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APPLICATION OF HEAVY METALS IN STREET


DUST IN THE MONITORING OF CHANGES IN
ENVIRONMENT

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by PSP Volume 25 – No. 1/ 2016, pages 103-112 Fresenius Environmental Bulletin

APPLICATION OF HEAVY METALS IN STREET DUST IN


THE MONITORING OF CHANGES IN ENVIRONMENT
Wojciech Kwasowski1, Teresa Kozanecka1, Ewa Beata Górska2, Dariusz Gozdowski3, Pawel
Kowalczyk4*
1
Department of Environmental Soil Sciences, Warsaw University of Life Sciences-SGGW, Nowoursynowska 166, 02-787 Warsaw, Poland,
2
Department of Microbial Biology, Faculty of Agriculture and Biology, Warsaw University of Life Sciences-SGGW, Nowoursynowska 166,
02-787 Warsaw, Poland,
3
Department of Experimental Statistics and Bioinformatics, Faculty of Agriculture and Biology, Warsaw University of Life Sciences-
SGGW,
4
Bionicum LTD, Chełmska 21, 00-724, Warsaw, Poland.

ABSTRACT The sources of heavy metals in street dust


include for instance the components of exhaust
The presented investigations were focused on fumes, rubbed off road pavements, car tires and
the content of heavy metals (Zn, Cu, Pb, Cd) in metal elements of car engines. The dust comprises
street dust from localities in Central Poland with also airborne soil particles as well as atmospheric
variable urban, industrial and transportation rain of industrial and urban dusts. Existing literature
development. Forms soluble in 20% HCl were [3,7] clearly indicates gradual pollution by trace
subject to the analysis. It has been concluded that elements of agricultural and forest soils lying
the content of Zn, Cu, Pb and Cd in street dust did adjacent to transportation routes.
not depend on the agglomeration size but usually on The excessive content of heavy metals in the
the degree of urbanization and industrial environment influences the biological properties of
development. The content of Zn and Cd in street soils and groundwater, and causes pollution of the
dust was significantly influenced by transportation. food chain [6, 8, 9, 10]. At present, heavy metals
In Central Poland the pattern of heavy metals in can be found almost everywhere, in soil and in
street dust is according to the following series of food. The presence of street dust with heavy metals
decreasing values: Zn>Cu>Pb>Cd or causes that they are accumulated in human bodies
Zn>Pb>Cu>Cd. and thus become health hazards [8, 11, 12]. The
aim of the investigations was testing the content of
KEYWORDS: heavy metals in street dust from areas with diverse
Heavy metals, street dust, soil, urban development urban, industrial and transportation development,
located in Central Poland.

INTRODUCTION
MATERIAL AND METHODS
Development of human civilization influences
the increase of heavy metal content in soil, The investigations were conducted in Central
atmosphere and water, which may cause Poland (Fig. 1). Four objects differing in the degree
irreversible harmful effects in these environmental of urban, industrial and transportation development
elements. One of the sources of heavy metals in the were selected:
environment may also be street dust deposited on
the margins and surfaces of roads and streets [1, 2 ,
3, 4, 5, 6,7].

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FIGURE 1
Localization of investigate place

Object 1 – Warsaw city with the highest Object 3 – Karczew town situated about 40
degree of urban and transportation development km from Warsaw, characterized by a larger number
from among the selected objects, inhabited by about of enterprises than Wiązowna: foodstuffs, meat,
2 million resident and migrant population. The poultry, and dairy produce, production of plastics
investigations were conducted in 8 sites along roads and cables, wrapping, as well as printing, chemical
located in the Warszawa-Ursynów district with and iron-work enterprises;
intense traffic comprising motor cars and urban Object 4 – Lipsko town situated about 150 km
transportation. Worth noting is the fact that the from Warsaw, a town with high industrial
localities along the margins of the investigated development (production of sandwich panels, fruit
roads were subject to frequent sweeping and and vegetable production, dairy and meat produce,
washing; metal industry), surrounded by farmlands and
Object 2 – Wiązowna village with a low forests.
population density of 91 pop./km2 (average Three regions with low (nos. 1, 2, 3, 10, 11,
population in Poland: 124 pop./km2), situated about 12, 19, 20, 21), medium (nos. 4, 5, 6, 13, 14, 15, 22,
50 km from Warsaw; an agglomeration with 23, 24) and high (nos. 7, 8, 9, 16, 17, 18, 25, 26, 27)
recreationalservicehousing functions; traffic density were selected in each of the objects
(except Warsaw) (Table 1).

