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psaikhwan@engr.tu.ac.th
PREVIOUSLY….
Last lecture we learned about ‘Atom’
What is an atom? What is it composed of?
What is an element?
What information do we get from a periodic table?
What is electronic structure of an atom?
What are valence electrons?
2
WHAT IS NEXT?
This lecture
Relationship between electron structures
of atom and chemical reaction
Why H joins O water (H2O)
Why N joins O nitric oxide (NO)
3
PURE SUBSTANCE
Materials that are the same throughout and have a fixed, definite
composition
Element Compound
Cannot be broken down into Can be decomposed by a chemical
anything simpler by chemical or change into simpler substances with
physical means a fixed mass ratio
Only 8 elements make up 99% of E.g. sugar, salt, water (compound of
earth’s surface hydrogen and oxygen elements)
E.g. oxygen, silicon, aluminum, iron
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MIXTURE
A mixture has unlike parts and a composition that can vary from
sample to sample
Can be separated into components by physical means (e.g.
crushing, bending, melting, freezing, distillation, drying)
Homogeneous Mixture
Mixed uniformly throughout a given sample; does not vary in composition
from one region to another
E.g. Salt water solution, solid solution like brass (alloy of copper and zinc)
Heterogeneous
Within a sample, different regions have different compositions
E.g. Soil, salt and pepper mixture, oil in water, colloid
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PHYSICAL AND CHEMICAL CHANGES
Physical changes Chemical changes
Does not result in change of identity Alters the identity of matter, producing new
of the matter substances with different chemical properties
Involve physical properties changes e.g. spoiling of food, burning sugar
ONLY Sugar C12H12O11 C(s) + CO2(g) + H2O(g)
e.g. Change of state (boiling,
freezeing, melting, condensing,
vaporizing)
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COMPOUND AND CHEMICAL CHANGES
Atom - smallest elemental unit ( e.g. He atom)
Molecule
smallest unit or group of atoms that still retains the
characteristic chemical properties of a substance
Examples:
oxygen, hydrogen gas - diatomic molecules
Ozone - triatomic oxygen molecule
Noble gases: helium, neon - “monatomic” molecules or
molecule that has only one atom (can also be considered
as element, e.g. He element or He atom or He molecule)
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ATOM, MOLECULE, ELEMENT, COMPOUND…DON’T GET
CONFUSED
Molecule Molecule
Pure substance
Element consists of single atomic species.
Hydrogen gas (H2)
Oxygen gas (O2)
Molecule
Compound is a group of atoms from different elements bonded
Water (H2O)
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SO WHAT IS A CHEMICAL REACTION?
Change in matter in which different chemical substances are created by
forming or breaking chemical bonds
Reactants Products
Breaking chemical bonds of reactants
Energy is used
Forming chemical bonds of products
Energy is released.
Chemical energy may be released or
absorbed depending whether the new
bonds formed are weaker or stronger
Endothermic Energy is used A
Exothermic Energy is released B
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INTERESTING CHEMICAL REACTIONS
Let’s watch a video to see some chemical reactions.
https://www.youtube.com/watch?v=FofPjj7v414
WHY ONLY SOME ELEMENTS REACT WITH EACH OTHER?
This can be explained by understanding of how chemical bonds
are formed.
As chemical bonding = is a sharing, or losing and gaining of electrons
between atoms or group of atoms
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VALENCE ELECTRONS
Determine chemical properties of
an atom
Octet rule
Atoms attempt to acquire an outer shell of
8 electrons (or the filled s and p orbitals)
Electrons can be gained/lost/shared
For atoms with 1-2-3 outer electrons
(e.g. group IA-IIIA) loosely bound, and
easily become positive ions
For atoms with 5-7 outer electrons
(group V-VIIA), tend to gain electrons and
form negative ions
Example: sodium (Na) (group IA has 1
electron in the outer shell)
Transition elements tend to use inner electrons
in reactions as well, not considered here. 13
LOSING/GAINING ELECTRONS
Loss
What is an electronic structure
of Magnesium (Mg)?
12 electrons
1s2 2s2 2p6 3s2
So losing 2 electrons in 1s will
make no. of valence electrons
= 8 Stable according to the
Octet rule.
Mg + energy Mg2+ + 2e-
Ionization Ion
energy cation
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CHEMICAL BONDS
Being attractive holding atoms together in compounds
Can be described in terms of molecular
(delocalized) or atomic (localized) orbitals
3 types:
Ionic
Electrons transferred between atoms
Binding force = electrostatic force between the +ively charged
ions and -ively charged ions
Remember, Mg prefer losing 2 electrons
What about Cl? What is its electronic structure?
