NEET(UG)-2018

NEET(UG)–2018 TEST PAPER WITH ANSWER

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CHEMISTRY
46. A mixture of 2.3 g formic acid and 4.5 g oxalic acid 51. In the reaction
is treated with conc. H 2 SO 4 . The evolved gaseous OH O – Na +
mixture is passed through KOH pellets. Weight
(in g) of the remaining product at STP will be CHO
+ CHCl 3 + NaOH
(1) 1.4 (2) 3.0 (3) 2.8 (4) 4.4
the electrophile involved is
Ans. (3)
47. Nitration of aniline in strong acidic medium also 
(1) dichloromethyl cation (CHCl 2 )
gives m-nitroaniline because

(1) In spite of substituents nitro group always goes (2) formyl cation (CHO)
to only m-position.
(2) In electrophilic substitution reactions amino (3) dichloromethyl anion (CHCl 2)
group is meta directive.
(4) dichlorocarbene (:CCl 2 )
(3) In absence of substituents nitro group always
goes to m-position Ans. (4)

(4) In acidic (strong) medium aniline is present as 52. Carboxylic acid have higher boiling points than
anilinium ion. aldehydes, ket ones an d even alcoh ols of
Ans. (4) comparable molecular mass. It is due to their

48. Which of the following oxides is most acidic in (1) formation of intramolecular H-bonding
nature? (2) formation of carboxylate ion
(1) MgO (2) BeO (3) BaO (4) CaO (3) more extensive association of carboxylic acid via
Ans. (2) van der Waals force of attraction
49. The difference between amylose and amylopectin (4) formation of intermolecular H-bonding.
is Ans. (4)
(1) Amylopectin have 1  4 -linkage and 1  6
53. Compound A, C 8 H 10 O, is found to react with NaOI
-linkage
(produced by reacting Y with NaOH) and yields a
(2) Amylose have 1  4 -linkage and 1  6 yellow precipitate with characteristic smell.
-linkage
A and Y are respectively
(3) Amylopectin have 1  4 -linkage and 1  6
-linkage
(1) H 3C CH2–OH and I2
(4) Amylose is made up of glucose and galactose
Ans. (1)
50. Regarding cross-linked or network polymers, which (2) CH2 – CH2–OH and I2
of the following statements is incorrect?
(1) They contain covalent bonds between various
linear polymer chains. CH– CH 3 and I2
(3)
(2) They are formed from bi-and tri-functional OH
monomers.
CH3
(3) Examples are bakelite and melamine.
(4) They contain strong covalent bonds in their (4) CH OH and I2
3
polymer chains.
Ans. (4) Ans. (3)
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54. The correct difference between first- and 58. Magnesium reacts with an element (X) to form an
second-order reaction is that ionic compound. If the ground state electronic
2
(1) the rate of a first-order reaction does not depend configuration of (X) is 1s 2s 2 2p 3 , the simplest
on reactant concentration; the rate of a second- formula for this compound is
order reaction does depend on reactant (1) Mg2 X3 (2) MgX2
concentrations. (3) Mg2 X (4) Mg3 X2
(2) the half-life of a first-order reaction does not Ans. (4)
depend on [A] 0 ; the half-life of a second-order 59. Iron exhibits bcc structure at room temperature.
reaction does depend on [A] 0 Above 900°C, it transforms to fcc structure. The
(3) a first-order reaction can be catalyzed; ratio of density of iron at room temperature to that
a second-order reaction cannot be catalyzed. at 900°C (assuming molar mass and atomic radii of
(4) the rate of a first-order reaction does depend iron remains constant with temperature) is
on reactant concentrations; the rate of a
second-order reaction does not depend on 3 4 3 3 3 1
(1) (2) (3) (4)
reactant concentrations 2 3 2 4 2 2
Ans. (2)
Ans. (3)
55. Among CaH 2 , BeH 2 , BaH 2 , the order of ionic
60. Which one is a wrong statement ?
character is
(1) Total orbital angular momentum of electron in
(1) BeH 2 < CaH 2 < BaH 2 's' orbital is equal to zero
(2) CaH 2 < BeH 2 < BaH 2 (2) An orbital is designated by three quantum
(3) BeH 2 < BaH 2 < CaH 2 numbers while an electron in an atom is
(4) BaH 2 < BeH 2 < CaH 2 designated by four quantum numbers.
Ans. (1) (3) The electronic configuration of N atom is
56. Consider the change in oxidation state of Bromine
2 2 1 1 1
corresponding to different emf values as shown in 1s 2s 2p x
2p y 2p z

the diagram below:

1.82 V 1.5 V (4) The value of m for d z2 is zero

BrO 4 BrO 3 HBrO
Ans. (3)
Br Br2 61. Consider the following species:
1.0652V 1.595 V
CN + , CN –, NO and CN
Then the species undergoing disproportionation is:- Which one of these will have the highest bond order?
(1) BrO 3– (2) BrO 4– (1) NO (2) CN –
(3) Br2 (4) HBrO (3) CN+ (4) CN
Ans. (4) Ans. (2)
57. In which case is the number of molecules of water 62. Which of the following statements is not true for
maximum? halogens ?
(1) 18 mL of water (1) All form monobasic oxyacids.
(2) 0.18 g of water (2) All are oxidizing agents.
(3) 0.00224 L of water vapours at 1 atm and (3) All but fluorine show positive oxidation states.
273 K (4) Chlorine has the highest electron-gain
(4) 10 –3
mol of water enthalpy.
Ans. (1) Ans. (Bonus)

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63. Which one of the following elements is unable to pH of which one of them will be equal to 1 ?
form MF 63– ion ? (1) b (2) a
(1) Ga (2) AI (3) B (4) In (3) d (4) c
Ans. (3) Ans. (4)
64. In the structure of ClF 3 , the number of lone pairs 70. The solubility of BaSO 4 in water 2.42 ×10 3 gL –1
of electrons on central atom 'Cl' is at 298 K. The value of solubility product (K sp )
(1) one (2) two (3) four (4) three will be
Ans. (2) (Given molar mass of BaSO 4 = 233 g mol –1 )
65. Considering Ellingham diagram, which of the (1) 1.08 × 10 –10 mol 2 L –2
following metals can be used to reduce alumina ? (2) 1.08 × 10 –12 mol 2 L –2
(1) Fe (2) Zn (3) Mg (4) Cu (3) 1.08 × 10 –14 mol 2 L –2
Ans. (3) (4) 1.08 × 10 –8 mol 2 L –2
Ans. (1)
66. The correct order of atomic radii in group 13
elements is 71. Given van der Waals constant for NH 3 , H 2 and CO 2

(1) B < Al < In < Ga < Tl are respectively 4.17, 0.244, 1.36 and 3.59, which
(2) B < Al < Ga < In < Tl one of the following gases is most easily liquefied?
(3) B < Ga < Al < Tl < In (1) NH 3 (2) H 2
(4) B < Ga < Al < In < Tl (3) O 2 (4) CO 2
Ans. (4) Ans. (1)

67. The correct order of N-compounds in its decreasing 72. The compound A on treatment with Na gives B, and
order of oxidation states is with PCl 5 gives C. B and C react together to give
(1) HNO 3 , NO, N 2 , NH 4 Cl diethyl ether. A, B and C are in the order
(2) HNO 3 , NO, NH 4 Cl, N 2 (1) C2 H 5 OH, C 2 H 6 , C 2 H 5 Cl
(3) HNO 3 , NH 4 Cl, NO, N 2 (2) C2 H 5 OH, C 2 H 5 Cl, C 2 H 5 ONa
(4) NH4 Cl, N 2 , NO, HNO 3 (3) C2 H 5 Cl, C 2 H 6 , C 2 H 5 OH
Ans. (1) (4) C2 H 5 OH, C 2 H 5 ONa, C 2 H 5 Cl
Ans. (4)
68. On which of the following properties does
coagulating power of an ion depend ? 73. Hydrocarbon (A) reacts with bromine by substitution
(1) The magnitude of the charge on the alone to form an alkyl bromide which by Wurtz reaction
(2) Size of the ion alone is converted to gaseous hydrocarbon containing less
(3) Both magnitude and sign of the charge the ion than four carbon atoms. (A) is
(4) The sign of charge on the ion alone (1) CHCH (2) CH 2 =CH 2
Ans. (3) (3) CH 3 –CH 3 (4) CH 4
Ans. (4)
69. Following solutions were prepared by mixing
different volumes of NaOH and HCl of different 74. The compound C 7H 8 undergoes the following
concentrations : reactions :