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TABLE 1
Content of heavy metals in street dust in localities outside Warsaw (mg∙kg -1).

Object no. Locality Zn Cu Pb Cd


1 Wiązowna 17.0 16.5 4.5 0.25
2 27.0 81.6 5.0 0.30
3 25.0 6.9 5.0 0.10
4 30.0 9.4 12.5 0.25
5 48.5 12.6 15.5 0.80
6 53.5 8.1 28.0 0.70
7 113.0 25.7 15.0 0.50
8 83.5 49.5 14.0 0.25
9 37.5 12.1 10.5 0.40
10 Karczew 30.0 9.35 12.5 0.40
11 74.0 48.8 8.0 0.28
12 89.0 62.6 233.2 0.32
13 44.0 112.9 28.0 0.36
14 63.0 137.7 28.0 0.29
15 94.0 49.8 15.6 0.40
16 95.0 22.6 12.0 0.56
17 132.0 67.0 93.6 0.68
18 52.0 52.6 9.2 0.42
19 Lipsko 44.4 8.6 9.4 0.28
20 88.8 15.0 37.8 0.66
21 71.6 20.2 24.6 0.38
22 91.6 22.0 21.0 0.44
23 95.4 20.9 34.0 0.54
24 101.2 36.0 30.8 0.54
25 182.0 32.2 34.4 1.1
26 211.0 30.1 42.2 0.8
27 253.6 31.2 42.8 0.9
Cv (%) 68.7 87.7 81.67 49.0

Regions with low traffic density included KCl was measured electrometrically, and after
roads running through forests, fields and housing mineralization in dry conditions in 480oC the
zones, entrance road to the municipal waste dump, material was dissolved in 20% HCl in an Ethos Plus
transportation stops, roads running through remote Melestone microwave digester. As a result,
areas and roads with small enterprises located along solutions of Zn, Cu, Pb and Cd forms soluble in
them. Roads with medium traffic density were 20% HCl were obtained. The content of the
located in the centres of the analyzed objects in investigated elements was determined using atomic
sites with medium density, including entrance roads adsorption spectrophotometry (AAS). Certified
to certain objects and state roads. Most sites with reference material EnviroMAT SS-2 was used for
high traffic density were located along the main each series of analyses.
entrance roads in the analyzed objects, The concordance of the obtained results with
characterized by everyday intense traffic density of reference material was at the level of 100%.
both motor cars and public transportation, with Assessment of the content of the elements in street
numerous enterprises, warehouses and housing dust was made by comparing the obtained results
objects. with the heavy metal content in soils considered as
the geochemical background for soils in Poland
Samples of street dust were collected to plastic [13], as well as by comparison to norms of the
bags from the road margins, from three points along Ministry of the Environment [14] Regulation of the
10 m of the selected sites. Minister of the Environment of 9th September 2001
The dust samples were dried, sieved through a on the soil quality standards and ground quality
perlon sieve with mesh size of 1 mm, and ground in standards, Journal of Laws, no. 165, pos. 1359 of
an agate mortar. In this material the pH value in 4th October 2002) for soils, because ranges for

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street dust have not been established. Range RESULTS


correlation analysis was used to assess the
relationships between particular heavy metals. The The pH values in the samples of street dust
analyses were conducted using Statgraphics 4.1 were approximately the same in the analyzed
software. objects; they varied between 7.3 and 8.9. Zn, Cu,
Pb and Cd contents in street dust collected from the
road margins of the analyzed objects were variable;
the mean contents of heavy metals for the entire
analyzed area were: 85.8 mgkg-1 for Zn, 35.55
mgkg-1 for Cu, 21.9 mgkg-1 for Pb and 0.76 mgkg-
1
for Cd (Tables 1 and 2).

