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INTRODUCTION
MATERIAL AND METHODS
Development of human civilization influences
the increase of heavy metal content in soil, The investigations were conducted in Central
atmosphere and water, which may cause Poland (Fig. 1). Four objects differing in the degree
irreversible harmful effects in these environmental of urban, industrial and transportation development
elements. One of the sources of heavy metals in the were selected:
environment may also be street dust deposited on
the margins and surfaces of roads and streets [1, 2 ,
3, 4, 5, 6,7].
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FIGURE 1
Localization of investigate place
Object 1 – Warsaw city with the highest Object 3 – Karczew town situated about 40
degree of urban and transportation development km from Warsaw, characterized by a larger number
from among the selected objects, inhabited by about of enterprises than Wiązowna: foodstuffs, meat,
2 million resident and migrant population. The poultry, and dairy produce, production of plastics
investigations were conducted in 8 sites along roads and cables, wrapping, as well as printing, chemical
located in the Warszawa-Ursynów district with and iron-work enterprises;
intense traffic comprising motor cars and urban Object 4 – Lipsko town situated about 150 km
transportation. Worth noting is the fact that the from Warsaw, a town with high industrial
localities along the margins of the investigated development (production of sandwich panels, fruit
roads were subject to frequent sweeping and and vegetable production, dairy and meat produce,
washing; metal industry), surrounded by farmlands and
Object 2 – Wiązowna village with a low forests.
population density of 91 pop./km2 (average Three regions with low (nos. 1, 2, 3, 10, 11,
population in Poland: 124 pop./km2), situated about 12, 19, 20, 21), medium (nos. 4, 5, 6, 13, 14, 15, 22,
50 km from Warsaw; an agglomeration with 23, 24) and high (nos. 7, 8, 9, 16, 17, 18, 25, 26, 27)
recreationalservicehousing functions; traffic density were selected in each of the objects
(except Warsaw) (Table 1).
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TABLE 1
Content of heavy metals in street dust in localities outside Warsaw (mg∙kg -1).
Regions with low traffic density included KCl was measured electrometrically, and after
roads running through forests, fields and housing mineralization in dry conditions in 480oC the
zones, entrance road to the municipal waste dump, material was dissolved in 20% HCl in an Ethos Plus
transportation stops, roads running through remote Melestone microwave digester. As a result,
areas and roads with small enterprises located along solutions of Zn, Cu, Pb and Cd forms soluble in
them. Roads with medium traffic density were 20% HCl were obtained. The content of the
located in the centres of the analyzed objects in investigated elements was determined using atomic
sites with medium density, including entrance roads adsorption spectrophotometry (AAS). Certified
to certain objects and state roads. Most sites with reference material EnviroMAT SS-2 was used for
high traffic density were located along the main each series of analyses.
entrance roads in the analyzed objects, The concordance of the obtained results with
characterized by everyday intense traffic density of reference material was at the level of 100%.
both motor cars and public transportation, with Assessment of the content of the elements in street
numerous enterprises, warehouses and housing dust was made by comparing the obtained results
objects. with the heavy metal content in soils considered as
the geochemical background for soils in Poland
Samples of street dust were collected to plastic [13], as well as by comparison to norms of the
bags from the road margins, from three points along Ministry of the Environment [14] Regulation of the
10 m of the selected sites. Minister of the Environment of 9th September 2001
The dust samples were dried, sieved through a on the soil quality standards and ground quality
perlon sieve with mesh size of 1 mm, and ground in standards, Journal of Laws, no. 165, pos. 1359 of
an agate mortar. In this material the pH value in 4th October 2002) for soils, because ranges for
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TABLE 2
Mean contents of heavy metals in street dust in particular studied objects (mgkg-1)
In Warsaw, the content of zinc in street dust 26, 27) along which were situated industrial
collected from the margins of the streets near bus- enterprises and transportation routes – even 7 and 8
stops varied between 70.7 and 126.0 mgkg-1, and times (Tables 1 and 2). In Wiązowna and Karczew
attained averagely 93.5 mgkg-1. The content of zinc the street dust contained averagely less Zn than the
in Warsaw insignificantly varied among the street dust from Lipsko and Warsaw.
