xy VLE data for methanol/water at 1 atm

Temp (oF) Temp (oC) x (mole f) y (mole f) y_calc Diagonal

212 100 0 0 0 0
209.12 98.4 0.012 0.068 0.164522 0.012
206.42 96.9 0.02 0.121 0.203265 0.02
204.44 95.8 0.026 0.159 0.226586 0.026 VLE for MeOH/H2O system @ 1 atm VLE for MeOH/H2O system @ 1 atm
203.18 95.1 0.033 0.188 0.250089 0.033
Liquid Vapor Equilibrium
201.38 94.1 0.036 0.215 0.259262 0.036

y (mole frac MeOH)

Diagonal
197.96 92.2 0.053 0.275 0.304281 0.053 220
1
194 90 0.074 0.356 0.349368 0.074
191.48 88.6 0.087 0.395 0.373577 0.087

Temperature (oF)
210
0.9
188.42 86.9 0.108 0.44 0.408558 0.108
0.8
185.72 85.4 0.129 0.488 0.439742 0.129 200

182.12 83.4 0.164 0.537 0.485687 0.164 0.7

179.6 82 0.191 0.572 0.517318 0.191 190

0.6
174.38 79.1 0.268 0.648 0.595187 0.268
172.58 78.1 0.294 0.666 0.618443 0.294 180
0.5
169.7 76.5 0.352 0.704 0.666301 0.352
167.54 75.3 0.402 0.734 0.703963 0.402 170 0.4
165.56 74.2 0.454 0.76 0.740321 0.454 0.3
160
163.76 73.2 0.502 0.785 0.771772 0.502
161.6 72 0.563 0.812 0.809295 0.563 0.2
150
159.62 70.9 0.624 0.835 0.844504 0.624
0.1
156.56 69.2 0.717 0.877 0.894496 0.717
140
154.58 68.1 0.79 0.91 0.931129 0.79 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0
152.96 67.2 0.843 0.93 0.956498 0.843 MeOH Content (mole fraction) 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
152.42 66.9 0.857 0.939 0.963042 0.857 x (mole frac MeOH)
150.26 65.7 0.938 0.971 0.999729 0.938
149 65 1 1 1.026572 1 y_calc = 1.026572 * x^0.4139722
This is a curve fit via Polymath.
(Curve above is simple connect the dots)

Experimental data from the compilation by Gmehling, J. and Onken, U. 1977. Vapor-Liquid Equilibrium Data Collection, Dechema, Frankfurt, Germany, vol. 1, p. 60.

from Chemical Engineering Design and Analysis: An Introduction

T. M. Duncan and J. A. Reimer, Cambridge University Press, 1998.
Temp (oC) x (mole f) y (mole f)
100 0 0
98.4 0.012 0.068
96.9 0.02 0.121
95.8 0.026 0.159 xy VLE data for methanol/water at 1 atm
95.1 0.033 0.188 1
94.1 0.036 0.215
92.2 0.053 0.275
90 0.074 0.356 0.9
88.6 0.087 0.395
86.9 0.108 0.44 0.8
85.4 0.129 0.488
83.4 0.164 0.537 0.7
82 0.191 0.572
79.1 0.268 0.648
0.6
78.1 0.294 0.666
76.5 0.352 0.704
75.3 0.402 0.734 0.5
74.2 0.454 0.76
73.2 0.502 0.785 0.4
72 0.563 0.812
70.9 0.624 0.835
0.3
69.2 0.717 0.877
68.1 0.79 0.91
67.2 0.843 0.93 0.2
66.9 0.857 0.939
65.7 0.938 0.971 0.1
65 1 1
0 0
0
0.068 0.068
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.121 0.121
0.159 0.159
0.188 0.188
0.215 0.215
0.275 0.275
0.356 0.356
0.395 0.395
0.44 0.44
0.488 0.488
0.537 0.537
0.572 0.572
0.648 0.648
0.666 0.666
0.704 0.704
0.734 0.734
0.76 0.76
0.785 0.785
0.812 0.812
0.835 0.835
0.877 0.877
0.91 0.91
0.93 0.93
0.939 0.939
0.971 0.971
1 1
0.8 0.9 1
Temp (oC) x (mole f) y (mole f)
100 0 0
98.4 0.012 0.068 xy VLE data for methanol/water at 1 atm
96.9 0.02 0.121 1
95.8 0.026 0.159
95.1 0.033 0.188
0.9
94.1 0.036 0.215
92.2 0.053 0.275
90 0.074 0.356 0.8
88.6 0.087 0.395
86.9 0.108 0.44 0.7
85.4 0.129 0.488
83.4 0.164 0.537
0.6
82 0.191 0.572
79.1 0.268 0.648
78.1 0.294 0.666 0.5
76.5 0.352 0.704
75.3 0.402 0.734 0.4
74.2 0.454 0.76
73.2 0.502 0.785
0.3
72 0.563 0.812
70.9 0.624 0.835
69.2 0.717 0.877 0.2
68.1 0.79 0.91
67.2 0.843 0.93 0.1
66.9 0.857 0.939
65.7 0.938 0.971 0
65 1 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
ol/water at 1 atm

5 0.6 0.7 0.8 0.9 1