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2-Butyne-1,4-diol
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Label Elements
Signal Word
Danger
Hazard Statements
Toxic if swallowed
Toxic in contact with skin
Precautionary Statements
Prevention
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Wear protective gloves/protective clothing/eye protection/face protection
Use only outdoors or in a well-ventilated area
Do not breathe dust/fume/gas/mist/vapors/spray
Contaminated work clothing should not be allowed out of the workplace
Response
Immediately call a POISON CENTER or doctor/physician
Inhalation
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Skin
Wash contaminated clothing before reuse IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse
skin with water/shower If skin irritation or rash occurs: Get medical advice/attention
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing
Ingestion
Rinse mouth Do NOT induce vomiting
Storage
Store locked up
Store in a well-ventilated place.
Keep container tightly closed
Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
None identified
General Advice Immediate medical attention is required. Show this safety data sheet to the doctor in
attendance.
Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
MSDS –2-Butyne-1,4-diol Page 2 of 9
Indenta Chemicals (India) Pvt. Ltd.
Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Immediate medical
attention is required.
Inhalation Move to fresh air. Do not use mouth-to-mouth method if victim ingested or inhaled the
substance; give artificial respiration with the aid of a pocket mask equipped with a one-
way valve or other proper respiratory medical device. Immediate medical attention is
required. If not breathing, give artificial respiration.
Ingestion Do not induce vomiting. Call a physician or Poison Control Center immediately.
Most important symptoms/effects
Causes burns by all exposure routes. May cause allergic skin reaction. Product is a
corrosive material. Use of gastric lavage or emesis is contraindicated. Possible
perforation of stomach or esophagus should be investigated: Ingestion causes severe
swelling, severe damage to the delicate tissue and danger of perforation: Symptoms of
allergic reaction may include rash, itching, swelling, trouble breathing, tingling of the
hands and feet, dizziness, lightheadedness, chest pain, muscle pain or flushing
Suitable Extinguishing Media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Unsuitable Extinguishing Media No information available
NFPA
Personal Precautions Use personal protective equipment. Evacuate personnel to safe areas. Ensure adequate
ventilation. Keep people away from and upwind of spill/leak. Avoid dust formation.
Environmental Precautions Should not be released into the environment. Do not flush into surface water or sanitary
sewer system. See Section 12 for additional ecological information.
Methods for Containment and Sweep up or vacuum up spillage and collect in suitable container for disposal. Avoid dust
Clean Up formation.
Handling Do not get in eyes, on skin, or on clothing. Use only under a chemical fume hood. Wear
personal protective equipment. Do not ingest. Do not breathe vapors/dust. Avoid dust
formation.
Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Corrosives area.
Exposure Guidelines
Engineering Measures Ensure adequate ventilation, especially in confined areas. Ensure that eyewash
stations and safety showers are close to the workstation location.
Test Specifications
Physical state Solid
Appearance Beige
pH 6.4 100 g/L aq.sol
Melting Point/Range 54 - 58 °C / 129.2 - 136.4 °F
Boiling Point/Range 238 °C / 460.4 °F
Flash Point 152 °C / 305.6 °F
Vapor Pressure 1.33 mbar @ 102 °C
Acute Toxicity
Product Information
Oral LD50 Category 3. ATE = 50 - 300 mg/kg.
Dermal LD50 Category 3. ATE = 200 - 1000 mg/kg.
Mist LC50 Category 3. ATE = 0.5 - 1 mg/l.
Component Information
Component LD50 Oral LD50 Dermal LC50 Inhalation
2-Butyne-1,4-diol 176 mg/kg (Rat female) 659 mg/kg (Rat) 0.69 mg/L/4h (Rat)
Formaldehyde 500 mg/kg ( Rat ) LD50 = 270 mg/kg ( Rabbit ) 0.578 mg/L ( Rat ) 4 h
Ecotoxicity
Do not empty into drains. Contains a substance which is:. Harmful to aquatic organisms. The product contains following
substances which are hazardous for the environment.
Component Freshwater Algae Freshwater Fish Microtox Water Flea
2-Butyne-1,4-diol 430 mg/L EC50 = 96 h 49.3 - 58.3 mg/L LC50 96 h EC50 = 1343 mg/L 48 h 26.8 mg/L EC50 = 48 h
480 mg/L EC50 = 72 h EC50 = 2940 mg/L 17 h
Formaldehyde Not listed Leuciscus idus: LC50 = 15 Not listed EC50 = 20 mg/L 96h
mg/L 96h EC50 = 2 mg/L 48h
Persistence and Degradability Soluble in water Persistence is unlikely based on information available.
Bioaccumulation/ Accumulation No information available.
Mobility Will likely be mobile in the environment due to its water solubility
Waste Disposal Methods Chemical waste generators must determine whether a discarded
chemical is classified as a hazardous waste. Chemical waste generators
must also consult local, regional, and national hazardous waste
regulations to ensure complete and accurate classification
Component RCRA - U Series Wastes RCRA - P Series Wastes
Formaldehyde - 50-00-0 U122 -
DOT
UN-No UN2716
Proper Shipping Name 1,4-Butynediol
Hazard Class 6.1
Packing Group III
TDG
UN-No UN2716
Proper Shipping Name 1,4-Butynediol
Hazard Class 6.1
Packing Group III
All of the components in the product are on the following Inventory lists: X = listed
International Inventories
Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL
2-Butyne-1,4-diol X X - 203-788-6 - X X X X X
Formaldehyde X X - 200-001-8 - X X X X X
Legend:
X - Listed
E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA.
F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA.
N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover
the designated polymer made with any free-radical initiator regardless of the amount used.
P - Indicates a commenced PMN substance
R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA.
S - Indicates a substance that is identified in a proposed or final Significant New Use Rule
T - Indicates a substance that is the subject of a Section 4 test rule under TSCA.
XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA
Inventory Data Base Production and Site Reports (40 CFR 710(B).
Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater.
Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low
concern reactants that comprises one of the eligibility criteria for the exemption rule.
SARA 313
CERCLA
Not applicable