TABLES DE THERMODYNAMIQUE

(à 25˚C)

Etat ∆G˚f ∆H˚f Cp S˚

Composé Physique (kJ.mol-1) (kJ.mol-1) (J.mol-1.K-1) (J.mol-1.K-1)

Ag s 0 0 25.52 42.68
AgBr s -96.94 -100.42 52.38 107.11
AgCl s -109.50 -126.78 50.79 96.23
Ag2CO3 s -12.22 -81.17 111.63 167.36
AgF s -184.89 -202.92 51.92 83.68
AgI s -66.32 -61.92 54.39 115.48
AgNO3 s -29.58 -120.50 93.22 141.00
Ag2O s -10.84 -30.54 66.78 121.75
Ag2S s -39.62 -31.78 75.31 143.51
Ag2SO4 s -618.40 -715.88 131.46 200.41

Al s 0 0 24.35 28.33
AlBr3 s -504.42 -527.18 101.67 180.25
AlCl3 s -630.15 -705.34 91.38 110.67
AlF3 s -1410.13 -1489.50 75.10 66.53
AlI3 s -305.10 -309.20 98.91 189.54
Al2O3 s -1582.36 -1675.70 78.70 51.04
Al(OH)3 s -1147.17 -1284.49 93.14 71.13
Al2(SO4)3 s -3108.34 -3440.90 259.41 239.32

Ba s 0 0 26.36 67.78
BaBr2 s -717.35 -755.21 74.52 148.53
BaCl2 s -809.60 -859.39 75.31 123.64
BaCO3 s -1102.65 -1216.29 88.03 112.13
BaF2 s -1151.73 -1203.74 78.45 96.23
BaI2 s -599.65 -604.59 80.37 167.36
BaO s -523.71 -553.54 45.27 70.29
BaSO4 s -1352.69 -1465.24 101.75 132.21

Br2 l 0 0 71.55 152.21

C s (gr) 0 0 8.49 5.73

C 2H 2 g +209.19 +226.70 44.06 200.79
C 2H 4 g +68.10 +52.26 43.72 219.45
C 2H 6 g -32.93 -84.70 52.93 229.49
C 3H 8 g -23.47 -103.85 73.89 269.91

CO g -137.28 -110.50 29.29 197.90

CO2 g -396.35 -395.50 37.20 213.64

Ca s 0 0 26.28 41.63
CaBr2 s -664.96 -682.83 68.20 133.89
CaCl2 s -755.84 -800.82 72.84 113.80
CaCO3 s -1128.84 -1206.87 82.01 92.88
CaF2 s -1168.93 -1221.31 71.13 68.83
CaI2 s -531.83 -535.55 75.31 145.27
Ca(NO3)2 s -741.49 -936.80 149.37 193.22
CaO s -604.17 -635.55 42.68 39.75
Ca(OH)2 s -898.60 -986.21 87.53 83.39
CaSO4 s -1320.22 -1432.60 99.66 106.69

Cd s 0 0 25.90 51.46
CdCl2 s -344.22 -391.62 76.57 115.48
CdO s -226.06 -255.64 42.97 54.81
CdS s -145.10 -149.37 55.10 69.04
CdSO4 s -822.99 -933.45 100.42 123.01

Cl2 g 0 0 33.97 222.97

Co s 0 0 24.81 30.04
CoCl2 s -269.66 -312.54 78.49 109.20
CoSO4 s -760.82 -867.76 138.28 113.30

Cr s 0 0 23.35 23.77
CrCl3 s -482.16 -552.29 90.12 123.01
Cr2O3 s -1048.01 -1129.68 104.52 81.17
Cr2(SO4)3 s -280.54 -609.61 302.55 269.87

Cs s 0 0 32.01 84.35
CsBr s -380.53 -394.55 51.76 113.39
CsCl s -414.59 -442.83 52.47 101.17
CsF s -525.59 -554.67 51.97 88.28
CsI s -331.79 -336.81 51.55 125.52