TABLE 2
Mean contents of heavy metals in street dust in particular studied objects (mgkg-1)

Element Locality Range Mean value Mean for the Geochemical


entire area background
Zn Warszawa 70.70-126.0 93.5 17.0-253.6 5.0-59.0
Wiązowna 17.0-113.0 48.3
Karczew 30.0-132.0 74.8 85.8 30.0
Lipsko 44.0-253.6 126.6
Cu Warszawa 12.8-39.3 30.9 6.9-137.7 0.4-23.5
Wiązowna 6.9-81.6 24.7
Karczew 9.4-137.7 62.6 35.6 7.1
Lipsko 8.6-32.2 24.0
Pb Warszawa 13.5-29.8 20.3 4.5-233.2 0.5-21.0
Wiązowna 4.5-28.0 12.2
Karczew 8.0-93.6 24.2 21.9 9.8
(8.0-233.2)* (48.9)* (28.1)*
Lipsko 9.40-42.80 30.80
Cd Warszawa 0.45-1.95 1.60 0.10-1.95 0.03-1.00
Wiązowna 0.10-0.80 0.39 0.76 0.18
Karczew 0.28-0.68 0.41
Lipsko 0.28-1.10 0.64
Explanations: * calculated for mean value

In Warsaw, the content of zinc in street dust 26, 27) along which were situated industrial
collected from the margins of the streets near bus- enterprises and transportation routes – even 7 and 8
stops varied between 70.7 and 126.0 mgkg-1, and times (Tables 1 and 2). In Wiązowna and Karczew
attained averagely 93.5 mgkg-1. The content of zinc the street dust contained averagely less Zn than the
in Warsaw insignificantly varied among the street dust from Lipsko and Warsaw.
analyzed sites (Tables 2 and 3). The variability In areas outside Warsaw in some localities
coefficient was 21.6%. Higher amounts of zinc in (sites 7, 17, 24, 25, 26, 27), the Zn content in street
Warsaw were noted in sites where street dust was dust exceeded the admissible concentrations of this
not swept away frequently (sites 4, 5). The average element in natural and protected soils >100 mgkg-1
content of Zn in the street dust from Warsaw announced in the Journal of Laws by the Ministry
exceeded three times the geochemical background of the Environment in 2002 (tab.7). These sites
estimated for the soils of Poland [15] and exceeded include transportation routes with high density of
the average value obtained for all objects. motorcars and urban transportation, near which
In turn, in areas outside the Warsaw occurred services and production enterprises. The
agglomeration, the highest contents of zinc were variability coefficient for zinc in street dust
noted in street dust in Lipsko town located at the collected from areas outside Warsaw was
largest distance from Warsaw (Tables 1 and 2). In significantly higher and reached 68.7% (Table 1) in
Lipsko the content of Zn in street dust averagely comparison to the data from Warsaw (Table 3).
exceeded four times the geochemical background
for soils of Poland and in some localities (sites 25,

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TABLE 3
Heavy metal content in street dust collected from selected sites in Warsaw (mg∙kg -1)

No. Sites Zn Cu Pb Cd
1. At exit road from Warsaw 77.5 12.8 16.5 1.90
2. Bus-stop on Nowoursynowska Str. 70.7 25.2 14.2 0.45
3. Bus-stop on Nowoursynowska Str. 94.0 37.1 13.5 1.90
4. Corner of Ciszewskiego and 121.1 23.0 17.5 1.57
Anody streets
5. Entrance road to parking lot 126.0 32.5 29.8 1.40
6. Klinika bus-stop 94.5 39.3 22.5 1.85
7. Stary Ursynów bus-stop 81.5 16.1 19.1 1.75
8. Old campus near Economical 82.5 25.1 26.5 1.95
Building
Range 70.7 -126.0 12.8-39.3 13.5-29.8 0.45-1.95
Mean (93.5) (30.9) (20.3) (1.60)
Cv (%) 21.6 35.8 29.3 31.3