analyzed sites (Tables 2 and 3). The variability In areas outside Warsaw in some localities
coefficient was 21.6%. Higher amounts of zinc in (sites 7, 17, 24, 25, 26, 27), the Zn content in street
Warsaw were noted in sites where street dust was dust exceeded the admissible concentrations of this
not swept away frequently (sites 4, 5). The average element in natural and protected soils >100 mgkg-1
content of Zn in the street dust from Warsaw announced in the Journal of Laws by the Ministry
exceeded three times the geochemical background of the Environment in 2002 (tab.7). These sites
estimated for the soils of Poland [15] and exceeded include transportation routes with high density of
the average value obtained for all objects. motorcars and urban transportation, near which
In turn, in areas outside the Warsaw occurred services and production enterprises. The
agglomeration, the highest contents of zinc were variability coefficient for zinc in street dust
noted in street dust in Lipsko town located at the collected from areas outside Warsaw was
largest distance from Warsaw (Tables 1 and 2). In significantly higher and reached 68.7% (Table 1) in
Lipsko the content of Zn in street dust averagely comparison to the data from Warsaw (Table 3).
exceeded four times the geochemical background
for soils of Poland and in some localities (sites 25,
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TABLE 3
Heavy metal content in street dust collected from selected sites in Warsaw (mg∙kg -1)
No. Sites Zn Cu Pb Cd
1. At exit road from Warsaw 77.5 12.8 16.5 1.90
2. Bus-stop on Nowoursynowska Str. 70.7 25.2 14.2 0.45
3. Bus-stop on Nowoursynowska Str. 94.0 37.1 13.5 1.90
4. Corner of Ciszewskiego and 121.1 23.0 17.5 1.57
Anody streets
5. Entrance road to parking lot 126.0 32.5 29.8 1.40
6. Klinika bus-stop 94.5 39.3 22.5 1.85
7. Stary Ursynów bus-stop 81.5 16.1 19.1 1.75
8. Old campus near Economical 82.5 25.1 26.5 1.95
Building
Range 70.7 -126.0 12.8-39.3 13.5-29.8 0.45-1.95
Mean (93.5) (30.9) (20.3) (1.60)
Cv (%) 21.6 35.8 29.3 31.3
Comparison of the obtained Zn content with insignificantly and reached: 12.23; 20.30; 24.16;
the values given in literature reports from the last 30.8 mgkg-1, respectively (Table 2). The highest
10 years (Table 4) allows to conclude that the Zn content of lead in street dust (233.2 mgkg-1) was
content in Central Poland again reveals an uptrend. noted in Karczew (site 12) in a sample collected
This increase may be caused by the appearance of from the entrance road to the municipal waste dump
new zinc sources in the environment or the increase as well as in street dust collected from the main exit
of values from existing sources such as rise of road from this town surrounded on both sides by
transportation density and poor condition of the houses (site 17), and in Lipsko in street dust from
vehicles, road quality, increased number of housing roads adjacent to industrial enterprises (sites 25, 26,
and small enterprises. 27). The variability coefficient of lead in street dust
Copper in street dust varied in the from the area outside Warsaw was 81.67% and
investigated areas between 6.9 and 137.7 mgkg-1 higher than in Warsaw (Tables 1, 2, 3). In Warsaw
and clearly differed between the sampling localities the content of lead in street dust was rather
(Tables 1, 2, 3). In Warsaw, Wiązowna and Lipsko, invariable, which may be explained by a similar
the average values of Cu in street dust were similar traffic density, good quality of vehicles, similar
and lower than the average for the entire analyzed urban conditions as well as frequent road sweeping.
area. Only in Karczew situated 40 km from These measures largely caused decrease of the
Warsaw, averagely higher values of Cu were noted content of lead and other heavy metals in street
in street dust in comparison to the average for the dust. In Warsaw there is a lowest variability
entire analyzed area. Higher Cu contents were coefficient for lead in street dust (29.3%), which
observed in street dust collected from roads along suggests that the main source of lead pollution in
which were situated shops, industrial enterprises Warsaw is traffic (Table 2).