Cu s 0 0 24.52 33.35
CuBr s -105.19 -107.95 54.77 96.23
CuCl s -120.83 -138.07 48.70 87.03
CuCl2 s -161.67 -205.85 72.68 108.07
CuI s -69.33 -67.78 54.18 96.65
Cu2O s -147.53 -170.29 65.31 92.93
CuO s -127.19 -155.85 42.22 42.59
Cu(OH)2 s -372.67 -450.37 95.19 108.37
Cu2S s -86.06 -79.50 81.59 120.92
CuS s -48.91 -48.53 47.66 66.53
CuSO4 s -660.82 -769.98 98.78 109.24

F2 g 0 0 31.46 202.92

Fe s 0 0 24.27 27.15
FeCl2 s -303.47 -342.25 76.32 120.08
FeCl3 s -334.01 -399.40 96.65 142.34
FeO s -251.50 -272.04 49.66 60.75
Fe2O3 s -740.99 -825.50 104.77 87.45
Fe3O4 s -1015.50 -1118.38 148.57 146.44
Fe(OH)2 s -492.08 -574.04 97.03 87.86
Fe(OH)3 s -705.63 -832.61 101.50 104.60
FeS s -97.86 -95.39 54.64 67.36
FeS2 s -166.06 -177.40 62.09 52.93
FeSO4 s -825.04 -928.85 100.54 120.96
Fe2(SO4)3 s -2271.45 -2582.99 263.47 307.52

H2 g 0 0 28.87 130.58
H3BO3 s -969.14 -1094.53 81.34 88.70
HBr g -53.43 -36.40 29.12 198.57
HCOOH l -359.49 -422.79 99.16 128.99
HCl g -95.27 -92.30 29.12 186.69
HF g -273.22 -271.12 29.16 173.64
 HI g +1.59 +26.48 29.12 206.31
HNO3 g -74.01 -134.31 53.51 266.35
H 2O l -237.18 -285.80 75.40 69.96
H 2O g -228.58 -241.80 34.23 188.74
H 2O 2 l -120.50 -187.86 89.33 109.62
H3PO4 s -1106.96 -1261.48 106.23 110.54
H 2S g -36.20 -20.60 33.97 205.69
H2SO4 l -690.07 -814.00 138.95 156.9

Hg l 0 0 27.87 76.02
HgBr2 s -152.17 -169.45 75.31 170.33
Hg2Br2 s -178.70 -204.18 106.52 218.74
HgCl2 s -184.05 -230.12 73.93 144.52
Hg2Cl2 s -210.41 -264.85 101.96 192.46
HgF2 s -374.09 -422.58 74.85 116.32
Hg2F2 s -427.34 -485.34 100.29 160.67
HgI2 s -99.04 -105.44 77.40 170.71
Hg2I2 s -111.09 -119.08 105.86 241.29
HgO s -58.53 -90.79 44.89 70.29
HgS s -50.29 -58.16 46.40 81.59

I2 s 0 0 54.43 116.15
I2 g +19.37 +62.43 36.86 260.58

K s 0 0 29.29 64.68
KBr s -380.45 -393.80 52.3 95.94
KCN s -102.05 -113.47 66.36 127.78
K2CO3 s -1064.87 -1150.18 114.22 155.52
KCl s -408.78 -436.68 51.71 82.55
KClO4 s -300.37 -430.12 112.38 151.04
KF s -537.69 -567.35 50.29 66.61
K3AlF6 s -3163.31 -3326.28 221.08 284.51
KI s -323.05 -327.90 53.01 106.40
KNO3 s -392.54 -492.46 96.27 132.88
KOH s -378.99 -424.68 65.61 79.29
K2SO4 s -1315.91 -1433.86 130.00 175.73