Comparison of the obtained Zn content with insignificantly and reached: 12.23; 20.30; 24.16;
the values given in literature reports from the last 30.8 mgkg-1, respectively (Table 2). The highest
10 years (Table 4) allows to conclude that the Zn content of lead in street dust (233.2 mgkg-1) was
content in Central Poland again reveals an uptrend. noted in Karczew (site 12) in a sample collected
This increase may be caused by the appearance of from the entrance road to the municipal waste dump
new zinc sources in the environment or the increase as well as in street dust collected from the main exit
of values from existing sources such as rise of road from this town surrounded on both sides by
transportation density and poor condition of the houses (site 17), and in Lipsko in street dust from
vehicles, road quality, increased number of housing roads adjacent to industrial enterprises (sites 25, 26,
and small enterprises. 27). The variability coefficient of lead in street dust
Copper in street dust varied in the from the area outside Warsaw was 81.67% and
investigated areas between 6.9 and 137.7 mgkg-1 higher than in Warsaw (Tables 1, 2, 3). In Warsaw
and clearly differed between the sampling localities the content of lead in street dust was rather
(Tables 1, 2, 3). In Warsaw, Wiązowna and Lipsko, invariable, which may be explained by a similar
the average values of Cu in street dust were similar traffic density, good quality of vehicles, similar
and lower than the average for the entire analyzed urban conditions as well as frequent road sweeping.
area. Only in Karczew situated 40 km from These measures largely caused decrease of the
Warsaw, averagely higher values of Cu were noted content of lead and other heavy metals in street
in street dust in comparison to the average for the dust. In Warsaw there is a lowest variability
entire analyzed area. Higher Cu contents were coefficient for lead in street dust (29.3%), which
observed in street dust collected from roads along suggests that the main source of lead pollution in
which were situated shops, industrial enterprises Warsaw is traffic (Table 2).
(e.g. poultrymeat produce or cable manufactory), The content of lead in street dust in Warsaw
along the entrance road to the municipal waste was about twice higher than the geochemical
dump and roads to other localities (sites: 2, 8, 11, background. The mean contents of Pb in street dust
12, 13, 14, 17, 18). In comparison to studies from Warsaw were similar to the content of lead in
conducted in 1998–2007 in Central Poland, the areas outside Warsaw (Table 2). In street dust
content of copper in street dust shows an uptrend collected in sites 12 and 17, lead content (50 mgkg-
(Table 4). The presented studies indicate that in 1
) exceeded values given by the Ministry of the
30% of the analyzed sites, street dust collected Environment for soils in natural and protected areas
outside Warsaw exceeded the norms for copper for (group A) tab.7.
type A soils given in the appendix to the Regulation Comparison of the obtained results with
of the Minister of the Environment from 2002 on earlier studies of street dust from Central Poland
the quality of soils and grounds reaching < 30 shows that from 2003 the content of lead in the
mgkg-1 Cu for unpolluted soils (group A), environment is maintained at a similar level (Table
(tab.7). 4).
The mean values of lead in street dust from The highest content of cadmium – averagely
Warsaw, Wiązowna, Karczew and Lipsko varied 1.60 mgkg-1 – was noted in street dust from

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Warsaw. The mean content of cadmium in street 3). As evidenced by the obtained results, the largest
dust from Warsaw exceeded the geochemical source of cadmium in the environment was traffic
background of this element (0.18 mgkg-1) almost as well as various industries.
10 times and showed low variability among the Earlier investigations [2, 16, 17] and the
particular sites (Tables 2 and 3). In turn, the content presented analyses of street dust indicate that the
of cadmium in street dust from areas outside mean content of cadmium in the environment in the
Warsaw was about 3 to 4 times lower than the study area is maintained at a similar level for the
content of cadmium in Warsaw (Tables 1 and 2). last 10 years (Table 4).
Usually, higher contents of cadmium in areas
outside Warsaw were noted in the vicinity of
various industrial enterprises (sites 25, 26, 27), as
well as in street dust collected from roads in
housing zones (sites 5 and 6). The variability
coefficient for cadmium in areas outside Warsaw
was 49.0% and similar to the variability coefficient
of street dust from Warsaw (31.3%) (Tables 1 and

