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Mechanism (E1):
and/or ketones.
Pinacol-Pinacolone rearrangement:
Pinacol (2,3-dimethyl-2,3-butanediol) when treated with an
acid is converted into pinacolone.
Mechanism:
b. IUPAC system:
Ethers are regarded as alkoxy derivatives, the larger
group is chosen as the parent one, e.g.
Preparation of ethers
1- From alcohols (dehydration):
Limited to the preparation of symmetrical ethers and
large scale production.
Conc. HI/Heat
C6H5OCH3 C6H5OH + CH3I
Zeisel method:
Used to determine the number of methoxyl or ethoxyl
groups in the molecule.