(e.g. poultrymeat produce or cable manufactory), The content of lead in street dust in Warsaw
along the entrance road to the municipal waste was about twice higher than the geochemical
dump and roads to other localities (sites: 2, 8, 11, background. The mean contents of Pb in street dust
12, 13, 14, 17, 18). In comparison to studies from Warsaw were similar to the content of lead in
conducted in 1998–2007 in Central Poland, the areas outside Warsaw (Table 2). In street dust
content of copper in street dust shows an uptrend collected in sites 12 and 17, lead content (50 mgkg-
(Table 4). The presented studies indicate that in 1
) exceeded values given by the Ministry of the
30% of the analyzed sites, street dust collected Environment for soils in natural and protected areas
outside Warsaw exceeded the norms for copper for (group A) tab.7.
type A soils given in the appendix to the Regulation Comparison of the obtained results with
of the Minister of the Environment from 2002 on earlier studies of street dust from Central Poland
the quality of soils and grounds reaching < 30 shows that from 2003 the content of lead in the
mgkg-1 Cu for unpolluted soils (group A), environment is maintained at a similar level (Table
(tab.7). 4).
The mean values of lead in street dust from The highest content of cadmium – averagely
Warsaw, Wiązowna, Karczew and Lipsko varied 1.60 mgkg-1 – was noted in street dust from
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Warsaw. The mean content of cadmium in street 3). As evidenced by the obtained results, the largest
dust from Warsaw exceeded the geochemical source of cadmium in the environment was traffic
background of this element (0.18 mgkg-1) almost as well as various industries.
10 times and showed low variability among the Earlier investigations [2, 16, 17] and the
particular sites (Tables 2 and 3). In turn, the content presented analyses of street dust indicate that the
of cadmium in street dust from areas outside mean content of cadmium in the environment in the
Warsaw was about 3 to 4 times lower than the study area is maintained at a similar level for the
content of cadmium in Warsaw (Tables 1 and 2). last 10 years (Table 4).
Usually, higher contents of cadmium in areas
outside Warsaw were noted in the vicinity of
various industrial enterprises (sites 25, 26, 27), as
well as in street dust collected from roads in
housing zones (sites 5 and 6). The variability
coefficient for cadmium in areas outside Warsaw
was 49.0% and similar to the variability coefficient
of street dust from Warsaw (31.3%) (Tables 1 and
TABLE 4
Changes in the heavy metal content in street dust in Warsaw and outside Warsaw during the last 10 years
based on the results of various authors and the soil geochemical background (mgkg-1)
Year Zn Cu Pb Cd
1998 * 230.9 (61-460) 57.4 (11-156) 79.9 (24-282) 0.95 ( 0.2-2.6)
2003 ** 63.6 (13-173) 30.6 (3-84) 33.8 (12-124) 0.67 (0.48-2.16)
2007*** 65 ( 22-133) 20.5 (6-62) 20.1 (8-72) 0.80 (0.46 - 1.34)
2012**** 85.8 (17.0-253.6) 35.6 (6.9-137.7) 21.9 (4.5-233.2) 0.76 (0.1-1.95)
28.1*
Background 30.0 (5.0-59.0) 7.1 (0.4-23.5) 9.8 (0.5-21.0) 0.18 (0.03-1.0)
* Czarnowska K., Bednarz I. (2000)
** Kozanecka T., Czarnowska K., Jaworska A. (2003)
*** Kozanecka T., Czarnowska K., Łaszczyk K. (2007
**** this report
The calculated range coefficients between the significantly influenced the increased content of
content of particular heavy metals in street dust cadmium and lead. This causes that in these areas
from areas outside the Warsaw agglomeration have the increased supply of one of these elements at the
shown positive relationships between Zn and Pb, same time contributed to the increase of the content
Zn and Cd as well as Pb and Cd (Table 5). The of each of these elements in street dust.