17 electrons 1s2 2s2 2p6 3s2 3p5
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CHEMICAL BONDS
Ionic bond
Cl: 17 electrons 1s2 2s2 2p6 3s2 3p5
What if Cl gains 1 electron?
Cl- : 1s2 2s2 2p6 3s2 3p6
Filled p orbital, 8 valence electrons Stable according to the Octet rule
So Mg is happy to lose 2 electrons, Cl is happy to accept 1
Mg2+ + 2Cl- MgCl2
Magnesium cations are held with chloride anions by attractive force
between positive charges and negative charges.
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CHEMICAL BONDS
Ionic bond
Chemical bond of electrostatic attraction
Form crystalline solids with orderly
geometric structure
This is why salt is in a crystal form!
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COMMON IONS OF SOME ELEMENTS
Element Symbol Ion
Lithium Li 1+ Group I
Sodium Na 1+ Metal
Potassium K 1+
Magnesium Mg 2+
Group II
Calcium Ca 2+
Metal
Barium Ba 2+
Aluminum Al 3+ Group III
Oxygen O 2-
Group VI
Sulfur S 2-
Hydrogen H 1+, 1-
Fluorine F 1-
Chlorine Cl 1- Group VII
Bromine Br 1-
Iodine I 1-
COMMON IONS OF SOME TRANSITION ELEMENTS
Element Symbol Ion
Zinc Zn 2+
Tungsten W 6+
Silver Ag 1+
Cadmium Cd 2+
Chromium Cr 2+, 3+, 6+
Manganese Mn 2+, 4+, 7+
Iron Fe 2+, 3+
Cobalt Co 2+, 3+
Nickel Ni 2+, 3+
Variable-charge
Copper Cu 1+, 2+
ions
Tin Sn 2+, 4+ Cr3+ (CrO4)2- (Cr2O7)2-
Gold Au 1+, 3+ What are charges of
Mercury Hg 1+, 2+ these chromium ions?
Lead Pb 2+, 4+
CHEMICAL BONDS
Covalent
Octets achieved through sharing of electrons
Typically between nonmetallic elements, r.h.s of periodic table
Bonding = electrostatic attraction between cations and shared
pairs of electrons
Eg. O2 : 2 oxygen atoms are held together by covalent bond, why?
What is an electronic structure of O atom?
O: 8 electrons: 1s2 2s2 2p4 2 shared pairs of
6 valence electrons want 2 more electrons electrons = double
bond
Another O atom also wants 2 more electrons
So they share!
One share paired of electron = single bond
There are also double bond and triple bond.
O=O 20
CHEMICAL BONDS
Covalent
Let’s try to figure out covalent bonds in following covalent molecules!
Molecule Lewis dot structure Line representation
H2
HF
AlF3
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CHEMICAL BONDS
Covalent
Let’s try to figure out covalent bonds in following covalent molecules!
Molecule Lewis dot structure Line representation
H2 O
C2 H4
C2 H2
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CHEMICAL BONDS
Covalent
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CHEMICAL BONDS
Covalent
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CHEMICAL BONDS
Metallic bonds
Outer electrons move freely throughout metal
“Electron gas” within rigid lattice of metal atoms
Conduct heat and electricity well
Metal atoms are held together by electrostatic attraction between cations
and sea of electrons.
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CHEMICAL BONDS
Watch this video!
https://www.youtube.com/watch?v=QXT4OVM4vXI
IONIC COMPOUND NAMES
Cation (with positive charge) is called by the element name
e.g. Mg2+ = Magnesium ion
Anion is called by the element name + change ending to –ide
e.g. H- = Hydride This is when you only have
two elements involved in
the ionic compound
Single-charge ion
Name of cation + Name of anion
NaCl = Sodium chloride
HCl = Hydrogen chloride dissolves in water to make hydrochloric acid
Variable-charge ion
Name of cation (No of charge) + Name of anion
FeO = Iron (II) oxide
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IONIC COMPOUND NAMES
Polyatomic ions = groups of 2 or more atoms binding together an
act like monoatomic ions
Ion name Formula
Acetate (C2H3O2)2-
Ammonium (NH4)+
Borate (BO3)3-
Carbonate (CO3)2-
Chlorate (ClO3)-
Chromate (CrO4)2-
Cyanide (CN)-
Dichromate (Cr2O7)2-
Hydrogen carbonate (or bicarbonate) (HCO3)-
Hydrogen sulfate (or bisulfate) (HSO4)-
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IONIC COMPOUND NAMES
Polyatomic ions = groups of 2 or more atoms binding together an
act like monoatomic ions
Ion name Formula
Hydroxide (OH)-
Hypochlorite (ClO)-
Nitrate (NO3)-
Nitrite (NO2)-
Perchlorate (ClO4)-
Permanganate (MnO4)-
Phosphate (PO4)3-
Phosphite (PO3)3-
Sulfate (SO4)2-
Sulfite (SO3)2-
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COVALENT COMPOUND NAMES
Molecular - composed of two or more nonmetals
Same elements can combine to form a number of different
compounds e.g. CH4, C2H4 (ethylene or dicarbon tetrahydride)
Two rules
First element in formula named first with number indicated by
Greek prefix
Stem name of second element next; Greek prefix for number;
ending in “-ide” for two elements) e.g. -monoxide,
-dioxide, -fluoride, -chloride
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COVALENT COMPOUND NAMES
31
CHEMICAL EQUATION
An equation telling you what’s going on
Reactant 1 (s) + Reactant 2 (l) Product 1 (g) + Product 2 (g)
Examples Stoichiometric equation
Photosynthesis
6CO2 (g) + 6H2O (l) 1C6H12O6 (s) + 6O2 (g)
6 moles of carbon dioxide + 6 moles of water
sugar + 6 moles of oxygen
Stoichiometric coefficients
Stoichiometric ratio
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WHAT IS MOLE?
