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2. b) i) The gas molecules move faster because they have more kinetic energy.
Because of the faster motion, more collisions occur causing the pressure
to increase.
ii) The molecules are moving slower so in order to keep the pressure
constant (same number of collisions) the volume must decrease to give
the molecules less space to move around in.
iii) By adding more molecules, the number of collisions increases. The
container must be cooled to slow down the molecules so that the number
of collisions is reduced to the original level.
W
6. a) PV = RT
M
720 4
v 0.0821 295 V = 25.565 litre
760 4
b) PM = dRT
800
44 d 0.0821 373 d = 1.5124 g/lt
760
3 .2
7. a) Mol. wt. (M) = 22.4;
V
w
V = Vol. In lit. apply pV =
RT
M
w = Wt. of the gas in g at 473 K and 16 atm]
b) According to gas equation,
P1V1 P2 V2
T1 T2
750 mm 500 mL P2 400 mL
273 15 k 273 50 K
P2 =
750 mm 500mL 323K = 1051 mm
288K 400mL
8. a) H2 > He > N2
1
Rate of diffusion of the gas and MN2 MHe MH2
M
r1 M2
b)
r2 M1
1 M2 M 1
2
4 M1 M1 16
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RSM79PhIGSCH(S)2
w1
M w M 2 1
ratio of mole fraction = 1 = 1 2 =
w2 w 2 M1 3 16
M2
1: 24
1
9. a) Mass of electron on atomic weight scale is amu
1837
1
Mass of 1 mole of electron = g
1837
3 8.314 107 298
3RT
We have C = =
M 1/ 1837
r.m.s. speed of an electron = 1.16 107 cm/sec
To calculate rms speed of UF6 put M = 238 + 6 19 = 352
VavH 2 TH2 MCH4
b)
VavCH 4 MH2 TCH4
VavH 2
= 1.632
VavCH 4
3 3
10 a) K.E. of one mole of a gas = RT = 2 300 = 900 calories
2 2
b) Change in translation kinetic energy per mole
= RT2 T1 = 2 100 = 300 cals.
3 3
2 2
Change in translation kinetic energy for 3.45 g Ne
3.45
= 300 = 51.29 cal.
20.18
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RSM79PhIGSCH(S)3
LEVEL - II
1. b) The volume must increase in order to keep the collisions constant. The
molecules are moving faster since they are heated so they need more space to
keep the pressure constant.
2. a) The reading will be high since the tires are warm. This is not offset by the fact
that you decreased in altitude, which would make the reading low.
b) You need to add air to the tires.
b) Mg + 2HCl MgCl2 + H2
24g 22.4 lit at N.T.P.
2Al + 6HCl 2AlCl3 + 3H2
2 27 = 54g 3 22.4 lit at N.T.P.
Let V be volume of liberated H2 at N.T.P.
760 V 699 1200
or V = 1103.7 ml
273 273
Let weight of Mg in alloy be x gm wt. of Al = (1 – x)g
22400 x 22400
By problem, 3 (1 – x) = 1103.7
24 54
x = 0.4525, % of Al = 54.75%
Wt. of Mg = 0.4525g
Wt. of Al = (1 – 0.4525)g = 0.5475gm
% of Mg = 45.25
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RSM79PhIGSCH(S)4
V / 430 d0 16
V / 367 .5 dm dm
2
430
dm = 16 21.91
367 .5
100 86.16 13.89
Again for 100 gms the volume =
dm d d0
100 86.16 13.84
or d = 23.3
21.91 d 16
d d
b) From the extrapolation of vs P curve to P = 0 the value of is found
P P P0
to be 1.517 gm lit–1.
RT
d
M = 1.517 0.082 273 = 34
P0
The atomic weight of P = 34 – 3 1.008 = 30.98
4 3
8. i) Volume of 1 molecule = r
3
( r = 150 pm = 150 10–10 cm)
4 22
Volume of 1 molecule = (150 10 10 ) 3
3 7
V1 = 1.41 10–23 cc/molecule
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RSM79PhIGSCH(S)5
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RSM79PhIGSCH(S)6
LEVEL – I
P1V1 P2 V2
1.
T1 T2
P1 V1 P1 V2
V2 = 4V1
T1 2 2T1
(D)
r1 x M2
2. 1 =4
r2 x 2 M1
M2
16
M1
M1 1
M2 16
(A)
V1
t1 M t M2
4. 2 or 2
V2 M1 5 2
t2
t 22 25 (20 )2
or
M2 2 32
(B)
7. Gases with the same molecular weight diffuses at the same rate
CO2 and N2O (molecular weight 44)
(A)
r1 p1 M2 2 32
9. = = 8:1
r2 p2 M1 1 2
(C)
12. More is the value of a mass is the liquifaction and bigger is the size of molecule
bigger is the ‘b’ value
(B)
y
13. CxHy + O2 xCO2 + H2O
2
0.2
y
0 0.2x 0.2
2
given 0.2x = 8
x=4
0.1y = 0.1
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RSM79PhIGSCH(S)7
y = 10
C4H10
(A)
14. After the introduction of 3g of B the pressure was became half it means no. of
moles of B
2 3
or
MA MB
M 2
or A
MB 3
(C)
w
16. PV = RT
M
723 780 3.2
0.0821 683
760 1000 M
M = 256
256
atomicity = =8
32
(D)
P1 P2
17.
T1 T2
12 14.9
300 T2
T2 = 372.5 K
= 99.5°C
(C)
r1 T2
18.
r2 T1
T2
2 =
273
T2= 273 4 = 1092 K
(D)
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