increase of zinc content in street dust has
TABLE 5
Rank correlation coefficients between the content of particular heavy metals in street dust from outside
Warsaw
Zn Cu Pb Cd
Zn 1.000 0.347 0.725* 0.689*
Cu 0.347 1.000 0.290 0.008
Pb 0.725* 0.290 1.000 0.630*
Cd 0.689* 0.008 0.630* 1.000
* statistically significant correlations at the level P=0.05
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TABLE 6
Mean values reflected as average and median values (in parentheses) of the heavy metal content in street
dust from sites with variable traffic density outside Warsaw (mgkg-1)*
Traffic density Zn Cu Pb Cd
low 51.87 (44.4)a 29.95 (16.5)a 37.78 (9.4)a 0.33 (0.30)a
medium 69.02 (63.0)a 45.49 (22.0)a 23.71 (28.0)a 0.48 (0.44)a
high 128.84 (113.0)b 35.89 (31.2)a 30.41 (15.0)a 0.62 (0.56)a
*The different letters refer to statistically significant differences between various levels of traffic density
(statistically significant differences were noted only for Zn).
It has also been observed that the traffic industrial town in China [18]. The high variability
density in a given area variously influenced the coefficient for Zn indicates that the content of Zn in
heavy metal content in street dust (Table 6). The street dust is influenced by many factors, such as
content of Zn in street dust was significantly higher e.g. technical quality of vehicles, quality of petrol,
in sites with high traffic density in comparison to technical condition of the machines, equipment and
objects with low or medium traffic density. In turn, chimney channels, road quality and other local
the development of urbanization and traffic did not factors.
significantly influence the increase of the Cu, Pb The variability of these factors has impact on
and Cd contents. It should be emphasized than in the increase of zinc in the environment, as
the case of cadmium, its content rises with the evidenced by the presented investigations. In the
development of traffic and industry. study area, the content of copper is lower than the
content of zinc in comparison to data from other
countries [19]. The maximal content of copper
DISCUSSION (137.7 mgkg-1) in street dust noted in the area with
the waste dump was close to the values obtained in
The presented investigations show that the Madrid (188 mgkg-1) [20] (167 mgkg-1) [21], and
heavy metal content in street dust from Central was 10 times lower than in Istanbul (1385 mgkg-1)
Poland was variable and did not depend on the [3]. The mean contents of Cu in street dust from
agglomeration size. A lower content of Zn was Central Poland are close to those noted in Accra,
usually observed in Warsaw, which is the largest Ghana (2976 mgkg-1) [5].
agglomeration, with a high degree of urban and Despite a high variability coefficient, the
traffic development and in small localities, located content of Cu in street dust from Central Poland is
close to Warsaw, whereas higher contents of Zn maintained at a similar level for the last 10 years
were noted in Lipsko, which is located at the largest with a slight uptrend.