Li s 0 0 24.18 29.08
LiBr s -340.91 -350.20 49.20 74.06
Li2CO3 s -1132.02 -1215.87 95.40 90.17
LiCl s -384.05 -408.27 48.41 59.29
LiF s -584.67 -612.96 41.92 35.65
LiI s -269.66 -270.08 50.29 85.77
Li2O s -562.12 -598.73 53.47 37.91
LiOH s -438.69 -484.67 49.75 42.68

Mg s 0 0 24.89 32.68
MgBr2 s -499.23 -518.82 73.81 119.24
MgCO3 s -1012.65 -1096.21 75.56 65.69
MgCl2 s -591.87 -641.41 71.17 89.54
MgF2 s -1070.23 -1123.40 63.64 57.24
Mg(NO3)2 s -588.61 -789.94 141.92 164.01
MgO s -568.98 -601.24 37.07 26.94
Mg(OH)2 s -833.70 -924.66 77.66 63.18
MgS s -340.74 -347.27 41.84 42.68
MgSO4 s -1170.68 -1284.91 95.60 91.63

Mn s 0 0 26.32 32.01
MnBr2 s -371.16 -384.93 75.31 138.07
MnCO3 s -817.60 -894.96 81.55 85.77
MnCl2 s -441.20 -482.00 72.97 118.20
MnF2 s -752.41 -794.96 67.99 92.26
MnI2 s -243.43 -242.67 75.35 150.62
MnO s -362.67 -384.93 44.77 59.83
MnO2 s -465.26 -520.07 54.22 53.14
Mn2O3 s -879.02 -956.88 98.74 110.46
Mn3O4 s -1281.60 -1386.58 148.07 153.97
MnS s -218.49 -214.22 49.96 78.24
MnSO4 s -957.34 -1065.25 100.42 112.13

N2 g 0 0 29.29 191.50
NH3 g -16.57 -46.10 35.15 192.51
N2H4 g +158.53 +95.19 51.80 240.16
NH4Cl s -203.22 -314.55 86.65 94.98
NH4I s -112.05 -202.09 81.67 112.97
NO g +86.69 +90.37 29.83 210.62
N2O g +104.14 +82.01 38.83 219.83
NO2 g +51.84 +33.05 36.65 239.74
N2O4 g +98.28 +9.67 77.61 304.30

Na s 0 0 27.99 51.17
NaBr s -349.36 -361.41 51.88 86.82
NaCl s -384.22 -411.20 50.79 72.13
NaCN s -80.54 -90.71 68.62 118.49
Na2CO3 s -1048.22 -1130.77 111.34 138.78
NaHCO3 s -849.56 -947.26 87.78 102.09
NaF s -543.42 -573.63 47.15 51.30
Na3AlF6 s -3140.76 -3305.36 219.53 238.49
NaI s -284.64 -287.86 52.47 98.32
NaNO3 s -365.68 -466.52 93.05 116.32
Na2O s -379.28 -417.98 68.91 75.06
NaOH s -381.96 -428.02 59.66 64.43
Na2S s -361.54 -372.38 79.45 97.91
Na2SO4 s -1269.51 -1387.21 128.37 149.62

Ni s 0 0 25.82 29.87
NiCl2 s -259.16 -305.43 71.55 97.70
NiO s -212.46 -240.58 44.31 38.07
NiS s -90.25 -92.88 54.68 52.93
NiSO4 s -93.99 -198.74 135.98 133.89

