ACIDS AND BASES 11) 4 g of copper(II) oxide, CuO reacts
completely with 50 cm3 of hydrochloric
Exercise 1 acid, HCl. [Relative atomic mass: Cu,64;O,16;Cl;35.5;H,1] 1) State the relationship between the (a) Write a chemical equation to represent concentration of hydrogen ions, H+ and the the reaction between hydrochloric acid pH value of an acid and copper(II) oxide. 2) What is meant by a strong acid and a weak (b) Calculate the number of moles of acid? copper(II) oxide in this reaction. 3) You are given 1.0 mol dm-3 aqueous nitric (c) Calculate the mass, in grams, of acid and 1.0 mol dm-3 aqueous ethanoic copper(II) chloride, CuCl2 formed in acid. Which acid has a higher pH value? this reaction. Explain why the pH values of the two acids (d) Find the molarity of hydrochloric acid are different. which reacts completely with 4 g of 4) What is meant by a strong alkali and a weak copper(II) oxide. alkali? 12) 20 cm3 of water is added to 30 cm3 of 1.0 5) The pH value of potassium hydroxide, KOH mol dm-3 sodium hydroxide, NaOH solution. solution is higher than the pH value of Determine the molarity of the diluted ammonia, NH3 solution of the same solution. concentration. Explain why. 13) Find the volume of distilled water needed to 6) 2 mol of potassium chloride, KCl is add to 40 cm3 of 1.0 mol dm-3 sodium dissolved in water to make up 100 cm3 of hydroxide, NaOH solution to produce 0.25 solution. Calculate the concentration in g mol dm-3 sodium hydroxide, NaOH solution. dm-3. 14) In a titration, 40 cm3 of 0.25 mol dm-3 7) 75.6 g of solid zinc nitrate, Zn(NO3)2 is potassium hydroxide, KOH solution is dissolved in water to make up 250 cm3 of needed to neutralize 20 cm3 of nitric acid, solution. Calculate the concentration in mol HNO3. Calculate the molarity of the nitric dm-3. acid, HNO3. 8) Given that the molarity of 100 cm3 of copper 15) X g of zinc oxide, ZnO was found to sulphate, CuSO4 solution is 2.0 mol dm-3. completely neutralize 25 cm3 of 0.2 mol Calculate dm-3 hydrochloric acid, HCl. Calculate the (a) The number of moles of CuSO4 in the value of X. solution [Relative atomic mass: Zn,65;O,16] (b) The mass of CuSO4 in the solution [relative atomic mass: Cu,64;S,32;O,16] 9) 50 cm3 of 2.0 mol dm-3 HCl reacted with excess zinc powder. Calculate the volume, in cm3, of hydrogen gas released at room conditions. [Molar volume: 24 dm3 mol-1 at room conditions] 10) Calculate the molarity of 25 cm3 of H2SO4 which reacted completely with 2.5 g of calcium carbonate, CaCO3. [Relative atomic mass: Ca,40;C,12;O,16]