TABLE 4
Changes in the heavy metal content in street dust in Warsaw and outside Warsaw during the last 10 years
based on the results of various authors and the soil geochemical background (mgkg-1)

Year Zn Cu Pb Cd
1998 * 230.9 (61-460) 57.4 (11-156) 79.9 (24-282) 0.95 ( 0.2-2.6)
2003 ** 63.6 (13-173) 30.6 (3-84) 33.8 (12-124) 0.67 (0.48-2.16)
2007*** 65 ( 22-133) 20.5 (6-62) 20.1 (8-72) 0.80 (0.46 - 1.34)
2012**** 85.8 (17.0-253.6) 35.6 (6.9-137.7) 21.9 (4.5-233.2) 0.76 (0.1-1.95)
28.1*
Background 30.0 (5.0-59.0) 7.1 (0.4-23.5) 9.8 (0.5-21.0) 0.18 (0.03-1.0)
* Czarnowska K., Bednarz I. (2000)
** Kozanecka T., Czarnowska K., Jaworska A. (2003)
*** Kozanecka T., Czarnowska K., Łaszczyk K. (2007
**** this report

The calculated range coefficients between the significantly influenced the increased content of
content of particular heavy metals in street dust cadmium and lead. This causes that in these areas
from areas outside the Warsaw agglomeration have the increased supply of one of these elements at the
shown positive relationships between Zn and Pb, same time contributed to the increase of the content
Zn and Cd as well as Pb and Cd (Table 5). The of each of these elements in street dust.
increase of zinc content in street dust has

TABLE 5
Rank correlation coefficients between the content of particular heavy metals in street dust from outside
Warsaw

Zn Cu Pb Cd
Zn 1.000 0.347 0.725* 0.689*
Cu 0.347 1.000 0.290 0.008
Pb 0.725* 0.290 1.000 0.630*
Cd 0.689* 0.008 0.630* 1.000
* statistically significant correlations at the level P=0.05

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TABLE 6
Mean values reflected as average and median values (in parentheses) of the heavy metal content in street
dust from sites with variable traffic density outside Warsaw (mgkg-1)*

Traffic density Zn Cu Pb Cd
low 51.87 (44.4)a 29.95 (16.5)a 37.78 (9.4)a 0.33 (0.30)a
medium 69.02 (63.0)a 45.49 (22.0)a 23.71 (28.0)a 0.48 (0.44)a
high 128.84 (113.0)b 35.89 (31.2)a 30.41 (15.0)a 0.62 (0.56)a
*The different letters refer to statistically significant differences between various levels of traffic density
(statistically significant differences were noted only for Zn).

