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End of Question 1
C=N
N=N
N≡N
C≡N
What is a chromophore?
A coloured compound.
herbicides
birdicides
aviacides
miticides
c) Non-monochromatic radiation
a) Hypochromic
b) Hyperchromic
c) Hypsochromic
d) Bathochromic
The wavenumber of a transition is 2000 cm–1. In what part of the electromagnetic spectrum does this
come?
Infrared.
Ultraviolet-visible.
Radiowave.
Microwave.
According to the Beer-Lambert Law, on which of the following does absorbance not depend?
Solution concentration.
The principles of green chemistry include the eliminating the ________ treatments.
a) Costly
b) Harmful
c) Hard
d) Easy
Green chemistry applies across the __________ of a chemical product like design, manufacture and use.
a) Life cycle
b) Properties
c) Uses
d) Efficiency
a) Low efficiency
a) Structural investigation
Which of the following transitions are of weak intensities and lie in the visible region?
a) n→n*
b) σ→σ*
c) π→π*
d) n→σ*
a) –OH
b) –SH
c) –OR
d) –O2
Covalent bonding
Non-covalent bonding
Atomic forces
Thermodynamics
4. Supramolecules are very common in nature, which of the following is an example of a supramolecule?
Caffeine
Glucose
DNA
Thymine
Van der Waal's forces are insignificant in supramolecular chemistry due to the fact that they are very
weak.
True
False
7. Using the appropriate supramolecular host, it is possible to bind which of these guests?
Anions
All of these
Cations
Neutral species
8. What type of guest would a crown ether (essentially a cyclic poly ether) be able to bind?
Cations
Neutral species
Anions
There is a lot of interest in the area of supramolecular catalysis at the moment, why is this?
It would be useful for cutting down on the amount of solvent in the reaction and hence decreases costs.
This is of particular significance to large scale industrial processes.
It would allow very efficient and stereoselective catalysis of often very difficult reactions.
It is thought that a supramolecular catalyst would be capable of replacing catalytic metals in reactions,
thereby reducing cost while increasing efficiency.
There is actually very little interest in this area, due to the fact that it is very difficult to make a
supramolecular catalyst.
The 'lock-and-key' principle states that it is possible to bind any guest if the host is big enough.
True
False
How many signals does the aldehyde (CH3)3CCH2CHO have in 1H NMR and 13C NMR spectra?
Fluorine is monotopic (19F). What would you expect to see in the mass spectrum of F2?
The spectrum contains peaks at m/z = 38 and 19, and these are probably of different intensities.
Which of hydrogens a-d in the following molecule gives a triplet signal in a normal 1H NMR spectrum?
a) hydrogen a
b) hydrogen b
c) hydrogen c
d) hydrogen d
Which of (a)-(d) indicates the correct order of carbon chemical shifts of the four carbons of the following
compound.
a) C1
b) C2
c) C4
d) C6
Which carbon of (a)-(d) of hex-3-en-2-one shows the largest (most downfield) chemical shift
in the NMR spectrum?
a) C1
b) C2
c) C4
d) C6
Which carbon of (a)-(d) of hex-3-en-2-one shows the largest (most downfield) chemical shift
in the NMR spectrum?
Your answer:
c) Molecular vibrations are due to periodic motions of atoms in molecules, and include bond
stretching, torsional changes, and bond angle changes.
Correct answer:
a) Infrared radiation is higher in energy than UV radiation.
Which is the correct order of increasing wave number of the stretching vibrations of (1) C-H
(alkane), (2) O-H (alcohol), (3) C=O (ketone), and (4) C≡C (alkyne)?