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Ê = Q − W
▪ Major energy contributions
• Kinetic energy – related to velocity of system
• Potential energy – related to positon in a “field” (e.g., gravity)
• Internal energy – related to system’s temperature
o Internal energy, U, convenient for systems at constant volume & batch systems
2
u g
Eˆ = Uˆ + + h
2gc gc
o Enthalpy, H = U+PV, convenient for systems at constant pressure & flowing systems
2
u g
Eˆ = Hˆ + + h
2gc gc
u 2
g
Hˆ + + z = Q − W
2gc gc
For adiabatic, steady-state, ideal (reversible) flow (using WS as positive value)
u 2
g
Wˆ s = Hˆ + + z
2gc gc
P2
u 2
g
= V dP +
ˆ + z
P1
2g c gc
P2 P2
dP
Wˆ s Vˆ dP =
P1 P1
Ws = VdP = H
P1
▪ Evaluate integral using equation of state
• Simplest gas EOS is the ideal gas law
• Simplest liquid EOS is to assume incompressible (i.e., constant density
with respect to pressure)
P2 P
dP 1 2 P −P
Ws = = dP = 2 1
P1
P1
+ g z + + wˆ s + g hˆf = 0
2 P1
Updated: January 4, 2019
10
Copyright © 2019 John Jechura (jjechura@mines.edu)
Pump equations
Pumping requirement expressed in terms of power, i.e., energy per unit time
Hydraulic horsepower – power delivered to the fluid
▪ Over entire system
( u2 ) P
Whhp = m ( −wˆ s ) = ( V ) + g z + + g hˆf
2
( )
= V ( P ) + ( V ) ( g z ) + ( V ) g hˆf + ( V ) ( u2 )
1
2
▪ Just across the pump, in terms of pressure differential or head:
Also use the head equation usually using gpm, ft, specific gravity, and hp
lbm ft
8.33719 32.174
gal gal
Whhp hp o
2
ft sec
min sec ft lb f / sec 32.174 lbm ft
60
min 550
hp lb f sec2
1 gal
= ft o
3958 min
gc ( P )pump gc ( P )pump
hpump = =
g g ( owater )
(144 )
=− ( 61.2 ) = 291 ft
( 0.485)( 62.3665)
Hydraulic power:
Whhp =
( 360 gpm)( 61.2 psi) = 12.85 hp OR Whhp =
( 360 gpm )( 0.485 )(291 ft ) = 12.84 hp
1714 3958
P2
P2 P2
dP
Ws = VdP = RT = RT ln
P1 P1
P P1
W RT P ( −1)/
Wˆ s = s = 1 2 − 1
M M − 1 P1
Can also determine discharge temperature
( −1)/
P
T2 = T1 2
P1
=
xC i p ,i
=
xC i p ,i
x C i V ,i x C −R
i p ,i
Use the ideal gas heat capacities, not the real gas heat capacities
Heat capacities are functions of temperature. Use the average
value over the temperature range
(1.3−1)/1.3
900
T2 = ( 580 ) = 747°R 287°F
300
ln( P2 / P1 )
1/ m
P
RP = 2 m=
P1 ln(RP )
1015
ln
115 ln( 8.8 )
m= = = 1.98 m = 2
ln( 3 ) ln( 3 )
( −1)/ (1.3−1)/1.3
P 1/m 1015 1/2
= (120 + 460 ) = ( 580 )2.97
0.2308
T2 = T1 2 = 746°R 286°F
P1 115
Wˆ s =
( 1.3)(1.986 )( 580 ) 341.7 ( )
1.3−1 /1.3
1015 (1.3−1)/1.3
− 1 + − 1
( )(
16 1.3 − 1 ) 115 341.7
= 178 Btu/lb
IS =
( H )S=0
( H ) fluid
Wfluid =
WS =0
IS
Total
Energy
To
Device
( −1)/
P2
−1
( T )S =0 P
So: ( T )act = = T1 1
IS IS
P ( −1)/
2
−1
P
T2,act = T1 + ( T )act = T1 1 + 1
IS
P =
( − 1) /
( − 1) /
( −1) /
Wˆ p
1 RT P
Wˆact = = 1
2
− 1
p p M − 1 P1
Note:
Wˆ p Wˆ S =0
Wˆact = =
p IS
Wfluid
mech =
Wtotal Wtotal
mech =
Wfluid W Wfluid
Wtotal = = S =0
mech mechIS Wtotal = mechWfluid = mechISWS =0
p0
2 3
Volume
Suction
1 2 3 4 5
Discharge
Courtesy of Nuovo Pignone Spa, Italy
Pneumatic
Valve
Unloaders
for capacity
control
https://www.youtube.com/watch?v=E6_jw841vKE
Bett,K.E., et al
Thermodynamics for Chemical Engineers
Page 226
Siemens https://www.youtube.com/watch?v=s-bbAoxZmBg
https://www.energy.siemens.com/br/en/compression-
expansion/product-lines/single-stage/stc-sof.htm
https://www.turbomachinerymag.com/expander-compressors-an-introduction/
https://aceclearwater.com/product/case-study-ge-power-ducts/
Fuel
Combustion P3
chamber
P2
P1 shaft shaft
Compressor Turbine Load
P4 Combustion
Atmospheric air products
Assumptions
1) All gases are ideal, and compression processes are reversible and adiabatic (isentropic)
3 Patm = P1 = P4
T
Temperature
2
4
Entropy S
Note the equations apply to both the compressor and the turbine,since
thermodynamically the turbine is a compressor running backwards
Neglecting the differences in mass flow rates between the compressor and
the turbine, the net work is:
1
H.P./L.P. Turbine
A B
Entropy
Simple Cycle Gas Turbine Ideal Cycle Efficiency
( −1)/
T −T P
id = 1 − 4 1 = 1 − 1
T3 − T2 P2
Updated: January 4, 2019
65
Copyright © 2019 John Jechura (jjechura@mines.edu)
Modeling Gas Turbine with Aspen Plus
e
e Lin
compressor tries to adjust. The
Pressure Head
Stonewall Line
Surg
resulting pressure oscillations are Centrifugal
called SURGE
Stonewall
Reciprocating
• When gas flow reaches sonic
velocity flow cannot be increased.
Inlet Volume Flow
Rate
A compressor that takes in clean outside air and then compresses it through a series of rotating and
stationary compressor blades
FRESH AIR EXHAUST
COMPRESSION
MECHANICAL
ENERGY
A combustion section where fuel is added to the pressurized air and ignited. The hot pressurized
combustion gas expands and moves at high velocity into the turbine section.
FRESH AIR EXHAUST
COMBUSTION
COMPRESSION
MECHANICAL
ENERGY
A turbine that converts the energy from the hot/high velocity gas flowing from the combustion chamber
into useful rotational power through expansion over a series of turbine rotor blades
FRESH AIR EXHAUST
COMBUSTION
EXPANSION
COMPRESSION TURBINE
MECHANICAL
ENERGY