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0 OBJECTIVES
This experiment was conducted to determine the initial and final boiling points
of petroleum sample, the percentage of distilled amount against temperature of petroleum
product sample and to determine the quantity of various fractions of petroleum sample. ASTM
Distillation is the most common method for obtaining distillation data (volume % distilled vs
temperature) of gasoline, naphtha, kerosene and gas oil. 100 ml of sample is distilled at uniform
rate of 2.079 ml per min, the distillate is condensed. The sample used was Petrol. The
experiment was conducted by setting the analyser and apparatus based on the lab manual. From
the result, the IBP (Initial Boiling Point) was obtained at 50C and at the rate of distillation
average of 4 ml per min. While the Final Drop (FBP) obtained at 173C From the data that was
obtained from the experiment, at temperature of 56C, 85.5C, and 173C, the amount of
distillation was at 10%, 50%, and 90% respectively. As the temperature increase, the amount
of distillation also increased but the time taken for each 10ml also increases overtime. The total
time taken for it to reach to the last drop was 46 minutes and 59 seconds. The first recorded
data has no distillation rate because the data was to indicate the initial boiling point of the petrol.
However, after the first recorded data, the distillation rate can be calculated using the difference
of the previous data with the current data over the time taken need for it to reach to the current
volume. From the graph, this prove that the first 12 minutes has higher rate distillation because
of the lighter fraction of the petrol are being vaporize and the rate began to slow down due to
the heavier portion of the petrol that are being vaporized. From the data obtained, the
percentage of oil distilled was 90% and the percentage of residue was 7.4% which come to
total of 97.4% of oil recovery. The percentage of recovery is high, because it contains various
fraction of the oil. From the experiment, the light distillate produces at the temperature range
of 50C until 85.5C (naphtha, gasoline) and the middle distillate is produced at the temperature
range of 101C until 173C (kerosene, diesel). From the conducted experiment, it can be
deduced that the amount of distillation increased as the temperature increased where the higher
the temperature will be easier for the sample to be vaporized. The remaining liquid residue in
the flask was due to the presence of very high boiling point compound in the sample. The
percentage of the recovery and residual cannot reach 100% distillation due to the percentage
of the light vapours that vaporized to the surrounding during condensation time.
3.0 INTRODUCTION AND THEORY
ASTM Distillation it the standard Test Method at atmospheric pressure for determining the
characteristic of the boiling range for petroleum products. As the working principle, it is based
on the differential or simple distillation. A batch of liquid petroleum product is charge into a
still fitted with heating device. Next, it will be boil slowly and releasing the vapour that will
rapidly withdraw into the condenser. After that, the condensate then being collect in the
receiver (ASTM DIstillation, 2012). ASTM test method covers the atmospheric distillation of
the petroleum products by batch distillation unit in laboratory. It determines the quantitatively
boiling range characteristics of such a light and middle distillate, aviation gasoline, diesel fuel,
turbine fuels, marine fuels, naphtha, kerosene, Grade 1 and 2 burner fuels and some other more.
It is designed for the analysis for distillate fuels where are not applicable to residual-containing
product in appreciable quantities. Besides, ASTM covers both of automated and manual control
instruments (Ahmed, 2014). In addition, ASTM test methods are an industry standard test for
petroleum that are widely accepted for reliability and quality (ASTM Petroleum Test Methods,
2018). There are ASTM D86 for the atmospheric distillation suitable for the low boiling
fractions and ASTM D1160 for the vacuum distillation for the high boiling fractions (Eser,
2017).
Figure 1: TBP, ASTM, EFV curves
Other than ASTM method, there are another two type of method that are commonly used
to generate laboratory data of the crude oil; True Boiling Distillation (TBP) and Equilibrium
Flash Vaporization (EFV).
Table 1: Time and temperature for volume of distilled of petroleum oil distillation according
to ASTM method
Record
Volume distilled : 90 ml
60 Volume Distilled
40
Linear (Volume
20 Distilled)
0
0 50 100 150 200
Temperature (℃)
DISCUSSION
ASTM Distillation is the most common method for obtaining distillation data (volume %
vs temperature) of gasoline, naphtha, kerosene and gas oil. In ASTM distillation, 100ml of
sample is distilled at average rate 2.079 ml per min, the distilled is condensed. The main
purpose of this experiment is to determine the percentage of distilled amount against
temperature of petroleum sample, initial and final boiling point of petroleum sample, and lastly
is to determine the quantity of various fractions of petroleum sample. For this experiment,
petrol was used as the sample.