Mole is away to count particles just like a dozen is a way to
count items
1 dozen = 12 items whereas 1 mole = 6.02 x 1023 particles
A dozen of eggs = 12 eggs
A dozen of Krispy Kreme donuts = 12 donuts
1 mole of carbon black (C) 6.02 x 1023 atoms of C
1 mole of hydrogen gas (H2) 6.02 x 1023 molecules of H2 2x6.02x1023atoms
of H
1 mole of oxygen gas (O2) 6.02 x 1023 molecules of O2 2x6.02x1023atoms
of O
1 mole of water (H2O) 6.02 x 1023 molecules of H2O 2x6.02x1023atoms of
H and 6.02x1023 atoms of O
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ccxv
35
MOLE AND MASS
We can link mole and mass
Molecular mass = mass of 1 mole of element or compound
1 mole of C (atom) = 12.01 g
1 mole of H (atom) = 1.008 g
1 mole of H2 (hydrogen gas) = 2 moles of H atoms = 2 x 1.008 g
1 mole of H2O (water)
= 2 moles of H atom + 1 mole of O atom
= 2 x 1.008 + 16.00
about 18 g
36
BALANCING CHEMICAL EQUATIONS
Correct equation should be balanced
obey Law of Conservation of Mass
all elements on reactants side also on product side
equal numbers of atoms of each element on reactant side as on
product side
37
TYPES OF CHEMICAL REACTIONS
Oxidation–Reduction (redox)
Reaction in which electrons are transferred from one atom to
another
Oxidation: loss of e-, reduction: gain of e-
Substance gaining e- oxidizing agent
Substance giving e- reducing agent
2Fe2O3 (s) + 3C(s) 4 Fe(s) + 3CO2
Fe changes from 3+ 0 It gains e-
C changes from 0 4+ It loses e-
Fe2O3 is an oxidizing agent
C is a reducing agent
Fe2O3 is reduced by C
C is oxidized by Fe2O3
REDOX REACTION = REDUCTION + OXIDATION
Watch this video!
https://www.youtube.com/watch?v=lQ6FBA1HM3s
TYPES OF CHEMICAL REACTIONS
Combination Reaction
Synthesis in which two or more substances combine to form a single compound. E.g.
4Fe(s) + 3O2(g) -> 2Fe2O3(s) rust forming
Decomposition Reaction
Compound broken down into elements, simpler compounds or both
Opposite of combination. E.g. XY -> X + Y
Replacement Reaction
Atom or polyatomic ion is replaced by a different atom or polyatomic ion
E.g. XY + Z -> XZ +Y (replacing one of the components)
Ion Exchange Reaction
Ions of one compound interact with ions of another to form either a (1) precipitate,
(2) gas or (3) water
E.g. AX + BY -> AY +BX (swapping reaction)
To what chemical reaction class does this reaction belong?
2 Mg(s) + O2(g) → 2 MgO(s)
A. combination
B. ion exchange
C. decomposition
D. replacement
RP
Reversible reaction
Never get 100% conversion
42
PREDICTION SHIFT FROM EQUILIBRIUM
Le Chatelier’s Principle
Change in the direction opposing the disturbance
Concentration
Add more reactants/remove products Produce more products to reduce
the reactants
Add more products/remove reactants Change
Pressure
Increase pressure
change in a way that reduce total pressure
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PREDICTION SHIFT FROM EQUILIBRIUM(2)
Le Chatelier’s Principle
Change in the direction opposing the disturbance
Temperature
Increase temperature change in a way that reduce temperature
e.g. Exothermic reaction Reaction giving out heat
If you increase temperature, C will absorb heat and reverse
back to A and B to reduce the temperature.
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