It has also been observed that the traffic industrial town in China [18]. The high variability
density in a given area variously influenced the coefficient for Zn indicates that the content of Zn in
heavy metal content in street dust (Table 6). The street dust is influenced by many factors, such as
content of Zn in street dust was significantly higher e.g. technical quality of vehicles, quality of petrol,
in sites with high traffic density in comparison to technical condition of the machines, equipment and
objects with low or medium traffic density. In turn, chimney channels, road quality and other local
the development of urbanization and traffic did not factors.
significantly influence the increase of the Cu, Pb The variability of these factors has impact on
and Cd contents. It should be emphasized than in the increase of zinc in the environment, as
the case of cadmium, its content rises with the evidenced by the presented investigations. In the
development of traffic and industry. study area, the content of copper is lower than the
content of zinc in comparison to data from other
countries [19]. The maximal content of copper
DISCUSSION (137.7 mgkg-1) in street dust noted in the area with
the waste dump was close to the values obtained in
The presented investigations show that the Madrid (188 mgkg-1) [20] (167 mgkg-1) [21], and
heavy metal content in street dust from Central was 10 times lower than in Istanbul (1385 mgkg-1)
Poland was variable and did not depend on the [3]. The mean contents of Cu in street dust from
agglomeration size. A lower content of Zn was Central Poland are close to those noted in Accra,
usually observed in Warsaw, which is the largest Ghana (2976 mgkg-1) [5].
agglomeration, with a high degree of urban and Despite a high variability coefficient, the
traffic development and in small localities, located content of Cu in street dust from Central Poland is
close to Warsaw, whereas higher contents of Zn maintained at a similar level for the last 10 years
were noted in Lipsko, which is located at the largest with a slight uptrend.
distance from the Warsaw agglomeration. These Lead is not an element that is indispensable
results can be explained by the differences in the for the physiological functions of organisms and its
quality of the technical condition of the vehicles, values exceeding the geochemical background pose
industrial enterprises and better road pavements in a hazard to the environment. The presented
Warsaw in comparison to areas outside Warsaw. As investigations have shown similar contents of these
indicated by the investigations of Al-Khashmann elements in street dust in the studied areas. The
[3], significant Zn sources in Jordan in the maximal content of Pb in street dust (233.2 mgkg-
Industrial Centre at Karak were transportation and 1
) from the entrance road to the waste dump is a
car services, quality of car carburettors, iron-works, hazard for the environment and the population. In
steelworks, heaters, aluminium industry and most sites of the study areas, the content of lead in
housing. These anthropogenic factors influenced street dust has almost twice exceeded the
also the high correlation between the content of Zn background for soils in Poland. Similar
and Pb, which is evidenced also by the results of relationships were noted by Atiemo [5] in Accra,
this report. The maximal contents of Zn (253.6 Ghana. A low variability coefficient for lead in
mgkg-1) in street dust in our investigations are Warsaw suggests that the main factor influencing
similar to those obtained in Jordan (123 mgkg-1) lead content in street dust is the quality of vehicles
[3], and Accra in Ghana (213.0; 371.0 mgkg-1) [5]. and the applied petrol. It is worth noting that
In turn the mean content of Zn (85.50 mgkg1) in sweeping of dust from the street margins
Central Poland is similar to the mean value in an significantly influences the decrease of Pb in the

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environment. These studies show that the the content in other European cities, e.g. 1.4 mgkg-
development and intensification of traffic did not 1
Cd were noted in Oslo [20].
increase the content of lead in street dust during the The content of heavy metals in street dust
last 10 years in the studied sites in Central Poland. in the study area followed a pattern according to the
The obtained results show that the decreasing values (mean values in mgkg-1): Zn
development of transportation and heavy industry (85.8) > Cu (35.5) > Pb (21.9) > Cd (0.76). Such
(steelworks, electric industry, urbanization, etc.) pattern of heavy metals in street dust was
significantly influences the zinc content and characteristic for the Warsaw agglomeration as well
statistically insignificantly influences the content of as smaller localities such as Wiązowna and
Cd in street dust, which is also confirmed by the Karczew.
results of other authors [3,4]. The only exception was the area of Lipsko,
The investigations show that the content of located at the largest distance from Warsaw, where
cadmium in street dust in the study area depended the heavy metals from street dust followed a pattern
on the agglomeration size. In comparison to the according to the decreasing quantities (mean values
geochemical background, the increase of cadmium in mgkg-1): Zn (126.6) > Pb (30.8) > Cu (24.0) >
in Warsaw was the highest, almost 10 times higher, Cd (0.64). This series of heavy metals in street dust
whereas in towns located at the largest distances is similar to the series of metals occurring in arable
from Warsaw, this increase varied from 2 to 5 soils situated close to communication routes and
times. These data indicate that the circulation of subject to strong anthropopression, and in street
cadmium in the environment is influenced mainly dust from Warsaw.(Table 7) [1, 22].
by the development of urbanization, industry and
traffic. The content of Cd in street dust from
Warsaw in comparison to other reports is similar to

