æñÙ ¥æØÚUÙ ·ð¤
âÌã ÜðÂÙ ·ð¤ çÜØð ÕðãÌÚU ãæð»æ çÁââð ©âÂÚU Á´» Ù Ü»ð ¥æñÚU €Øæð´?
[E8(Fe21/Fe)520.44 V]
¥æñÚU çÎØæ »Øæ E8(A21/A)522.37V : E8(B21/B)520.14 V

56/2/N 14
 ¥Íßæ
(a) CH3COOH ·ð¤ °·¤ 0.001 mol L21 çßÜØÙ ·¤è ¿æÜ·¤Ìæ 3.90531025 S cm21
ãñÐ §â·¤è ×æðÜÚU ¿æÜ·¤Ìæ ¥æñÚU çßØæðÁÙ (a) ·¤è çÇU»ýè ·¤æ ÂçÚU·¤ÜÙ ·¤èçÁ°Ð
çÎØæ »Øæ l8(H1)5349.6 S cm2 mol21 ¥æñÚU l8 (CH3COO2)540.9 S cm2 mol21.
(b) çßléÌ ÚUæâæØçÙ·¤ âðÜ ·¤æð ÂçÚUÖæçáÌ ·¤èçÁ°Ð €Øæ ãæðÌæ ãñ ÁÕ çßléÌ÷ ÚUæâæØçÙ·¤ âðÜ
·ð¤ E8cell âð Ü»æØæ »Øæ Õæs çßÖß ’ØæÎæ ãæð ÁæÌæ ãñÐ
(a) Calculate E8cell for the following reaction at 298 K :
2Cr(s)1 3Fe21(0.01M) ® 2Cr31(0.01M) 1 3Fe(s)
Given : Ecell50.261 V
(b) Using the E8 values of A and B, predict which one is better for coating the
surface of iron [E8(Fe21/Fe)520.44 V] to prevent corrosion and why ?
Given : E8(A21/A)522.37 V : E8(B21/B)520.14 V
OR
(a) The conductivity of 0.001 mol L 21 solution of CH 3 COOH is
3.90531025 S cm21. Calculate its molar conductivity and degree of
dissociation(a).
Given l8(H1)5349.6 S cm2 mol21 and l8 (CH3COO2)540.9 S cm2 mol21.
(b) Define electrochemical cell. What happens if external potential applied
becomes greater than E8cell of electrochemical cell ?

56/2/N 15 P.T.O.