Professional Documents
Culture Documents
Abstract
Hydrocarbons like LPG, CNG etc., which are used as fuel gases and also vapours of
many solvents, which are used in various processes in chemical plants, and factories can
pose an explosion and fire hazard. Hence the detection and measurement of their
concentration at places where they are likely to occur is a must to avoid gas cloud explosion.
This article reviews the various chemical and electronic devices for the detection of
flammable gases. It also describes the various types of sensors used on electronic
instruments for detecting the flammable gases.
1. Introduction
Many of the chemicals used or produced in the chemical factories are combustible and
their vapour in the air can form combustible mixtures causing the possibility of explosion
when ignited. The hydrocarbons like LPG, CNG etc., which are used as fuel gases in chemical
plants, factories and in domestic kitchens, are all combustible. When they leak, they can
form explosive mixtures. Hence whenever these flammable gases/ vapours are used, it is
necessary to monitor the working area for the presence of these gases. Some of these
combustible gases like CO, Hydrazine, and Benzene are also highly toxic with very low
threshold limit value (TLV) of exposure. Hence they have to be detected at a very low
concentration levels much before they form a combustible mixture. The two main categories
of detection devices, which can be directly used in the field for sensing these gases, are
the chemical detectors and the electronic instruments.
Till recently chemical detector tubes were not manufactured in India. They had to be imported
at exorbitant cost. There were also not many indigenous manufacturers of electronic instruments
in India. A few who manufactured them were totally dependent on imported sensors.
Chemo Electronic laboratory has developed for the first time in India the chemical
detector tubes for several of the combustible gases and vapours and also for toxic gases.
They have also developed the full range of electronic instruments for various applications.
The sensors used in these instruments include (1) Pellistors which is the sensor of choice
for the combustible gases (2) Electrochemical sensor suitable for many toxic gases and
combustible gases (3) Solid state sensors, which can detect many of the toxic and combustible
gases at concentration as low as parts per million to as high as 100% v/v. (4) other sensors
like thermal conductivity detector and photo ionisation detector etc. Among these sensors
Chemo Electronic Laboratory has also indigenously developed various type of Pellistors,
electrochemical sensors for toxic and combustible gases and also thermal conductivity
detectors. They are the only sensor manufacturers in India.
The present article gives an overview of the sensors and the instruments, for the
detection of combustible gases and what Chemo Electronic Laboratory has done.
150 Proceedings of National Symposium on Industrial and Fire Safety 2006
3. Electronic Instruments
While detector tubes make on the spot measurements of gases present in the
environment at the time of measurement, they are not suitable for continuous measurement
Detection of Flammable Gases 151
of gas concentration. For this purpose electronic instruments are best suited. These
electronic instruments use a sensor, which forms the heart of the instrument. When the
sensor encounters the combustible gas it causes some physical or chemical change in the
sensor, which is proportional to the gas concentration. This change is converted into a
current or voltage signal by the signal processing circuit in the instrument and related
to the gas concentration and is displayed on a digital display. Figure-3 shows the schematic
diagram of a typical electronic instrument. In the following sections a brief description
of the sensors is given followed by a method.
current which results when they are irradiated with U.V. light from a PID lamp can be
measured to detect these VOC molecules and to determine their concentration.
This technique lacks specificity though it is extremely sensitive. Any molecule having
ionisation potential lower than the energy of UV light transmitted by the lamp is ionised
and leads to ionisation current. All such molecules contribute to the ionisation current.
Hence this method cannot determine the individual concentration when a mixture of VOC
is present in the air. Yet this sensor is very useful for the detection of many of the VOC
when a single gas is present and its identity is known.
3.2 Uniphos Instruments
Chemo Electronic laboratory has developed a variety of instruments using one or the
other of the sensors described earlier. The instruments include (1) Portable or table top
models for field application (2) Personal / Hand held or pocket size instruments with user
settable alarms for protecting the workers from hazards of toxic / combustible gas exposure
(3) Various types of fixed monitoring systems for area monitoring, consisting of a controller,
which is kept in the control room and a transmitter, which contains the sensor head, kept
in the area where gas concentration measurement is necessary.
4. Conclusion
Among the various instruments and devices available for the detection of combustible
gases, the user has to make the choice. The choice is dictated by the sample volume,
frequency of measurement, concentration range, location and presence of other possible
interfering gases present at the site of measurement.
If the sample is very small, and the measurement is occasional the detector tubes are
suitable and it is cost effective.
For the purpose of leak detection from pipelines, storage tanks etc. a portable instrument
with a sampling probe which can detect even at parts per million level has been found
to be ideal. The portable instruments are possible either using a Photo Ionization Detector
(PID) or a Solid State Sensor. However, as PIDs are very costly, flammable gas leak detectors
generally use Solid State Sensors. In some applications, it is necessary to detect combustible
gases in the concentration range of 0-100% v/v. For such applications it is necessary that,
the instrument has a solid-state sensor for detecting at ppm level, a pellistor to detect
between the lower and upper explosive limit of detection (LEL UEL) and a TCD which
works in the range of 1 100% v/v.
Nondispersive Infrared (NDIR) absorption based instruments are also used for the
detection of hydrocarbons. They are suitable in the range of 1- 100% v/v.
* * * * *