M M 3Cl / 
2 A 
2 Br /Fe Zn/HCl
a. 60mL HCl 40mL NaOH C 7 H 8  B 
C
10 10
The product 'C' is
M M
b. 55mL HCl 45mL NaOH (1) m–bromotoluene
10 10
(2) o–bromotoluene
M M (3) 3–bromo–2,4,6–trichlorotoluene
c. 75mL HCl 25mL NaOH
5 5 (4) p–bromotoluene
M M Ans. (1)
d. 100mL HCl 100mL NaOH
10 10
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75. Which oxide of nitrogen is not a common pollutant 80. The bond dissociation energies of X 2, Y 2 and XY
introduced into the atmosphere both due to natural are in the ratio of 1 : 0.5 : 1. H for the formation
and human activity ? of XY is –200 kJ mol –1
. The bond dissociation
(1) N2 O 5 energy of X 2 will be
–1
(2) NO 2 (1) 200 kJ mol
–1
(3) N2 O (2) 100 kJ mol
–1
(3) 800 kJ mol
(4) NO
–1
(4) 400 kJ mol
Ans. (1)
76. For the redox reaction Ans. (3)

MnO 4– + C 2 O 42– + H + Mn 2+ + CO 2 + H 2 O 81. Identify the major products P, Q and R in the

the correct coefficients of the reactants for the following sequence of reaction :
balanced equation are Anhydrous
AlCl3 (i) O2
MnO 4– C 2 O 42– H +
+CH 3 CH 2 CH 2 Cl  P  + Q +R
(ii) H O /  3
(1) 16 5 2
(2) 2 5 16 P Q R
(3) 2 16 5
(4) 5 16 2 CH 2CH 2CH 3 CHO
Ans. (2) (1) , , CH 3 CH 2 –OH
77. Which one of the following conditions will favour
maximum formation of the product in the reaction,
A2 (g) + B 2 (g)  X2 (g) rH = –X kJ ?
(1) Low temperature and high pressure CH 2CH 2CH 3 CHO COOH
(2) Low temperature and low pressure (2) , ,
(3) High temperature and high pressure
(4) High temperature and low pressure
Ans. (1)
CH(CH 3)2 OH
78. The correction factor 'a' to the ideal gas equation (3) , , CH 3 CH(OH)CH 3
corresponds to
(1) density of the gas molecules
(2) volume of the gas molecules
OH
(3) electric field present between the gas molecules CH(CH 3)2
(4) , , CH 3 –CO–CH 3
(4) forces of attraction between the gas molecules
Ans. (4)
79. When initial concentration of the reactant is doubled, Ans. (4)
the half-life period of a zero order reaction
82. Which of the following compounds can form a
(1) is halved
zwitterion ?
(2) is doubled
(1) Aniline (2) Acetanilide
(3) is tripled
(3) Benzoic acid (4) Glycine
(4) remains unchanged
Ans. (4)
Ans. (2)
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83. The type of isomerism shown by the complex 88. Which of the following is correct with respect to
[CoCl2 (en)2 ] is –I effect of the substituents ? (R = alkyl)
(1) Geometrical isomerism (1) – NH 2 < – OR < – F
(2) Coordination isomerism (2) –NR2 < – OR < – F
(3) Ionization isomerism (3) – NH 2 > – OR > – F
(4) Linkage isomerism (4) – NR 2 > – OR > – F
Ans. (1) Ans. (1/2)
84. Which one of the following ions exhibits d–d 89. Which of the following carbocations is expected to
transition and paramagnetism as well ?
be most stable ?
(1) CrO 42– (2) Cr 2 O 72–
(3) MnO 4– (4) MnO 2– NO 2
4
Ans. (4)
85. The geometry and magnetic behaviour of the
(1)
complex [Ni(CO) 4 ] are 
(1) square planar geometry and diamagnetic Y H
(2) tetrahedral geometry and diamagnetic
(3) square planar geometry and paramagnetic NO 2
(4) tetrahedral geometry and paramagnetic

Ans. (2)
86. Iron carbonyl, Fe(CO) 5 is (2)
(1) tetranuclear (2) mononuclear
Y H
(3) trinuclear (4) dinuclear
Ans. (2) NO 2
87. Match the metal ions given in Column I with the spin
magnetic moments of the ions given in Column II
(3) H
and assign the correct code :
Y
Column I Column II 
a. Co 3+ i. 8 B.M. NO 2

b. Cr 3+ ii. H
35 B.M. 
(4) Y
c. Fe 3+ iii. 3 B.M.

d. Ni 2+ iv. 24 B.M. Ans. (3)

90. Which of the following molecules represents the
v. 15 B.M. 2
order of hybridisation sp , sp 2 , sp, sp from left to
a b c d right atoms ?
(1) iv v ii i (1) HC  C – C  CH
(2) i ii iii iv (2) CH 2 = CH – C  CH
(3) iv i ii iii
(3) CH 2 = CH – CH = CH 2
(4) iii v i ii
(4) CH 3 – CH = CH – CH 3
Ans. (1)
Ans. (2)
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