distance from the Warsaw agglomeration. These Lead is not an element that is indispensable
results can be explained by the differences in the for the physiological functions of organisms and its
quality of the technical condition of the vehicles, values exceeding the geochemical background pose
industrial enterprises and better road pavements in a hazard to the environment. The presented
Warsaw in comparison to areas outside Warsaw. As investigations have shown similar contents of these
indicated by the investigations of Al-Khashmann elements in street dust in the studied areas. The
[3], significant Zn sources in Jordan in the maximal content of Pb in street dust (233.2 mgkg-
Industrial Centre at Karak were transportation and 1
) from the entrance road to the waste dump is a
car services, quality of car carburettors, iron-works, hazard for the environment and the population. In
steelworks, heaters, aluminium industry and most sites of the study areas, the content of lead in
housing. These anthropogenic factors influenced street dust has almost twice exceeded the
also the high correlation between the content of Zn background for soils in Poland. Similar
and Pb, which is evidenced also by the results of relationships were noted by Atiemo [5] in Accra,
this report. The maximal contents of Zn (253.6 Ghana. A low variability coefficient for lead in
mgkg-1) in street dust in our investigations are Warsaw suggests that the main factor influencing
similar to those obtained in Jordan (123 mgkg-1) lead content in street dust is the quality of vehicles
[3], and Accra in Ghana (213.0; 371.0 mgkg-1) [5]. and the applied petrol. It is worth noting that
In turn the mean content of Zn (85.50 mgkg1) in sweeping of dust from the street margins
Central Poland is similar to the mean value in an significantly influences the decrease of Pb in the
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environment. These studies show that the the content in other European cities, e.g. 1.4 mgkg-
development and intensification of traffic did not 1
Cd were noted in Oslo [20].
increase the content of lead in street dust during the The content of heavy metals in street dust
last 10 years in the studied sites in Central Poland. in the study area followed a pattern according to the
The obtained results show that the decreasing values (mean values in mgkg-1): Zn
development of transportation and heavy industry (85.8) > Cu (35.5) > Pb (21.9) > Cd (0.76). Such
(steelworks, electric industry, urbanization, etc.) pattern of heavy metals in street dust was
significantly influences the zinc content and characteristic for the Warsaw agglomeration as well
statistically insignificantly influences the content of as smaller localities such as Wiązowna and
Cd in street dust, which is also confirmed by the Karczew.
results of other authors [3,4]. The only exception was the area of Lipsko,
The investigations show that the content of located at the largest distance from Warsaw, where
cadmium in street dust in the study area depended the heavy metals from street dust followed a pattern
on the agglomeration size. In comparison to the according to the decreasing quantities (mean values
geochemical background, the increase of cadmium in mgkg-1): Zn (126.6) > Pb (30.8) > Cu (24.0) >
in Warsaw was the highest, almost 10 times higher, Cd (0.64). This series of heavy metals in street dust
whereas in towns located at the largest distances is similar to the series of metals occurring in arable
from Warsaw, this increase varied from 2 to 5 soils situated close to communication routes and
times. These data indicate that the circulation of subject to strong anthropopression, and in street
cadmium in the environment is influenced mainly dust from Warsaw.(Table 7) [1, 22].
by the development of urbanization, industry and
traffic. The content of Cd in street dust from
Warsaw in comparison to other reports is similar to
TABLE 7
Regulation of the Minister of the Environment of 9 September 2001 on the soil quality standards and
ground quality standards. Journal of Laws, no. 165, pos. 1359 of 4 October 2002
Allowable concentrations
of heavy metals in soils
Regulation of the Minister of the Environment of 9 October 2002
Heavy (mgkg-1 )
metals Group A Group B Group C
Depth in m; C in ppt
0-0,3 0-2
As 20 20 60
Ba 200 200 1000
Cr 50 150 500
Sn 20 20 350
Zn 100 300 1000
Cd 1 4 15
Co 20 20 200
Cu 30 150 600
Mo 10 10 250
Ni 35 100 300
Pb 50 100 600
Hg 0,5 2 30
• A- land in an area subjected protection, B-land classified as agricultural land except land under ponds and
ditches, woodlands and urban and built-up (without the industrial areas of arable lands fossil and
communication), C industrial areas, utilities and fossil sites
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Received: 10.06.2015
Accepted: 26.11.2015
CORRESPONDING AUTHOR
Pawel Kowalczyk
Bionicum LTD
Chełmska 21
00-724 Warsaw – POLAND
e-mail:pawel.kowalczyk@bionicum.com.pl
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