O2 g 0 0 29.37 205.06
O3 g +163.18 +142.67 38.91 238.82

P s (rouge) 0 0 21.38 22.80

PCl3 g -267.78 -287.02 71.88 311.67
PCl5 g -305.43 -374.89 111.63 352.71

Pb s 0 0 26.44 64.81
PbBr2 s -259.95 -276.44 80.54 161.75
PbCl2 s -315.39 -360.66 73.14 135.98
PbF2 s -630.82 -676.97 74.14 112.97
PbI2 s -173.43 -175.14 81.17 175.18
PbO s -188.87 -219.28 46.02 65.27
PbO2 s -250.35 -277.40 62.89 76.57
Pb3O4 s -616.14 -733.50 146.98 210.87
PbS s -98.78 -100.42 49.50 91.21
PbSO4 s -813.24 -920.06 104.31 148.53
 S s 0 0 31.92 22.76
SO2 g -302.97 -296.80 39.92 248.53
SO3 g -373.61 -395.70 50.75 256.23
Sb s 0 0 25.02 45.52
SbBr3 s -226.06 -259.83 108.53 179.91
SbCl3 s -324.47 -382.00 106.86 187.02
SbI3 s -94.98 -96.23 97.57 215.48
Sb2O3 s -626.60 -708.77 101.25 123.01
Sb2O5 s -829.27 -971.94 117.61 125.10

Si s 0 0 20.00 18.83
SiO2 s -855.29 -909.06 44.93 41.84

Sn s 0 0 26.99 51.55
SnCl2 s -281.92 -325.10 79.33 129.70
SnCl4 l -440.16 -511.28 150.62 258.57
SnO s -256.69 -285.77 44.31 56.48
SnO2 s -519.82 -580.74 52.59 52.30
SnS s -106.44 -108.37 49.25 76.99
SnS2 s -159.03 -167.36 70.12 87.45

Zn s 0 0 25.40 41.63
ZnBr2 s -310.62 -327.61 65.69 136.82
ZnCl2 s -369.70 -416.31 67.53 108.37
ZnCO3 s -731.28 -812.53 80.08 82.42
ZnF2 s -713.46 -764.42 65.69 73.64
ZnI2 s -210.20 -209.20 65.69 161.08
ZnO s -318.11 -348.11 40.25 43.51
ZnS s -196.94 -201.67 57.74 46.02
ZnSO4 s -872.62 -978.64 114.35 128.03

TABLE THERMODYNAMIQUE
POUR QUELQUES IONS

∆G˚f ∆H˚f Cp S˚
Ion (kJ.mol-1) (kJ.mol-1) (J.mol-1.K-1) (J.mol-1.K-1)

Cl- -131.25 -167.15 55.23

F- -278.82 -332.63 -9.62
Fe2+ -84.94 -87.86 -113.39
Fe3+ -10.54 -47.70 -293.30
H+ 0 0 0
H 3O + -237.19 -285.85 69.96
OH- -157.28 -230.00 -10.54
Sn2+ -27.20 -8.79
Sn4+ 2.51 30.54
 ENERGIES DE LIAISON

A) Liaisons simples (kJ.mol-1)

H-H : 435.97 H-S : 338.90 O-O : 138.07

H-F : 563.17 C-C : 347.27 S-S : 213.38
H-Cl : 431.79 C-Cl : 326.35 F-F : 153.13
H-Br : 366.10 C-Br : 276.14 Cl-Cl : 242.67
H-I : 298.74 C-O : 351.46 Br-Br : 192.88
H-C : 414.22 C-N : 292.88 I-I : 151.04
H-N : 389.11 N-N : 158.99 I-Cl : 210.46
H-O : 464.22 N-Cl : 200.83 I-Br : 177.82

B) Liaisons multiples (kJ.mol-1)

C=C : 615.05 C≡N : 878.64

C≡C : 811.70 N=N : 418.4
C=O : 711.28 N≡N : 945.58
O=O : 497.00

CHALEURS DE COMBUSTION (kJ.mol-1)

CO (g) -283.01
H2 (g) -285.85
CH4 (g) -890.36
C2H4 (g) -1410.97
C2H6 (g) -1559.88
C3H8 (g) -2221.66
C (graphite) -393.51
C (diamant) -395.39
CH3OH (g) -763.96
CH3CH2OH (g) -1409.25
CH3COOH (g) -919.73
CH3COCH3 (g) -1821.38