TABLE 7
Regulation of the Minister of the Environment of 9 September 2001 on the soil quality standards and
ground quality standards. Journal of Laws, no. 165, pos. 1359 of 4 October 2002

Allowable concentrations
of heavy metals in soils
Regulation of the Minister of the Environment of 9 October 2002
Heavy (mgkg-1 )
metals Group A Group B Group C
Depth in m; C in ppt
0-0,3 0-2
As 20 20 60
Ba 200 200 1000
Cr 50 150 500
Sn 20 20 350
Zn 100 300 1000
Cd 1 4 15
Co 20 20 200
Cu 30 150 600
Mo 10 10 250
Ni 35 100 300
Pb 50 100 600
Hg 0,5 2 30
• A- land in an area subjected protection, B-land classified as agricultural land except land under ponds and
ditches, woodlands and urban and built-up (without the industrial areas of arable lands fossil and
communication), C industrial areas, utilities and fossil sites

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CONCLUSIONS heavy metals in street dust from small towns


in Yongchuan, Chongqing. Fresen Environ
Street dust may be a good indicator to assess Bull.22, 556-560.
changes occurring in various urban and rural [9] Wei N, Yang L. 2010, A review of heavy
environments, areas with a variable degree of metal contaminations in urban soils, urban
industrialization and different traffic density. The road dusts and agricultural soils from China,
content of Zn, Cu, Pb, and Cd in street dust usually Microchemical Journal, 94: 99-107.
did not depend on the agglomeration size but on the [10] Marazioti C., Maramathas C., Marazioti
degree of urbanization and industrialization as well P.,Maraziotis E. 2009, Multi-element
as traffic density. The type, technical condition and composition of airborne particulate matter in
number of vehicles significantly influenced the the patras urban area, Greece. Fresen Environ
content of Zn and Cd in street dust. Likewise, Bull.18, 960-9679960-.8, 6: 960-967.
frequent road sweeping contribute to the decrease [11] Papas D., Efstathiou G.A., Zoumakis N.M.,
of the heavy metal content in street dust. In Central Koutroubelis S., Apostolos G. Kelessis A.G.,
Poland the content of the analyzed heavy metals is Petrakakis M.J. 2010, Modelling of traffic
according to the following patterns of decreasing pollution at an urban site using a microscale
values: Zn (85.8) > Cu (35.5) > Pb (21.9) > Cd CFD dispersion model. Fresen Environ
(0.76) or Zn (126.6) > Pb (30.8) > Cu (24.0) > Cd Bull.19,1997-2001 6:
(0.64). [12] Wyszkowska J., Borowik A., Kucharski M. ,
Kucharski J. 2013, Effect of cadmium, copper,
and zinc on plants, Soil microorganisms and
REFERENCES soil enzymes. J. Elem.769–796
[13] Kwasowski W., Kozanecka T. 2010.
Evaluation of the content of zinc and lead in
[1] Czarnowska K., Bednarz I. 2000. Heavy
selected vegetative organs of potatoes
metals in street dust from Warsaw, 51: 29-36.
(Solanum tuberosum) growing in the vicinity
[2] Kozanecka T., Czarnowska K., Jaworska A.
2003. Content of heavy metals in road of the Warszawa- Poznań speedway. Fresen
coarse dust of Warsaw environs. Soil science Environ Bull, 19, 378-382
[14] Kozanecka T., Kazem-Bek A., Czarnowska
yearbooks, 54: (3): 73-78.
K., Kwasowski W. 2010. Application of algae
[3] Al-Kashman O. 2000. Heavy metal
and lichens in the monitoring of changes in the
distribution in dust, street dust and soils from
the work place in Karak Industrial Estate, natural environment. Fresen Environ Bull, 19,
Jordan. Atmospheric Environment, 38: 6803- 553-557.
[15] Plum L.M, Rink L., Haase H. 2010. The
6812.
essential toxin: impact of zinc on human
[4] Shi Xingmin, Chen L., Wang J. 2013.
health, Int. J. Environ. Res. Public Health 7,
Multivariate analysis of heavy metal pollution
1342-1365
in street dusts of Xianyang city, NW China.
Environ. Earth Sci. 69, 1973-1979. [16] Xue Xu, Xinwei Lu, Xiufeng Han, Ni Zhao.
[5] Atiemo M.S., Ofosu G.F, Kuranchie-Mensah 2015. Ecological and health risk assessment of
metal in resuspended particles of urban street
H., Tutu A.O, Palm N.D.M., Blankson A.
dust from an industrial city in China.
2011. Contamination assessment of heavy
CURRENT SCIENCE, 108. 72: (1):72-79.
metals in road dust from selected roads in
[17] Czarnowska K. 1996. Total content of heavy
Accra, Ghana. Research Journal of
Environmental and Earth Sciences, 3; (5): metals in bedrocks as the geochemical
473-480. background of soils. Soil Science Yearbooks
57, 43-50.
[6] Yap C.K., Chew W.Y., Tan S.G. 2012, Heavy
[18] Regulation of the Minister of the Environment
metal concentrations in Ceilling Fan and
of 9 September 2001 on the soil quality
Roadside car park dust collected from
standards and ground quality standards.
residential colleges in university Putra
Malaysia, Serdang, Selangor. Pertanika J. Journal of Laws, no. 165, pos. 1359 of 4
Trop. Agric. Sci. 35: (1): 75-83. October 2002.
[19] Wyszkowska J., Kucharski J., Lajszner W.
[7] Zhang B., Luo B., Jiang T., Mei Z. 2014,
2006. The effects of copper on soil
Concentration of nutrients in street dusts of
biochemical properties and its interaction with
mega-city, chengdu, Southwest China.
Fresen.Environ.Bull. 23: 2239-224. other heavy metals. Polish J. of Environ. Stud.
[8] Wang S.M., Li Q., Wang Z.D., Gao X. 2013, 15: (6): 927-934.
Concentration distribution and composition of