The experiment was conducted by setting the analyser and apparatus. The result of the
experiment was obtained initially at the rate of distillation average of 4 ml per min and
temperature was at 50C, which is the initial boiling point. As the experiment continued, when
the temperature was at 66C, the rate of distillation drops significantly beyond this temperature.
From the plotted graph (volume distilled against temperature), the gradient of the graph will
represent the rate of distillation. The gradient of the graph begins to decrease significantly when
reaching 100C and above. This prove that a highly volatile fuel is more likely to form a
flammable or explosion mixture with air than a low volatile fuel.
Next is about the initial and final boiling point of the petrol. From the data that was
obtained from the experiment, at temperature of 56C, 85.5C, and 173C, the amount of
distillation was at 10%, 50%, and 90% respectively. As the temperature increase, the amount
of distillation also increased but the time taken for each 10ml also increases overtime. The total
time taken for it to reach to the last drop was 46 minutes and 59 seconds.
The first recorded data has no distillation rate because the data was to indicate the initial
boiling point of the petrol. However, after the first recorded data, the distillation rate can be
calculated using the difference of the previous data with the current data over the time taken
need for it to reach to the current volume. From the graph, this prove that the first 12 minutes
has higher rate distillation because of the lighter fraction of the petrol are being vaporize and
the rate began to slow down due to the heavier portion of the petrol that are being vaporized.
However, there are some residue due to its higher boiling point that cannot be reach during the
experiment makes it cannot be vaporize.
From the data obtained, the percentage of oil distilled was 90% and the percentage of
residue was 7.4% which come to total of 97.4% of oil recovery. The percentage of recovery is
high, because it contains various fraction of the oil. It can be classified as three category which
are light, middle, and heavy distillate. From the experiment, the light distillate produce at the
temperature range of 50C until 85.5C(naphtha, gasoline) and the middle distillate is produced
at the temperature range of 101C until 173C(kerosene, diesel). At the residual percentage
consists of moisture contain. The total recovery percentage cannot reach 100% because of the
extremely light vapour that has escaped the condensation process during the experiment was
being conducted.
TUTORIALS
1. Measure the percentage recovery (sample being distilled) in the measuring cylinder.
= 90 %
= 7.4%
= 7.4 ml + 90 ml
= 97.4 ml
= 97.4%
= 100 ml – 97.4 ml
= 2.6 ml
= 2.6%
4. Plot graph volume % distilled (percentage recovery) versus temperature of distillation
80
60
Volume Distilled
40
20
0
0 50 100 150 200
Temperature (℃)
5.0 CONCLUSION AND RECOMMENDATION
From the conducted experiment, it can be deduced that the amount of distillation
increased as the temperature increased where the higher the temperature will be easier for the
sample to be vaporized. The remaining liquid residue in the flask was due to the presence of
very high boiling point compound in the sample. From Figure 1, the first drop was produced at
50 ℃ (initial boiling point) and the final boiling point of 173 ℃ obtained at 90 ml of final
volume of distilled. It is because the increased the temperature, the higher the volume of petrol
distilled and vaporized as well the longer the time taken for the petrol to reach the final boiling
point from starting of the first drop compared at a low temperature. From Table 1, the
percentage of oil distilled was 90% and the percentage of residue was 7.4% which come to
total of 97.4% of oil recovery. The percentage of recovery is high, because it contains various
fraction of the oil. It can be observed that light distillate produces at the temperature range of
50C until 85.5C (naphtha, gasoline) and the middle distillate is produced at the temperature
range of 101C until 173C (kerosene, diesel). Lastly, the percentage of the recovery and
residual cannot reach 100% distillation due to the percentage of the light vapours that vaporized
to the surrounding during condensation time.
RECOMMENDATION
There are several recommendations that need to be done when conducting the
experiment to get an accurate and precise result. Firstly, make sure not to use the recycle petrol
or sample to avoid the decrease quality of petrol used. Next, clean all the apparatus before used
to ensure that it is contamination free. Furthermore, make sure eyes are parallel and at the same
level of thermometer when taking the reading of temperature as well as the measuring cylinder
when taking the reading of volume distilled to avoid any parallax error to obtain an accurate
result. Finally, use the suitable apparatus to measure the volume of any sample to avoid error
of the reading in the future.
REFERENCES