111
by PSP Volume 25 – No. 1/ 2016, pages 103-112 Fresenius Environmental Bulletin

[20] Xue Xu, Xinwei Lu, Xiufeng Han, Ni Zhao.


Ecological and health risk assessment of metal
in resuspended particles of urban street dust
from an industrial city in China. 2015,
CURRENT SCIENCE, 108. 72 1, (2015),
p.72-79;
[21] Kozanecka T., Czarnowska K., Łaszczyk K.
2007. Content of trace elements in street dust
from the ZegrzeMrągowo road. Soil science
yearbooks 32: (1): 140-144.
[22] Wang G., Oldfield F., Xia D., Zhang W. 2012.
Magnetic properties and correlation with
heavy metals in urban street dust. A case study
from the city of Lanzhou, China, Atmospheric
Environment, 46: 289-298
[23] Yongming H, Peixuan D, Jungi C, Posmentier
E. S. 2006. Multivariate analysis of heavy
metal contamination in urban dusts of Xi’an,
Central China. Sci Total Environ, 355: 176-
186.
[24] Miguel D.E., Llamas J.F., Cghacon E., Berg
T., Larssen S., Royset O., Vadset M. 1997,
Origin and patterns of distribution of trace
elements in street dust: unleaded petrol and
urban lead. Atmospheric Environment. 31:
2733-2740.
[25] Sutherland T.A., Tolosa C., 2000. Multi-
element analysis of road deposited sediment in
urban drainage basin, Honolulu, Hawaii.
Environ. Pollution. 110: 483-495.
[26] Czarnowska K., Chlibiuk M., Kozanecka T.
2002. Trace elements in arable soils along
roads around Warsaw. Soil Science Yearbooks
53, 67-74.

Received: 10.06.2015
Accepted: 26.11.2015

CORRESPONDING AUTHOR

Pawel Kowalczyk
Bionicum LTD
Chełmska 21
00-724 Warsaw – POLAND

e-mail:pawel.kowalczyk@bionicum.com.pl

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